DBL 5404 - 2014
DBL 5404 - 2014
DBL 5404 - 2014
Foreword
DBL 5404 describes the requirements for parts manufactured from thermoplastics for the direct and
indirect areas in the passenger compartment.
Changes
In comparison with DBL 5404, edition 2010-12, the following changes have been made:
- New designation of the product versions with clear allocation of the material
- Implementation of thermoplastics with long glass fibers – product versions 70 to 79
- New material group added – PMMA
- Test conditions revised
- Emission test added for PBT and PE-based parts
Contents
1 Scope .....................................................................................................................................................6
2 Normative references ............................................................................................................................6
3 Terms and definitions ............................................................................................................................7
4 General requirements ............................................................................................................................8
5 Abbreviated material designation for documentation ............................................................................9
6 Use of recycled materials in vehicle interiors ........................................................................................9
7 Test methods for part assessment ........................................................................................................9
8 Technical data on the component........................................................................................................16
9 Material approval process....................................................................................................................26
10 Test methods for the qualification ........................................................................................................27
Annex A (Normative) – Requirements profiles .............................................................................................32
Annex B (Normative) – Data sheet ...............................................................................................................37
(1) Do not use the designation of the product versions for new constructions
AA
PV Material Material description Application examples
(1)
10 27 ABS+PC Blend of acrylonitrile butadiene styrene Electroplated components
and polycarbonate (only for
electrodeposition applications)
20 28 PC+ABS Blend of polycarbonate and ABS, Basic carrier center console,
reduced temperature resistance fascias, kinematic parts, pillar trim
(application temperature max.105 °C)
and high notched impact strength
30 29 PC+ABS Blend of polycarbonate and acrylonitrile Pillar trim, first-aid box lid
butadiene styrene, high temperature
resistance (application temperature max.
110 °C) and notched impact strength
00 32 PC+ABS-GF10 Blend of polycarbonate and acrylonitrile Door lining attachment strip
butadiene styrene with 10 % glass fibers
00 33 PC+ABS-GF20 Blend of polycarbonate and acrylonitrile Fascia for instrument cluster
butadiene styrene with 20 % glass fibers
00 34 PC+PET-MX20 Blend of polycarbonate and polyethylene Power outlet lid
terephthalate with 20 % minerals
00 38 PE-HD Polyethylene, high density Defroster outlet, air ducting parts
00 39 PE-LD Polyethylene, low density Defroster outlet, air ducting parts
01 40 PE (Sinter) Polyethylene rotation-sintered Air ducting parts
10 42 PP Polypropylene copolymer with higher Footwell cover
stiffness, modulus of elasticity ∼
1500 MPa
20 43 PP Polypropylene copolymer with lower Dust receptacles, caps
stiffness, flexible, modulus of elasticity ∼
700 MPa
00 44 PP-GF 20 Polypropylene with 20 % glass fibers Covers
00 45 PP-GF 30 Polypropylene with 30 % glass fibers Power outlet
00 46 PP-NF 50 Polypropylene with 50 % natural fibers Hooks, retainers
00 47 PP-T10 Polypropylene with 10 % talcum Spare tire well cover
00 48 PP-T15 Polypropylene with 15 % talcum Rear-end door trim
00 49 PP-T20 Polypropylene with 20 % talcum Housing parts, cable ducts
00 50 PP-T30 Polypropylene with 30 % talcum Detachable parts
00 52 PP-T40 Polypropylene with 40 % talcum Housing parts
00 53 PP-M10 Polypropylene with 10 % minerals Side walls, covers
(e.g. Wollastonite)
00 54 PP-HI High-impact polypropylene Trim
(e.g. elastomer modified)
00 55 PP-HI-T20 High-impact polypropylene with Trim
20 % talcum (e.g. elastomer modified)
00 56 PP-HI-M15 High-impact polypropylene with Trim (commercial vehicles)
15 % minerals (e.g. elastomer modified)
00 57 PP-HI-M25 High-impact polypropylene with Trim (commercial vehicles)
25 % minerals (e.g. elastomer modified)
00 58 PP-HC High crystalline polypropylene, Trunk sill, cable duct
improved scratch resistance
01 59 PPO Polyphenylene oxide (SB modified) Switch lever, waistrails
60 PP-HI-GF25 High-impact polypropylene with Thin-walled window frame trims
25 % glass fibers, soft-touch, improved
scratch resistance
65 PMMA Polymethyl methacrylate with improved Lens of instrument cluster
temperature resistance
66 PMMA Polymethyl methacrylate Optical waveguide in interior
70 PP-LGF20 Polypropylene reinforced with Instrument panel
20 % long glass fibers (impact modified)
Table 2 for materials with APS approval from localized production (North America, Europe, Asia).
The qualified raw material types do not relieve the supplier of requesting component material approval.
1 Scope
Parts manufactured from thermoplastics for the direct and indirect areas of the passenger compartment,
the air intake and the heating.
2 Normative references
The following referenced documents are indispensable for the application of this document.
For dated references, only the edition cited applies. For undated references, the latest edition of the
referenced document (including any amendments) applies.
