Ultrameter Operation Manual Model 4P: Myron L
Ultrameter Operation Manual Model 4P: Myron L
Ultrameter Operation Manual Model 4P: Myron L
Operation
Manual
Model 4P
MYRON L
COMPANY
10 - 02 (WEB) EG
Instrument Illustration
Conductivity Cell
(Built-in
Electrodes)
Temperature
Sensor
Preprogrammed
variable conductivity/
TDS ratios
Units of Measurement Parameter
Ω Megohms - cm Resistivity
USER mode LOBATT CAL MEMORY
M Ω Kilohms - cm Resistivity
for programming KCl K
NaCl mS
mS - millisiemens/cm
special temperature 442 µS (millimhos/cm) Conductivity
compensation User PPM µS - microsiemens/cm
factor and PPT
RATIO % / °C (micromhos/cm) Conductivity
conductivity/TDS BUFFER
PPM - parts per million TDS
COND RES TDS
ratio PPT - parts per thousand TDS
Parameters (3)
Displayed here:
• Temperature
readout COND RES TDS These 3 Measurement keys will:
• USER temperature • Turn instrument on
compensation or • Measure parameter
conductivity/TDS • Exit any function
ratio
• Memory Storage/
Recall
4P CAL
MS
Up key/Memory Store
MCLR
MR
Down key/Memory Recall
This key for: MYRON L
• Calibration COMPANY
• Memory Clear TM
• Solution selection
• Confirmation
ULTRAMETER
Wrist/neck strap slot
(user supplied)
1
FEATURES and SPECIFICATIONS C. Specification Chart
E. Ultrameter Models
ULTRAMETER MODELS 3P 4P 6P
2 3
TABLE OF CONTENTS B. Rules for Calibration in the Ultrameter . . . . . . . . . . . . 13
1. Calibration Steps . . . . . . . . . . . . . . . . . . . . . . .13
Instrument Illustration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1 2. Calibration Limits . . . . . . . . . . . . . . . . . . . . . . .14
C. Calibration Procedures . . . . . . . . . . . . . . . . . . . . . . . . 14
FEATURES and SPECIFICATIONS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 1. Conductivity or TDS Calibration . . . . . . . . . .14
A. Features . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 2. User Calibration Conductivity/TDS . . . . . . . .15
B. General Specifications . . . . . . . . . . . . . . . . . . . . . . . . . . 2 3. Resistivity Calibration . . . . . . . . . . . . . . . . . . . 15
C. Specification Chart . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 4. Reloading Factory Calibration . . . . . . . . . . . .15
D. Warranty/Service . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3 5. Temperature Calibration . . . . . . . . . . . . . . . . 16
E. Ultrameter Models . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3 VII. MEMORY . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .16
A. Memory Storage . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16
I. INTRODUCTION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .7 B. Memory Recall . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .16
C. Clearing a Record/Memory Clear . . . . . . . . . . . . . . . . 16
II. RULES of OPERATION. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
A. Operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .7 VIII. CHANGING from CENTIGRADE to FAHRENHEIT . . . . . . . . . . . .17
B. Characteristics of the Keys . . . . . . . . . . . . . . . . . . . . . . 7
C. Operation of the Keys . . . . . . . . . . . . . . . . . . . . . . . . . . 8 IX. TOTAL RETURN to FACTORY SETTINGS . . . . . . . . . . . . . . . . . 18
1. Measurement Keys in General . . . . . . . . . . . . 8
2. COND, RES and TDS keys . . . . . . . . . . . . . . .8 X. CALIBRATION INTERVALS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .19
3. CAL/MCLR key . . . . . . . . . . . . . . . . . . . . . . . . . 8 A. Suggested Intervals . . . . . . . . . . . . . . . . . . . . . . . . . . .19
4. UP or DOWN keys . . . . . . . . . . . . . . . . . . . . . . .9 B. Calibration Tracking Records . . . . . . . . . . . . . . . . . . . 19
C. Conductivity, RES, TDS Practices . . . . . . . . . . . . . . .19
III. AFTER USING the ULTRAMETER
Maintenance of the Conductivity Cell . . . . . . . . . . . . . . . 9 XI. CARE and MAINTENANCE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .20
A. Temperature Extremes . . . . . . . . . . . . . . . . . . . . . . . . 20
