CHEM 101 Recitation - Week 8

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CHEM 101 – Recitation Week 8

Ch. 7, 49. Calculate the theoretical yield of the product (in moles) for each initial amount of reactants.
Ti (s) + 2 Cl2 (g)  TiCl4 (s)
a. 4 mol Ti, 4 mol Cl2

c. 12.4 mol Ti, 18.8 mol Cl2

Concept: Writing and balancing chemical equations

Ch. 7, 51. Zinc sulfide reacts with oxygen according to the following reaction:
2 ZnS (s) + 3 O2 (g)  2 ZnO (s) + 2 SO2 (g)
A reaction mixture initially contains 4.2 mol ZnS and 6.8 mol O2. Once the reaction has occurred as
completely as possible, what amount (in moles) of the excess reactant remains?

Concept: Stoichiometric Relationships: Limiting Reactant, Theoretical Yield, Percent Yield, and Reactant
in Excess

Ch. 7, 59. Urea (CH4N2O) is a common fertilizer that is synthesized by the reaction of ammonia (NH3)
with carbon dioxide:

2 NH3 (aq) + CO2 (aq)  CH4N2O (aq) + H2O (l)

In an industrial synthesis of urea, a chemist combines 136.4 kg of ammonia with 211.4 kg of carbon
dioxide and obtains 168.4 kg of urea. Determine the limiting reagent, theoretical yield of urea, and
percent yield for the reaction. MW urea = 60.054 g/mol; MW ammonia = 17.031 g/mol; MW carbon
dioxide = 44.01 g/mol; MW water = 18.01 g/mol.

Concept: limiting reactant and yield

Ch. 8, 23. What is the molarity of NO3- in each solution?


c. 0.150 M Al(NO3)3

Concept: mass to mol conversion

Ch. 8, 27. A laboratory procedure calls for making 400.0 mL of a 1.1 M NaNO3 solution. What mass of
NaNO3 (in g) do we need?

Concept: Mass to mass conversion

Ch. 8, 29. If 123 mL of a 1.1 M glucose solution is diluted to 500.0 mL, what is the molarity of the
diluted solution?

Concept: same as previous


s
Ch. 9, 38. The air in an inflated balloon (defined as the system) warms over a toaster and absorbs 115 J
of heat. As it expands, it does 77 kJ of work. What is the change in internal energy for the system?
Concept: work-pressure Volume work

1
Ch. 9, 40. A kilogram of aluminum metal and a kilogram of water are each warmed to 75 °C and placed
in two identical insulated containers. One hour later, the two containers are opened, and the temperature
of each substance is measured. The aluminum has cooled to 35 °C, while the water has cooled only to 66
°C. Explain this difference.

Concept: quantifying Heat and Work

Honors only

Ch. 8, 33. Consider the precipitation reaction:

2 Na3PO4 (aq) + 3 CuCl2 (aq) → Cu3(PO4)2 (s) + 6 NaCl (aq)

What volume of 0.175 M Na3PO4 solution is required to completely react with 95.4 mL of 0.102 M
CuCl2?

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