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Safety data sheet

Page: 1/11
BASF Safety data sheet
Date / Revised: 07.09.2017 Version: 5.0
Product: Mythic®
(30683965/SDS_CPA_TH/EN)
Date of print 11.04.2019

1. Substance/preparation and manufacturer/supplier identification

Mythic®
Use: crop protection product, insecticide

Manufacturer/supplier:
BASF SE
67056 Ludwigshafen
GERMANY
Operating Division Crop Protection
Telephone: +49 621 60-27777
Telefax number: +49 621 60-28566
E-mail address: Produktinformation-Pflanzenschutz@basf.com

Emergency information:
International emergency number:
Telephone: +49 180 2273-112

2. Hazard identification
Classification according to UN GHS 2009

Classification of the substance and mixture:

Acute toxicity: Cat. 4 (oral)
Acute toxicity: Cat. 3 (Inhalation - mist)
Skin corrosion/irritation: Cat. 3
Hazardous to the aquatic environment - acute: Cat. 1
Hazardous to the aquatic environment - chronic: Cat. 1

Label elements and precautionary statement:

Pictogram:
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BASF Safety data sheet
Date / Revised: 07.09.2017 Version: 5.0
Product: Mythic®

(30683965/SDS_CPA_TH/EN)
Date of print 11.04.2019

Signal Word:
Danger

Hazard Statement:
Harmful if swallowed. Causes mild skin irritation. Toxic if inhaled. Very toxic to aquatic life. Very toxic
to aquatic life with long lasting effects.

Precautionary Statement:
If medical advice is needed, have product container or label at hand. Keep out of reach of children.
Read label before use.

Precautionary Statements (Prevention):

Use only outdoors or in a well-ventilated area. Avoid breathing mist. Do not eat, drink or smoke when
using this product. Wash contaminated body parts thoroughly after handling.

Precautionary Statements (Response):

Call a POISON CENTER or doctor/physician. IF INHALED: Remove person to fresh air and keep
comfortable for breathing. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel
unwell. Rinse mouth. Collect spillage. If skin irritation occurs: Get medical advice/attention.

Precautionary Statements (Storage):

Store in a well-ventilated place. Keep container tightly closed. Store locked up.

Precautionary Statements (Disposal):

Dispose of contents/container to hazardous or special waste collection point.

Other hazards which do not result in classification:

See section 12 - Results of PBT and vPvB assessment.
If applicable information is provided in this section on other hazards which do not result in
classification but which may contribute to the overall hazards of the substance or mixture.

May produce an allergic reaction. Contains: 1,2-BENZISOTHIAZOL-3(2H)-ONE

3. Composition/information on ingredients
Chemical nature

crop protection product, insecticide, suspension concentrate (SC)

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BASF Safety data sheet
Date / Revised: 07.09.2017 Version: 5.0
Product: Mythic®

(30683965/SDS_CPA_TH/EN)
Date of print 11.04.2019

Hazardous ingredients

Chlorfenapyr
Content (W/W): 21.4 % Acute Tox.: Cat. 3 (Inhalation - dust)
CAS Number: 122453-73-0 Acute Tox.: Cat. 4 (oral)
Aquatic Acute: Cat. 1
Aquatic Chronic: Cat. 1
M-factor acute: 100
M-factor chronic: 100

1,2-benzisothiazol-3(2H)-one
Content (W/W): < 0.05 % Acute Tox.: Cat. 4 (oral)
CAS Number: 2634-33-5 Skin Corr./Irrit.: Cat. 2
Eye Dam./Irrit.: Cat. 1
Skin Sens.: Cat. 1
Aquatic Acute: Cat. 1
M-factor acute: 10

propane-1,2-diol
Content (W/W): < 10 %
CAS Number: 57-55-6

4. First-Aid Measures

General advice:
First aid personnel should pay attention to their own safety. If the patient is likely to become
unconscious, place and transport in stable sideways position (recovery position). Immediately
remove contaminated clothing.

If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.

Call a poison control center or physician for treatment advice.

On skin contact:
Immediately wash thoroughly with soap and water, seek medical attention.

Call a poison control center or physician for treatment advice.

On contact with eyes:

Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an
eye specialist.

