Plastic Marking Document
Plastic Marking Document
Plastic Marking Document
Table of Contents
1 Introduction
2 Scope
3 Marking requirements
3.1 Part weight
3.2 Character size
3.3 Marking legibility
3.4 Marking method
3.5 Marking location
4 Marking identification symbols
4.1 Material identification for basic polymers
4.1.1 Polymer blends
4.1.2 Laminates
4.2 Ignition-resistant (flame retardant) materials
4.3 Filler and Reinforced Composition Marking
4.3.1 Marking for Additional materials
4.4 Plasticizers
4.4.1 Supplemental Requirements for plasticizers
Page 1
5951-1741-1 15-March-2017
1 Introduction
This document provides the requirements for marking HP's plastic parts and products. This marking
will be used during subsequent recycling, reuse, or disposal.
2 Scope
The requirements of this standard apply to all molded plastic parts used in products specified by or
purchased for HP that are manufactured after 01-Jan-2005. This standard does not apply to plastic
packaging materials.
This standard specifies uniform requirements for physically marking products and parts made of
polymeric (plastic) materials according to internationally recognized standards:
HP plastic parts and products are to be physically marked in accordance with this standard so
they can be identified, separated, and processed for recycling.
The abbreviated terms included in this standard are consistent with the ISO/DIS 11469 Plastics
- Generic Identification and Marking of Plastic Products and ISO-1043-1 through ISO-1043-4
Plastics - Symbols standards and specify the requirements for generic marking of polymers.
3 Marking requirements
If the part size, geometry, and cosmetic and effective function allow, all plastic parts and products
must be physically marked with the appropriate symbols or codes (identified in the tables within this
standard) to designate the following:
Basic polymer in the part (Section 4.1)
Flame retardant material used (Section 4.2)
Filler or reinforcement used to fabricate the part (Section 4.3)
Plasticizer used (Section 4.4)
Recycled content (Section 4.5)
Section 5.0 identifies additional coding and information.
The requirements to be followed used when marking plastic parts and products are included in the
following subsections.
Page 2
5951-1741-1 15-March-2017
manufacturers (ODMs), must notify HP in writing to determine the recycling impact of the unmarked
part.
All manufacturers, including OEMs, CMs, and ODMs, are strongly encouraged to include physical
marking, where practical, on all parts weighting less than 25 grams. Where physical marking on parts
weighing less than 25 grams is required, this requirement will be noted on applicable drawings or
procurement documents.
Page 3
5951-1741-1 15-March-2017
Page 4
5951-1741-1 15-March-2017
Page 5
5951-1741-1 15-March-2017
PS polystyrene SB styrene-butadiene
Page 6
5951-1741-1 15-March-2017
Page 7
5951-1741-1 15-March-2017
Page 8
5951-1741-1 15-March-2017
Page 9
5951-1741-1 15-March-2017
Page 10
5951-1741-1 15-March-2017
[1] The materials may be further defined; for example by their chemical symbols or by additional
symbols defined in the relevant International Standard.
[2] In the case of metals (ME), the type(s) of metal must be indicated by its chemical symbol.
[3] A specific material may be further defined
4.4 Plasticizers
Compositions containing plasticizers must be physically marked with the abbreviated term for the
polymer, followed by a hyphen, then the symbol "P" followed by the abbreviated term of the plasticizer
in parentheses, as described in ISO 1043-3.
For example, a PVC containing dibutyl phthalate is marked: >PVC-P(DBP)<
Supplemental requirements for plasticizers are shown in Table 5.
4.4.1 Supplemental requirements for plasticizers
Table 5 provides uniform symbols for components relating to plasticizers, to form abbreviated terms.
It includes typical abbreviated terms that have come into established use.
Requirements:
1. The first appearance of an abbreviated term in a text must be enclosed in parentheses and shall be
preceded by the chemical name written in full. For example, Alkysulfonic acid ester (ASE).
2. Only capital letters shall be used for the symbols.
3. Mixtures of plasticizers are not considered.
4. Unless otherwise indicated, the alkyl groups are n-alkyl groups and phthalates are esters of o-
phthalic acid.
