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Prefeasibility Report
1 EXECUTIVE SUMMARY: ........................................................................................................................... 3
2 INTRODUCTION .......................................................................................................................................... 4
2.1 BRIEF DESCRIPTION OF THE PROJECT ...........................................................................................................4
2.2 NEED FOR THE PROJECT AND ITS IMPORTANCE TO REGION: ...........................................................................4
2.3 EMPLOYMENT GENERATION (DIRECT AND INDIRECT) DUE TO THE PROJECT.................................................4
1 EXECUTIVE SUMMARY:
M/s India Pesticides Limited enhancing its production capacity of Agrochemicals and
intermediates form 10TPD to 100 TPD (by addition of 90 TPD) at existing and proposed
location at Plot no: K2 to K11 & D2 to D4, Phase-1, UPSIDC Industrial area, Village-
Mahfona,Tehsil- Sandila, District- Hardoi, (U.P).
No National Parks, Wildlife Sanctuaries, Tiger/ Elephant Reserves, Wildlife Corridors etc. falls
within 10 km radius from the plant site. Bahca Nadiis flowing at a distance of 6.73 km in NW
direction.
2 INTRODUCTION
2.1 Brief Description of the Project
The existing unit is manufacturing agrochemicals and intermediates at the same existing and
proposed location at Plot no: K2 to K11 & D2 to D4, Phase-1, UPSIDC Industrial area, Village-
Mahfona, Tehsil- Sandila, District- Hardoi,(U.P).It is proposed to enhance the production
capacity of Agrochemicals ingredients and intermediates form 10TPD to 100 TPD (by addition
of 90 TPD).
Site is well-connected with SH-25 at a distance of 0.72 km (S). The project location map shown
in Figure 1.1.
The role of the pesticides in the well-being of human race needs no emphasis. Pesticide usage
has be come essential in order to maximize agriculture production and reduce public health
pestilence. The rapid changes in cropping patterns, increased fertilization and adoption of
programs for high yielding varieties have all contributed to increased use of pesticides. Further,
pest problems keep on changing with the changing environment. New physiological kinds evolve
as a result of mutations to withstand new conditions in nature. Many pest species develop
resistant strains when the same Pesticide is used far too often. The problems of pest resurgence
and secondary pest out-breaks crop up with the indiscriminate use of pesticides. These associated
problems offer a great scope for revolutionizing the use of pesticides. However, in India though
the over call pesticide growth figures may appear impressive, the rate of consumption per hectare
of cultivated and is very low in comparison per hectare of cultivated land is very low in
comparison to other countries. India used 180 g of pesticides/ha as against 10,790g, 1870 g and
1490 g/ha used in Japan, Europe and U.S.A. respectively. India spent just Rs. 2.15/ha on
pesticides while Japan and U.S.A spent Rs.110/ha and Rs.35/ha respectively during the same
period. India consumed 12 gm. of pesticides per kg of fertilizer used against 146 gm in Japan
and 19 gm in U.S.A. This is one of the major factors that can be attributed to low per hectare
yields in our country since the crops and especially the high yielding varieties cannot manifest
their production potential in absence of proper pest protection. That the production potential
remains suppressed for want of protection can be exemplified by considering how in wheat, a
crop comparatively resistant to insect pestilence, we have had a “revolution” where as in paddy
which is one of the most heavily infested crops, we have had no break-through. In case of wheat,
the per hectare yield in India rose from 827 kg to 1338 kg. Corresponding yields of paddy in
India on the other hand was 1826kg as against 6185 kg 5326 kg , 5105 kg and 4000 kg. in Japan,
Egypt, USA and USSR respectively.
Within the country itself, there is a great imbalance between different regions with regard to the
use of pesticides. Of the total of approximately Rs.5000 million spent on pesticides in at the farm
level, south contributed for about 45 per cent of the total consumption in the rest of the country.
