Present Status of Feedstock Management & Technology Developments in Ethanol Sector

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Present Status of Feedstock

Management
&
Technology Developments in
Ethanol Sector
Jai Uppal, Consultant
B.Sc. Chem. Engg., M.S.E. (Michigan, USA)
F.I.E.. L.M.I.I.Ch.E., L.M.I.M.A.
Sr. Advisor, Center for Alternate Energy Research (CAER),
(University of Petroleum & Energy Studies)
Email: jaiuppal@gmail.com; M: +919811171121

New Delhi, September 25, 2007


Feedstocks For Ethanol
Production
‹ Sugars: –
– Sugarcane,
– sweet sorghum,
– sugar beet,
– molasses (by-product of sugar
production) - ‘A’, ‘B’ & ‘C’ heavy molasses
– fruits etc
‹ Starches: –
– Grains (Corn, wheat, rice, barley,
sorghum) etc
– Tubers (Cassava, potato etc)
‹ Cellulose – Grass, wood, MSW etc
Indian Feedstocks
‹ Molasses – main raw material + 90% of
Ethanol/Alcohol Production
‹ Sugarcane – technology available and
tested but cannot be used as sugarcane
price very high – unviable for Ethanol
‹ Sweet Sorghum – high yielding variety
being developed. Production technology
being tested – one plant set up – This year
commercial production.
‹ Tropical Sugar Beet – high yielding variety
being tested – plant set up – trials taken -
This year commercial production
Indian Feedstocks
‹ Fruits – only for wine
‹ Grains used for potable alcohol
production as it is costly – rice,
sorghum, barley, malt
‹ Damaged/unusable grain – sorghum

‹ Tubers – Cassava has been used in


south India for potable Alcohol
‹ Cellulose – Technology not yet
developed
Indian Feedstocks
‹ Molasses most economical feedstock
‹ Sugarcane most energy efficient crop
- hard to beat.
‹ However, water intensive & one year crop.
‹ Negative impact in draughts and cost of
production rises dramatically by up to
30% but not as volatile as crude oil
‹ During drought, less water intensive crops
may be economical
– Sweet sorghum/tropical sugar beet – about
4/6 months crop water intensity 1/3
Indian Ethanol Potential
‹ This year’s 12 mill T of Molasses
availability (for Ethanol). Can
produce 2.7 bill L of Ethanol
‹ Surplus Sugar produced this year 9
mill Tonnes – no where to sell as
surplus in the world – glut !
‹ 5 mill tonne of sugar/ can be
converted to 2.8 bill L of Ethanol
‹ E10 Blending Program requires 1.2
bill L of Ethanol
Indian Ethanol Potential
‹1 mill ha (of 60 mill ha) of irrigated
land can produce 5 bill L of Ethanol
‹ 5% damaged grain – 11 mill T can
produce – 4 bill L of Ethanol
‹ Surplus Biomass of 500 mill T can
produce 100 bill L per year
‹ Or 50% of 120 mill T of Bagasse
from sugar mills can produce 12 bill
L of Ethanol
Indian Ethanol Blending Program
(EBP)
‹ Ethanol Used in WW II – ‘Power
Alcohol’ in UP
‹ Technology Azeotropic distillation
using benzene
‹ Stopped after the War

‹ R&D & Trials in 1979-80, 91-92,

‹ Pilot projects in 2002 – 3 locations,


300 dispensing stations
Indian EBP
‹ E5 blending made mandatory in 9 states
& 4 UTs from Jan 1, 2003
‹ Made conditional from Oct 2004

‹ Resumed in 2006 & picks up momentum in


2007 – E5 introduced in Delhi 1st time !
‹ Announcement to introduce E5 in all India
except J&K, NE and Islands
‹ Intention to introduce E10 by Nov 2008

‹ Alcohol capacity of +3.5 bill L

‹ Installed Ethanol capacity of about 1.5 bill L


Ethanol Requirement for EBP

Year % Ethanol Gasoline


Blend Requirement Demand
(MMT) (MMT)
2006/07 5 0.5 10.07

2011/12 10 1.29 12.85

2011/12 25 3.21 12.85


Feedstocks for Ethanol Production
CANE
CANE JUICE GRAIN GRAIN BEET
MOLASSES

WET MILLING
DRY MILLING
GLUTEN

FIBRES
SLURRY
PREPARATION SLURRY
PRE -
DILUTION PREPARATION JUICE
CLARIFICATION
EXTRACTION
LIQUIFACTION
LIQUIFACTION

CONCENTRA-
TION SACCHARIFI SACCHARIFIC
CATION ATION

FERMENTATION FERMENTATION FERMENTATION FERMENTATION FERMENTATION

Distillation

HIGH QUALITY- ENA DEACTIVATED SPIRIT

AZEOTROPIC MOLECULAR SIEVE


DISTILLATION(HEXANE)