DIN EN ISO 527-5 Plastics – Determination of Tensile Properties – Part 5: Test Conditions for
Unidirectional Fiber-reinforced Plastic Composites
DIN EN 20105-A02 Textiles - Tests for Colour Fastness - Part A02: Grey Scale for Assessing Change
in Colour
DIN EN ISO 22088-3 Plastics - Determination of Resistance to Environmental
Stress Cracking (ESC) – Part 3: Bent Strip Method
DIN EN ISO 306 Plastics - Thermoplastic Materials - Determination of Vicat Softening Temperature
(VST)
DIN EN ISO 6603-2 Determination of Puncture Impact Behavior of Rigid Plastics
Part 2: Instrumented Puncture Test
DIN EN ISO 2813 Paints and Varnishes – Determination of Specular Gloss of Non-Metallic Paint
Films at 20°, 60° and 85°
DIN IEC 60093 Methods of Test for Insulating Materials for Electrical Purposes; Volume
Resistivity and Surface Resistivity of Solid Electrical Insulating Materials (VDE
0303 Part 30)
DIN EN ISO 291 Plastics - Standard Atmospheres for Conditioning and/or Testing (ISO 291:2008)
DIN EN ISO 1183-1 Methods for Determining the Density of Non-Cellular Plastics. Part 1: Immersion
Method, Liquid Pyknometer Method and Titration Method
DIN EN ISO 1183-2 Plastics - Methods for Determining the Density of Non-Cellular
Plastics – Part 2: Density Gradient Column Method
DIN EN ISO 1183-3 Plastics - Methods for Determining the Density of Non-Cellular Plastics - Part 3:
Gas Pyknometer Method
DIN EN ISO 3451-1 Plastics – Determination of Ash – Part 1: General Methods
DIN EN 13130-4 Materials and Articles in Contact with Foodstuffs - Plastics Substances Subject to
Limitations Part 4: Determination of 1,3-Butadiene in Plastics
DIN EN ISO 4628-1 Evaluation of Degradation of Coatings - Designation of Quantity and Size of
Defects, and of Intensity of Uniform Changes in Appearance Part 1: General
Introduction and Designation System
DIN EN ISO 294-1 Injection Moulding of Test Specimens of Thermoplastic Materials. Part 1: General
Principles, and Moulding of Multipurpose and Bar Test Specimens
DIN EN ISO 13468-2 Plastics – Determination of the Total Luminous Transmittance of Transparent
Materials - Part 2: Double-beam Instrument
DIN 53435 Bending Test and Impact Test on Dynstat Test Pieces
DIN 50011-1 : 1978-01 Testing of Materials, Structural Components and Equipments - Warming Cabinet -
Definitions, Requirements
DIN 5031-3 Optical Radiation Physics and Illuminating Engineering
DIN EN ISO 11664-3 Colorimetry - Part 3: CIE Tristimulus Values
DIN 75220 Ageing Automobile Components in Solar Simulation Units
DIN EN ISO 11664-4 Colorimetry - Part 4: CIE 1976 L*a*b* Colour Space
VDA 278 Thermal Desorption Analysis of Organic Emissions for the Characterization of
Non-Metallic Materials for Automobiles
VDA 270 Determination of the Odour Characteristics of Trim Materials in Motor Vehicles
VDA 280-1 Farbmessung am Kraftfahrzeug – Farbmessung von Kunststoffoberflächen im
Fahrzeuginnenraum (Colorimetry for Motor Vehicles - Color Measurement of
Plastic Surfaces of Interiors for Motor Vehicles)
Direct passenger compartment The direct passenger compartment includes all components that
can be reached by the customer's hand during the normal use of
the vehicle (including glove box).
Indirect passenger compartment The indirect passenger compartment is the inner volume of the
safety cell of a vehicle, the detachable parts, e.g. doors and the
trunk.
4 General requirements
For safety requirements, homologation and quality, the existing statutory requirements and laws
shall be complied with. In addition, the relevant requirements of Daimler AG apply.
With regard to constituents, the materials shall comply with current statutory regulations. For the relevant
information regarding banned substances and declaration requirements, refer to DBL 8585 and DBL 6714.
The parts shall be free of production defects of any type which would impair the processing and
utilization properties or the appearance.
In particular, surfaces and cut edges shall not release any substances (e.g. auxiliary production materials,
release agents, contamination) which could lead to an impairment of the surface quality.
Visible decorative plastic parts shall comply with the requirements of our styling unit with regard to surface
gloss. The part-specific requirements are available from the styling unit.
The technical data from Table 3 tested on the part, the corresponding machine, material and process
parameters, and the sampling and the results of any strength calculations shall be documented
in an MB data sheet for DBL 5404 (available in DOC-Master).
Abbreviated designation for drawings in the block for material: e.g. Thermoplastic PC + ABS
and DBL 5404.29
Abbreviated designation for drawings in the block for material: e.g. Thermoplastic with material approval
PP-HI-T17 and DBL 5404.90
Where recycled materials are used, there is an increased risk of possible fluctuations in the individual
delivery batches. Compliance with these DBL requirements shall therefore be ensured and documented
for each batch by the raw material producer by appropriate quality measures across the complete delivery
period. Proof of compliance with these DBL requirements shall be provided to the part manufacturer in the
works test certificate!
Reprocessable materials from process start-ups, tool changes and production faults (e.g. sprue cake)
at the plastics processor's works shall not enter the production process. Exceptions are, for blow molding
processes, small quantities of reprocessable material from molded part trimmings, provided that the added
quantity is clearly limited and that with the maximum permitted content the requirements with regard to
odor, fogging and emissions as specified in VDA 278 / DBL 8585 can be proven to be maintained on the
finished part.