On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.
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BASF Safety data sheet
Date / Revised: 07.09.2017 Version: 5.0
Product: Mythic®

(30683965/SDS_CPA_TH/EN)
Date of print 11.04.2019
If swallowed, seek medical advice immediately and show this container or label. Do not induce
vomiting unless told to by a poison control center or doctor. Call a poison control center or physician
for treatment advice. Take patient to hospital immediately. Medical monitoring for at least 7 days.

Note to physician:
Symptoms: The most important known symptoms and effects are described in the labelling (see
section 2) and/or in section 11., Further important symptoms and effects are so far not known.
Symptoms of poisoning may only appear after several hours or several days.
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
antidote.

5. Fire-Fighting Measures

Suitable extinguishing media:

water spray, carbon dioxide, foam, dry powder

Unsuitable extinguishing media for safety reasons:

water jet

Specific hazards:
carbon monoxide, carbon dioxide, hydrogen chloride, nitrogen oxides, organochloric compounds
The substances/groups of substances mentioned can be released in case of fire.

Special protective equipment:

Wear self-contained breathing apparatus and chemical-protective clothing.

Further information:
In case of fire and/or explosion do not breathe fumes. Keep containers cool by spraying with water if
exposed to fire. Collect contaminated extinguishing water separately, do not allow to reach sewage
or effluent systems. Dispose of fire debris and contaminated extinguishing water in accordance with
official regulations.

6. Accidental Release Measures

Personal precautions:
Use personal protective clothing. Avoid contact with the skin, eyes and clothing. Do not breathe
vapour/spray.

Environmental precautions:
Do not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater.

Methods for cleaning up or taking up:

For small amounts: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose
binder, kieselguhr).
For large amounts: Dike spillage. Pump off product.
Collect waste in suitable containers, which can be labeled and sealed. Clean contaminated floors
and objects thoroughly with water and detergents, observing environmental regulations. Incinerate or
take to a special waste disposal site in accordance with local authority regulations. Dispose of
absorbed material in accordance with regulations. Wear suitable protective equipment.
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BASF Safety data sheet
Date / Revised: 07.09.2017 Version: 5.0
Product: Mythic®

(30683965/SDS_CPA_TH/EN)
Date of print 11.04.2019
7. Handling and Storage

Handling
Ensure thorough ventilation of stores and work areas. No special measures necessary if stored and
handled correctly. When using do not eat, drink or smoke. Hands and/or face should be washed
before breaks and at the end of the shift. Remove contaminated clothing and protective equipment
before entering eating areas.

Protection against fire and explosion:

No special precautions necessary. The substance/product is non-combustible. Product is not
explosive.

Storage
Segregate from foods and animal feeds.
Further information on storage conditions: Keep away from heat. Protect from direct sunlight.

Storage stability:
Storage duration: 36 Months

8. Exposure controls and personal protection

Components with occupational exposure limits

No occupational exposure limits known.

Personal protective equipment

Respiratory protection:
Suitable respiratory protection for lower concentrations or short-term effect: Combination filter for
gases/vapours of organic, inorganic, acid inorganic, alkaline compounds and toxic particles (e. g. EN
14387 Type ABEK-P3)

Hand protection:
Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact
(Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to
EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) etc.

Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)

Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting
boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case
of dust).

General safety and hygiene measures:

The statements on personal protective equipment in the instructions for use apply when handling
crop-protection agents in final-consumer packing. Avoid contact with the skin, eyes and clothing.
Wearing of closed work clothing is recommended. Take off immediately all contaminated clothing.
Store work clothing separately. Keep away from food, drink and animal feeding stuffs. No eating,
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BASF Safety data sheet
Date / Revised: 07.09.2017 Version: 5.0
Product: Mythic®

(30683965/SDS_CPA_TH/EN)
Date of print 11.04.2019
drinking, smoking or tobacco use at the place of work. Hands and/or face should be washed before
breaks and at the end of the shift.

9. Physical and Chemical Properties

Form: suspension
Colour: white to light brown
Odour: sweetish, characteristic
Odour threshold: Not determined since toxic by inhalation.

pH value: approx. 6 - 8
(approx. 25 °C)
(measured with the undiluted
substance)

Freezing point: approx. 0 °C

(1,013.3 hPa)
Information applies to the solvent.
Boiling point: approx. 100 °C
(1,013 mbar)
Information applies to the solvent.

