Chemistry (Question Paper)

MTTS – 2 (CHEMISTRY)
51. Only one oxidation state is possible for

(a) Sc (b) Fe (c) Zn (d) Ti
52. If  is the degree of dissociation of Na 2SO4 , the van’t Hoff (i) used for calculating molecular mass
is
(a) 1  2 (b) 1  2 (c) 1  (d) 1 
53. Malachite is an ore of

(a) iron (b) copper (c) mercury (d) zinc
54. Two molecules of propanal on aldol condensation form.

(a) H 3C  CHOH  CH 2  CHO (b) H3C  CH2  CH  CH3   CHOH  CHO
(c) C2H5  CHOH  CH  CH3   CHO (d)  COH  CH2  CHO
55. The potential of the following cell is 0.34V at 25o C . Calculate the standard reduction potential of the
copper half-cell
Pt H2 1atm  | H 1M  Cu 2 1M  Cu
(a) -3.4 V (b) + 3.4 V (c) -0.34 V (d) + 0.34 V
56. 6  CH3 3 C  OH  2Al  2  CH3 3 C  O Al  3H 2 

3
Above reaction indicates
(a) alcohols are acidic in nature (b) alcohols are basic in nature
(c) alcohols are neutral in nature (d) none of these
57. The number of Phosphorus - Oxygen bonds in P4 O10 is

(a) 16 (b) 12 (c) 8 (d) 4
58. The IUPAC name of  Ni  PPh 3 2 Cl2  is

(a) bis-dichloro (triphenylphosphine) nickel (II)
(b) dichlorobis (triphenylphosphine) nickel (IV)
(c) dichlorotriphenylphosphine nickel (II)
(d) triphenylphosphine nickel (II) dichloride
59. The following ion imparts colour in its aqueous solution:

(a) Cr 3 (b) Zn 2 (c) Cu  (d) Sc3
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60. The limiting radius ratio for tetrahedral shape is
(a) 0 to 0.155 (b) 0.225 to 0.414 (c) 0.155 to 0.225 (d) 0.414 to 0.732
61. Under which of the following sets of conditions, G is always negative?

(a) H  ve and S  ve (b) H  ve and S  ve
(c) H   ve and S  ve (d) H   ve and S  ve
62. The conjugated diketone among following is

(a)  - napthol (b) catechol (c) pyrogallol (d) benzoquinone
63. On the extraction of iron, the slag produced is

(a) CO (b) FeSiO3 (c) MgSiO 3 (d) CaSiO3
64. In which case Raoult’s law is not applicable?

(a) 1 M NaCl (b) 1M Urea (c) 1 M glucose (d) 1M sucrose
  HCl
65. A  NaOH  H 2 O   B   Propanoic acid and A is
(a) Propane (b) Nitropropane (c) Propanol (d) Propanenitrile
66. The common oxidation state exhibited by all lanthanoids is

(a) +3 (b) +4 (c) +1 (d) +2
67. Which has maximum paramagnetic character?

4 2
(a)  Fe  CN 6  (d)  Mn  H 2O 6 
2 2
(b) Cu  H 2O 4  (c) Cu  NH3 4 
68. Which of the following metals is obtained by electrolytic reduction process?

(a) Fe (b) Cu (c) Ag (d) Al
69. Only one monohalogen derivative is possible for

(a) neopentane (b) n-butane (c) propane (d) isobutane
70. Magnetic moment 2.84 B.M. is given by (At. Numbers: Ni = 28, Ti = 22, Cr = 24, Co = 27)
(a) Co2 (b) Cr 2 (c) Ni 2 (d) Ti3
71. Lexan is
(a) an epoxy resin (b) a biodegradable (c) a linear ester (d) a polycarbonate
72. A first order reaction is found to have a rate constant, k  4.2 1012 s 1 . Find the half-life of the
reaction
(a) 1.26 1013 s (b) 1.65 1011 s (c) 1.65 1011 s (d) 1.26 1013 s
73. The S  S  S bond angle in S8 molecule is

(a) 109.5o (b) 105o (c) 110o (d) 60o
74. The final product in the following reaction sequence is

NaNO2,HCl KCN LiAlH4
p-chloroaniline ? ?
?
0-50 C
(a) p-chlorobenzamide (b) p – chlorophenol
(c) p – chlorobenzylamine (d) p – chlorobenzyl alcohol
75. The following carbohydrate is a non reducing sugar

(a) sucrose (b) maltose (c) lactose (d) glucose
 product is rate  k  A  B . What is the rate constant, if the

Rate law for the reaction A  B 
2
76.
rate of reaction at a given temperature is 0.22Ms1 , when  A  1M and  B  0.25M ?
(a) 3.52M2s 1 (b) 0.88M2s 1 (c) 1.136M 2s 1 (d) 0.05M2s 1
77. Identify x and y in the following sequence.

C2 H 5 Br 
x
 product  y
 C3H 7 NH 2
(a) x  KCN, y  LiAlH 4 (b) x  CH3 NH 2 , y  HNO2

(c) x  KCN, y  H 3O (d) x  CH3Cl, y  AlCl3 / HCl
4
78. Heat of combustion of methane is -800 kJ. What is heat of combustion for 4  10 kg of methane?
(a) -800 kJ (b) 3.2 104 kJ (c) 20kJ (d) 1600kJ
79. The order of reactivity of RCH 2 OH, R 2CHOH & R 3COH towards halogen acids is as,
(a) RCH 2 OH  R 2CHOH  R 3COH (b) R 3COH  RCH 2OH  R 2CHOH
(c) R 3COH  R 2CHOH  RCH 2OH (d) both the orders a & b
80. The activation energy of a reaction at a given temperature is found to be 2.303 RT J mol1 . The ratio
of rate constant to the Arrhenius factor is
(a) 0.01 (b) 0.1 (c) 0.02 (d) 0.001
81. An aqueous solution freezes at 0.186o C  Kf  1.86 Kb  0.512 what is the elevation in boiling
point?
(a) 0.186 (b) 0.512 (c) 0.86 (d) 0.0512
82. The process of converting hydrated alumina into anhydrous alumina is called
(a) roasting (b) smelting (c) dressing (d) calcination
83. Which one is the anhydride of HClO 4 ?