7.1 Density
Standard: DIN EN ISO 1183 Part 1-3
Test conditions: Method A - Buoyancy method
00 to 69 00 to 69
Product versions 70 to 79
80 to 99 80 to 99
Standard DIN 53435 (Dynstat) DIN EN ISO 178 DIN EN ISO 178
Test specimens 10 mm x 15 mm x d 80 mm x 10 mm x d 80 mm x 10 mm x d
Test specimen (instrument panel only) - - 80 mm x 25 mm x d
Test speed - 10 mm/min 10 mm/min
Span width - 64 mm 64 mm
Copyright Daimler AG 2014
Specification detail: With grained specimens, ensure that the grained specimen surface is not
in the tensile zone (strike rear side).
00 to 69 00 to 69
Product versions 70 to 79
80 to 99 80 to 99
Standard (DIN 53435) ISO 179 ISO 179
Test specimens 10 mm x 15 mm x 80 mm x 10 mm x 80 mm x 10 mm x d
d d
Test specimen (instrument panel - - 120 mm x 15 mm x
only) d
Span width - 62 mm 62 mm
Span width (instrument panel only) - - 70 mm
Impact direction - broadside broadside
* only valid for ABS + PC of product versions 05 and 83 (target value for component <3 mg/kg)
7.10 Fogging
Standard: DBL 5306
Test conditions: Method B
7.12 Odor
Standard: VDA 270
Conditioning: The samples shall be subjected to conditioning as soon as possible after
production. The parts shall be stored there in standard atmosphere
DIN EN ISO 291-23/50-2 for 7 days (7d at 23 °C/50 % RH)
and then welded air-tight in aluminum foil.
Test conditions: Method B3 (small parts as agreed with the responsible process/materials
engineering department of the Daimler receiving plant: Method A3)
Application: The test shall be performed if cleaning, sliding or lubricating compounds are used
on the part or during the production process. The supplier shall ensure that the
plastics used have an adequate resistance to environmental stress cracking
at 0,3 % and 1 % outer fiber strain.
Test equipment:
Bending device: in accordance with DIN EN ISO 22088-3
Felts: EMPA, Cat. No. 701
(Empa Testmaterialien, Mövenstr. 12, CH-9015 St. Gallen)
Kleenex: KIMWIPES Lite 200, Kimberly-Clark, Code 7101
Test specimens: 30*70*thickness of component or specimen panel
Test substances: All substances or auxiliaries used in the assembly and process
(e.g. grease, anti-creak coatings, etc.).
Test method:
The test specimens shall be conditioned in standard atmosphere DIN EN ISO 291-23/50-2 for 48 h
(for materials containing polyamides, see Section 7.18).
Evaluation:
Assess the test specimens in clamped condition under a reflected-light stereomicroscope at approx.
10 x magnification.
Rating Evaluation
1 no visible change
2 surface becoming mat
3 fine cracks
4 heavy cracking, breaks
Requirement:
Rating 1 is required for the parts, i.e. the parts shall not exhibit any visible changes after the test.
Application: The test of the resistance to cosmetics shall be performed on all parts that could
come into contact with cosmetics during the use of the vehicle.
The parts in question shall be specified by the development department.
The test is intended to assess the effect of cosmetic products on interior surfaces.
Copyright Daimler AG 2014
Test equipment:
Test substance: Sunscreen test substance – For the composition, always refer to the latest valid
DBL 5399.
Kleenex: KIMWIPES Lite 200, Kimberly-Clark, Code 7101
Test equipment: Digital scales with resolution 0,001 g
Application: Disposable pipette
Test method:
• Apply three drops or 0,07 g of the test substance to the component surface.
• Store the wetted test pieces in a circulating air cabinet (DIN 50011-1: 1978-01) at 60 °C for 24 h.
• Following storage, condition the specimens for one hour in standard atmosphere
DIN EN ISO 291-23/50-2. Then clean the test pieces using a 1 % washing-up liquid solution
and dry with Kleenex.
Following cleaning, the specimens shall be assessed on the basis of the following definitions:
Immediately after cleaning and after 24 ± 0,5 h assess visually in accordance with DIN EN ISO 4628-1.
Assessment of the surface after application of mechanical load in accordance with DIN EN ISO 4628-1.
Changes impairing the component function are not permissible. Changes beyond rating 2 shall be agreed
with the component manager.
Application: The resistance to care products shall be tested on all surfaces of interior parts
which are visible and accessible by the customer during cleaning work. In the
case of parts which cannot be tested meaningfully using the crockmeter,
the test exposure shall be simulated manually.
Test substances: For the composition of test substances 1-6, refer to the latest edition of
DBL 5399.
Test method:
The test specimens shall be conditioned in standard atmosphere DIN EN ISO 291-23/50-2 for 48 h
(for materials containing polyamides, see Section 7.18).
• The test shall be conducted at room temperature in accordance with DIN EN ISO 291.
• Impregnate felt for at least 5 min
• Insert felt in finger.
• Briefly place on folding towel (approx. 1 sec) and lift off again immediately
• Perform care test using test substances / parameters indicated above
• Following exposure, clean the tested surface with 1 % washing-up liquid solution, rinse and dab dry
using a Kleenex wipe.