Flash point: (ASTM D93)

No flash point - Measurement made
up to the boiling point.
Evaporation rate:
not applicable

Flammability (solid/gas): not flammable

Lower explosion limit:
As a result of our experience with this
product and our knowledge of its
composition we do not expect any
hazard as long as the product is used
appropriately and in accordance with
the intended use.
Upper explosion limit:
As a result of our experience with this
product and our knowledge of its
composition we do not expect any
hazard as long as the product is used
appropriately and in accordance with
the intended use.
Ignition temperature:
Based on the water content the
product does not ignite.

Thermal decomposition: No decomposition if stored and

handled as prescribed/indicated.
Explosion hazard: not explosive
Fire promoting properties: not fire-propagating
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BASF Safety data sheet
Date / Revised: 07.09.2017 Version: 5.0
Product: Mythic®

(30683965/SDS_CPA_TH/EN)
Date of print 11.04.2019
Vapour pressure: approx. 23.3 hPa
(20 °C)
Information applies to the solvent.

Density: approx. 1.13 g/cm3

(20 °C)
Relative vapour density (air):
not applicable

Solubility in water: dispersible

Partitioning coefficient n-octanol/water (log Pow):
not applicable

Viscosity, dynamic: approx. 757 mPa.s

(20 °C)

Other Information:
If necessary, information on other physical and chemical parameters is indicated in this section.

10. Stability and Reactivity

Conditions to avoid:
See MSDS section 7 - Handling and storage.

Thermal decomposition: No decomposition if stored and handled as

prescribed/indicated.

Substances to avoid:
strong acids, strong bases, strong oxidizing agents

Hazardous reactions:
No hazardous reactions if stored and handled as prescribed/indicated.

Hazardous decomposition products:

No hazardous decomposition products if stored and handled as prescribed/indicated.

11. Toxicological Information

Acute toxicity

Assessment of acute toxicity:

Of high toxicity after short-term inhalation. Of moderate toxicity after single ingestion. Virtually
nontoxic after a single skin contact.

Experimental/calculated data:
LD50 rat (oral): 560 - 567 mg/kg

LC50 rat (by inhalation): 0.571 mg/l 4 h (OECD Guideline 403)

An aerosol was tested.

LD50 rabbit (dermal): > 2,000 mg/kg

No mortality was observed.
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BASF Safety data sheet
Date / Revised: 07.09.2017 Version: 5.0
Product: Mythic®

(30683965/SDS_CPA_TH/EN)
Date of print 11.04.2019

Irritation

Assessment of irritating effects:

Skin contact causes slight irritation. Not irritating to the eyes.

Experimental/calculated data:
Skin corrosion/irritation rabbit:

Serious eye damage/irritation rabbit:

Respiratory/Skin sensitization

Assessment of sensitization:
There is no evidence of a skin-sensitizing potential.

Experimental/calculated data:
modified Buehler test guinea pig: (OECD Guideline 406)

Germ cell mutagenicity

Assessment of mutagenicity:
Mutagenicity tests revealed no genotoxic potential. The product has not been tested. The statement
has been derived from the properties of the individual components.

Carcinogenicity

Assessment of carcinogenicity:
The product has not been tested. The statement has been derived from the properties of the
individual components. The results of various animal studies gave no indication of a carcinogenic
effect.

Reproductive toxicity

Assessment of reproduction toxicity:

The product has not been tested. The statement has been derived from the properties of the
individual components. The results of animal studies gave no indication of a fertility impairing effect.

Developmental toxicity

Assessment of teratogenicity:
The product has not been tested. The statement has been derived from the properties of the
individual components. Animal studies gave no indication of a developmental toxic effect at doses
that were not toxic to the parental animals.

Specific target organ toxicity (single exposure):

Assessment of STOT single:

Based on the available information there is no specific target organ toxicity to be expected after a
single exposure.

Remarks: The product has not been tested. The statement has been derived from the properties of
the individual components.
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BASF Safety data sheet
Date / Revised: 07.09.2017 Version: 5.0
Product: Mythic®

(30683965/SDS_CPA_TH/EN)
Date of print 11.04.2019
Repeated dose toxicity and Specific target organ toxicity (repeated exposure)

Assessment of repeated dose toxicity:

The product has not been tested. The statement has been derived from the properties of the
individual components. No substance-specific organtoxicity was observed after repeated
administration to animals.