Plant would have an additional manpower of 200 which includes skilled -40; trained-70 and
workers -90.
Page |5
3 PROJECT DESCRIPTION
3.1 Type of Project including interlinked and interdependent projects,
The Proposed Project comes under ‘Section 5(b)’ Pesticides industry and pesticides specific
intermediates (excluding formulation)
As per EIA notification dated 14th September 2006 and its amendment thereof proposed project
comes under in category A.
No interlinked project.
3.2 Location (specific location and project boundary & project lay out) with coordinates
Proposed expansion project of Agrochemical ingredients and its intermediates shown in Figure
1.1.
Project Site
The land break of the proposed project marked in the following plot.
Page |6
3.3 Details of alternate sites considered and the basis of selecting the proposed site,
particularly the environmental considerations considered should be highlighted
There is no interlinked project. This is expansion of existing plant and as such no alternative site
consideration was needed.
Since the objective is to manufacture pesticides, a lush green & friendly environment is being
selected for installing the plant. The existing site is located in notified industrial estate where all
common environmental infrastructure facilities are available and also site is well connected to
rail, road and port.
The project is not likely to cause any significant impact to the ecology of the area since adequate
preventive measures will be adopted to control various pollutants within permissible limits.
Green belt development around the area has been and shall be taken up as an effective pollution
mitigative technique.
Expanded capacities not to exceed 90 TPD. Total production to restrict to 100 TPD. List of the
product are shown in below Table.
Capacity of 48 Existing Products: 10 TPD
S.No Tag No Product Capacity
1. Thiamethoxam
2. Profenophos
3. Ethion
4. Fipronil 10 TPD
5. Temephos
6. Triazophos
7. Acephate
8. Quinalphos
9. Phosphamidan
10. DDVP
11. Chlorpyriphos
12. Monocrotophos
13. Malathion
14. Cypermethrin
15. Fenvalerate
Page |9
16. Acrinathrin
17. Deltamethrin
18. Metam Sodium
19. Kresoxim Methyl
20. Azoxystrobin
21. Hexaconazole
22. Tebuconazole
23. Folpet
24. Chloropropham
25. Cymoxanil
26. Ethepon
27. Ketaconazole
28. Ziram
29. Thiram
30. F-Phthalide
31. Miconazole
32. Penaconazole
33. Metiram
34. Prosulphocarb
35. Benthiocarb
36. Orbencarb
37. Methiobencarb
38. E.PT.C
39. Molinate
40. Clodinofop Propargyl
41. Pretilachlor
42. Quizalofop-p-ethyl
43. Metamitron
44. Napropamide
45. Trimethylphosphite
46. Pthalide
47. Mancozeb
48. Captan
5 F-22 Zineb
6 F-23 Etridiazole
7 F-24 Tricyclazole
8 F-25 Chlorothalonil
9 F-26 Trichlopyr
10 F-27 Difenoconazole
11 F-28 Ipconazole 90 TPD
12 F-29 Dodine
13 H-12 Imazethapyr
14 H-13 Metribuzin
15 H-14 Bispyribac Sodium
16 H-15 Metolachlor
17 H-16 Diuron
18 I-19 Acequinocyl Tech
19 I-20 Pyriproxyfen
20 I-21 Novaluran
21 I-22 Propargite
22 IN-3 PTBSA(N-Phenyl-N-(Trichloromethyl)-
Thio-benzensulfonamide
23 IN-4 Caprolactam Disulfide
24 IN-5 Propargile Alcohol
25 IN-6 Trichloro Methoxy Nitrobenzene
* Total capacity of existing and proposed products and intermediates manufacturing to be
restricted to 100 TPD with maximum 27 products manufactured at a time.
Since the production are made in a batch process and volume vary depending upon the marketing
demand as can be seen in the product wise capacity indicated in the EC letter which sums upto
more than 100 TPD. Therefore, individual production capacity not to be mentioned in the EC
letter. Only total 100 TPD to be indicated.
