ISO Marking Codes
ISO Marking Codes
ISO Marking Codes
Abstract This document provides a standard for the marking of HP's plastic
parts and products, to be used for subsequent decision-making
during recycling, reuse, or disposal.
Applicability The requirements of this standard apply to all plastic parts and
products specified by or purchased for HP that are manufactured
after 01-Jan-2005. Management of these requirements is mandatory
for persons specifying plastic parts and products for use by HP.
Status APPROVED
Table of Contents
1 Introduction
2 Scope
3 Marking requirements
3.1 Part weight
3.2 Character size
3.3 Marking legibility
3.4 Marking method
3.5 Marking location
4 Marking identification symbols
4.1 Material identification for basic polymers
4.1.1 Polymer blends
4.1.2 Laminates
4.2 Ignition-resistant (flame retardant) materials
4.3 Filler and Reinforced Composition Marking
4.3.1 Marking for Additional materials
4.4 Plasticizers
4.4.1 Supplemental Requirements for plasticizers
5 Supplemental Identification
5.1 Commercial blends
5.2 Indication of special characteristics
6 References
1 Introduction
This document provides the requirements for marking HP's plastic parts and products. This marking will
be used during subsequent recycling, reuse, or disposal.
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2 Scope
The requirements of this standard apply to all molded plastic parts used in products specified by or
purchased for HP that are manufactured after 01-Jan-2005. This standard does not apply to plastic
packaging materials.
This standard specifies uniform requirements for physically marking products and parts made of
polymeric (plastic) materials according to internationally recognized standards:
• HP plastic parts and products are to be physically marked in accordance with this standard so
they can be identified, separated, and processed for recycling.
• The abbreviated terms included in this standard are consistent with the ISO/DIS 11469 Plastics -
Generic Identification and Marking of Plastic Products and ISO-1043-1 through ISO-1043-4
Plastics - Symbols standards and specify the requirements for generic marking of polymers.
3 Marking requirements
If the part size, geometry, and cosmetic and effective function allow, all plastic parts and products must
be physically marked with the appropriate symbols or codes (identified in the tables within this standard)
to designate the following:
• Basic polymer in the part (Section 4.1)
• Flame retardant material used (Section 4.2)
• Filler or reinforcement used to fabricate the part (Section 4.3)
• Plasticizer used (Section 4.4)
Section 5.0 identifies additional coding and information.
The requirements to be followed used when marking plastic parts and products are included in the
following subsections.
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revisions. Production Change Orders should include instructions for updating the marking code whenever
material is changed.
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Compositions with a mixture of fillers or reinforcing materials must include the filler’s indicator and
percentage within parentheses (curved brackets).
For example, a polyamide 66 containing a mixture of 15% mineral powder and 25% glass fiber is
indicated as follows: >PA66-(GF25+MD15)<
There must be no space before or after the plus (+) sign.
Symbols for fillers and reinforcing materials are identified in Table 4.
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4.4 Plasticizers
Compositions containing plasticizers must be physically marked with the abbreviated term for the
polymer, followed by a hyphen, then the symbol "P" followed by the abbreviated term of the plasticizer in
parentheses, as described in ISO 1043-3.
For example, a PVC containing dibutyl phthalate is marked: >PVC-P(DBP)<
Supplemental requirements for plasticizers are shown in Table 5.
4.4.1 Supplemental requirements for plasticizers
Table 5 provides uniform symbols for components relating to plasticizers, to form abbreviated terms. It
includes typical abbreviated terms that have come into established use.
Requirements:
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1. The first appearance of an abbreviated term in a text must be enclosed in parentheses and shall be
preceded by the chemical name written in full. For example, Alkysulfonic acid ester (ASE).
2. Mixtures of plasticizers are not considered.
3. Unless otherwise indicated, the alkyl groups are n-alkyl groups and phthalates are esters of o-phthalic
acid.
4. No symbol is used in the abbreviated terms to indicate normal (n-) linear alcohols. For branched (iso)
alcohols, the additional symbol l is used with one exception: in view of the worldwide usage of the
symbol O for 2-ethylhexyl (for example in DOA and DOP), this practice is observed in this part of ISO
1043 and the n-octyl group is designated NO (as in DNOP). Because of this dual usage, the
application of the rule specified in Requirement 1 is most important.
5. The symbol l designates iso-branched groups (for example, DIOP). However, DTDP is sometimes
used instead of DITDP because di-n-tridecyl phthalate is not a plasticizer: when DTDP is used, the
application of the rule specified in 1 (one) is most important.
