Chapter-5-Periodic-Classification-Of-Elements/: Dobereiner's Triads

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Early Models of Periodic Table
Dobereiner’s Triads
Dobereiner arranged a group of three elements with similar properties in the order of increasing
atomic masses and called it a triad. He showed that the atomic mass of the middle element is
approximately the arithmetic mean of the other two. But, Dobereiner could identify only following
three triads from the elements known at that time.
Newlands’ Law of Octaves

sa (do) re (re) ga (mi) ma (fa) pa (so) da (la) ni (ti)
H Li Be B C N O
F Na Mg Al Si P F
Cl K Ca Cr Ti Mn Fe
Co and Ni Cu Zn Y In As Se
Br Rb Sr Ce and La Zr ______ _____

When the elements are arranged according to increasing atomic masses, the physical and chemical
properties of every eighth element are similar to that of the first.
Newlands compared these octaves to the series of eight notes of a musical scale.
Assumptions and Limitations:

1. The law was applicable for elements with atomic masses up to 40.
2. Properties of new elements discovered did not fit into the law of octaves.
3. In a few cases, Newlands placed two elements in the same slot to fit elements in the table.
4. He also grouped unlike elements under the same slot.
Mendeleev’s Periodic Table and Law

The physical and chemical properties of elements are periodic functions of their atomic weights.
Features of Mendeleev’s Periodic Table

● Twelve horizontal rows, which were condensed to 7, known as periods.
● Eight vertical columns known as groups.
● Groups I to VII subdivided into A and B subgroups.
● Groups VIII doesn’t have any subgroups and contains three elements in each row.
● Elements in the same group exhibit similar properties.
Achievements of Mendeleev’s Periodic Table

1. A systematic study of elements: Elements with similar properties were grouped together, that
made the study of their chemical and physical properties easier.
2. Correction of atomic masses: Placement of elements in Mendeleev’s periodic table helped in
correcting the atomic masses of certain elements. For example, the atomic mass of beryllium was
corrected from 13.5 to 9. Similarly, atomic masses of indium, gold, platinum etc., were also
corrected.
3. Prediction of properties of yet to be discovered elements: Eka-boron, eka-aluminium and
eka-silicon were the names given to yet to be discovered elements. The properties of these
elements could be predicted accurately from the elements that belonged to the same group. These
elements, when discovered were named scandium, gallium, and germanium respectively.
4. Placement of noble gases: When discovered, they were placed easily in a new group called
zero group of Mendeleev’s table, without disturbing the existing order.
Limitations of Mendeleev’s Periodic Table

1. Position of hydrogen: Hydrogen resembles both, the alkali metals (IA) and the halogens (VIIA)
in properties, so, Mendeleev could not justify its position.
2. Position of isotopes: Atomic weight of isotopes differ, but, they were not placed in different
positions in Mendeleev’s periodic table.
3. Anomalous pairs of elements: Cobalt (Co) has higher atomic weights but was placed before
Nickel (Ni) in the periodic table.
4. Placement of like elements in different groups: Platinum (Pt) and Gold (Au) has similar
properties but were placed in different groups.
5. Cause of periodicity: He could not explain the cause of periodicity among the elements.
Modern Periodic Table

Modern Periodic Law
The physical and chemical properties of elements are the periodic function of their atomic numbers.
Cause of periodicity – It is due to the repetition of same outer shell electronic configuration at a
certain regular interval.
Periods in Modern Periodic Table

Elements present in the same period have the same number of shells which is equal to the
period number.
On moving from left to right in a given period, the number of electrons in the valence shell increases
from one to eight while the number of shells remains the same.
Number of Elements in a Period

The first period contains only two elements 1Hand2He and is known as the shortest period.
The second period (3Lito10Ne) and the third period (11Na to 18Ar) contain 8 elements each and are
known as short periods.
The fourth period (19K to 36Kr) and the fifth period (37Rb to 54Xe) contain 18 elements each and are
called long periods.
The sixth period contains 32 elements (55Cs and 86Rn) and is also known as the longest period.
The seventh period is an incomplete period.
(After the recent discoveries of the new elements and their addition to the periodic table, the seventh
period is officially complete)
Groups in Modern Periodic Table

The modern periodic table contains 18 vertical columns known as groups.
Group 1 elements are known as alkali metals.
Group 2 elements are known as alkaline earth metals.
Group 15 elements are known as pnicogens.
Group 16 elements are known as chalcogens.
Group 17 elements are known as halogens.
Group 18 elements are known as noble gases.
Alkali Metals
The elements in the first group, lithium (Li), sodium (Na), potassium (K), rubidium (Rb), caesium
(Cs), and francium (Fr) are called alkali metals.
They were given the name because they all react with water to form alkalis.
The alkali metals are all shiny, soft, highly reactive solids at standard temperature and pressure and
readily lose their outermost electron to form cations with charge +1.
Number of valence electrons = 1
Alkali Earth Metals

