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    Cryoscopic Constants For Various Solvents

    Uploaded by

    Keisha
    This document contains 20 practice problems related to colligative properties involving vapor pressure, boiling point elevation, freezing point depression, and osmotic pressure. The problems provide data about the mass or molar amount of solutes like urea, glucose, and ethyl alcohol dissolved in solvents like water, ether, and benzene. Learners are asked to use these values to calculate various colligative properties based on equations relating solute concentration to vapor pressure, boiling/freezing points, and osmotic pressure.

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    Cryoscopic Constants For Various Solvents

    Uploaded by

    Keisha
    294 views2 pages
    This document contains 20 practice problems related to colligative properties involving vapor pressure, boiling point elevation, freezing point depression, and osmotic pressure. The problems provide data about the mass or molar amount of solutes like urea, glucose, and ethyl alcohol dissolved in solvents like water, ether, and benzene. Learners are asked to use these values to calculate various colligative properties based on equations relating solute concentration to vapor pressure, boiling/freezing points, and osmotic pressure.

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    Phychem

    Original Title

    ProblemSet

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    This document contains 20 practice problems related to colligative properties involving vapor pressure, boiling point elevation, freezing point depression, and osmotic pressure. The problems provide data about the mass or molar amount of solutes like urea, glucose, and ethyl alcohol dissolved in solvents like water, ether, and benzene. Learners are asked to use these values to calculate various colligative properties based on equations relating solute concentration to vapor pressure, boiling/freezing points, and osmotic pressure.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    294 views2 pages

    Cryoscopic Constants For Various Solvents

    Uploaded by

    Keisha
    This document contains 20 practice problems related to colligative properties involving vapor pressure, boiling point elevation, freezing point depression, and osmotic pressure. The problems provide data about the mass or molar amount of solutes like urea, glucose, and ethyl alcohol dissolved in solvents like water, ether, and benzene. Learners are asked to use these values to calculate various colligative properties based on equations relating solute concentration to vapor pressure, boiling/freezing points, and osmotic pressure.

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    Problem Set

    Colligative Properties

    1. A solution contains 5 g of urea (M2 = 60.05) per 100 g of water. What will be the vapor
    pressure of this solution at 25C?
    2. At 50C the vapor pressure of ethyl alcohol is 219.9 mm Hg. If 6 g of a nonvolatile
    solute of molecular weight 120 are dissolved in 150 g of water and ethyl alcohol, what
    will be the relative vapor pressure lowerings in the two solvents?
    3. A solution composed of 10 g of a nonvolatile organic solute in 100 g of diethyl ether has
    a vapor pressure of 426.0 mm at 20C. If the vapor pressure of the pure ether is 442.2
    mm at the same temperature, what is the molecular weight of the solute?
    4. At 25C 10.50 liters of pure N2, measured at 760 mm Hg are passed through an aqueous
    solution of a nonvolatile solute whereby the solution loses 0.2455 g in weight. If the
    total pressure above the solution is also 760 mm, what is the vapor pressure of the
    solution and the mol fraction of solute?
    5. If 30 g of diphenyl are dissolved in 250 g of benzene, what will be the boiling point of
    the resulting solution under atmospheric pressure?
    6. A solution consisting of 5.00 g of an organic solute per 25.00 g of CCl4 boils at 81.5C
    under atmospheric pressure. What is the molecular weight of the solute?
    7. Calculate the molar heat of vaporization of ethyl alcohol using the data given in Molal
    Boiling Point Elevation Constants.
    8. What weight of glycerol would have to be added to 1000 g of water in order to lower it
    freezing point 10C?
    9. An aqueous solution contains 5% by weight urea and 10% by weight of glucose. What
    will be its freezing point?
    10. Compare the weights of methanol and glycerol which would be required to lower the
    freezing point of 1000 g of water 1C.
    11. Calculate the heat of fusion per mole of phenol using the data given in Cryoscopic
    Constants for Various Solvents.
    12. A sample of CH3COOH is found to freeze at 16.4C. Assuming that no solid solution is
    formed, what is the concentration of impurities in the sample?
    13. A mixture which contains 0.550 g of camphor and 0.045 g of an organic solute freezes
    at 157.0C. The solute contains 93.46% of C and 6.54% of H by weight. What is the
    molecular formula of the compound?
    14. When dissolved in 100 g of a solvent whose molecular weight is 94.10 and whose
    freezing point is 45.0C, 0.5550 g of a solute of molecular weight 110.1 gave a freezing
    point depression of 0.382C. Again, when 0.4372 g of solute of unknown molecular
    weight was dissolved in 96.50 g of the same solvent, the freezing point lowering was
    found to be 0.467C. From these data find (a) the molecular weight of the unknown
    solute, (b) the cryoscopic constant of the solvent, and (c) the heat of fusion of the
    solvent per mole.
    15. An aqueous solution contains 20 g of glucose per liter. Assuming the solution to be
    ideal, calculate the osmotic pressure at 25C.
    16. The osmotic pressure of an aqueous solution containing 45.0 g of sucrose per liter of
    solution is 2.97 atm at 0C. Find the value of the universal gas constant and compare
    the result with the accepted value.
    17. A solution of 1.00 g of antipyrine (C11H12N2O) in 100 cc of aqueous solution gave an
    osmotic pressure of 1.18 atm at 0C. Calculate the molecular weight of the compound
    and compare the result with the expected from the given formula.
    18. An aqueous solution freezes at –1.50C. Calculate (a) the normal boiling point, (b) the
    vapor pressure at 25C, and (c) the osmotic pressure at 25C of the given solution.
    19. The average osmotic pressure of human blood is 7.7 atm at 40C. (a) What should the
    total concentration of various solutes in the blood? (b) Assuming this concentration to
    be essentially the same as the molality, find the freezing point of blood.
    20. The vapor pressure of an aqueous solution at 25C is 23.45 mm. Calculate its osmotic
    pressure.

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