③ lithium Aluminium

Hydride ( LAH
)
⑨
Nucleophilic Reducing agent

by Acts
only of bond
in
presence polar covalent
( ⇐ ) ( EN ) ( EN) ( N
o etc .

Isolated non -

polar multiple bond can 't be Reduced .

( a- c) u

(0--0) ( NEN ) withcodaafent

* non -

polar multiple bonds present in extended

conjugation pond
pdar
dinar
can be Reduced .

I LAH
f - -
-
H

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cautious

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-E-HesH
non .
!

T not
Isolated
in
conjugation
non -
polar bond .

thief
nanny ayy , till line Hel
→
.
t

+
body
 ③

quota of >nifty
Ere a "

hit
-

H
Hydridedonor H

H -

:÷÷÷÷: ÷→÷÷÷÷÷÷
"

:÷÷
cut )
! r -
Ehr '

solvent
atom
K

nihilo
(?
•

Goto
'

u r -
d -

r
'

④ ←
from Regent Ctr)
 otis
I
' '

④ areas ,
-
-

② Halted

⑤ af -
% - oh
,
-10¥
② DzO④
-

if the molecule (comp cos more e-

deficient easily,
Reduceabk .

H -0
faster attack
deficient
→
- -

→ e

Reduction
capacity

II
> ketone > ester > remade > aced
Aldehyde
R od H
-
'
- R - rid -

o pi
-
R - Faith R-E
acid-Base B@
① R -
I
'
-
o- H ¥ A -
di -

o -

ae%da.tt beg ,
t

A④ o_O

②
C
R -
O

d'
pi -

o -
Es r
-
CEE l
-
R
'
→ r -
O

I took
*
(
1
H H

RnI¥ry
H LAH

PH
R -
c -
H
P

LAH is not sensitive towards acid

(for Redaction
)
 Substrate Reduced product
T
-Reagent
PT
Rtd -

H - LAH ether
,
-
R -
c -
H
I
°
Hz0④ H
11
' LAH, ether PH*
R -
C -

R → → H
R
Hz0⑦ g
-
-

'
R
H
R -
di -
OH → → R -
d -
OH

8-
'
'
H PH
r -
o - R → →
R -
c
-
H 1- R' OH

c'Ice
*
rights
lot
?goe①m
"
r -
→ →
,

H
R
CHINK
-

R
aft Rothko H
GH
→ - -
-

OH
0
55°C minor
ldyy major
-

/¥,¥yo⑦7
R -

R -
CEN
-

¥
LAH ether ,
R -

UI NTL
,
lttgoto
R -

N°2 R Nth
11430+0
-

-
CAH ether →

* Ar -
NO → → Ar - NEN -
Ar
,

R N ⇐ O R NH
- → →
-913
-
-

pH
iii.
•

to
ester • jo
→ →
[igndioh
R X - → → R -
H
Ar -

X → → Ar - H

R -
co -
Nth → → Ratan Hz
' '
R CONHR
-
→ → RAIN HR
 Redaction
of carbonyl compounds .

Esther exception
① ay fusty
-
-
H
alcohol aggregate ,

②
Uts -

at ex -
F -
H ¥71 cuz
-

CHEH - -
H

H
major
( crofton aldehyde) ( crotge alcohol )
*

③
l_at=eH-F H¥I asanas on -

extended (cinnamaldekyde )
conjugation afrit)

⑨ Ph -
cereal -
% -
Oct Ph -

ctlzctftfotl + Ho -
et

'Eoet¥
.ae?Ifn-iuoaH-0
aisc
⑤ as -
E -

air

µ
mg④

pylon
⑥

wouldn't
Ring Break
 Acids
Reduction
of & their derivatives
LAH ether
⑦ ,

UB Cath
diz Cay) ,y- Coot ¥+0 )µUI0H
-

palmate acid
eeltyl alcohol

⑧ Utz -

ctfu -
Coon → Utz
-

Utah -

azote
"
⑨ Dh -

ctfu -
cook → Ph -

Utz CHICHEN
-

④ abides →
④ as
-8 old as - -

④ R - I -

MHz

R I
'
"→
④ - -
NH -
r

R I NIR
④ -

'm -

,
→

⑤ Ph -

NH -

co -

at
,
"→

④ IT Ig
Nos
4-
④ I
at
,
-9,1-91 ,

Nose
⑧
¥N0z 4-

④ "-
again ,
② N OH "→
q
-
ph
-

ph
④ as-
e
s
1st
→
④ 97391 a

④ Ph -

U →

④ cuz
ayy
④ In ÷
↳
 ④ NBS (N - Bromo succinami.de) NCSC
ok
C Ey
°
imide
family
I
-

,§µ
, ,

&
Cb
Allylic Benzylic
Bromihatior
Wohl
)
( Zeglier
Reaction

Free Radikal Mechanism

(c) Reactions involved :

&
Cb
Allylic Benzylic Brom : nation via FRM

EAR

⑦ oxidation

(9)
-
Decarboxylation
NBS His Bra

¥ ¥iEo¥
Bromham
'

Driving force
⇐¥ Induced dipole ti Br
interaction

ye -41
,
BO
 Factors
affecting Reactivity of NBS

① solvent
② medium
§
③ Temp
⑨ substrate 's Santerre

preparation :

¢ No÷s
Brt HBR
-

N -

H t Bra
,

:÷÷*+ns÷÷÷÷÷÷*
me

tho
preferable solvent
SUE Cabo agents! Bro
)
.

substrate t NBS → Subs -

Br t
my

✓ insoluble in
coly

sales Br
-
two
layer
seperationcseas.gg