The elements in the second group, beryllium(Be), magnesium (Mg), calcium (Ca), strontium (Sr),
barium (Ba), and radium (Ra) are called alkaline earth metals.
They were given the name because their oxides are alkaline in nature.
They are all shiny, silvery-white, somewhat reactive hard solids at standard temperature and
pressure. They lose two electrons from their outermost shell to form cations with charge +2.
Halogens
The elements in the seventeenth group (F, Cl, Br, I and As) are called halogens and exist as
diatomic molecules. The symbol ‘X’ is often used generically to refer to any halogen.
They were given the name halogen, from the Greek words, Hal- (“salt”) and -gen (“to produce”),
because they all produce a wide range of salts on reacting with metals.
The halogens exist at room temperature in all three states of matter: Solid- Iodine, Astatine. Liquid-
Bromine. Gas- Fluorine, Chlorine.
Noble Gases
The elements in the eighteenth group, helium (He), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe),
and the radioactive radon (Rn) are called noble gases.
They are all odourless, colourless and monatomic gases with very low chemical reactivity.
Since their valence shell is considered to be “full”, they have little tendency to participate in chemical
reactions.
When discovered and identified, scientists thought they are exceedingly rare, as well as chemically
inert, and therefore these gases were also given the names ‘rare’ or ‘inert’ gases.
Classification of Modern Periodic Table

The modern periodic table is also classified into metals, nonmetals and metalloids.
Metals
Metals are electropositive as they form bonds by losing electrons.
In general cases, oxides of metals are basic in nature.
Nonmetals
Nonmetals are electronegative as they form bonds by gaining electrons.
In general cases, oxides of non-metals are acidic in nature.

Metalloids
The elements which show the properties of both metals and nonmetals are called metalloids or
semimetals.
For example – Boron, silicon, germanium, arsenic, antimony, tellurium, and polonium.
Trends in the Modern Periodic Table
Trends in Modern Periodic Table

In a group – Elements have the same number of valence electrons.
Down the group – number of shells increases.
In a period – Elements have the same number of shells.
Along the period – valence shell electrons increase by one unit.
Variation of Valency
Valency of an element can be calculated from the electronic configuration in two ways –
Valency = number of valence electrons (if they are 1, 2, 3 or 4).
Valency = 8 – number of valence electrons (if they are 5, 6, 7 or 8).
All the elements of a group have the same number of valence electrons. Therefore, they all have the
same valency.
Variation of Atomic Size

Atomic size or radii: It is defined as the distance from the centre o the nucleus to the valence shell of
the atom.
Along the period – Atomic radius decreases because effective nuclear charge increases by one unit
and it pulls valence electrons or the electron cloud closer to the nucleus.
Down the group – Atomic radius increases because new shells are added, hence, the distance
between the nucleus and valence electrons or the electron cloud increases.
Variation of Metallic Properties

Along the period – Metallic character decreases because the tendency to lose valence electrons
decreases due to increasing nuclear charge.
Down the group- As the distance between the nucleus and outermost electron increases, nuclear
pull decreases. This increases the tendency of an atom to lose valence electron/s, hence metallic
character increases.
Variation of Nonmetallic Properties

Along the period – Non-metallic character increases as the tendency to gain electrons in the valence
shell increases due to increasing nuclear charge.
Down the group – As the distance between the nucleus and valence shell increases, nuclear pull
decreases. This decreases the tendency of an atom to gain an electron its valence shell, hence non-
metallic character decreases.
Variation of Electronegativity
Along the period – Electronegativity increases as the tendency to gain electrons in the valence shell
increases due to increasing nuclear charge.
Down the group – As the distance between the nucleus and valence shell increases, nuclear pull
decreases. This decreases the tendency of an atom to gain an electron, hence electronegativity
decreases.
Introduction to Periodic Classification of Elements
Why Classification?
Without the classification of elements, it would be extremely difficult and time-consuming to
individually study the chemistry of all the elements. Hence, to simplify and systematize the study of
elements and their compounds, they are classified into groups and periods.

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Newlands’ Law of Octaves

Co and Ni Cu Zn Y In As Se

Br Rb Sr Ce and La Zr ______ _____

Assumptions and Limitations:

Mendeleev’s Periodic Table and Law

Features of Mendeleev’s Periodic Table

Achievements of Mendeleev’s Periodic Table

Limitations of Mendeleev’s Periodic Table

Modern Periodic Table

Periods in Modern Periodic Table

Number of Elements in a Period

Groups in Modern Periodic Table

Alkali Earth Metals

Number of valence electrons = 2

Number of valence electrons = 7

Number of valence electrons = 8

Classification of Modern Periodic Table

In general cases, oxides of metals are basic in nature.

In general cases, oxides of non-metals are acidic in nature.

Trends in the Modern Periodic Table

Trends in Modern Periodic Table

Down the group – number of shells increases.

In a period – Elements have the same number of shells.

Along the period – valence shell electrons increase by one unit.

Valency = number of valence electrons (if they are 1, 2, 3 or 4).

Valency = 8 – number of valence electrons (if they are 5, 6, 7 or 8).

Variation of Atomic Size

Variation of Metallic Properties

Variation of Nonmetallic Properties

Introduction to Periodic Classification of Elements

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Br Rb Sr Ce and La Zr __ _