IV. SPECIFIC RECOMMENDED MEASURING PROCEDURES . . . .9 B. Battery Replacement . . . . . . . . . . . . . . . . . . . . . . . . . . 20
A. Measuring Conductivity/Total Dissolved Solids . . . . .9 C. Cleaning Cell Cup . . . . . . . . . . . . . . . . . . . . . . . . . . . . .20
B. Measuring Resistivity . . . . . . . . . . . . . . . . . . . . . . . . . . 10
XII. TROUBLESHOOTING . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .21
V. SOLUTION SELECTION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .10
A. Why Solution Selection is Available. . . . . . . . . . . . . . 10 XIII. ACCESSORIES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .22
B. The 4 Solution Types. . . . . . . . . . . . . . . . . . . . . . . . . . 10 A. Conductivity/TDS Standard Solutions . . . . . . . . . . . 22
C. Calibration of Each Solution Type . . . . . . . . . . . . . . .10 B. Soft Protective Case . . . . . . . . . . . . . . . . . . . . . . . . . . 22
D. Procedure to Select a Solution . . . . . . . . . . . . . . . . . 10 C. Data Port . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .22
E. Application of USER Solution Type . . . . . . . . . . . . . .11 D. pH Buffer Solutions . . . . . . . . . . . . . . . . . . . . . . . . . . . 23
1. User Programmable Tempco . . . . . . . . . . . . 11 E. pH Sensor Storage Solution . . . . . . . . . . . . . . . . . . . 23
2. Disabling Temperature Compensation . . . . 12
3. User Programmable Conductivity to TDS XIV. TEMPERATURE COMPENSATION (Tempco)
Ratio . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12 of Aqueous Solutions . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23
A. Standardized to 25°C . . . . . . . . . . . . . . . . . . . . . . . . . .23
VI. CALIBRATION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .13 B. Tempco Variation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23
A. Calibration Intervals . . . . . . . . . . . . . . . . . . . . . . . . . . . .13 C. An Example . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24
D. A Chart of Comparative Error . . . . . . . . . . . . . . . . . . . .25
E. Other Solutions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .25
4 5
XV. CONDUCTIVITY CONVERSION to I. INTRODUCTION
TOTAL DISSOLVED SOLIDS (TDS) . . . . . . . . . . . . . . .26 Thank you for selecting the Ultrameter™ Model 4P, one of the Myron L
A. How it’s Done . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .26 Company’s latest in a new line of instruments utilizing advanced
B. Solution Characteristics . . . . . . . . . . . . . . . . . . . . . . . .26 microprocessor-based circuitry. This circuitry makes it extremely accurate
C. When does it make a lot of difference? . . . . . . . . . . . 27 and very easy to use (see pages 2 & 3 for Features and Specifications on
this and other models). For your convenience, your Ultrameter has a brief
XVI. TEMPERATURE COMPENSATION (Tempco) set of instructions on its bottom, and a pocket sized card with abbreviated
and TDS DERIVATION . . . . . . . . . . . . . . . . . . . . . . . . . . .27 instructions is included with the instrument.
A. Conductivity Characteristics . . . . . . . . . . . . . . . . . . . . 27 Special note ...... Conductivity, Resistivity, and TDS require mathematical
B. Finding the Tempco of an Unknown . . . . . . . . . . . . . 28 correction to 25°C values (ref. Temperature Compensation, pg. 23). On
C. Finding the TDS Ratio of an Unknown . . . . . . . . . . . 28 the left of the Ultrameter’s liquid crystal display is shown an indicator of
the salt solution characteristic used to model temperature compensation
XVII. GLOSSARY . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .29 of conductivity and its TDS conversion. The indicator can be KCl, NaCl,
442 or USER. Selection affects the temperature correction of
NOTES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 30 conductivity, and the calculation of TDS from compensated conductivity
(ref. Conductivity Conversion to Total Dissolved Solids (TDS), pg. 26).