Aspiration hazard

No aspiration hazard expected.

Other relevant toxicity information

Misuse can be harmful to health.

Sweating and accompanying fever, digestive problems, emesis and diarrhea are common initial
clinical signs of oral ingestion. Subsequent symptoms may include tremor and convulsions,
tachycardia, muscle stiffness and weakness of limbs (sometimes leading to paralysis), hepatic and
renal dysfunction, pancreatitis, drowsiness and sudden disturbance of consciousness, followed by
coma.

12. Ecological Information

Ecotoxicity

Assessment of aquatic toxicity:

Very toxic to aquatic life with long lasting effects.
The product has not been tested. The statement has been derived from substances/products of a
similar structure or composition.

Toxicity to fish:
LC50 (96 h) 0.0239 mg/l, Oncorhynchus mykiss (Flow through.)

Aquatic invertebrates:
EC50 (48 h) 0.012 mg/l, Daphnia magna (static)

Aquatic plants:
EC50 (72 h) 4.09 mg/l, Selenastrum capricornutum (OECD Guideline 201)

Mobility

Assessment transport between environmental compartments:

The product has not been tested. The statement has been derived from the properties of the
individual components.

Information on: Chlorfenapyr

Assessment transport between environmental compartments:
Following exposure to soil, adsorption to solid soil particles is probable, therefore contamination of
groundwater is not expected.
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BASF Safety data sheet
Date / Revised: 07.09.2017 Version: 5.0
Product: Mythic®

(30683965/SDS_CPA_TH/EN)
Date of print 11.04.2019

Persistence and degradability

Assessment biodegradation and elimination (H2O):

The product has not been tested. The statement has been derived from the properties of the
individual components.

Information on: Chlorfenapyr

Assessment biodegradation and elimination (H2O):
Not readily biodegradable (by OECD criteria).
----------------------------------

Information on: Chlorfenapyr

Elimination information:
approx. 20 % CO2 formation relative to the theoretical value (OECD 301B; ISO 9439; 92/69/EEC,
C.4-C) (aerobic)
----------------------------------

Bioaccumulation potential

Assessment bioaccumulation potential:

The product has not been tested. The statement has been derived from the properties of the
individual components.

Information on: Chlorfenapyr

Bioaccumulation potential:
Bioconcentration factor: 116, Cyprinus carpio
Accumulation in organisms is not to be expected.
----------------------------------

Additional information

Other ecotoxicological advice:

Do not discharge product into the environment without control.

13. Disposal Considerations

Must be sent to a suitable incineration plant, observing local regulations.

Contaminated packaging:
Contaminated packaging should be emptied as far as possible and disposed of in the same manner
as the substance/product.

14. Transport Information

Domestic transport:
Hazard class: 9
Packing group: III
ID number: UN 3082
Hazard label: 9, EHSM
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (contains CHLORFENAPYR)
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BASF Safety data sheet
Date / Revised: 07.09.2017 Version: 5.0
Product: Mythic®

(30683965/SDS_CPA_TH/EN)
Date of print 11.04.2019

Sea transport
IMDG
Hazard class: 9
Packing group: III
ID number: UN 3082
Hazard label: 9, EHSM
Marine pollutant: YES
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (contains CHLORFENAPYR)

Air transport
IATA/ICAO
Hazard class: 9
Packing group: III
ID number: UN 3082
Hazard label: 9, EHSM
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (contains CHLORFENAPYR)

15. Regulatory Information

Hazard determining component(s) for labelling: CHLORFENAPYR

Other regulations

If other regulatory information applies that is not already provided elsewhere in this safety data
sheet, then it is described in this subsection.

16. Other Information

Vertical lines in the left hand margin indicate an amendment from the previous version.

The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. This safety data sheet is neither a
Certificate of Analysis (CoA) nor technical data sheet and shall not be mistaken for a specification
agreement. Identified uses in this safety data sheet do neither represent an agreement on the
corresponding contractual quality of the substance/mixture nor a contractually designated use. It is the
responsibility of the recipient of the product to ensure any proprietary rights and existing laws and
legislation are observed.