F-16 : Mancozeb
Process description:-
Step-1: In a SS reactor ethylene diamine and water are charged under stirring condition and temp.
is raised to about 45-50oC.Now CS2 is added slowly under reflux. Then, measured quantity of
caustic lye addition is started slowly so that pH of the mass is maintained around 10. The mass is
kept under these conditions for 6- 8 hours till the reactions is complete.
Step-2: In a SS reactor manganese sulphate is dissolved in water under stirring and mass temp. is
raised to 30-35oC. Now the mass of step (1) is charged slowly within a period of one and a half
hours. Then the mass is allowed to settle. The slurry is filtered under vacuum to get wet cake of
Maneb.
Step-3: Maneb is reacted under stirring conditions with zinc sulphate (32%) solution at 30oC.
After 30 mins interval, left over mass of step(1) i.e. NABAM is added and maintained for one
hour. At the temp of 30oC, calculated amount of china clay is added to the slurry and stirred for
half an hour . This slurry is filtered, washed under vacuum and dried in a dryer to get the product
MANCOZEB.
Reactions:-
• Ethylene diamine + CS2+ caustic lye →
+ water NABAM +
Na2SO4
(mod. Temp & low vacuum)
• NABAM + MnSO4 → Maneb
(mod. Temp & low vacuum)
• Maneb + zinc sulphate+ NABAM → MANCOZEB
(mod. Temp & low vacuum)
Environmental aspects:-
Emissions:-Lean vapours from reactor reflux are sucked out to plant scrubber system.
Liquid effluents:- Inorganic salts in water are sent to ETP.
Solid effluents:-Sodium sulfate is by-product for sale.
P a g e | 12
Process description:-
Carboxin is manufactured by reacting acetoacetanilide with sulfuryl chloride (SO2Cl2) to give
2‐chloro‐3‐oxo‐N‐phenylbutanamide intermediate .
This intermediate is furtherreacted with 2‐mercaptoethanol in presence of sodium
hydrogencarbonate to give 2‐(2‐hydroxyethylthio)‐3‐oxo‐N‐phenylbutanamide . Finally it is
cyclysed using PTSA to give carboxin crude and crystallised in methanol to give carboxin
technical
O O O
O O Cl Cl
+ S
H3C N H3C N
O
H Cl H
Acetoacetanilide
2-chloro-3-oxo-N-phenylbutanamide
O
sodiumhydrogen carbonate
O O S
HO N
SH
H3C N
+ HO
H
O CH3
Cl H 2-[(2-hydroxyethyl)sulfanyl]-3-oxo-N-phenylbutanamide
O
O
S
S Pera toluene sulphuric acid N
HO N
H
H O CH3
O CH3
2-methyl-N-phenyl-5,6-dihydro-1,4-oxathiine-3-carboxamide
Formula Weight: 235.3
Production Capacity :-4TPD.
Batch time:-24 hrs.
Environmental aspects:-
1. Emission: No
2. Liquid effluents: Aqueous effluent sent to Multiple effect evaporated system
3.Solids: Organic salts are sent to secured Land-fill system.
4.Solvent recovery: Solvent(methyl alcohol)is distilled and reused in the process.
P a g e | 13
F-19: Diafenthiuron
Process description:-
Diafenthiuron is prepared by condensation of 2,6-diisopropyl-4-phenoxyphenyl isothiocyanate
with tert-butylamine in presence of isopropyl alcohol as solvent. The products is filtered and
dried. Isopropyl alcohol is distilled and recycled.
Reactions:-
2,6-diisopropyl-4-phenoxyphenyl isothiocyanate + tert-butylamine
→ 1-tert Butyl-3-(2,6-diapropyl-4-phenoxyphenol thiourea)
Environmental aspects:-
1.Emission: No
2.Liquid effluents: No liquid effluent(aqueous or organic) is generated in the process.
3.Solids: Organic residues are sent to secured landfill system.