Evaluation:
Assess felts and abrasion on the tested surface in a daylight booth (daylight in accordance with
DIN 5031 Part 3 D65) immediately following the test and after a regeneration period of 24 h by analogy
with DIN EN ISO 4628-1 according to the following scale:
Requirement:
Rating ≤ 2; is required for the parts and the felt surface, i.e. the parts shall exhibit only a very slight visible
change after the test.
Copyright Daimler AG 2014
Application: The hot light aging test shall be performed on all surfaces that are exposed to
direct sunlight and which are visible and accessible during the use of the vehicle.
In order to achieve a reproducible water content of the polyamide parts during testing, first dry and then
condition the components in the following atmospheres.
Materials Temperature
Long glass fiber-reinforced materials containing PP with high thermal
120°
load, e.g. instrument panel
Long glass fiber-reinforced materials containing PP with low thermal
100°
load, e.g. door module
Specimens: If the test specimen cannot be taken from the part, the value shall be tested on
specimen sheets 3 mm thick or shall be taken from the raw material data sheet
and indicated in the initial sampling.
Application: For optical waveguides only
Standard: DIN EN ISO 13468-2
Old 21 31 41 51 00 00
New 02 03 04 05 08 11
ABS-GF15
ABS+PC
ABS+PA
ABS
ABS
ABS
Section Test Unit
7.1 Density g/cm³ 1,05 1,05 1,06 1,09 1,15 1,06
±0,03 ±0,03 ±0,03 ±0,03 ±0,02 ±0,03
7.2 Residue on ignition % ≤5 ≤5 ≤5 ≤5 15 ± 2 ≤5
7.3.1 Stress at 3,5% strain MPa ≥ 40 ≥ 40 ≥ 60 ≥ 50 ≥ 60 ≥ 40
Notched impact strength at 23°C ≥6 ≥ 16 ≥8 ≥ 12 ≥ 45
Dynstat
kJ/m²
7.4.1 kJ/m²
Notched impact strength at -25°C ≥3 ≥ 10 ≥6 ≥8 ≥ 10
Impact strength at 23°C kJ/m² ≥5
7.4.2
Impact strength at -25°C kJ/m²
7.3.1 Stress at 3,5% strain MPa
Notched impact strength at 23°C kJ/m²
7.4.1
ISO
Target value:
If a specific value has been entered in the line of Table 3, the test shall be performed for that product
version.
X:
If an X has been entered in the line, check in Section 7 whether this test is to be excluded for this
components (e.g. not a surface part).
Should this not be the case, the test shall be performed in accordance with the standard specified there.
Old 00 00 00 00 00 00
New 12 15 16 17 18 19
(GF30+MD25)
PBT+ASA-
PA6-GF15
PA6-GF25
ABS+PA-
PARA6-
GF20
GF15
PA 6
Section Test Unit
7.1 Density g/cm³ 1,20 1,12 1,23 1,30 1,74 1,31
±0,02 ±0,02 ±0,02 ±0,02 ±0,04 ±0,03
15 ±
7.2 Residue on ignition % 20 ± 2 ≤5 15 ± 2 25 ± 2 55 ± 3
2
7.3.1 Stress at 3,5% strain MPa ≥ 50 ≥ 45 ≥ 50 ≥ 70 ≥ 120 ≥ 110
Notched impact strength at 23°C
Dynstat
kJ/m² ≥ 20
7.4.1 kJ/m²
Notched impact strength at -25°C ≥ 10
Impact strength at 23°C kJ/m² ≥ 14 n.br. ≥8 ≥9 ≥4 ≥ 10
7.4.2
Impact strength at -25°C kJ/m² ≥ 11 ≥5
7.3.1 Stress at 3,5% strain MPa
Notched impact strength at 23°C kJ/m²
7.4.1
ISO
Target value:
If a specific value has been entered in the line of Table 3, the test shall be performed for that product
version.
X:
If an X has been entered in the line, check in Section 7 whether this test is to be excluded for this
components (e.g. not a surface part).
Should this not be the case, the test shall be performed in accordance with the standard specified there.
Old 00 00 00 10 20 30
New 22 23 24 27 28 29
PC + ASA
PBT+ASA-
PC+ABS
PC+ABS
ABS+PC
GF20
PC
Section Test Unit
7.1 Density g/cm³ 1,38 1,19 1,15 1,10 1,13 1,15
±0,03 ±0,02 ±0,02 ±0,02 ±0,02 ±0,02
7.2 Residue on ignition % 20 ± 2 ≤5 ≤5 ≤5 ≤5 ≤5
7.3.1 Stress at 3,5% strain MPa ≥ 130 ≥ 60 ≥ 60 ≥ 50 ≥ 55 ≥ 60
Notched impact strength at 23°C ≥ 20 ≥ 20 ≥ 10 ≥ 15 ≥ 20
Dynstat
kJ/m²
7.4.1 kJ/m²
Notched impact strength at -25°C ≥ 10 ≥8 ≥7 ≥ 10 ≥ 12
Impact strength at 23°C kJ/m² ≥ 10
7.4.2
Impact strength at -25°C kJ/m² ≥5
7.3.1 Stress at 3,5% strain MPa
Notched impact strength at 23°C kJ/m²
7.4.1
ISO
Target value:
If a specific value has been entered in the line of Table 3, the test shall be performed for that product
version.
X:
If an X has been entered in the line, check in Section 7 whether this test is to be excluded for this
components (e.g. not a surface part).