5. No symbol is used in the abbreviated terms to indicate normal (n-) linear alcohols. For branched
(iso) alcohols, the additional symbol l is used with one exception: in view of the worldwide usage of
the symbol O for 2-ethylhexyl (for example in DOA and DOP), this practice is observed in this part of
ISO 1043 and the n-octyl group is designated NO (as in DNOP). Because of this dual usage, the
application of the rule specified in Requirement 1 is most important.
6. The symbol l designates iso-branched groups (for example, DIOP). However, DTDP is sometimes
used instead of DITDP because di-n-tridecyl phthalate is not a plasticizer: when DTDP is used, the
application of the rule specified in 1 (one) is most important.
7. For plasticizers based on di-esters of the same alcohol, the first symbol of the abbreviated term is
D.
8. The letter P may be used in place of F for "phosphate" in abbreviated terms for plasticizers.
Page 11
5951-1741-1 15-March-2017
9. Several plasticizers having "iso" names indicating branched groups may consist of several isomers.
For this reason, no single IUPAC name can describe the detailed chemical composition of each of
these plasticizers.
10. Some plasticizers consisting of esters of more than one alcohol are known by the combined
number and letter code, for example, 711A is an alternative common name for heptyl nonyl
undecyl adipate (HNUA). The first digit represents the number of carbon atoms in the shortest alkyl
group and the second and third digits represent that of the longest alkyl group in the plasticizer:
thus 7 denotes heptyl and 11 denotes undecyl. The letter at the end of the code is either A, which
denotes adipate, or P, which denotes phthalate.
Table 5: Plasticizers
Abbreviated Term Common name IUPAC* equivalent CAS-RN**
ASE Alkysulfonic acid ester Alkysulfonates or not known
Alkyl alkanesulfonates
ATBC (or TBAC) tributyl o-acetylcitrate(or tributyl o-acetylcitrate 77-90-7
acetyl tributylcitrate)
ATEC (or TEAC) triethyl o-acetylcitrate(or triethyl o-acetylcitrate 77-89-4
acetyl triethyl citrate)
ATEHC actyltri-(2-ethylhexyl) tris(2-ethylhexyl)2- 144-15-0
citrate actyloxypropane-
1,2,3-tricarboxylate
BAR butylo-acetylricinoleate Butyl ®-12- 140-04-5
acetoxyoleate
BBP Benzyl butyl phthalate same 85-68-7
BCHP Butyl cyclohexl phthalat same 84-64-0
BNP Butyl nonyl phthalate same not known
BOA Benzyl octyladipate benzyl2-ethyhexyl 3089-55-2
adipate
BOP Butyl octyl phthalate butyl2-ethylhexyl 85-69-8
phthalate
BST Butyl stearate same 123-95-5
DBA Dibutyl adipate same 105-99-7
BEP di-(2-butoxyethyl) bis(2-butoxyethyl) 117-83-9
phthalate phthalate
DBF dibutyl fumarate same 105-75-9
DBM dibutyl maleate same 105-76-0
Page 12
5951-1741-1 15-March-2017
Table 5: Plasticizers
Abbreviated Term Common name IUPAC* equivalent CAS-RN**
DBP dibutyl phthalate same 84-74-2
DBS dibutyl sebacate same 109-43-3
DBZ dibutyl azelate same 2917-73-9
DCHP dicyclohexyl phthalate same 84-61-7
DCP dicapryl phthalate bis(1-methylheptyl) 131-15-7
phthalate
DDP didecyl phthalate same 84-77-5
DEGDB diethylene glycol oxydiethylene 120-55-8
dibenzoate dibenzoate
DEP diethyl phthalate same 84-66-2
DHP diheptyl phthalate same 3648-21-3
DHXP dihexyl phthalate same 84-75-3
DIBA diisobutyl adipate same 141-04-8
DIBM diisobutyl maleate same 14234-82-3
DIBP diisobutyl phthalate same 84-69-5
DIDA diisobutyl adipate see 8 27178-16-1
