(Jee 2023 - Chemistry) - (Top 100 Problems) PDF

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(1) B,C (2) A,C


(3) B,A (4) C,B
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(1) B > A > C (2) A > B > C


(3) C > B > A (4) C > A > B
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22. Mesityl oxide is a common name of
[Main March 17,20210)]
(a) 3-Methyl cyclohexane carbaldehyde
(b) 2, 4-Dimethyl pentan-3-one
(c) 2-Methyl cyclohexanone
(d) 4-Methylpent-3-en-2-one
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25.
1.
2.
0.1 M KMnO4 is used for following titration. What volume of the solution in
(mL) will be required to react with 0.158 g of Na2S2O3?
3.
S2O32- + MnO-4 + H2O → MnO2(s) + SO2-4 + OH-
A. 26.7 mL
B. 50 mL
C. 65 mL
D. 75 mL
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7.
The gas phase decomposition of dimethyl ether follows first order kinetics.
The reaction is carried out in constant volume container at 500°C and has a
8. half-life of 14.5 min. Initially only dimethyl ether is present at a pressure of
0.40 atm. The total pressure of the system after 12 min is Z/100 atm. The
value of Z is [Given 100.25 = 1.778]

CH3 — O — CH3 (g) CH4 (g) + H2 (g) + CO(g)


Consider the reaction A → 2 B + C, ΔH = -15 kcal . The energy of activation of
backward reaction is 20 kcal mol-1. In presence of catalyst, the energy of
9. activation of forward reaction is 3 kcal mol-1. At 400 K the catalyst causes the
rate of the forward reaction to increase by the number of times equal to-
10.
If E0 ClO-3/ClO-4 = -0.36 V & E0 ClO-3/ClO-4 = 0.33V at 298 K. The equilibrium
concentration of perchlorate ion (ClO-4) which was initially 1.0 M in ClO-3
11. when the reaction starts to attain the equilibrium,

2ClO-3 ⇌ ClO-2 + ClO- Given: Anti log(0.509) = 3.329

A. 0.0236 M
B. 0.0190 M
C. 0.123 M
D. 0.191 M
12.
A current of 1.93 ampere is passed through 200 mL of 0.5 M Zinc sulphate
(aq.) solution for 50 min with a current efficiency of 80%. If volume of
13. solution remain constant, then [ Zn2+] after deposition of Zn2+ is:
A. 0.38 M
B. 0.26 M
C. 0.35 M
D. 0.076 M
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61. The correct statement on the isomerism associated with the following
complex ions.
(a) [Ni(H2O)5NH3]2+
(b) [Ni(H2O)4(NH3)2]2+ and
(c) [Ni(H2O)3(NH3)3]2+ is:

(A) (a) and (b) show only geometrical isomerism


(B) (a) and (b) show geometrical and optical isomerism
(C) (b) and (c) show geometrical and optical isomerism
(D) (b) and (c) show only geometrical isomerism
62. How many acidic group is present in given amino acid

NH3—CH—CH—CH2—COO –
|
COO–
63. D-Glucose and D-mannose are:
(A) enantiomers (B) functional isomers
(C) epimers (D) metamers
64. Amylopectin is composed of
(A) a -D-glucose with C1— C4 and C1— C6 linkage
(B) a -D-glucose with C1— C4 and C2— C6 linkage
(C) b -D-glucose with C1— C4 and C2—C6 linkage
(D) b -D-glucose with C1— C4 and C1— C6 linkage
65. The structure of D-(+)-glucose is

The structure of L-(-)-glucose is

(A) (B) (C) (D)


66. On complete hydrogenation, natural rubber produces
(A) ethylene-propylene copolymer
(B) vulcanised rubber
(C) polypropylene
(D) polybutylene
67. Identify the pollutant gases largely responsible for the discoloured and
lustreless nature of marble of the Taj Mahal.
(A) SO2 and O3 (B) O3 and CO2
(C) SO2 and NO2 (D) CO2 and NO2
68. When silver nitrate solution is added to potassium iodide solution then the
sol produced is :
[Main July 22, 2021(II)]
(a) Agl/I– (b) Agl/Ag+
(c) Kl/NO 3– (d) AgNO3/NO 3–f
69. 14. The increasing order of the boiling point of the major products A, B and C
of the following reactions will be:
(Main Sep. 06. 2021) (II)]

(a) B < C < A (b) C < A <B


(c) A < B < C (d) A<C<B
70. Gold numbers of some colloids are: Gelatin: 0.005 - 0.01, Gum arabic:
0.15 - 0.25; Oleate: 0.04 - 1.0; Starch: 15 - 25. Which among these is a
better protective colloid ?
[Main Online April 10,2016]

(a) Gelatin (b) Starch


(c) Oleate (d) Gum arabic
71. Among the electrolytes Na2SO4, CaCl2, Al2(SO4)3 and NH4Cl, the most
effective coagulation agent for Sb2S3 sol is
[JEE 2009]
(A) Na2SO4 (B) CaCl2
(C) Al2(SO4)3 (D) NH4Cl
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75. 17. Which of the following compounds produces an optically inactive
compound on hydrogenation?
[Main Sep. 83.2020 (I)]

(a) (b)

(c) (d)
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Extraction of copper from copper pyrites (CuFeS2) does not involve

78. A.

B.

C.

D.
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80.
Based on the compounds of group 15 elements, the incorrect statements are

A.
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B.

C.

D.
Upon heating KClO3 in the presence of catalytic amount of MnO2, a gas W is
formed. Excess amount of W reacts with white phosphorus to give X. The
reaction of X with HNO3 gives Y and Z.
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Potassium Dichromate (K2Cr2O7) - Qualitative Analysis
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9o.
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A benzenoid organic compound A(C8H8O) gives B and white crystalline
solid C with Cl2 and NaOH. On hearing compound B gives a compound with
unpleasant smell with CH3 - CH2 - NH2 and alcoholic KOH. Compound A is
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99.
Match the following drugs with correct functional group test

100. P. Carbylamines
A. Chloroxylenol
B. Penicillin Q. Baeyer’s reagent
C. Sulpha Pyridine R. FeCl3 test
D. Norethindrone S. Sodium hydrogen sulphate
100.

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