4.Solvent recovery: Solvent(isopropyl alcohol)is distilled and reused in the process.
F-20: Propineb
Process description:-
Step-1: Carbon disulphide and propylenediamine (PDA) are reacted under controlled conditions in a
reactor to produce Propylene BisdithioCarbamic Acid. This acid is neutralized in the same reactor with
Ammonia solution to get Ammonium salt.
The ammonium salt forms an aqueous medium and is a common ingredient for production of
PROPINEB.
Step-2: The ammonium salt solution is reacted with Zinc sulfate solution to form Zinc salt of
Propylene Bisdithiocarbamate . The Zinc salt is insoluble in aqueous medium and forms a slurry.
Also Ammonium sulfate is formed as a byproduct.
Step-3: To improve purity of the product the slurry is filtered and washed to remove ammonium
sulfate. The Zinc salt is obtained as a cake.
Step-4: The cake is re-slurried and additives like Sodium LignoSulphonate( Na-SLS) are added
to make slurry process-able.
Step-5:The slurry is then Spray Dried to get Propineb powder with moisture content less then
1%.
Step-6:The powder is grounded to reduce particle size to specification.
P a g e | 14
Reactions:-
• CS2+ PDA → Propylene BisdithioCarbamic Acid
• Propylene Bisdithio Carbamic Acid + ammonia sol. →ammonium salt of PBDC
• ammonium salt of PBDC + Zinc sulfate sol. →Zn-PBDC + (NH4)2SO4
(propineb)
Environmental aspects:-
Emissions: Ammoniais released and sucked to water scrubber system.
F:21 Paclobutrazol
(2RS,3RS)-1-p-Chlorophenyl-2-(1,2,4-triazol-1-yl)-4,4-dimethylpentan-3–ol
Process description :
α -Chloropinacolone was reacted with 1,2,4-triazole to produce a-triazolylpinacolone, which was
further reacted with p-chlorobenzyl chloride and finally reduced by NaBH4 to yield
Paclobutrazol
Cl
O Cl
Cl O
H
O + N
N
N
N
+ N
N
N N N
II Cl III
Cl
OH
N
N
N
Production Capacity :- 0.4 tons/day.
Batch time:- 24 hr
Environmental aspects:-
1.Emission: No
2.Liquid effluents: aqueous effluent sent to Multiple effect evaporated system .
3.Solids: Organic residues are sent to secured landfill system.
4.Solvent recovery: Solvent(toluene)is distilled and reused in the process.
P a g e | 15
F-22: Zineb
Process description:-
Step-1: Carbon disulphide (CS2) and Ethylene diamine (EDA) are reacted under controlled conditions in
a reactor to produce Ethylene BisdithioCarbamic Acid. This acid is neutralized in the same reactor with
Castic lye (NaOH) solution to get Sodium salt of Ethylene Bisdithiocarbamate(Na-EBDC).
The sodium salt forms an aqueous medium and is a common ingredient for production of ZINEB and
MANCOZEB.
Step-2:- The Na-EBDC solution is reacted with Zinc chloride solution to form Zinc salt of Ethylene
Bisdithiocarbamate (Zn-EBDC). The Zinc salt is insoluble in aqueous medium and forms a slurry. Also
NaCl is formed as a byproduct.
Step-3:- To improve purity of the product the slurry is filtered and washed to remove NaCl. The
Zinc salt is obtained as a cake.
Step-4:- The cake is re-slurried and additives like Sodium LignoSulphonate( Na-SLS) are added
to make slurry process-able.
Step-5:- The slurry is then Spray Dried to get Zineb powder with moisture content less then 1%.
Step-6:- The powder is grounded to reduce particle size to specification.
Step-7:- The powder is then adjusted for Active ingredient by addition of filters in a Blender.
