SAFETY DATA SHEET (according to 1907/2006/EC, Article 31)

DIFFU - THERM  Diffusions - Rot BDR (Aerosol)

1. Identification of substance:
Trade name: Diffusions - Red (Penetrant red), (water washable)
Article number: BDR
Manufacturer/Supplier
Manufacturer/distributor
Helmut Klumpf
Technische Chemie KG
Industriestr. 15
D - 45699 Herten Phone.: (02366) 1003 - 0 Fax: (02366) 1003 - 11 e-mail: klumpf@diffu-therm.de
Advice:
Helmut Klumpf, Techn. Chemie KG, H. Klumpf
Emergency advice:
As stated above or next emergency phone

2. Hazards identification
Hazards designation:
F+ Extremely flammable
Xn Harmful
Information pertaining to particular dangers for man and environment:
R 12 Extremely flammable.
R 40 Possible risks of irreversible effects.
R 65 Harmful; can cause lung disease.
R 67 Vapours may cause drowsiness and dizziness.

3. Composition/information on ingredients
Chemical characterization (preparation):
Penetrant with agent of:
Paraffins, isoparaffins, naphthenes, aromatic, hydrocarbons with wetting agents and red azo dyes.
CAS-No. Name of chemical EINECS-number EWG-no. weight % Symbols R-phrases
64742-94-5 aromatic hydrocarbons 265-198-5 649-424-00-3 < 20 Xn, N 51/53,65, 66, 67
64742-47-8 aliphatic hydrocarbons 265-149-8 < 20 Xn 65, 66
8008-20-6 Destillate (Erdöl) 232-366-4 < 40 Xn 65, 66
106-97-8 N-Butane 270-990-9 601-004-00-0 ≤20 F+ 12
74-98-6 Propane 200-827-9 601-003-00-5 ≤20 F+ 12
isodecanol ethoxy --- --- ≤10 Xn 22, 36/38
aliphatic alcohol C12-18 linear, ethoxy --- ≤5 N, Xi 38, 50
56358-09-9 azo dyes <1 N, Xn 40, 51/53, 65,
57712-94-4 C.I: Solvent Red 19 66, 67

4. First aid measures

General information:
Change soaked clothes and clean them before putting on.
After inhalation:
Ensure supply of fresh air.
In the event of symptoms refer for medical treatment.
After skin contact:
In case of contact with skin wash off with soap and water.
After eye contact:
In case of contact with eyes rinse thoroughly with plenty
of water and seek medical advice.
After swallowing
Do not induce vomiting; instantly call for medical help. Instantly call for doctor
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SAFETY DATA SHEET (according to 1907/2006/EC, Article 31)
DIFFU - THERM  Diffusions - Rot BDR (Aerosol)
5. Fire fighting measures
Suitable extinguishing material:
ABC powder, foam, carbon dioxide.
Extinguishing material that must not be used for safety reasons:
Full water jet.
Special exposure hazards extinguishing from the substance or
preparation itself, combustible products or resulting gases:
None
Special protective equipment for fire fighters:
None
Additional information’ s:
Cool containers at risk with water spray jet.
Danger for bursting of aerosols when heated for more than 50°C.
Aerosols that burst in fire can be mightily shot away.

6. Accidental release measures

Personal precautions:
Ensure adequate ventilation. Keep away sources of ignition.
Environmental precautions:
Do not discharge into the subsoil/soil.
Do not discharge into the drains/surface waters/groundwater.
Methods for cleaning up/taking up:
Take up with absorbent material (e.g. sand, sawdust, kieselguhr, general-purpose binder).

7. Handling and storage

Handling:
Advice on safe handling:
Provide good room ventilation even at ground level (vapours are heavier than air).
Avoid formation of aerosols.
Advice on protection against fire and explosion:
Keep away from sources of ignition. Do not smoke.
Storage:
Requirements for storage rooms and vessels:
Filled aerosols must not be exposed to:
1. Heating of more than 50°C by sun beams or other heat sources.
2. Storage in gates, passages, wells of staircases, buildings, floors, and lofts.
Keep container in a well-ventilated place.
Advice on storage compatibility:
Do not store together with oxidizing agents.
Further information on storage conditions:
Keep container in a well-ventilated place.
Classification acc. to prescription:
Aerosols (Aerosol containers) (TRG 300)

8. Exposure controls/personal protection

Additional advice on system design:
No other information’ s, see point 7.

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SAFETY DATA SHEET (according to 1907/2006/EC, Article 31)
DIFFU - THERM  Diffusions - Rot BDR (Aerosol)
Ingredients with occupational exposure limits to be monitored:
CAS - NR. Name of chemical % Code Value Unit
less aromatic hydrocarbon mixture MAK 20 (100) ml/m³(mg/m³)
106-97-8 butane ≤20 MAK 1000 (2350) ml/m³(mg/m³)
74-98-6 propane ≤20 MAK 1000 (1800) ml/m³(mg/m³)
Additional information’ s:
None
Personal protection equipment:
Respiratory protection:
Respiratory protection in the event of aerosol or mist formation.
Hand protection:
Gloves (oil-resistant)
Skin Protection:
Light protective clothing.
Eye protection:
Tightly fitting goggles
General protective measures:
Avoid contact with eyes.
Avoid prolonged and/or repeated contact with skin.
Hygiene measures:
At work do not eat, drink, smoke, or take drugs.
Remove soiled or soaked clothing immediately.
Cloths contaminated with product should not be kept in trouser pockets.