6. For plasticizers based on di-esters of the same alcohol, the first symbol of the abbreviated term is D.
7. The letter P may be used in place of F for "phosphate" in abbreviated terms for plasticizers.
8. Several plasticizers having "iso" names indicating branched groups may consist of several isomers.
For this reason, no single IUPAC name can describe the detailed chemical composition of each of
these plasticizers.
9. Some plasticizers consisting of esters of more than one alcohol are known by the combined number
and letter code, for example, 711A is an alternative common name for heptyl nonyl undecyl adipate
(HNUA). The first digit represents the number of carbon atoms in the shortest alkyl group and the
second and third digits represent that of the longest alkyl group in the plasticizer: thus 7 denotes
heptyl and 11 denotes undecyl. The letter at the end of the code is either A, which denotes adipate, or
P, which denotes phthalate.
Table 5: Plasticizers
Abbreviated Term Common name IUPAC* equivalent CAS-RN**
ASE Alkysulfonic acid ester Alkysulfonates or not known
Alkyl alkanesulfonates
BAR butylo- Butyl ®-12- 140-04-5
acetylricinoleate acetoxyoleate
BBP Benzyl butyl phthalate same 85-68-7
BCHP Butyl cyclohexl same 84-64-0
phthalat
BNP Butyl nonyl phthalate same not known
BOA Benzyl octyladipate benzyl2-ethyhexyl 3089-55-2
adipate
BOP Butyl octyl phthalate butyl2-ethylhexyl 85-69-8
phthalate
BST Butyl stearate same 123-95-5
DBA Dibutyl adipate same 105-99-7
BEP di-(2-butoxyethyl) bis(2-butoxyethyl) 117-83-9
phthalate phthalate
DBF dibutyl fumarate same 105-75-9
DBM dibutyl maleate same 105-76-0
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Table 5: Plasticizers
Abbreviated Term Common name IUPAC* equivalent CAS-RN**
DBP dibutyl phthalate same 84-74-2
DBS dibutyl sebacate same 109-43-3
DBZ dibutyl azelate same 2917-73-9
DCHP dicyclohexyl phthalate same 84-61-7
DCP dicapryl phthalate bis(1-methylheptyl) 131-15-7
phthalate
DDP didecyl phthalate same 84-77-5
DEGDB diethylene glycol oxydiethylene 120-55-8
dibenzoate dibenzoate
DEP diethyl phthalate same 84-66-2
DHP diheptyl phthalate same 3648-21-3
DHXP dihexyl phthalate same 84-75-3
DIBA diisobutyl adipate same 141-04-8
DIBM diisobutyl maleate same 14234-82-3
DIBP diisobutyl phthalate same 84-69-5
DIDA diisobutyl adipate see 8 27178-16-1
DIDP diisodecyl phthalate see 8 26761-40-0
DIHP diisoheptyl phthalate as above 41451-28-9
DIHXP diisohexyl phthalate same 71850-09-4
DINA diisononyl adipate see 8 33703-08-1
DINP diisononyl phthalate see 8 28553-12-0
DIOA diisooctyl adipate see 8 1330-86-5
DIOM diisooctyl maleate see 8 1330-76-3
DIOP diisooctyl phthalate see 8 27554-26-3
DIOS diisooctyl sebacate see 8 27214-90-0
DIOZ diisooctyl azelate see 8 26544-17-2
DIPP diisooctyl phthalate same 605-50-5
DMEP di-(2-methyloxyethyl) bis(2-methoxyethyl) 117-82-8
phthalate phthalate
DMP dimethyl phthalate same 131-11-3
DMS dimethyl sebacate same 106-79-6
DNF dinonyl fumarate same 2787-63-5
DMN dinonyl maleate same 2787-64-6
DNOP di-n-octyl phthalate dioctyl phthalate 117-84-0
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Table 5: Plasticizers
Abbreviated Term Common name IUPAC* equivalent CAS-RN**
DNP dinonyl phthalate same 14103-61-8
DNS dinonyl sebacate same 4121-16-8
DOA dioctyl3) adipate bis(2-ethylhexyl)3) 103-23-1
adipate
DOIP dioctyl isophthalate bis(2-ethylhexyl) 137-89-3
isophthalate
DOP dioctyl phthalate bis(2-ethylhexyl) 117-81-7
phthalate
DOS dioctyl sebacate bis(2-ethylhexyl) 122-62-3
sebacate
DOTP dioctyl terephthalate bis(2-ethylhexyl) 6422-86-2
terephthalate
DOZ dioctyl azelate bis(2-ethylhexyl) 2064-80-4
azelate
DPCF diphenyl cresyl diphenyl x-tolyl 26444-49-5
phosphate orthophosphate where
x demotes o, m, p or
mixture
DPGDB di-x--propylene glycol not possible not known
dibenzoate
DPOF diphenyl octyl 2-ethylhexyl diphenyl 1241-94-7
