Linnaeite

Download as pdf or txt
Download as pdf or txt
You are on page 1of 1

Linnaeite Co2+ Co3+

2 S4

c 2001-2005 Mineral Data Publishing, version 1

Crystal Data: Cubic. Point Group: 4/m 3 2/m. Dominantly octahedral crystals, to 5 mm;
commonly massive, granular and compact. Twinning: On {111}.

Physical Properties: Cleavage: Imperfect on {001}. Fracture: Uneven to subconchoidal.


Hardness = 4.5–5.5 VHN = 435–558, average 492 (50 g load). D(meas.) = 4.5–4.8
D(calc.) = 4.85

Optical Properties: Opaque. Color: Pale gray to steel-gray. Luster: Metallic, easily
tarnished.
R: (400) 41.5, (420) 41.8, (440) 42.2, (460) 43.0, (480) 44.0, (500) 45.0, (520) 46.0, (540) 47.0,
(560) 48.0, (580) 49.0, (600) 49.9, (620) 50.7, (640) 51.6, (660) 52.4, (680) 53.1, (700) 53.7

Cell Data: Space Group: F d3m. a = 9.43 Z=8

X-ray Powder Pattern: Müsen, Germany.


2.83 (100), 1.670 (80), 2.36 (70), 1.815 (60), 0.988 (50), 3.34 (40), 1.090 (40)

Chemistry: (1) (2) (3)


Co 40.71 48.70 57.96
Ni 7.35 4.75
Cu 8.79 2.40
Fe 1.30 2.36
S 41.43 41.70 42.04
insol. 0.14 0.40
Total 99.72 100.31 100.00
(1) Gladhammar, Sweden; corresponds to (Co2.14 Cu0.43 Ni0.39 Fe0.07 )Σ=3.03 S4.00 . (2) Carroll Co.,
Maryland, USA; corresponds to (Co2.54 Ni0.25 Fe0.13 Cu0.12 )Σ=3.04 S4.00 . (3) Co2+ Co3+
2 S4 .

Polymorphism & Series: Forms a series with polydymite.

Mineral Group: Linnaeite group.

Occurrence: In hydrothermal veins with other cobalt and nickel sulfides.

Association: Chalcopyrite, pyrrhotite, millerite, bismuthinite, gersdorffite, carrollite, cattierite,


ullmannite, marcasite, pyrite, galena, sphalerite.

Distribution: In Sweden, from the Bastnäs mine, near Riddarhyttan, Västmanland [TL],
and at Gladhammar, Kalmar. At Outokumpu, Finland. In Germany, from Müsen, North
Rhine-Westphalia; at Altenberg, Saxony; in the Grube Georg, near Horhausen, Westerwald. At
Kladno, Czech Republic. In the USA, from the Springfield and Mineral Hill mines, Carroll Co.,
Maryland; and at the Mine La Motte, Madison Co., Missouri. In Congo (Zaire), in the Musonoi
mine, near Kolwezi, Katanga (Shaba) Province. At the N’Kana mine, Kitwe, from the Chambishi
Southeast prospect, and in the Rhokana mine, Zambia. In the Wonderland and Selukwe Peak
mines, Selukwe, Zimbabwe. From Tsumeb, Namibia. Known from a number of other minor
occurrences.

Name: In honor of Carl von Linné [Carolus Linnaeus] (1707–1778), Swedish taxonomist.

References: (1) Palache, C., H. Berman, and C. Frondel (1944) Dana’s system of mineralogy,
(7th edition), v. I, 262–265. (2) De Jong, W.F. and H.W.V. Williams (1927) Die Verbindungen
Fe3 S4 , Co3 S4 , Ni3 S4 und ihre Struktur. Z. Anorg. Allg. Chem. 161, 311–315 (in German).
(3) Berry, L.G. and R.M. Thompson (1962) X-ray powder data for the ore minerals.
Geol. Soc. Amer. Mem. 85, 103. (4) Criddle, A.J. and C.J. Stanley, Eds. (1993) Quantitative data
file for ore minerals, 3rd ed. Chapman & Hall, London, 323.
All rights reserved. No part of this publication may be reproduced, stored in a retrieval system or transmitted in
any form or by any means, electronic, mechanical, photocopying, recording, or otherwise without the prior written
permission of Mineral Data Publishing.

You might also like