IUPAC NOMENCLATURE by Bharat Panchal

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2 → di Comblexgb

3→ tri C. Which already contain


4- > tetra diitoi )
5s
benke
6s here 2- bis
3- tris
4- tetakis
5- →
bentakis
6 > hexakis
BASIC
OF ORGANIC
IUPAC NOMENCLATURE

Prefix + Word Root + suffix

2%
"
no .
of carbons i
" meth

Bond functional Group
substituent close /open .

G. → eth
1-
Type
R -

alkyl ↳ → boob
ane
-

✗ - Halo Cyclo ↳ → but


= ene
NO - Mito G- → bent
,
E. The
→ hex
No -
Nitroso
G- hebt
Alkoxy

OR -

(8 → Oct

↳ → Non
Cie → dec
Nomenclatural
p → Parent chain
N →
Numbering
Alphabetical order
A →

preference order

254 9 → Grouts
rant B → Bond ( = , =)
Success
5 → substituent
N
at → Normal
COMMON Prefix ⑨

CH] -
CH ]

du -
Eso #⑨
A-
Tertiary
CH]

CHS -

& -
Neo ⑨
CH
, A

secondary
Functional Group

Alcohol -

OH -
01
Amine -
NH
,
-
amine
Nitrile -
CN -
nitrile
Isonitrile ◦ -

NC -
isonilrile
11
Ketone e o one
-
-
-

d- H
Aldehyde -
-
al
carboxylic Acid - É -
ou -
Oic acid
Ester
Amide
-

¥°_ E- MHz -

-
alkylalranoate
amide
Acid Halide -
É -
✗ -041 halide
NOMENCLATURE OF
ˢA{ATa%Ha¥?%eAdRB°_ eachother
by single bond

C- C- C Propane
2→G > methyl
c- C- C- C- c. Pentane
3.→ Bro Bromo
I 2 3 45
C- C- C- C- C
2- Methyl pentane
& 1
a
I 4 5
21
C- C- C- C- C 3- Bromo -2 -
methyl
1 pentane
Br
5 4 3 29
if two dist . substituent are
C- C- C- C- C
I present at same position , preference
④ ③ will be given ace to alphabetical
-

Bromo
_ .

methyl
order

2- Bromo -
4- methyl pentane
2- Rrs method
• 2 1 45 6 I > as methyl

C- C- C- c- C- C 4 → as Methil


' '
c c

2,74 Trim ethyl hexane


-
CYCLIC HYDROCARBONS

F) Gedo butane
it
Fᵈ¥1 Probyicydobutane
-
1- Pentyl cyclopentane

I 2 3

e- c- c- C- C
4 5
[% 1- Bromo - 2- Chiro

1- Br cyclo butane
±
.

2- Cydobrobylbentane
UNSATURATED HYDROCARBONS
c- care attached to each other
= ene
by atleast one multiple bond
E. yne

c- c- c
prob C- CIC -
C
-
g ene
-

But - 2- yne
3 2 1 , z z ,

Cl
5 4 3 2 a

C -
C -
C -
C :-C C. E. C- d- G- C- C- C
'
Br I 2 3 4 56 7
4- Bromo bent tyne
"

3- Chloro hebt -4 en -
I yne
-

(9%9947)
-

truth vowel rule


.
→ .

-
=
No two vowel
present with each other
C. =
C- c- CIC if two different bond [= , -= ) are

present at same position preference


I 2 3 45
,

will be give to double bond

pent -
1- end -
4- yne

word root ends with "


a
"

2
l 3 4 5

C- C G- C
-

C -

Penta -1,4 diene


-
CYCLIC

g Cydoboob -1 ene
4
-

3 21
C- C- C=c
1-

It
Cydobuta -13 -

diene
3- Aedobentge

but -1 ene
②a- metal
-

±④
chloro
Bromo

$ 2
3- Bromo - 5- chlo.ro -
4- methyl

cyclo bent Here


-
Alcohol -
OH -
01 5 19 ] 2 I

e- C- C- C- C
{ d- on Ethan -1-0-1
0h
'

PM 4- Chloro benteen -2-01

l{_{- Protean -2-01



I 2 3 4 5 5 1932 I

C
c- c- c- c- c
C- C- C-
-
C
,

tou tou on

Pentane -2,4 -
diol 4- Brom bent - -
ten -3-01
OH
C- C. Ethane -1,2 diol
2/45 -

¥_④
1 I
on on Glycol


3- Bromo -
4-
ethyl
cydobentan -1-01 Propane -1,2 ]
G-
C- C ,
-
biol

outoutoll Glycerol
Amines R MH ,
-
R MH
-
- R R - M R
-

K 3. amine
i amine 2° amine

I 2 I
c- C- C- C- MHz C- C- C Boban -
2- amie
4 3 21 1
Bulan 1- amine
-
NH
,

MHz MHz
C- C- C - C
I 21 3 4 Fi ,
4- Chloro

NIL ¥ cyclohexane/ -1 .

