11 DPP 02a Iupac of Alkane Emerge 1657625376769

EMERGE 2024
IUPAC NOMENCLATURE
IUPAC OF ALKANE 02A
Marking Scheme : Single Correct (+3,-1) M M: 66 Time : 45 min
1. Select the correct name of the compound whose structure is
(a) Butyl chloride (b) Isobutyl chloride (c) sec-Butyl chloride (d) tert-Butyl chloride
(e) More than one of the above
2. What would be the best name for the following compound ? (Neglect any cis-trans isomerism that
ispossible.)
(a) 1-ethyl-3,4-dimethylcyclohexane (b) 3-ethyl-1,6-dimethylcyclohexane
(c) 1-ethyl-4,5-dimethylcyclohexane (d) 5-ethyl-1,2-dimethylcyclohexane
(e) 4-ethyl- 1 ,2-dimethylcyclohexane
3. What is the parent name for the following alkane ?
(Note : The parent name corresponds to the longest continuous chain of carbon atoms.)
(a) Heptane (b) Octane (c) Nonane (d) Decane
4. Which of the following structures contain the sec-butyl group ?
(a) (b) (c)
(d) (e)
5. Which of the following is the isobutyl group?

(a) (CH3)4C — group (b) (CH3)3C — group
(c) (CH3)2CHCH2 — group (d) CH3CH2CH(CH3) — group
6. Identify the correct IUPAC name
(a) 2,2-dimethyl-4-ethyl heptane (b) 5-Ethyl-2-methyl hexane
(c) 1,3-dimethyl butane (d) 3-Ethyl-1,1-dimethyl cyclohexane
7. Total number of carbon atoms present in parent chain is:
(a) 5 (b) 6
(c) 7 (d) None of these
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8. IUPAC name of the following compound is :
(a) 4-(1-methylethyl)-5-(1,1-dimethylethyl) octane (b) 441 ,1-dimethylethyl)-5-(1-methylethyl)octane

(c) 2,2,5-trimethyl-4,5-dipropylhexane (d) 4-isopropyl-5-(1,1-dimethylethyl)octane
9. Give the complete IUPAC name for the structure below. Be careful to identify longest carbon chain :
(a) 3, 5, 6-Trimethyl octane (b) 3, 4, 6-trimethyl octane

(c) 1, 2, 3, 6-tetramethyl heptane (d) None of these
10. The structure shown
(a) 1°, 2° and 3° carbon atoms (b) 1° and 2° carbon atoms only
(c) 1° and 3° carbon atoms only (d) 2° and 3° carbon atoms only
11. Find the correct option(s) about Compound (P)
(a) Total number of substituent in compound (P) are 2

(b) Total number of carbons in parent chain of compound (P) is 10
(c) Their is no complex substituent present in compound (P).
(d) All options are correct.
12. Correct IUPAC name of the compound is:
(a) 5-Ethyl-4-methyl octane (b) 4-methyl-5-ethyl octane

(c) 4-methyl-3-propyl heptane (d) 4-Ethyl-5-methyl octane
13. Among the following compounds 2,3-dimethylhexane is:
(a) (b) (c) (d)
2
14. (i) (ii) (iii)
(iv) (v)
The relationship between (ii) & (iv) is

(a) chain isomer (b) positional isomer (c) Functional group isomer (d) metamer
15. The IUPAC name of neopentane is :
(a) 2-methylpropane (b) 2, 2-dimethylbutane (c) 2-rn ethylbutane (d) 2, 2-dimethylpropane
16. Correct IUPAC name of the following compound is:
(a) 4-(1,1-dimethylethyl)-5-ethyloctane (b) 5-ethyl-4-(1,1-dimethylethyl)octane

(c) 5-(1,1-dimethylethyl)-4-ethyloctane (d) 5-ethyl-5-(1,1-dimethylethyl)octane
17. Correct IUPAC name for is
(a) 2-ethyl-3-methylpentane (b) 3,4-dimethylhexane

(c) 2-sec-butylbutane (d) 2,3-dimethylbutane
18. The compound which has one isopropyl group is
(a) 2, 2, 3, 3-tetram ethyl pentane (b) 3, 3-dimethyl pentane
(c) 2, 2, 3-trimethyl pentane (d) 2-methyl pentane
19. Which of the following is the tert-butyl group?
(a) (CH3)4C — group (b) (CH3)3C— group
(c) (CH3)2CHCH2— group (d) CH3CH2CH(CH3)— group
20. Functional group not present in given compound is/are ?
(a) alcohol
(b) Ketone
(c) carboxylic acid
(d) amide
21. The IUPAC name of the following structure (CH3)C.C.C.(CH3)CH(CH3) is:
(a) 3-Methylhex-4-yn-2-ene (b) 3-Methylhex-2-en-4-yne
(c) 4-Methylhex-4-en-4-yne (d) All are correct
22. Select the correct name of the compound whose structure is
(a) 2,5-Diethyl-6-methyloctane
(b) 4,7-Diethyl-3-methyloctane
(c) 4-Ethyl-3,7-dimethylnonane
(d) 6-Ethyl-3,7-dimethylnonane
3
All students are advised to solve DPPs within allowed time only.
All discussions are scheduled in every 4th doubt discussion class
–MKA Sir (Guruji)
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11 DPP 02a Iupac of Alkane Emerge 1657625376769

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EMERGE 2024

Marking Scheme : Single Correct (+3,-1) M M: 66 Time : 45 min

1. Select the correct name of the compound whose structure is

(a) Heptane (b) Octane (c) Nonane (d) Decane

4. Which of the following structures contain the sec-butyl group ?

(a) (b) (c)

5. Which of the following is the isobutyl group?

(c) 7 (d) None of these

(a) 4-(1-methylethyl)-5-(1,1-dimethylethyl) octane (b) 441 ,1-dimethylethyl)-5-(1-methylethyl)octane

(a) 3, 5, 6-Trimethyl octane (b) 3, 4, 6-trimethyl octane

(a) Total number of substituent in compound (P) are 2

(a) 5-Ethyl-4-methyl octane (b) 4-methyl-5-ethyl octane

(a) (b) (c) (d)

The relationship between (ii) & (iv) is

(a) 4-(1,1-dimethylethyl)-5-ethyloctane (b) 5-ethyl-4-(1,1-dimethylethyl)octane

(a) 2-ethyl-3-methylpentane (b) 3,4-dimethylhexane

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