Reactions:-
• CS2+ EDA → Ethylene BisdithioCarbamic Acid
• Ethylene BisdithioCarbamic Acid + Castic lye (NaOH) → Na-EBDC
• Na-EBDC + Zinc chloride → Zn-EBDC + NaCl
(zineb)
Production Capacity :- 2 tons/day
Batch time:- 24 hr
Environmental aspects:-
Emissions:-No emissions.
Liquid effluents:- Inorganic salts in water are sent to ETP.
P a g e | 16
F-23: ETRIDIAZOLE
Process description:-
Etridiazole is prepared by the reaction of trichloroacetamidine with trichloro methane
sulfenylchloride in the presence of solvent ethylene dichloride followed by hydrolysis with
aqueous sodium hydroxide solution. This intermediate is allowed to react with sodium ethoxide
to get etridiazole. The product is filtered, washed and dried. EDC is distilled and recycled.
Reactions:-
Cl
Cl NH2 Cl Cl N
S Cl
Cl
NaOH
+ Cl + 3 x NaCl
Cl Cl
Cl NH Cl N S
trichloro trichloromethane 5-chloro-3-( trichloro methyl ) Sodium
acetamidine sulfenyl chloride -1,2,4-thiadiazole chloride
(CTMT)
Cl Cl
Cl N Cl N
Cl O
+ NaO
Cl Cl + NaCl
N S N S
Environmental aspects:-
1.Emission: No
2.Liquid effluents: Aqueous effluent is generated in the process was treated in PTRO and MEE.
Treated water is reuse.
3.Solvent recovery: Solvent(EDC)is distilled and reused in the process.
H-12: Imazethapyr
Process description:-
Step 1:- Charge 2 Amino 2,3 Di methyl Butane amide, Ethyl 5 Ethyl Pyridine Dicarboxylate and
sodium ethoxide in Toluene.
Step 2:- Heat the reaction mass to 50oC and distill ethanol from reaction mixture.
Step 3:- Raise and maintain the temp. at 110oC for few hours.
Step 4:- On completion of reaction,charge water to reaction mass and maintain pH 3.5 with HCl.
Step 5:- Cool the reaction mass to 30oC.Fill the crude imazethapyrand crystallize in ethanol.
Reactions:
P a g e | 17
Environmental aspects:-
1.Emission: No
2.Liquid effluents: Washed Water.
3.Solids: Organic salts are sent to secured landfill system
H-13: Metribuzin
Process description:-
Triazinoneis charged slowly in sulphuric acid in 4 hours. Temperature is raised to 45 C and
Dimethyl sulfate is charged. Maintain temp for 10 hours.When reaction shows completion of
methylation ,quench in 20% Soda ash solution.Finally adjust pH 10 with NaOH lye. Filter,
centrifuge and dry the wet cake to obtain the product.
Reactions:
Environmental aspects:-
1.Emission: No
2.Liquid effluents: Washed water
3. Solids: Organic salts are sent to secured landfill system.
P a g e | 18
1.0: Oxidation
2.0 :Condensation and deamination
3.0 :Hydrogenation.
4.0 Oxidation
5.0 Acylation
Process Descriptions:
Reactions:-
O
OH OH
1 O
O 2 O
OH OH
+ CH3(CH 2) 10 CHO
n-C 10H21
O O NHn-BU
3 4
2
O
O OH
OH
n-C 10H21
n-C 10H21 O
O NHn-BU 5
4
O OH
OH OH
n C12H25
n C12H25
O
O
7 8
P a g e | 19
Environmental aspects:-
1. Emission: No
2. Liquid effluents: aqueous effluents sent to Multiple effect evaporator system .
3. Solids: Organic residues are sent to secured landfill system .
4. Solvent recovery: Solvent (o-xylene) is distilled and reused in the process
O
NaOH O
S Cl + H2N + NaCl
S
O N
O H Sodium
benzene sulfonyl aniline N-phenyl benzene
chloride chloride
sulfonamide
Environmental aspects:-
1.Emission: Nil
2.Liquid effluents: Aqueous layer containing sodium chloride.