Addendum The selection can affect the reported conductivity of hot or cold
solutions, and will change the reported TDS of a solution. Generally,
I. HIGH RESISTIVITY MEASUREMENTS . . . . . . . . . . . . . . . . . . . . . .1 using KCl for conductivity, NaCl for resistivity, and 442™ (Natural Water
Offset Zero Calibration . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1 characteristic) for TDS will reflect present industry practice for
Cell Check. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .2 standardization. This is how your instrument, as shipped from the factory,
is set to operate.
II. USER MODE GAIN CALIBRATION . . . . . . . . . . . . . . . . . . . . . . . . . 3
A. Calibration of Ultrameter for Use in User Mode . . . . . 3 II. RULES of OPERATION
B. Setting User mode Calibration “Link” . . . . . . . . . . . . . 3 A. Operation
C. Canceling User Mode Calibration “Link” . . . . . . . . . . . 4 Using the instrument is simple:
• Rinse the conductivity cell with test solution 3 times and refill.
* CHECKING YOUR INSTRUMENTS SOFTWARE VERSION . . . . . . . . . 5 • Press the desired measurement key to start measurement.
Pressing the key again does no harm and restarts the 15 second
“off” timer.
• Note the value displayed or press the MS key to store
(ref. Memory Storage, pg. 16). It’s that simple!
6 7
CAL
C. Operation of the Keys (See Instrument Illustration on page 1) If MCLR is held down for about 3 seconds, CAL mode is not entered, but
1. Measurement Keys in General
Any of the 3 measurement keys in the upper part of the keypad turns on “S E L ” appears to allow Solution Selection (ref. pg. 10) with the Up or
the instrument in the mode selected. The mode is shown at the bottom Down keys. As in calibration, the CAL key is now an “accept” key.
of the display, and the measurement units appear at the right. Pressing a While reviewing stored records, the MCLR side of the key is active to
measurement key does this even if you are in a calibration sequence and allow clearing records (ref. Clearing a Record/Memory Clear, pg. 16).
also serves to abandon a change (ref. Leaving Calibration, pg. 14).
4. UP or DOWN keys
2. COND, RES and TDS keys
These 3 keys are used with solution in the Conductivity Cell. While measuring in any parameter, the or MR keys activate the
MS
Precautions:
• While filling cell cup, ensure no air bubbles cling on the cell wall. Memory Store and Memory Recall functions.
• If the proper solution is not selected (KCl, NaCl, 442 or USER) While in CAL mode, the keys step or scroll the displayed value up or
refer to Why Solution Selection is Available, pg. 10 and down. A single press steps the display and holding either key scrolls the
Procedure to Select a Solution, pg. 10. value rapidly.
a. COND Key While in Memory Recall, the keys move the display up and down the stack
Solution to be tested is introduced into the conductivity cell and a press of records (ref. Memory Recall, pg. 16).
of COND displays conductivity with units on the right. On the left is III. AFTER USING the ULTRAMETER
Maintenance of the Conductivity Cell
shown the solution type selected for conductivity. An overrange Rinse out the cell cup with clean water. Do not scrub the cell. For oily
condition will show only [- - - -] (ref. Solution Selection, pg. 10). films, squirt in a foaming non-abrasive cleaner and rinse. Even if a very
b. RES Key active chemical discolors the electrodes, this does not affect the
A press of R E S displays resistivity with units on the right. On the left accuracy; leave it alone (ref. Cleaning Conductivity/TDS/Resistivity Cell
Cup, pg. 20).
is shown solution type selected for resistivity (ref. Solution Selection, pg.
10). The range of display of Resistivity is limited to between 10 kilohms IV. THE SPECIFIC RECOMMENDED MEASURING
(KΩ ) and 30 megohms (MΩ ). A solution outside that range will only show PROCEDURES
[- - - -] in the display. If the proper solution is not selected (KCl, NaCl, 442 or USER), see
c. TDS key Solution Selection, Pg. 10.