Should this not be the case, the test shall be performed in accordance with the standard specified there.
Old 00 00 00 00 00 01
New 32 33 34 38 39 40
PC+ABS-
PC+ABS-
PC+PET-
PE Sinter
PE-HD
PE-LD
MX20
GF10
GF20
Section Test Unit
7.1 Density g/cm³ 1,20 1,27 1,36 0,95 0,92 0,93
±0,03 ±0,03 ±0,02 ±0,01 ±0,01 ±0,02
20 ±
7.2 Residue on ignition % 10 ± 2 20 ± 2 ≤5 ≤5 ≤5
2
7.3.1 Stress at 3,5% strain MPa ≥ 65 ≥ 65 ≥ 70 ≥ 17 ≥ 12
Notched impact strength at 23°C ≥5 ≥6 ≥4
Dynstat
kJ/m²
7.4.1 kJ/m²
Notched impact strength at -25°C ≥3
Impact strength at 23°C kJ/m² ≥ 10 ≥8 ≥ 25
7.4.2
Impact strength at -25°C kJ/m² ≥6 ≥5 ≥ 10
7.3.1 Stress at 3,5% strain MPa
Notched impact strength at 23°C kJ/m²
7.4.1
ISO
Target value:
If a specific value has been entered in the line of Table 3, the test shall be performed for that product
version.
X:
If an X has been entered in the line, check in Section 7 whether this test is to be excluded for this
components (e.g. not a surface part).
Should this not be the case, the test shall be performed in accordance with the standard specified there.
Old 10 20 00 00 00 00
New 42 43 44 45 46 47
PP-GF 20
PP-GF 30
PP-NF 50
PP-T 10
PP
PP
Section Test Unit
7.1 Density g/cm³ 0,90 0,90 1,04 1,13 1,13 0,97
±0,01 ±0,01 ±0,03 ±0,03 ±0,03 ±0,02
20 ± 30 ±
7.2 Residue on ignition % ≤5 ≤5 ≤5 10 ± 2
2 2
7.3.1 Stress at 3,5% strain MPa ≥ 22 ≥ 15 ≥ 50 ≥ 65 ≥ 55 ≥ 30
Notched impact strength at 23°C ≥4 ≥5
Dynstat
kJ/m²
7.4.1 kJ/m²
Notched impact strength at -25°C ≥2
Impact strength at 23°C kJ/m² ≥8 ≥6 ≥ 12 ≥ 10
7.4.2
Impact strength at -25°C kJ/m² ≥3
7.3.1 Stress at 3,5% strain MPa
Notched impact strength at 23°C kJ/m²
7.4.1
ISO
Target value:
If a specific value has been entered in the line of Table 3, the test shall be performed for that product
version.
X:
If an X has been entered in the line, check in Section 7 whether this test is to be excluded for this
components (e.g. not a surface part).
Should this not be the case, the test shall be performed in accordance with the standard specified there.
Old 00 00 00 00 00 00
New 48 49 50 52 53 54
PP-M10
PP-T15
PP-T20
PP-T30
PP-T40
PP-HI
Section Test Unit
7.1 Density g/cm³ 1,01 1,06 1,12 1,22 0,98 0,90
±0,03 ±0,03 ±0,03 ±0,04 ±0,01 ±0,01
15 20 30 40 10 ± 2 ≤5
7.2 Residue on ignition %
+2 +2 +3 +4
7.3.1 Stress at 3,5% strain MPa ≥ 26 ≥ 28 ≥ 36 ≥ 38 ≥ 25 ≥ 20
Notched impact strength at 23°C kJ/m²
Dynstat
7.4.1 kJ/m²
Notched impact strength at -25°C
Impact strength at 23°C kJ/m² ≥8 ≥6 ≥5 ≥4 ≥ 15 n.br.
7.4.2 ≥3 ≥3 ≥3 ≥2
Impact strength at -25°C kJ/m² ≥ 10
7.3.1 Stress at 3,5% strain MPa
Notched impact strength at 23°C kJ/m²
7.4.1
ISO
Target value:
If a specific value has been entered in the line of Table 3, the test shall be performed for that product
version.
X:
If an X has been entered in the line, check in Section 7 whether this test is to be excluded for this
components (e.g. not a surface part).
Should this not be the case, the test shall be performed in accordance with the standard specified there.
old 00 00 00 01 01 ---
New 55 56 57 58 59 60
Unit
PP-HI-GF25
PP-HI-M15
PP-HI-M25
PP-HI-T20
PP-HC
PPO
Section Test
7.1 Density g/cm³ 1,04 1,02 1,07 0,90 1,06 1,09
±0,03 ±0,02 ±0,02 ±0,03 ±0,03 ±0,03
20 15 25 25
7.2 Residue on ignition % ≤5 ≤5
+ 3,0 + 2,0 + 3,0 + 3,0
7.3.1 Stress at 3,5% strain MPa ≥ 20 ≥ 20 ≥ 20 ≥ 30 ≥ 70
Notched impact strength at 23°C ≥8 ≥8
Dynstat
kJ/m²
7.4.1 kJ/m²
Notched impact strength at -25°C ≥3
Impact strength at 23°C kJ/m² n.br. n.br. n.br. Tbd.
7.4.2
Impact strength at -25°C kJ/m² ≥ 10 ≥ 13 ≥7 Tbd.