ANHYDROUS ANHYDROUS
ALCOHOL/ETHANOL ALCOHOL/ETHANOL
Status of Indian Ethanol
Technology
‹ Average capacity of plant 40 KLPD as
against 300 to 1000 KLPD in USA/Brazil
‹ Level of average technology improving
‹ Cost of production – economies of scale
will be achieved as EBP progresses
‹ Some Plants converting to multi feedstock
plants
‹ Price around Rs 21.50 per L can be
brought down if blending program is
expanded
‹ Small inefficient plants will die !
Ethanol Process Technology
‹ Process steps in Ethanol Production
Technology:
1. Convert starch to sugar
2. Ferment Sugar using yeast to produce weak
solution of Alcohol (7% to 9%)
3. Distill alcohol to around 95% V/V
4. Dehydrate Alcohol using Mol. Sieve to +99.7%
‹ For Molasses step 1 is avoided – Technology
using Molasses and some grains is well
established
‹ However technology being commercialized
to handle sugar beet and sweet sorghum
‹ Continuous fermentation technology
becoming popular especially larger Plants
Simplified Ethanol Process
Flowsheet

Alcohol Production
Simultaneous
Grain crushing Mashing Sacchrification Fermentation Distillation

Molasses

Cane juice
Fermentation Technology
‹ Batch Fermentation – being phased out
‹ Continuous Fermentation:-
– without yeast recycle
– or with yeast recycle
‹ Theoretically yield (fermentation efficiency
in ascending order but in actual practice
may not be so)
‹ Effect of quality of molasses & control of
operation
Fermentation Technology
‹ Higher efficiencies being attained
despite the molasses quality
deteriorating
‹ Ethanol from ‘A’ heavy molasses and
‘B’ heavy molasses no problem
‹ Ethanol from Sugarcane juice not in
use but feasible by adding clarifying
and evaporation equipment
Distillation Technology
‹ Atmospheric Distillation being phased out
‹ Multi pressure (pressure-Vacuum)
technology becoming popular
‹ lower steam consumption & downtime

‹ Introduced much earlier in India – ahead


of Brazil in energy efficiency
‹ Reboilers instead of direct sparging of
steam
‹ Lower water consumption
Dehydration Technology
‹ Ethanol Production
– Technologies
‹ Molecular Sieve (MS) - Technology of 90s
‹ Azeotropic Distillation(AD) - Old Polluting Technology
‹ Membrane - Yet to be stabilized - Membrane life

‹ Molecular Sieve technology under license


from US firms – Pressure Swing
Adsorption (PSA) process
‹ Low steam consumption of 0.6 kg per L of
Ethanol & long life of Mol sieve established
– ahead of Brazil
‹ Higher level of Instrumentation and
DCS/PLC systems being introduced in
almost all in new plants
Effluent Treatment & Utilities
‹ Distillery Effluent very rich in organic matter
– very high BOD and COD
‹ Major Issue & also an opportunity to use rich
humus and nutrients in effluent
‹ Zero effluent discharge
‹ Primary Effluent Treatment Bio-methanation
‹ Bio-composting using press mud from sugar
mills and distillery effluent
‹ Reverse osmosis/Evaporation being used to
reduce quantity of effluent, increase DS and
reduce water consumption by recycling
‹ Incineration in Boilers or spray drying
‹ High Water use issues –being addressed
Effluent Treatment & Utilities
‹ Efficient Bio-methanation provides up to
90 to 100% of Fuel for steam for
distillation and dehydration
‹ Increasingly Ethanol plants are integrated
with sugar mills and have their own high
pressure boilers and turbines with
alternators to generate power not only for
the Distillery / Ethanol plant but also for
the offices and residences or other
industrial uses such as Alcohol based
chemicals etc.
Technology & Plant Sourcing
‹ All Alcohol/Ethanol Plants made in
India
‹ Indian Alcohol/Ethanol technology
and plant suppliers have arrived on
the world stage !
‹ Plants being sold in all most all
continents
‹ Indian Alcohol technology and plants
being sold all over the world because
it is efficient and with lower capital
costs
Thank You !

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