A press of TDS displays Total Dissolved Solids with units on the
N O T E : After sampling high concentration solutions or temperature
right. This is a display of the concentration of material calculated from extremes, more rinsing may be required.
compensated conductivity using the characteristics of a known material.
On the left is shown solution type selected for TDS (ref. Solution A. Measuring Conductivity/Total Dissolved Solids (TDS)
Selection, pg. 10). 1. Rinse cell cup 3 times with sample to be measured. (This
conditions the temperature compensation network and prepares
3. CAL/MCLR key the cell.)
CAL
A press of allows you to enter the calibration mode while 2. Refill cell cup with sample.
MCLR
measuring conductivity or TDS. Once in CAL mode, a press of this key 3. Press COND or TDS .
accepts the new value. If no more calibration options follow, the
instrument returns to measuring (ref. Leaving Calibration, pg. 14). 4. Take reading. A display of [- - - -] indicates an overrange
condition.
8 9
B. Measuring Resistivity 1. Press COND , R E S or TDS to select the parameter on which
Resistivity is for low conductivity solutions. In a cell cup the value may drift
from trace contaminants or absorption from atmospheric gasses, so you wish to change the
measuring a flowing sample is recommended. solution type. KCl
NaCl
CAL 442
1. Hold instrument at 30° angle (cup sloping downward). 2. Press and hold key
MCLR User
2. Let sample flow continuously into conductivity cell with no about 3 seconds to make
aeration. “S E L ” appear (see Figure 1).
Figure 1
(For demonstration purposes,
3. Press R E S key; use best reading. all 4 solution types are shown simultaneously.)
12 13
c. Leaving Calibration 2. User Calibration Conductivity/TDS
You know you are finished when the “CAL” icon goes out. Pressing any
measurement key abandons changes not yet accepted and exits a. Rinse conductivity cell three times with your standard.
calibration mode.
b. Refill conductivity cell with same standard.
2. Calibration Limits
There are calibration limits. A nominal “FAC” value is an ideal value stored c. Press COND or TDS , then press CAL twice in COND/three
MCLR
by the factory. Attempts to calibrate too far, up or down, from there will
cause the displayed value to be replaced with “FAC”. If you accept it times in TDS. The “CAL” icon will appear on the display.
(press the “Cal” key), you will have the original default factory calibration
for this measurement. The need to calibrate so far out that “FAC” appears d. Press or MR to step the displayed value toward the
MS
indicates a procedural problem, wrong standard solution, or a very dirty
cell cup (ref. Troubleshooting Chart, pg. 21). standard’s value or hold a key down to cause rapid scrolling of the
reading.
C. Calibration Procedures
1. Conductivity or TDS Calibration e. Press CAL once to confirm new value and end the calibration
MCLR
a. Rinse conductivity cell three times with proper standard (KCl, sequence for this particular solution type.
NaCl, or 442) (ref. Con./TDS Standard Solutions, pg. 22). For
user calibration see User Calibration Cond./TDS, pg. 15. 3. Resistivity Calibration
Resistivity is the reciprocal of Conductivity. Resistivity is calibrated only if
b. Refill conductivity cell with same standard. conductivity is calibrated for the same solution type.
c. Press COND or TDS , then CAL 4. Reloading Factory Calibration (Cond or TDS)
If calibration is suspect or known to be wrong, and no standard solution is
µS available, the calibration value can be replaced with the original factory
CAL 442
press MCLR , “CAL” icon will value for that solution. This “FAC” value is the same for all Ultrameters,
°C and returns you to a known state without solution in the cell. The “FAC”
appear on the display (see internal electronics calibration (which bypasses the electrodes and cell) is
COND
Figure 5). not intended to replace calibration with conductivity standard solutions. If
Figure 5
another solution type requires resetting, change solution type and
MR
d. Press or to step the displayed value toward the repeat this procedure.