3.Solids: Nil
IN-4: Dicaprolactamdisulfide :
Process description:-
Caprolactam was reacted with sulfur chloride in the presence of solvent, dicaprolactam disulfide
produced was filtered, washed and dried. Solvent was recycled in further batches.
Reactions:-
O O
2 xO + S2Cl2 S S N + NHHCl
N
HN
O
caprolactam Dicaprolactam disulfide Caprolactan HCl
Environmental aspects:-
1.Emission: Hydrochloric acid scrubbed in water
2.Liquid effluents: acidic effluent generated in the process is sent to ETP.
3.Solids: Inorganic residue sent to secured land fill system.
F-24 :Tricyclazole
Process description :
2-hydrazo-4-methyl-henzothiazole (HMBT) is reacted with formic acid (HCOOH) followed by
filtration. The wet cake obtained is directed for drying to get the final product Tricyclazole.
Reaction:
henzothiazole
Environmental aspects:
Emissions: No emissions.
Liquid effluents: Nil
Solid effluents: Nil
Solvent recovery: Formic acid and xylene are recovered for the process.
I-22: Propargite
Process description :
Propargite technical is manufactured in two steps. In first step intermediate chlorosufinate is
prepared by reaction of p-tert-butyl phenoxycyclohexanol and Thionyl chloride at a particular
temperature. Reaction mass is stirred for a period & further reacted with Propargyl alcohol in
presence of Triethylamine at a specified temperature for some time to get Propargite technical.
Environmental aspects:
Emissions: No emissions.
Liquid effluents: Nil
Solid effluents :Nil
Solvent recovery: Toluene is recovered, purified and recycled.
Process description:
2,6-Dihydroxy Benzoic Acid is treated with potassium carbonate in presence of toluene to
produce potassium salt of 2,6-Dihydroxy Benzoic Acid .The K-salt produced is reacted with 4,6-
Dimethoxy-2-methylsulfonylpyrimidine, at a high range of temperature, with help of steam then
acidified and purified, may be crystallised to give Bispyribac-Sodium.
P a g e | 23
Environmental aspects:
Emissions: No emissions.
Liquid effluents: Nil
Solid effluents :Nil
P a g e | 24
F-27: Difenoconazole
Process Description:
It is a single-step process. The potassium salt of 1H-1,2,4-triazole is reacted with 2-
(Bromomethyl)-2-[4-(4-chlorophenoxy)-2- chlorophenyl]-2-methyl-1,3-dioxolane (Bromoketal)
in N,N-dimethyl formamide in presence of catalytic quantity of potassium iodide at a particular
high temperature to give Difenoconzole technical.
After completion of the reaction, DMF is distilled out & the
reaction is quenched with water. It is extracted with toluene & the organic layer is washed
successively with water, HCl solution & water. The solvent toluene is distilled out & product is
crystallized from DMF-water system to get light beige coloured crystalline solid product. It is
centrifuged & dried to get pure Difenoconazole technical.
Reaction:
Environmental aspects:
Emissions: No emissions.
Liquid effluents: Nil
Solid effluents :Nil
Solvent recovery: Toluene is recovered.
F-29 :Dodine
Process Description:
Dodine technical is manufactured in a single step. In this single step molten Dodecilamine is
reacted with cynamide in presence of acetic acid at high range of temperature which gives
Dodine technical.
Reaction:
P a g e | 25
Environmental aspects:
Emissions: No emission.
Liquid effluents: Washed effluents.
Solid effluents : Nil
Solvent recovery: Mother liquor is recovered for reuse in process.
H-16: Diuron
Process Description:
3, 4-Dichlorophenyl isocyanate and xylene are charged and to this reaction mass, dimethylamine
is introduced. After the reaction is complete, the reaction mass is cooled, filtered and dried to get
Diuron.