phosphate orthophosphate or
octyl diphenyl
orthophosphate
DPP diphenyl phthalate same 84-62-8
DTDP diisotridecyl phthalate see 8 27253-26-5
(see note X)
DUP diundecyl phthalate same 3648-20-2
ELO epoxidized linseed oil not possible 8016-11-3
ESO epoxidized soya bean not possible 8013-07-8
oil
GTA glycerol triacetate same 102-76-1
HNUA heptyl nonyl undecyl not possible Not known
adipate (=711A)
HNUP heptyl nonyl undecyl not possible 68515-42-4
phthalate (=711P)
HXODA heptyl octyl decyl not possible not known
adipate (=610A)
HXODP heptyl octyl decyl not possible 68515-51-5
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Table 5: Plasticizers
Abbreviated Term Common name IUPAC* equivalent CAS-RN**
phthalate (=610P)
NUA nonyl undecyl adipate not possible not known
(=911A)
NUP nonyl undecyl not possible not known
phthalate (=911P)
ODA octyl decyl adipate decyl octyl adipate 110-29-2
ODP octyl decyl phthalate decyl octyl phthalate 68515-52-6
ODTM n-octyl decyl decyl octyl hydrogen not known
trimellitate Benzene1,2,4-
tricarboxylate
PO paraffin oil not possible 8012-95-1
PPA poly(propylene same not known
adipate)
PPS poly(propylene not possible not known
sebacate)
SOA sucrose octa-acetate sucrose octaacetate 126-14-7
TBAC tributyl o-acetylcitrate same 77-90-7
TBEP tri-(2-butoxyethyl) tris(2-butoxyethyl) 78-51-3
phosphate orthophosphate
TBP tributyl phosphate tributyl 126-73-8
orthophosphate
TCEF trichloroethyl tris(2-chloroethyl) 6145-73-9
phosphate orthophosphate
TCF tricresyl phosphate tri-x-tolyl 1330-78-5
orthophosphate where
x denotes o, m, p or
mixture
TDBPP tri-(2,3-dibromopropyl) tris(2,3- 126-72-7
phosphate dibromopropyl)
orthophosphate
TDCPP tri-(2,3-dichloropropyl) tris(2,3-dichloropropyl) 78-43-3
phosphate orthophosphate
TEAC triethyl o-acetylcitrate same 77-89-4
THFO tetrahydrofurfuryl same 5420-17-7
oleate
THTM triheptyl trimellitate triheptyl benzene- 1528-48-9
1,2,4-tricarboxylate
TIOTM triisooctyl trimellitate tris(6-methylheptyl) 27251-75-8
Benzene-1,2,4-
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Table 5: Plasticizers
Abbreviated Term Common name IUPAC* equivalent CAS-RN**
tricarboxylate
TOF trioctyl phosphate tris(2-ethylhexyl) 78-42-2
orthophosphate
TOPM tetraoctyl pyromellitate tetrakis(2-ethylhexyl) 3126-80-5
benzene-1,2,45-
tetracarboxylate
5 Supplemental identification
Additional identification marking, such as date code, country of origin, part model name, part version, ISO
supplemental part marking, and so forth, may be included on the part, upon Divisional discretion.
However, no additional information may replace the universal material marking code defined in this
standard.
To achieve maximum value from the plastic to be recycled, it is recommended that the HP part number,
along with the suffix to identify the supplier, be shown in the line below the material marking code. The
supplier suffix can be found in the appropriate HP material database; for example PIR, PSPEC,
microfiche, and so forth.
For example, to mark the 4093-0029 polycarbonate with 20% glass fiber supplied by company XYZ,
whose HP supplier code is #####, the marking would be:
>PC-GF20<
4903-0029 #####
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6 References
ASTM D1600, Standard Terminology Relating to Abbreviations and Codes for Terms
Related to Plastics.
ASTM D1972, Standard Practice for Generic Marking of Plastic Products
ISO 1043-1:1997 Plastics - Symbols. Part 1: Basic polymers and their special
characteristics.
ISO 1043-2:2000 Plastics- Symbols Part 2: Fillers and Reinforcing Materials.
ISO 1043-3:1996 Plastics-Symbols and abbreviated terms Part 3 Plasticizers
ISO 1043-4:1998 (E) Plastics-Symbols Part 4 Flame retardants.
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Revision History:
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