MS
standard’s value or hold a key down to cause rapid scrolling of the a. Press COND or TDS .
reading.
CAL CAL
e. Press once to confirm new value and end the calibration b. Press . (If in USER solution mode, press CAL key twice if
MCLR MCLR
sequence for this particular solution type. in Conductivity, and three times if in TDS to skip over tempco and
ratio adjustments.)
If another solution type is also to be measured, change solution type now
and repeat this procedure. c. Press MS key until “FAC ” appears and release.
CAL
d. Press to accept the factory calibration setting.
MCLR
14 15
5. Temperature Calibration 1. Press MR and scroll to location #3 .
Temperature calibration is not necessary in the Ultrameter.
CAL
VII. MEMORY 2. Press to clear old record #3 .
MCLR
This feature allows up to 20 readings with their temperatures to be stored
simultaneously for later recall. 3. Fill conductivity cell with sample.
2. “MEMORY ” will appear and MEMORY 5. The next memory stored will go into location #8 .
the temperature display will be
momentarily replaced by a 6. To clear all records: After MEMORY
442 µS
number (1-20) showing the
MR
position of the record. Figure °C pressing , scroll down
6 shows a reading of 1806 µS
COND
stored in memory record #4. to “CL r ALL ” in measurement
Figure 6
and temperature area
B. Memory Recall (see Figure 7).
1. Press one of the measurement keys. Figure 7
CAL
MR 7. Press . All records will be cleared.
MCLR
2. Press , “MEMORY ” will appear, and the display will show
memory. This space will be the place for the next memory record,
unless you scroll to another position before ending the recall
sequence. The next memory stored will go into the next highest
available memory location.
Example: You have locations 1-7 filled.You want to clear the conductivity
reading stored in record location #3 and replace it with a TDS reading. Figure 8 Figure 9
16 17
CAL
4. Press MCLR ; the display will change to the other unit. X. CALIBRATION INTERVALS
you pass the CLr ALL and the 1. Clean oily films or organic material from the cell electrodes with
C-F locations. The display will foaming cleaner or mild acid. Do not scrub inside the cell.
show a “FAC SEL ”
(see Figure 10). 2. Calibrate with solutions close to the measurements you make.
Figure 10 Readings are compensated for temperature based on the type
4. Press CAL to accept the resetting. of solution. If you choose to measure tap water with a KCl
MCLR
compensation, which is often done (ref. An Example, pg. 24),
and you calibrate with 442 solution because it is handy, the
further away from 25°C you are, the more error you have. Your
records of calibration changes will reflect temperature changes
more than the instrument’s accuracy.
3. Rinse out the cell with pure water after making measurements.
Allowing slow dissolving crystals to form in the cell contaminates
future samples.
18 19
XI. CARE and MAINTENANCE XII. TROUBLESHOOTING CHART
Ultrameters should be rinsed with clean water after use. Solvents should
be avoided. Shock damage from a fall may cause instrument failure.
Corrective Action
B. Battery Replacement
in place.
Dry Instrument THOROUGHLY . Remove the four (4) bottom
screws. Open instrument carefully; it may be necessary to rock the
bottom slightly side to side to release it from the RS-232 connector.
Carefully detach battery from circuit board. Replace with 9 volt alkaline
battery. Replace bottom, ensuring the sealing gasket is installed in the
groove of the top half of case. Re-install screws, tighten evenly and
1. Dirty electrodes.
Possible Cause
1 megohm.
C. Cleaning Conductivity/TDS/Resistivity Cell Cup
The conductivity cell cup should be kept as clean as possible. Flushing
with clean water following use will prevent buildup on electrodes.