Reaction:
H
Cl N Cl N N
C C
O + HN
O
Cl Cl
(DIURON)
Environmental aspects:
Emissions: NA
Liquid effluents: NA
Solid effluents :Organic residues sent to secured land fill system.
Solvent recovery: Solvent (xylene) is recovered and reused in the process
Process Description:
1, 2, 3-Trichloropropane, sodium carbonate, a catalyst and water are heated in an autoclave. The
resulting reaction mixture is then reacted with potassium hydroxide to get propargyl alcohol. The
product is isolated after workup and distillation.
Reaction:
Cl
OH
Na2CO3
Cl Cl HC C
KOH
Environment Aspects:
1. Emission: NA
2. Liquid effluents: Aqueous effluent containing inorganic salts to be treated in PTRO and
MEE.
3. Solids: NA
4. Solvent recovery: Solvent (Dichloroethane) is recovered and reused in the process.
I-21: Novaluran
Process Description:
To a solution of 3-Chloro-4-(1, 1, 2-trifluoromethoxy) ethoxyaniline in dichloroethane is added a
solution of 2, 6-difluorobenzoyl isocyanate. After the reaction is complete mass is filtered and
washed with dichloroethane and dried to give Novaluron.
Reaction:
P a g e | 27
F F F
F
F
F O O F
O
O + C
N
Cl NH2 F
F F F
F
F
F O
O
O O F
Cl NH NH
NOVALURON
Production Capacity : 1 TPD
Batch time: 24 hrs
Environment Aspects:
1. Emission: No
2. Liquid effluents: No
3. Solids: Organic residues are sent to secured landfill system
4. Solvent recovery: Solvent (dichloroethane) is distilled and reused in the process.
F-25: Chlorothalonil
Process Description:
Reaction:
P a g e | 28
CHLORINATION
2,4,5,6-Tetrachloro-isophthalonitrile
isoph thalonitrile
chlorothalonil
Environment Aspects:
1. Emission: No
2. Liquid effluents: No
3. Solids: Organic residues are sent to secured landfill system
4. Solvent recovery: Solvent(methyl alcohol)is distilled and reused in the process.
Process Description:
Preparation of ChloroButoxy Ethyl Acetate:
ChloroButoxy Ethyl Acetate obtained from the earlier step is reacted with Sodium salt of
Trichloro
Pyridinol in the presence of a Catalyst p-toluenesulfonicacid to obtain TrichlopyrButoxyEthyl
Ester.
Reaction:
P a g e | 29
2 butoxy ethanol
chloro aceticacid
Environmental aspects:-
1. Emission: No
2.Liquid effluents: No
3.Solids: Organic residues are sent to secured landfill system
4.Solvent recovery: Solvent(methyl alcohol)is distilled and reused in the process
H-15 :METOLACHLOR
Process Description:
2-ethyl-6-methylaniline ,2-bromo-1-methoxypropane is heated at reduced pressure to obtain pure
2-ethyl-6-methyl-N-[ 1'-methoxy-prop-2'-yl]-aniline then treated with chloroacetyl chloride in
presence of triethylamine to yields 2-ethyl-6-methyl-N-[1'-methoxy-prop-2'-yl]-
chloroacetanilide.
P a g e | 30
Reaction:
2-bromo-1-methoxypropane
2- ethyl-6- methylaniline
chloroacetyl chloride
Environmental aspects:-
1. Emission: No
P a g e | 31
2. Liquid effluents: No
3. Solids: Organic residues are sent to secured landfill system
4. Solvent recovery: Solvent (methyl alcohol) is distilled and reused in the process.
F-28 :IPCONAZOLE
Process Description:
5-(4-Chlorobenzyl)-2-isopropyl cyclopentanone, DMF, trimethylsulfoxonium bromide are stirred
and to this mixture 60% sodium hydride is added. Reaction mass is then poured in water and
extracted with toluene. Toluene is distilled to give the methylide intermediate.