(a) ClO 2 (b) Cl2 O 7 (c) Cl 2 O (d) Cl2 O 6
84. Lead pipes are not safe for drinking water, as

(a) Lead is unstable in presence of water (b) Lead reacts with CO 2
(c) Lead is not mouldable (d) Water containing air attach lead
85. Select the compound which is least reactive

(a) Vinyl halide (b) Secondary halide (c) Tertiary halide (d) Allyl halide
86. Why do 2o and 3o amines fail to undergo the carbylamines test?

(a) They combine with chloroform to give a stable compound
(b) They react with alcoholic KOH
(c) The nitrogen atom of the amine group does not have the required no. of hydrogen atoms
(d) All the above given reasons are correct
87. Which of the reagents is used to distinguish vicinal and geminal dihalides?
(a) KMnO4 (b) alc. KOH (c) HNO3 (d) H 2SO 4
88. How many coulombs of electricity are required for the oxidation of one mole of water to dioxygen?
(a) 9.65 104 C (b) 1.93 104 C (c) 1.93 105 C (d) 19.3 105 C
89. Which of the following bases is not present in DNA?

(a) Alanine (b) Guanine (c) Cytosine (d) None of the above
90. A system absorbs 600J of heat and work equivalent to 300J on its surrounding. The change in
internal energy is
(a) 300 J (b) 400 J (c) 500 J (d) 600 J
91. The ionic character of the metal halides MCl, MI, MBr, MF decreases in the order
(a) MF >MBr> MI >MCl (b) MI >MBr> MF >MCl
(c) MF >MCl>MBr> MI (d) MBr> MF > MI >MCl
92. Which one of the following has the smallest pKb value by considering the basic strength of amines in
aqueous solution?
(a) C 6 H 5 NH 2 (b) CH 3 NH 2 (c)  CH3 2 NH (d)  CH3 3 N
93. The geometry of XeOF2 is

(a) pyramidal (b) T-shaped (c) octahedral (d) tetrahedral
94. 2 to 3% iodine in alcohol is used as

(a) Iodoform (b) Iodal (c) Iodine water (d) Tincture iodine
95. A mixture has 18 g water and 414 g ethanol. The mole fraction of water in mixture is (assume ideal
behaviour of the mixture)
(a) 0.1 (b) 0.4 (c) 0.7 (d) 0.9
96. The drug which is not used as an analgesic is

(a) Serotonin (b) Morphine (c) Codeine (d) Heroin
97. The oxime obtained from propanone, on hydrogenation, forms

(a) Propan-1-amine (b) Ethyl methyl amine
(c) Isopropyl amine (d) Ethanamine
98. Based on the first law of thermodynamics, which one of the following is correct?
(a) for an isothermal process, q  w (b) for an isochoric process, U  q
(c) for an adiabatic process, U  w (d) for a cyclic process, q  w
99. Which is a monomer of neoprene in the following?

(a) CH 2  C  CH  CH 2 (b) CH 2  C  CH  CH 2
Cl CH3
(c) CH 2  CH  CH  CH  CH3 (d) CH 2  CH  CH  CH 2
100. Which oxyacid of sulphur contain S-S single bond?

(a) Oleum (b) Marshall’s acid (c) Dithionic acid (d) Thiosulphuric acid

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MTTS – 2 (CHEMISTRY)

51. Only one oxidation state is possible for

53. Malachite is an ore of

54. Two molecules of propanal on aldol condensation form.

56. 6  CH3 3 C  OH  2Al  2  CH3 3 C  O Al  3H 2 

57. The number of Phosphorus - Oxygen bonds in P4 O10 is

58. The IUPAC name of  Ni  PPh 3 2 Cl2  is

59. The following ion imparts colour in its aqueous solution:

SPACE FOR ROUGH WORK

61. Under which of the following sets of conditions, G is always negative?

62. The conjugated diketone among following is

63. On the extraction of iron, the slag produced is

64. In which case Raoult’s law is not applicable?

66. The common oxidation state exhibited by all lanthanoids is

67. Which has maximum paramagnetic character?

68. Which of the following metals is obtained by electrolytic reduction process?

69. Only one monohalogen derivative is possible for

SPACE FOR ROUGH WORK

73. The S  S  S bond angle in S8 molecule is

74. The final product in the following reaction sequence is

75. The following carbohydrate is a non reducing sugar

 product is rate  k  A  B . What is the rate constant, if the

77. Identify x and y in the following sequence.

SPACE FOR ROUGH WORK

83. Which one is the anhydride of HClO 4 ?

84. Lead pipes are not safe for drinking water, as

85. Select the compound which is least reactive

86. Why do 2o and 3o amines fail to undergo the carbylamines test?

89. Which of the following bases is not present in DNA?

SPACE FOR ROUGH WORK

93. The geometry of XeOF2 is

94. 2 to 3% iodine in alcohol is used as

96. The drug which is not used as an analgesic is

97. The oxime obtained from propanone, on hydrogenation, forms

99. Which is a monomer of neoprene in the following?

100. Which oxyacid of sulphur contain S-S single bond?

SPACE FOR ROUGH WORK

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