2b) Group 7 (Halogens) ) Chlorine Bromine and Iodine PDF

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Edexcel​ ​IGCSE​ ​Chemistry

Topic​ ​2:​ ​Inorganic​ ​chemistry


Group​ ​7​ ​(halogens)​ ​–​ ​chlorine,​ ​bromine​ ​and​ ​iodine

Notes

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2.5​ ​know​ ​the​ ​colours,​ ​physical​ ​states​ ​(at​ ​room​ ​temperature)​ ​and​ ​trends​ ​in
physical​ ​properties​ ​of​ ​these​ ​elements

● Chlorine​ ​is​ ​a​ ​yellow-green​​ ​gas


● Bromine​ ​is​ ​a​ ​red-brown​​ ​liquid
● Iodine​ ​is​ ​a​ ​purple​​ ​solid
● There​ ​is​ ​a​ ​trend​ ​in​ ​state​ ​from​ ​gas​ ​to​ ​liquid​ ​to​ ​solid​ ​down​ ​the​ ​group

2.6​ ​use​ ​knowledge​ ​of​ ​trends​ ​in​ ​Group​ ​7​ ​to​ ​predict​ ​the​ ​properties​ ​of​ ​other
halogens
● There​ ​is​ ​a​ ​trend​ ​in​ ​state​ ​from​ ​gas​ ​to​ ​liquid​ ​to​ ​solid​ ​down​ ​the​ ​group
● this​ ​is​ b
​ ecause​ ​the​ ​melting​ ​and​ ​boiling​ ​points​ ​increase​ ​as​ ​you​ ​go​ ​down​ ​the​ ​group
● from​ ​this,​ ​you​ ​can​ ​predict​ ​that​ ​any​ ​halogens​ ​above​ ​chlorine​ ​will​ ​be​ ​gases​ ​(their
boiling​ ​points​ ​will​ ​be​ ​even​ ​lower),​ ​and​ ​any​ ​below​ ​iodine​ ​will​ ​be​ ​solids​ ​(their
melting​ ​points​ ​will​ ​be​ ​even​ ​greater)

2.7​ ​understand​ ​how​ ​displacement​ ​reactions​ ​involving​ ​halogens​ ​and​ ​halides


provide​ ​evidence​ ​for​ ​the​ ​trend​ ​in​ ​reactivity​ ​in​ ​Group​ ​7

● A​ ​more​ ​reactive​ ​halogen​ ​can​ ​displace​ ​a​ ​less​ ​reactive​ ​in​ ​an​ ​aqueous​ ​solution​ ​of​ ​its
salt.
● E.g.​ ​Chlorine​ ​will​ ​displace​ ​bromine​ ​if​ ​you​ ​ ​bubble​ ​the​ ​gas​ ​through​ ​a​ ​solution​ ​of
potassium​ ​bromide:
Chlorine​​ ​+​ ​Potassium​ ​Bromide​ ​→​ ​Potassium​ ​Chloride​ ​+​ ​Bromine
● chlorine​ ​will​ ​displace​ ​bromine​ ​and​ ​iodine
● bromine​ ​will​ ​displace​ ​iodine​ ​but​ ​not​ ​chlorine
● iodine​ ​can​ ​replace​ ​neither​ ​chlorine​ ​or​ ​iodine

● This​ ​happens​ ​because​ ​as​ ​you​ ​go​ ​down​ ​the​ ​group,​ ​the​ ​reactivity​ ​of​ ​halogens
decreases.

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2.8​ ​(chemistry​ ​only)​ ​explain​ ​the​ ​trend​ ​in​ ​reactivity​ ​in​ ​Group​ ​7​ ​in​ ​terms​ ​of
electronic​ ​configurations

● The​ ​halogens​ ​react​ ​by​ ​gaining​ ​an​ ​electron​ ​in​ ​their​ ​outer​ ​shell,​ ​as​ ​you​ ​go​ ​down​ ​the
group:
o outer​ ​shell​ ​becomes​ ​further​ ​from​ ​the​ ​nucleus
o electron​ ​shielding​ ​increases
o attraction​ ​decreases​ ​between​ ​nucleus​ ​and​ ​outer​ ​electrons
o electrons​ ​are​ ​gained​ ​less​ ​easily
o halogens​ ​become​ ​less​ ​reactive

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