However, if very dirty samples — particularly scaling types — are allowed
to dry in the cell cup, a film will form. This film reduces accuracy. When
there are visible films of oil, dirt, or scale in the cell cup or on the
electrodes, use a foaming non-abrasive household cleaner. Rinse out
Resistivity readings
Resistivity readings
Conductivity/TDS/
Conductivity/TDS
Unable to calibrate
Symptom
Unstable
20 21
XIII. ACCESSORIES D. pH Buffer Solutions
pH buffers are available for your other Myron L Company instruments in
A. Conductivity/TDS Standard Solutions pH values of 4, 7 and 10. The Myron L buffer solutions are traceable to
Your Ultrameter has been factory calibrated with the appropriate Myron L NIST certified pH references and are color-coded for instant
Company NIST traceable KCl, NaCl, and our own 442 standard solutions. identification. They are also mold inhibited and accurate to within ±0.01
Most Myron L conductivity standard solution bottles show three values pH units @ 25°C. Order 4, 7 or 10 Buffer.
referenced at 25°C: Conductivity in microsiemens/micromhos and the
ppm/TDS equivalents based on our 442 Natural Water™ and NaCl E. pH Sensor Storage Solution
standards. All standards are within ±1.0% of reference solutions. Myron L Storage Solution prolongs the life of the pH sensor. It is available
in quarts and gallons. Order SSQ or SSG.
1. Potassium Chloride (KCl)
The concentrations of these reference solutions are calculated from data XIV. TEMPERATURE COMPENSATION (Tempco)
in the International Critical Tables, Vol. 6. The 7000 µS is the of Aqueous Solutions
recommended standard. Order KCl-7000.
Electrical conductivity indicates solution concentration and ionization of
2. 442 Natural Water™ the dissolved material. Since temperature greatly affects ionization,
442 Natural Water Standard Solutions are based on the following salt conductivity measurements are temperature dependent and are normally
proportions: 40% sodium sulfate, 40% sodium bicarbonate, and 20% corrected to read what they would be at 25°C.
sodium chloride, which represent the three predominant components
(anions) in freshwater. This salt ratio has conductivity characteristics A. Standardized to 25°C
approximating fresh natural waters and was developed by the Myron L Conductivity is very accurately measured in the Ultrameter by a method
Company over three decades ago. It is used around the world for that ignores fill level, electrolysis, electrode characteristics, etc., and uses
measuring both conductivity and TDS in drinking water, ground water, a microprocessor to perform temperature compensation. In simpler
lakes, streams, etc. The 3000 ppm is the recommended standard. Order instruments, conductivity values are usually assigned an average
442-3000. correction similar to KCl solutions for correction to 25°C. The correction to
an equivalent KCl solution is a standard set by chemists. It standardizes
3. Sodium Chloride (NaCl) the measurements and allows calibration with precise KCl solutions. In
This is especially useful in sea water mix applications, as sodium chloride the Ultrameter, this correction can be set to other solutions or tailored for
is its major salt component. Most Myron L standard solution labels show special measurements or applications.
the ppm NaCl equivalent to the conductivity and to ppm 442 values. The
14.0 mS is the recommended standard. Order NaCl-14.0. B. Tempco Variation
Most conductivity instruments use an approximation of the temperature
B. Soft Protective Case characteristics of solutions, perhaps even assuming a constant value.
Padded Cordura® Nylon carrying case features a belt clip for hands-free The value for KCl is often quoted simply as 2%/°C. In fact, KCl tempco
mobility. Model: UCC varies with concentration and temperature in a non-linear fashion. Other
® Registered trade mark of DuPont solutions have more variation still. The Ultrameter uses corrections that
change with concentration and temperature instead of single average
C. Data Port values. See Chart 1 on next page.
There is a 4 pin connector marked “Factory Use Only” on the bottom of
the Ultrameter. It is used to interrogate the instrument during final
inspection. Applications in the future for downloading recorded data are
being considered, but not implemented, as of this printing.
22 23
2.500%
D. A Chart of Comparative Error:
2.400% In the range of 1000 µS, the error using KCl on a solution that should be
compensated as NaCl or as 442, is shown in the graph below.