Cl amie
Butane -2,3 diamine -

-

4
C- C C
3
- -
MH C C
- - 21
meth
C- C- C- C
Y C
- -

I 2 I

c- °
d- Ethyl probate -
famine methyl

N -
Ethyl -
N -

methyl baton - 1- amice


B① ← Bromo

C. = C- in
2 I
probed

N Bromo
-
-
N -
brobyeeth -1 -
en - I -
amid
ketones R- § -

RI one

f&É Boban 2- one

t.EE?.~ji~Pentan-s-
-

one

s
5 Cydobentan -
tone

c- d- c=c
But -3 -
en -
2- one
2 3
i
4
Aldehyde -
§ -
h
-
al "

if Cq Cho included in Chai


is not
-

Carbaldehyde
"
if c
of Cho

included in chain
C- C- CHO

,§H°
3 2 I

Protean -
tab
µ cyclopentane -1
i. CHO -

carbaldehol

⑤ d-31c-⑨ 2
4 3 2 I

C- c- c- Cno
CHO

6t¥41
g.
3- Cyclo hex 2- enyl -

3- meths bulan -1 al
2- Ethyl
-

butane -1,4 dial-


?⃝
E- Eino is .


¥ c- C- Cleo
'
a
3- Aedobentylbroban tal
-

I 2 3

C- C- C bicarbaldehyde
Propane-1,2 ,
]
-

duo duo { no

identical treatment
Acid COOH Oic acid
Carboxylic
-
-

3 2 t
COOH
C- C- COOH

Protean -
toicacid a
# -
Cydobutane
-
1- carbolic
G- c- C- C- Coon acid
I 2 3

5 43 2 I
C- C- C
' 1
Pent -
4- en -
1- oicacid I
(004
Coon cooy

Propane -1,33 toicarboxslicacid


-
Est① R -
COO -
R
'

Ers
alkyl alkanet

C- C- COO
-
-

£ €-00 -

GI

Methyepropanoate Ethylbutanoate
Aromatic HYDROCARBONS

Cotto

¥1 Benzene }
Nabhthalene
{ Anthracene


""

Toluene
Chlorobenzene
Benzyl
- Cn - n

,
ICH }
Methyl benzene or Toluene
Benzae
ÉÉ
Benzo

¥Y 1- Bromo -

2- chlorobenzene
3ÑHUd
°

m
6
{ʰ °

3 M
1,2

1,3 or
or 1,6

1,5
-

-
O

m -
- ortho

meta

1,4 - b - para
4

P
I
ee Br

ÉÉ
"

FEI.rs .
ÉÉ 3

I
1,2 Diction benzene
-

1,1 -
Dibromo 1,4 Diiodo benzene
-

-
-

benzene or
or
0 - Di chlorobenzene m - pibnomo benzene b- Diiodobenzehe
40011 ICH Br
,
-

Phenol
f Benzoic acid
F Benzyl
bromide

pole "

¥" Aniline
¥4 Benloudenloride Acetobheone

3 Methoxy benney ion cool


◦✗ benzoic acid
Amesol 2- Hydroxy
or salicylic acid
CHO
• PU
€-1 Benzaldehyde "◦

2. Hydroxy benzaldehyde
Nill cooysalicyldetydl
F Benzene diazonium
chloride € ,
Tere bhthalic
acid
NOMENCLATURE OF POLY FUNCTIONAL GROUP

Carb Acid -
COOH
-

carboxy
}
.

Acid
sulphuric Acid sulbho
Sogn
-
-

ester E- or alkoxy Carbonyl


}
-
_

Acid Halide acid


_
-4
-

Halotormyl
Acid Amide _ -
nite Derivative -

carbonyl
,
Nitrile EN
-

cyano
} _= Bond
-

Isonitrile -
N :c _

isocyano
Aldehyde É formyl / 0×0
-1,7 } Bond
-
-

=
Ketone ,
-0×0 / keto

Alcohol OH hydroxy
}
-
-

Thiol SH Bond mercabto


- -
-

Amine amino
-

Nita -
in
'

-
Coote

:@ Hydroxy toicacid
3
3- -

2- nibobutan -

Nitro
hydroxy

⑦ M ←amiu
0×0
.

Ctg -
§ -
du -
du -
COOH
2- Amino -
3- hydroxy -4-0×0
4 I 2 1
5 benteen -
1- oicaa 'd

⑦ °

d
'

CH - -
CH -

COOH
, ,

4 ] 2
I

Cha CHO
GH CH
4- Chloro -3 methoxy
• - - -
-

,
⑥ batan tal
-

↓ methane .

Chloro
?⃝
?⃝
4 I 2
f

C- C- C- C- OH
7.9 2- Ameenobutan -1-01

OH

city &nˢ_ §
'
CH, 3-
ttydnoxybutan
• _

2-
-

one
,
0

OH
'
°
4 3- Ethyl 5-
hydroxy

cyclohexane -1
-
-
one

%¥°
COMMON NOMENCLATURE

c- C- C- c- C
n -
pentane

C- E- c- c isotsentane µ
c

c- d- c neo - pentane *
'
c
MA n -
Heptane

*E Iso -

Heptane

*.
neo -
Heblane
i
C- c- on on

&
tert-Butyl alcohol
i
C- 8 -
N
Hz
a
{
c- C ¥8 on
tert-Butyl amine
- -

Sec -

Butyl -
alcohol

i
C-C- MHz
ALOU Iso bentgl alcohol

µ¥Nᵗʰ neeopentglamlne

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