7.3.1 Stress at 3,5% strain MPa
Notched impact strength at 23°C kJ/m²
7.4.1
ISO
Target value:
If a specific value has been entered in the line of Table 3, the test shall be performed for that product
version.
X:
If an X has been entered in the line, check in Section 7 whether this test is to be excluded for this
components (e.g. not a surface part).
Should this not be the case, the test shall be performed in accordance with the standard specified there.
PMMA
PMMA
Section Test
7.1 Density g/cm³ 1,18 1,18
±0,02 ±0,02
7.2 Residue on ignition % ≤1 ≤1
≥ 75 ≥ 75
7.3.1 Stress at 3,5% strain MPa
(3) (3)
Dynstat
Target value:
If a specific value has been entered in the line of Table 3, the test shall be performed for that product
version.
X:
If an X has been entered in the line, check in Section 7 whether this test is to be excluded for this
components (e.g. not a surface part).
Should this not be the case, the test shall be performed in accordance with the standard specified there.
PP-LGF 20
PP-LGF 30
PP-LGF 30
Section Test
7.1 Density g/cm³ 1,04 1,12 1,12
±0,02 ±0,03 ±0,03
7.2 Residue on ignition % 20±2 30±3 30±3
Flexural strength kJ/m² ≥ 70 ≥ 65 ≥ 70
7.3.1
After aging (Section 7.19) kJ/m² ≥ 70 ≥ 60 ≥ 70
Impact strength at 23°C kJ/m² ≥ 25 ≥ 15 ≥ 40
ISO
7.4.2
After aging (Section 7.19) kJ/m² ≥ 25 ≥ 13 ≥ 40
Impact strength at -25°C kJ/m² ≥ 30 ≥ 10 ≥ 40
7.4.2
After aging (Section 7.19) kJ/m² ≥ 30 ≥8 ≥ 40
Tensile strength MPa ≥ 30 ≥ 40
Tensile test
Target value:
If a specific value has been entered in the line of Table 3, the test shall be performed for that product
version.
X:
If an X has been entered in the line, check in Section 7 whether this test is to be excluded for this
components (e.g. not a surface part).
Should this not be the case, the test shall be performed in accordance with the standard specified there.
Old 21 51 30 90 91 ---
New 80 83 85 90 91 92
PP-HI-T17
PP-HI-T20
PP-HI-T10
PC+ABS
ABS+PC
ABS
Section Test
7.1 Density* g/cm³ 1,05 1,09 1,15 1,03 1,04 0,97
7.2 Residue on ignition %
7.3.1 Stress at 3,5% strain MPa
Notched impact strength at 23°C
Dynstat
kJ/m²
7.4.1 kJ/m²
Notched impact strength at -25°C ≥3 ≥8 ≥ 12
Impact strength at 23°C kJ/m² n.br. n.br. n.br.
7.4.2
Impact strength at -25°C kJ/m² ≥ 10 ≥6 ≥ 10
7.3.1 Stress at 3,5% strain MPa
Notched impact strength at 23°C kJ/m²
7.4.1 kJ/m²
Notched impact strength at -25°C
ISO
Target value:
If a specific value has been entered in the line of Table 3, the test shall be performed for that product
version.
X:
If an X has been entered in the line, check in Section 7 whether this test is to be excluded for this
components (e.g. not a surface part).
Should this not be the case, the test shall be performed in accordance with the standard specified there.
*
The density test is not required, value entered for calculation using CAD system.
**:
The hot light aging test is not required if products already pigmented by the producer are used
(ready to use).
Copyright Daimler AG 2014
When all the requirements are fulfilled, the raw material producer may submit its product for approval.
Table 4
Figure 1
Figure 2
Test conditions:
Time period 42 days
Temperature 90 °C
Test equipment: Circulating air oven per DIN 50011-1 : 1978-01
Conditioning: The specimens shall not be tested until 7 days after manufacture at the earliest.
Test description: A line pattern in the form of a grid of at least (40 x 40) mm shall be created
(see Figure 3). Line spacing 2 mm.
2 mm ≥ 40 mm
Figure 3
The deviations shall be indicated as the delta value of values L*, a*, b*
and E*, e.g. ΔL*=value1, Δa*=value2, Δb*=value3, ΔE*=value4.
The individual values are thereby the mean values of at least 5 individual values.
At least 3 samples shall be tested.
Contact force: 5 N ± 0,05 N and 7 N ± 0,07 N. If the surface of relevant soft materials is
deformed so heavily under these test forces that the determination of gloss no
longer makes sense, a further test with a contact force of 3 N±0,03 N shall be
performed.
Test disc: Circular disc (diameter 16 mm ± 0,3 mm, thickness 1 mm ± 0,3 mm, see Figure 4)
of stainless steel. The edge shall be rounded and polished (radius 0,5 mm ± 0,01
mm); Quality and amount of wear of the disc shall be monitored. A differentiated
description of the steel grade and surface quality in the radius area will be
specified later.
16 mm 1 mm
r=0,5 mm
Figure 4
Conditioning: The specimens shall not be tested until 7 days after manufacture at the earliest.
Store the specimens in standard atmosphere in accordance with DIN EN ISO 291
for at least 48 hours.
Test description: A line pattern in the form of a grid of at least (40 x 40) mm shall be created
(see Figure 5).
The distance between the lines shall be small enough at 0,5 mm that the
complete area of (40 x 40) mm looks level. At least 80 lines shall be created.