2.300%
7%
2.200%
442 error with KCl tempco
2.100% 6%
% / °C NaCl error with KCl tempco
2.000% 5%
1.900% 4%
1.800% 3%
KCl % / °C
1.700%
2%
1.600%
Temperature 1%
1.500%
0 5 10 15 20 25 30 35 40 45 50 55 60
0%
Chart 1
(1)%
C. An Example of 2 different solution selections and the Temperature
(2)%
resulting compensation: 0 5 10 15 20 25 30 35 40 45 50 55
Chart 2
How much error results from treating natural water as if it were KCl at
15°C? Users wanting to measure natural water based solutions to 1% would
have to alter the internal compensation to the more suitable preloaded
A tap water solution should be compensated as 442 with a tempco of “442” values or stay close to 25°C. Some who have standardized to KCl
1.68 %/°C, where the KCl value used would be 1.90 %/°C. based compensation may want to stick with it, regardless of increasing
error as you get further from 25°C. The Ultrameter will provide the
Suppose a measurement at 15°C (or 59°F) is 900 microsiemens of true repeatability and convertibility of data needed for relative values for
uncompensated conductivity. process control.
Using a 442 correction of 10 (degrees below 25) x 1.68% indicates the E. Other Solutions
solution is reading 16.8% low. For correction, dividing by (.832) yields A salt solution like sea water or liquid fertilizer acts like NaCl. An internal
1082 microsiemens as a compensated reading. correction for NaCl can be selected for greatest accuracy with such
solutions. Many solutions are not at all similar to KCl, NaCl or 442. A sugar
A KCl correction of 10 (degrees below 25) x 1.9% indicates the solution solution, or a silicate, or a calcium salt at a high or low temperature may
is reading 19% low. Dividing by (.81) yields 1111 microsiemens for a require a “User” value peculiar to the application to provide readings
compensated reading. The difference is 29 out of 1082 = 2.7%. close to the true compensated conductivity.
24 25
to indicate a certain setpoint or minimum concentration or trend. The measurements, and should be reset for different dilutions or
Ultrameter gives the user the capability to take data in “KCl conductivity temperatures.
units” to compare to older published data, in terms of NaCl or 442, or as
may be appropriate. The Ultrameter can be used to reconcile data taken C. When does it make a lot of difference?
with other compensation assumptions, especially with its ability to allow First, the accuracy of temperature compensation to 25°C determines the
custom characteristics through the USER mode. accuracy of any TDS conversion. Assume we have industrial process
water to be pretreated by R.O. Assume it is 45°C and reads 1500 µS
XV. CONDUCTIVITY CONVERSION to uncompensated.
TOTAL DISSOLVED SOLIDS (TDS)
1. If NaCl compensation is used, an instrument would report 1035
Electrical conductivity indicates solution concentration and ionization of µS compensated, which corresponds to 510 ppm NaCl.
the dissolved material. Since temperature greatly affects ionization,
conductivity measurements are temperature dependent and are normally 2. If 442 compensation is used, an instrument would report 1024
corrected to read what they would be at 25°C (ref. Temperature µS compensated, which corresponds to 713 ppm 442.
Compensation, pg. 23).
The difference in values is 40%.
A. How it’s Done
Once the effect of temperature is removed, the compensated In spite of such large error, some users will continue to take data in the
conductivity is a function of the concentration (TDS). Temperature NaCl mode because their previous data gathering and process
compensation of the conductivity of a solution is performed automatically monitoring was done with an older NaCl referenced device.
by the internal processor, using data derived from chemical tables. Any
dissolved salt at a known temperature has a known ratio of conductivity to Those who want true TDS readings that will correspond to evaporated
concentration. Tables of conversion ratios referenced to 25°C have been weight will select the correct Solution Type. If none of the 3 standard
published by chemists for decades. solutions apply, the User mode must be used. Temperature
Compensation (Tempco) and TDS Derivation below, details the USER
B. Solution Characteristics mode.
Real world applications have to measure a wide range of materials and
mixtures of electrolyte solutions. To solve this problem, industrial users XVI. TEMPERATURE COMPENSATION (Tempco)
commonly use the characteristics of a standard material as a model for and TDS DERIVATION
their solution, like the KCl favored by chemists for its stability.