DIDP diisodecyl phthalate see 8 26761-40-0
DIHP diisoheptyl phthalate as above 41451-28-9
DIHXP diisohexyl phthalate same 71850-09-4
DINA diisononyl adipate see 8 33703-08-1
DINCH diisononyl diisononyl 166412-78-8
cyclohexanedicarboxylate cyclohexane-1,2-
dicarboxylate
DINP diisononyl phthalate see 8 28553-12-0
DIOA diisooctyl adipate see 8 1330-86-5
DIOM diisooctyl maleate see 8 1330-76-3
DIOP diisooctyl phthalate see 8 27554-26-3
DIOS diisooctyl sebacate see 8 27214-90-0
DIOZ diisooctyl azelate see 8 26544-17-2
DIPP diisooctyl phthalate same 605-50-5
Page 13
5951-1741-1 15-March-2017
Table 5: Plasticizers
Abbreviated Term Common name IUPAC* equivalent CAS-RN**
DMEP di-(2-methyloxyethyl) bis(2-methoxyethyl) 117-82-8
phthalate phthalate
DMP dimethyl phthalate same 131-11-3
DMS dimethyl sebacate same 106-79-6
DNF dinonyl fumarate same 2787-63-5
DMN dinonyl maleate same 2787-64-6
DNOP di-n-octyl phthalate dioctyl phthalate 117-84-0
DNP dinonyl phthalate same 14103-61-8
DNS dinonyl sebacate same 4121-16-8
DOA dioctyl3) adipate bis(2-ethylhexyl)3) 103-23-1
adipate
DOIP dioctyl isophthalate bis(2-ethylhexyl) 137-89-3
isophthalate
DOP dioctyl phthalate bis(2-ethylhexyl) 117-81-7
phthalate
DOS dioctyl sebacate bis(2-ethylhexyl) 122-62-3
sebacate
DOTP (or DEHT) dioctyl terephthalate bis(2-ethylhexyl) 6422-86-2
terephthalate
DOZ dioctyl azelate bis(2-ethylhexyl) 2064-80-4
azelate
DPCF (or DPCF) diphenyl cresyl phosphate diphenyl x-tolyl 26444-49-5
orthophosphate where
x demotes o, m, p or
mixture
DPGDB di-x--propylene glycol not possible not known
dibenzoate
DPHP di-(2-propylheptyl) bis(2-propylheptyl) 53306-54-0
phthalate benzene-1,2-
dicarboxylate
DPOP (or DPOF) diphenyl octyl phosphate 2-ethylhexyl diphenyl 1241-94-7
orthophosphate or
octyl diphenyl
orthophosphate
DPP diphenyl phthalate same 84-62-8
Page 14
5951-1741-1 15-March-2017
Table 5: Plasticizers
Abbreviated Term Common name IUPAC* equivalent CAS-RN**
DTDP diisotridecyl phthalate (see see 8 27253-26-5
note X)
DUP diundecyl phthalate same 3648-20-2
ELO epoxidized linseed oil not possible 8016-11-3
ESBO epoxidized soya bean oil not possible 8013-07-8
GTA glycerol triacetate same 102-76-1
HNUA heptyl nonyl undecyl not possible Not known
adipate (=711A)
HNUP heptyl nonyl undecyl not possible 68515-42-4
phthalate (=711P)
HXODA heptyl octyl decyl adipate not possible not known
(=610A)
HXODP heptyl octyl decyl phthalate not possible 68515-51-5
(=610P)
NUA nonyl undecyl adipate not possible not known
(=911A)
NUP nonyl undecyl phthalate not possible not known
(=911P)
ODA octyl decyl adipate decyl octyl adipate 110-29-2
ODP octyl decyl phthalate decyl octyl phthalate 68515-52-6
ODTM n-octyl decyl trimellitate decyl octyl hydrogen not known
Benzene1,2,4-
tricarboxylate
PO paraffin oil not possible 8012-95-1
PPA poly(propylene adipate) same not known
PPS poly(propylene sebacate) not possible not known
SOA sucrose octa-acetate sucrose octaacetate 126-14-7
TBAC (or ATBC) tributyl o-acetylcitrate same 77-90-7
TBEP tri-(2-butoxyethyl) tris(2-butoxyethyl) 78-51-3
phosphate orthophosphate
TBP tributyl phosphate tributyl 126-73-8
orthophosphate
TCEP (or TCEF) trichloroethyl phosphate tris(2-chloroethyl) 6145-73-9
Page 15
5951-1741-1 15-March-2017
Table 5: Plasticizers
Abbreviated Term Common name IUPAC* equivalent CAS-RN**
orthophosphate
TCP (or TCF) tricresyl phosphate tri-x-tolyl 1330-78-5
orthophosphate where