9. Physical and chemical properties

General Information
Form: Aerosol Colour: dark red Smell: characteristic
Data relevant for safety: (Product without power gas)
Boiling range: 203 - 263 °C (DIN 53 171)
Flash point: 67 °C (DIN 51 758)
Ignition temperature: > 200 °C (DIN 51 794)
Explosive properties: The Product is not explosive, but
may form flammable/explosive vapour-air mixture.
Explosion limits Lower e.l.: 0,6 Vol.%
Upper e.l.: 7 Vol.%
Vapour pressure (20°C): 30 mbar
Density (20°C): 0,872 g/cm³ (DIN 51 757)
Solubility in water (20°C): Emulsion in water
Viscosity (20°C): 3 mm²/s

10. Stability and reactivity

Conditions to avoid:
No decomposition if used correctly. No reactions by normal use
Materials to avoid:
No hazardous reactions known.
Hazardous decomposition products:
Ammonia

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SAFETY DATA SHEET (according to 1907/2006/EC, Article 31)
DIFFU - THERM  Diffusions - Rot BDR (Aerosol)
11. Toxicological information
Toxicity test:
Acute Toxicity:
Irritability/Corrosiveness:
Skin: Slight irritation
Eye: Slight irritation
Sensitization:
No sensitization known.
Additional information:
The possibility of a reductive fission causes the suspicion that AZO dye-stuffs release cancerogene
aromatic amines. It is dangerous if the AZO dye-stuffs are absorbed from the body. Resorption of those
dye-stuffs can be effected by inhalation, swallowing of dusts or aerosols as well as by skin contact

12. Ecological information

Data on elimination (persistence and degradability):
Can be eliminated from the water by precipitation or flocculation.
Danger class for water (WKG 2 German only) = dangerous for water
Behaviour in environment compartments:
Not known.
Ecotoxicological effects:
No data are available.
General information’ s:
Do not discharge product unmonitored into the environment.

13. Disposal considerations

Product:
Recommendations:
Hand over to authorized disposal agency.
Waste code No.:
EAV: 14 06 03 term: Mixture of solvent
Contaminated packaging:
Recommendations:
Container must be completely emptied and must not be opened by force.
Hand over to authorized disposal agency.
Waste code No.:
EAV: 15 01 10 term: Iron-metal containers with a contaminated rest of the contents

14. Transport information

Land transport ADR
UN-Nr.: 1950 Identification: DRUCKGASPACKUNGEN
Class: 2 Package Group: --
Classifications code: 5 F shipment category: 2
Labelling of the Package: UN 1950 AEROSOLE Label-no.: 2.1
Packing instruction: P 204, MP 9 Max.. gross/Package: 50 kg
Limited of volume: LQ 2 Exemption after chapter 3.4.3: Package 30 kg
Labelling of the Package: diamond (100 x 100 mm) with UN 1950.
Marine transport IMDG/GGVSee
UN-No.: 1950 Class: 2 Package Group: --
EMS-No.: F-D, S-U Label-no.: -- Marine Pollutant: -- Label: --
Proper Shipping Name: Aerosols (Limited Quantities Only) (Package 30 kg)

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SAFETY DATA SHEET (according to 1907/2006/EC, Article 31)
DIFFU - THERM  Diffusions - Rot BDR (Aerosol)
Air transport ICAO-TI and IATA-DGR
Class/Division: 2.1 UN/ID-Nr.: 1950
Package Group: --, Label: 2.1
Packing inst. Passenger aircraft: 203/Y203 Max. netto/Package: 75 kg/30 kg
Packing inst. Cargo aircraft: 203 Max. netto/Package: 150 kg
Proper Shipping Name: Aerosols, flammable

15. Regulatory information

Designation according to EC guidelines:
The product has been classified and labelled in accordance with EC Directives / Ordinance on
Hazardous Materials (GefStoffV).
Code letter and hazard designation for product:
F+ Extremely flammable
Xn Harmful
Risk - phrases:
12 Extremely flammable.
40 Possible risks of irreversible effects.
65 Harmful; can cause lung disease.
67 Vapours may cause drowsiness and dizziness.
Safety - phrases:
16 Keep away from sources of ignition - No smoking.
23 Do not breathe vapour/spray.
33 Take precautionary measures against static discharges.
36/37 Wear suitable protective clothing and gloves.
S 62 If swallowed, do not induce vomiting: seek medical advice immediately and show this
container or label
Special labelling:
Container is under pressure. Protect from sun and temperatures above 50°C. Do not open with
force or incinerate even after use. Do not spray into flames or onto glowing objects.
Keep away from sources of ignition - No smoking. Keep out of reach of children.
Use only in well ventilated areas.
National Regulations (German): TRGS 614
TA-Air/classification, compound, remarks: Class 3 (organic)
Water hazard class: WGK 2 (dangerous for water)
16. Other information
Restriction of occupation:
Observe employment restrictions for young people.
Recommended uses:
As PENETRANT at the penetration process by colours acc. to EN ISO 3452-1
[EN 571-1] (DIN 54 152 part 1) for finding surface cracks.

This information is based on our current knowledge and is intended to describe the product for
the purposes of health, safety and environmental requirements only. It should not therefore be
construed as guaranteeing any specific property of the product.

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