See Figure 5. The circular disc shall be moved transverse to the travel path on
the specimen surface during this process.
≥ 40 mm
0,5 mm
Figure 5
Scribing by moving the disc transverse to the travel path (see Figure 6).
Figure 6
Measure the scribed are using a reflectometer for the determination of gloss in
accordance with DIN 67530 or DIN EN ISO 2813 (e.g. micro-TRI-gloss from
Byk-Gardner). Determine the specular gloss R´ at an angle of incidence of 60°
and 85° (see DIN 67530 Section 4.3), and from this value, determine the change
in gloss.
The absolute specular gloss values before and after scribing shall be evaluated.
5404.90
Section Test Unit Tolerance Value
7.1 Density g/cm³ ±0,02 1,03
7.2 Residue on ignition % ±2 17
7.3.1 Stress at 3,5% strain MPa min. 20
Impact strength at 23°C kJ/m² min. n.br.
7.4.2
Impact strength at -25°C kJ/m² min. 11
Yield stress MPa min. 15
Strain at yield stress % min. 4
7.6. Elongation at break % min. 20
Tensile module data sheet MPa min. 1800
Tensile module specimen plates MPa min. 1600
7.7 Hot storage temperature °C min. 120
7.8 Vicat softening temperature °C min. 55
10.1 Surface resistivity (antistatic) Ohm ≤ 10^12
10.2 Solar simulation (indoor) Rating ≥ 4
Shrinkage parallel % ±0,1 1
10.3
Shrinkage normal % ±0,1 1
Change in yield stress after heat % of
original value max. -10
aging (42d/90°C)
10.4 Change in elongation at break % of
original value max. -30
after heat aging (42d/90°C)
Change in surface after heat Visible
none
aging (42 d/90 °C) change
Puncture impact at 23°C
- Maximum force N to be specified to be specified
- Deflection at maximum force mm to be specified to be specified
- Puncture energy J to be specified to be specified
10.5
Puncture impact at -25°C
- Maximum force N to be specified to be specified
- Deflection at maximum force mm to be specified to be specified
- Puncture energy J to be specified to be specified
10.6 Gloss (original value) 2 to 2,5
Scratch resistance (DEK 0000.35) to be specified to be specified
10.7
Scratch resistance (DEK 0000.85) to be specified to be specified
Scribing resistance (DEK 0000.35) to be specified to be specified
10.8
Scribing resistance (DEK 0000.85) to be specified to be specified
7.10 Fogging mg ≤ 1,0
Emissions VOC µg/g ≤ 200
7.11
Emissions fog µg/g ≤ 300
7.12 Odor Rating ≤ 3
Resistance to environmental
7.13 Rating
stress cracking
7.14 Resistance to cosmetics Rating max. 2
7.15 Resistance to care products Rating ≤ 2
7.16 Hot light aging Rating ≥ 4
7.17 Burning test mm/min ≤ 80
Copyright Daimler AG 2014
A.2 Visible grained trim parts for large-area, more rigid parts
5404.91
Section Test Unit Tolerance Value
7.1 Density g/cm³ ±0,02 1,04
7.2 Residue on ignition % ±2 20
7.3.1 3,5% bending strain MPa min. 21
Impact strength at 23°C kJ/m² min. 20
7.4.2
Impact strength at -25°C kJ/m² min. 7
Yield stress MPa min. 17
Strain at yield stress % min. 4
7.6. Elongation at break % min. 15
Tensile module data sheet MPa min. 2000
Tensile module specimen plates MPa min. 1800
7.7 Hot storage temperature °C min. 120
7.8 Vicat softening temperature °C min. 55
10.1 Surface resistivity (antistatic) Ohm ≤ 10^12
10.2 Solar simulation (indoor) Rating ≥ 4
Shrinkage parallel % ±0,1 1
10.3
Shrinkage normal % ±0,1 1
Change in yield stress after heat % of
original value max. -10
aging (42d/90°C)
10.4 Change in elongation at break % of
original value max. -30
after heat aging (42d/90°C)
Change in surface after heat Visible
none
aging (42 d/90 °C) change
Puncture impact at 23°C
- Maximum force N to be specified to be specified
- Deflection at maximum force mm to be specified to be specified
- Puncture energy J to be specified to be specified
10.5
Puncture impact at -25°C
- Maximum force N to be specified to be specified
- Deflection at maximum force mm to be specified to be specified
- Puncture energy J to be specified to be specified
10.6 Gloss (original value) 2 to 2,5
Scratch resistance (DEK 0000.35) to be specified to be specified
10.7
Scratch resistance (DEK 0000.85) to be specified to be specified
Scribing resistance (DEK 0000.35) to be specified to be specified
10.8
Scribing resistance (DEK 0000.85) to be specified to be specified
7.10 Fogging mg ≤ 1,0
Emissions VOC µg/g ≤ 200
7.11
Emissions fog µg/g ≤ 300
7.12 Odor Rating ≤ 3
Resistance to environmental
7.13 Rating
stress cracking
7.14 Resistance to cosmetics Rating max. 2
7.15 Resistance to care products Rating ≤ 2
7.16 Hot light aging Rating ≥ 4
7.17 Burning test mm/min ≤ 80
5404.92
Section Test Unit Tolerance Value
7.1 Density g/cm³ ±0,02 0,97
7.2 Residue on ignition % ±1 10
7.3.1 Stress at 3,5% strain MPa min. 20
Impact strength at 23°C kJ/m² min. n.br.