x denotes o, m, p or
mixture
TDBPP tri-(2,3-dibromopropyl) tris(2,3- 126-72-7
phosphate dibromopropyl)
orthophosphate
TDCPP tri-(2,3-dichloropropyl) tris(2,3- 78-43-3
phosphate dichloropropyl)
orthophosphate
TEAC (or ATEC) triethyl o-acetylcitrate same 77-89-4
THFO tetrahydrofurfuryl oleate same 5420-17-7
THTM triheptyl trimellitate triheptyl benzene- 1528-48-9
1,2,4-tricarboxylate
TIOTM triisooctyl trimellitate tris(6-methylheptyl) 27251-75-8
Benzene-1,2,4-
tricarboxylate
TOP (or TOF) trioctyl phosphate tris(2-ethylhexyl) 78-42-2
orthophosphate
TOPM tetraoctyl pyromellitate tetrakis(2-ethylhexyl) 3126-80-5
benzene-1,2,45-
tetracarboxylate
TOTM trioctyl trimelliate tris(2-ethylhexyl) 89-04-3
benzene-1,2,45-
tetracarboxylate
TPP triphenyl phosphate triphenyl 115-86-6
orthophosphate
TXP (or TXF) trixylyl phosphate tri-x,y-xylyl 25155-23-1
orthophosphate,
where x and y denotes
o, m, p or mixture
* IUPAC is the International Union of Pure and Applied Chemicals.
** CAS-RN identifies the Chemical Abstracts Service - Registry Number
Page 16
5951-1741-1 15-March-2017
5 Supplemental identification
Additional identification marking, such as date code, country of origin, part model name, part version,
ISO supplemental part marking, and so forth, may be included on the part, upon Divisional discretion.
However, no additional information may replace the universal material marking code defined in this
standard.
Page 17
5951-1741-1 15-March-2017
Page 18
5951-1741-1 15-March-2017
Page 19
5951-1741-1 15-March-2017
L linear T toughened
U ultra V very
U unplasticized W weight
U unsaturated X crosslinked; crosslinkable
6 References
ASTM D1600, Standard Terminology Relating to Abbreviations and Codes for Terms
Related to Plastics.
ASTM D1972, Standard Practice for Generic Marking of Plastic Products
ISO 1043-1:2011(E) Plastics - Symbols. Part 1: Basic polymers and their special
characteristics.
ISO 1043-2:2011(E) Plastics- Symbols Part 2: Fillers and Reinforcing Materials.
ISO 1043-3:2016(E) Plastics-Symbols and abbreviated terms Part 3 Plasticizers
ISO 1043-4:1998 (E) Plastics-Symbols Part 4 Flame retardants.
ISO 11469-2016 (E). Plastics - Generic Identification and Marking of Plastic Products.
SAE J1344. Marking of Plastics Parts.
Page 20
5951-1741-1 15-March-2017
Revision History:
Revision, Brief Description of change
Date,
Change Number
Rev F Added Organic phosphorus compounds to Table 4.
26-Aug-2003
Rev G Changed threshold guideline for marking from 3 grams to 25 grams.
03-Aug-2004
Rev H Reformatted to new template. Text was re-ordered and edited for clarity.
21-Feb-2005 Examples were added where needed.
Rev J Correction in section 4.2 to change “1000 PPM (0.1%)” to “1% by weight.”
21-Mar-2005
DCN 02752
Rev J1 Minor revision change to correct Table 3, “Not Allocated” numbers for Organic
29-Mar-2005 Phosphorus Compounds.
DCN 02754
01-Aug-2008 Ownership change. No revision change needed.
03-Jan-2012 Ownership change. No revision change needed.
24–June-2015 Company name and ownership change. No revision change needed.
Rev K Updates including:
15-March-2017 1) The additional of an option to include plastic recyclate and its content.
2) New symbol for polymers, fillers, reinforcing material, plasticizers and
special characters.
3) Correction of engraving code examples in previous revision
4) Correction of internal HP standards website
Page 21