The Ultrameter contains internal algorithms for characteristics of the 3
Users dealing with sea water, etc., use NaCl as the model for their most commonly referenced compounds. In the display, the solution type
concentration calculations. Users dealing with freshwater work with being used is shown on the left. Besides KCl, NaCl, and 442, there is the
mixtures including sulfates, carbonates and chlorides, the three “USER” choice. The benefit of USER mode is that one may enter the
predominant components “anions” in freshwater that the Myron L tempco and TDS conversion values of a unique solution from the
Company calls “natural water”. These are modeled in a mixture called keyboard.
“442” which the Myron L Company markets for use as a calibration
standard, as it does standard KCl and NaCl solutions. A. Conductivity Characteristics
When making conductivity measurements, the Solution Selection
The Ultrameter contains internal algorithms for these 3 most commonly determines the characteristic assumed as the instrument reports what a
referenced compounds. In the LCD display, the solution type being used measured conductivity would be if it were at 25°C. The characteristic is
is shown on the left. Besides KCl, NaCl, and 442, there is the “USER” represented by the tempco, expressed in %/°C. If a solution of 100 µS at
choice. The benefit of USER is that one may enter the temperature 25°C increases to 122 µS at 35°C, then a 22% increase has happened
compensation and TDS ratio by hand, greatly increasing accuracy of over this change of 10°C. The solution is said to have a tempco of 2.2
readings for a specific solution. That value remains a constant for all %/°C.
26 27
Another solution would have a different tempco because of its ionization XVII. GLOSSARY
activity. And, that tempco may be a little different at a different
concentration or temperature. This is why the Ultrameter uses Anions - Negatively charged ions.
mathematically generated models for known salt characteristics that vary See Solution Characteristics, pg. 26.
with concentration and temperature.
Algorithm - A procedure for solving a mathematical problem.
B. Finding the Tempco of an Unknown Solution See Temperature Compensation and TDS Derivation,
One may need to measure compensated conductivity of some solution pg. 27.
unlike any of the 3 standard salts. In order to enter a custom fixed tempco
for a limited measurement range, enter a specific value through the TDS - Total Dissolved Solids or the Total Conductive Ions
“USER” function. The tempco can be determined by 2 different in a solution. See Conductivity Conversion to TDS,
methods: pg. 26.
1. Heat or cool a sample of the solution to 25°C, and measure its Tempco - Temperature Compensation
conductivity. Heat or cool the solution to a typical temperature See Temperature Compensation, pg. 23.
where it is normally measured. After selecting USER function,
set the tempco to 0 %/°C as in Disabling Temperature USER - A mode of operation that allows the instrument user
Compensation, pg. 12 (No compensation). Measure the new (operator) to set a tempco and/or a TDS factor for their
conductivity and the new temperature. Divide the % decrease specific solution type. See Temperature Compensation,
or increase by the 25°C value. Divide that difference by the pg. 23 and Temperature Compensation (Tempco) and
temperature difference. TDS Derivation, pg. 27.
28 29
Ultrameter™
Operation
Manual
Addendum
Models 4P & 6P
displayed.
CAL
5. Press the MCLR key.
NOTES:
1. To maintain repeatability, use the same standard solutions for future
calibrations.
2. Calibration of the Ultrameter Gain Factor for User mode is not available
when the calibration link has been established. The other calibration
functions (i.e. Temperature Compensation %/C settings and TDS Ratio
settings) are still intact. To perform a calibration of the User mode as
described in the manual, the User Mode Link should be canceled. See
above Canceling User Mode calibration "Link".
3. Once a "link" has been established for User mode, the "link" will apply
to all measurement modes using User solution selection (i.e. TDS/User,
Cond/User or Res/User).
MR
2. Press the key until three numbers are displayed as shown.
If one of the listed versions is NOT displayed, and these functions are
required, contact the Myron L Company for information on upgrading
your instrument.
5