Methylide intermediate is added to a mixture of 1,2,4-1H triazole, NaOH and DMF. After the
reaction is over, reaction mass is quenched in water and extracted with cyclohexane. On cooling
the product is crystallized which is filtered, washed and dried.
Reaction:
O
O
+ + Br-
Cl S
NaOH Toluene
NMP NaOH
N
1H-1,2,4-triazole
HN
N
N
HO N
Cl
IPCONAZOLE
Environment Aspects:
1. Emission: NA
P a g e | 32
2. Liquid effluents: Aqueous effluent with high TDS and COD to be treated in PTRO and
MEE.
3. Solids: Organic residues are sent to secured landfill system
4. Solvent recovery: Solvents to be recovered and reused.
S C S + Cl Cl N+
Tetraline Cl Cl +
O-
carbon disulfide Chlorine carbanothioyl 2-nitro phenol
dichloride
NaOH
O O- O O-
N+ N+
Cl
O Cl O
Cl
Cl Cl +
Cl
S
Environmental aspects:-
1. Emission: No
2. Liquid effluents: Aqueous effluent is generated in the process was treated in PTRO and MEE.
Treated water is reused.
3.SolidEffluents : Solid residues are sent to secured land fill system.
4.Solvent recovery: Solvent chloroform are distilled and reused in the process.
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3.9 Availability of water its source, energy/power requirement and source should be given
Water: Total water required after expansion shall be 874 KLD source through ground water.
S.NO PARTICULARS WATER CONSUMPTION IN KLD
EXISTING ADDITIONAL TOTAL AFTER FULL
PROPOSED COMMISSIONING @100TPD
A Domestic 5 10 15
B Industrial
1 Process 25 286 311
2 Washing 15 30 45
3 Boiler 30 80 110
4 Cooling Tower 50 438 488
C Miscellaneous 10 30 40
TOTAL (A+B+C) 135 874 1009
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Power:
Existing plant requires 1000 KVA of power. Plant after complete expansion would require 3000
KVA.
3.9.1 Fuel
3.9.2 Quantity of waste to be generated (liquid and solid) and scheme for their
management /disposal
6 Inorganic chemical Any use only after TSDF site of RAMKY Group at Kanpur
sludge from ETP testing and proving the Dehat
same is not hazardous
waste. If proved
hazardous then for
Secured land- filling
7 Date expired / off speci. Incinerator The same will be adopted
Products
8 Chemical sludge from To HW incinerator Incinerator facility at TSDF site Ramky,
decontamination Kanpur
9 Discarded drums/ liner Wash water treated in Do
ETP & decontaminated
drums for recycling.
10 Contaminated filters / To HW incinerator do
liners
11 Spent carbon To HW incinerator Incinerator facility at TSDF site Ramky,
Kanpur / cement industries
12 Sludge from wet Incineration after ETP TSDF site of RAMKY Group at Kanpur
scrubber treatment Dehat
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4 SITE ANALYSIS
4.1 Connectivity
4.2 Temperature:
The climate of the region is hot. The year can be divided into three main seasons as
follows:
The average temperatures during summer and average temperature during winter are
reported to be around 40°C and 8° C respectively with maximum temperature recorded
48° C in May and 3° C in December.
Rainfall
The place receives rainfall from June to August. July is the rainiest month having rainfall up to 237 mm.
The annual rainfall in Sandila for the year 2009-2010 was observed to be 906 mm.
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5 PROPOSED INFRASTRUCTURE
6.1 Policy to be adopted (central/state) in respect of the project affected persons including home
oustees, land oustees and landless labourers (a brief outline to be given)
Not Applicable
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7.2 Estimated Project cost along with analysis in terms of economic viability of the project.
• Employment would be as per prevailing norms of state government for skilled and
unskilled people for the proposed project.
• Cordial relation with the industry shall be established and representation shall be made
to villagers for help for creation of facilities related to health, education, etc.