7.4.2
Impact strength at -25°C kJ/m² min. 11
Yield stress MPa min. 15
Strain at yield stress % min. 4
7.6. Elongation at break % min. 20
Tensile module data sheet MPa min. 1800
Tensile module specimen plates MPa min. 1600
7.7 Hot storage temperature °C min. 120
7.8 Vicat softening temperature °C min. 55
10.1 Surface resistivity (antistatic) Ohm ≤ 10^12
10.2 Solar simulation (indoor) Rating ≥ 4
Shrinkage parallel % ±0,1 1
10.3
Shrinkage normal % ±0,1 1
Change in yield stress after heat % of
original value max. -10
aging (42d/90°C)
10.4 Change in elongation at break % of
original value max. -30
after heat aging (42d/90°C)
Change in surface after heat Visible
none
aging (42 d/90 °C) change
Puncture impact at 23°C
- Maximum force N to be specified to be specified
- Deflection at maximum force mm to be specified to be specified
- Puncture energy J to be specified to be specified
10.5
Puncture impact at -25°C
- Maximum force N to be specified to be specified
- Deflection at maximum force mm to be specified to be specified
- Puncture energy J to be specified to be specified
10.6 Gloss (original value) 2 to 2,5
Scratch resistance (DEK 0000.35) to be specified to be specified
10.7
Scratch resistance (DEK 0000.85) to be specified to be specified
Scribing resistance (DEK 0000.35) to be specified to be specified
10.8
Scribing resistance (DEK 0000.85) to be specified to be specified
7.10 Fogging mg ≤ 1,0
Emissions VOC µg/g ≤ 200
7.11
Emissions fog µg/g ≤ 300
7.12 Odor Rating ≤ 3
Resistance to environmental
7.13 Rating
stress cracking
7.14 Resistance to cosmetics Rating max. 2
7.15 Resistance to care products Rating ≤ 2
7.16 Hot light aging Rating ≥ 4
7.17 Burning test mm/min ≤ 80
5404.83
Section Test Unit Tolerance Value
7.1 Density g/cm³ ±0,02 1,09
7.2 Residue on ignition % ≤5
7.3.1 Stress at 3,5% strain MPa min. 55
Notched impact strength at 23 °C
kJ/m² min. 14
(Dynstat)
7.4.2
Notched impact strength at -
kJ/m² min. 9
25 °C (Dynstat)
Yield stress MPa min. 38
7.6.
Elongation at break % min. 17
7.7 Hot storage temperature °C min. 100
7.8 Vicat softening temperature °C min. 105
7.10 Fogging mg ≤ 0,7
7.9 1,3 butadiene content mg/kg ≤ 1
Emissions VOC µg/g ≤ 50
7.11
Emissions fog µg/g ≤ 200
7.12 Odor Rating ≤ 3
7.14 Resistance to cosmetics Rating max. -
7.15 Resistance to care products Rating ≤ 2
Hot light aging, standard Rating ≥ 4
7.16
Hot light aging, convertible Rating ≥ 6
7.17 Burning test mm/min ≤ 80
A.5 Trim parts with good impact resistance and high heat resistance
5404.85
Section Test Unit Tolerance Value
7.1 Density g/cm³ ±0,02 1,15
7.2 Residue on ignition % ≤5
7.3.1 Stress at 3,5% strain MPa min. 65
Notched impact strength at 23 °C
kJ/m² min. 22
(Dynstat)
7.4.2
Notched impact strength at -
kJ/m² min. 13
25 °C (Dynstat)
Yield stress MPa min. 44
7.6.
Elongation at break % min. 44
7.7 Hot storage temperature °C min. 120
7.8 Vicat softening temperature °C min. 120
7.10 Fogging mg ≤ 0,7
7.9 1,3 butadiene content mg/kg ≤ 1
Emissions VOC µg/g ≤ 50
7.11
Emissions fog µg/g ≤ 200
7.12 Odor Rating ≤ 3
7.14 Resistance to cosmetics Rating max. -
7.15 Resistance to care products Rating ≤ 2
Hot light aging Standard Rating ≥ 4
7.16
Hot light aging Convertible Rating ≥ 6
7.17 Burning test mm/min ≤ 80
5404.80
Section Test Unit Tolerance Value
7.1 Density g/cm³ ±0,03 1,05
7.2 Residue on ignition % ≤5
7.3.1 Stress at 3,5% strain MPa min. 44
Notched impact strength at 23 °C
kJ/m² min. 7
(Dynstat)
7.4.2
Notched impact strength at -
kJ/m² min. 4
25 °C (Dynstat)
Yield stress MPa min. 35
7.6.
Elongation at break % min. 9
7.7 Hot storage temperature °C min. 90
7.8 Vicat softening temperature °C min. 96
7.10 Fogging mg ≤ 0,7
7.9 1,3 butadiene content mg/kg ≤ 1
Emissions VOC µg/g ≤ 50
7.11
Emissions fog µg/g ≤ 200
7.12 Odor Rating ≤ 3
7.14 Resistance to cosmetics Rating max. -
7.15 Resistance to care products Rating ≤ 2
Hot light aging Standard Rating ≥ 4
7.16
Hot light aging Convertible Rating ≥ 6
7.17 Burning test mm/min ≤ 80