केन्द्रीय विद्यालय संगठन, गरु

ु ग्राम संभाग
KENDRIYA VIDYALAYA SANGATHAN GURUGRAM REGION
कक्षा- XII Class-XII
2022-23
PRACTICE PAPER-II

SUBJECT-CHEMISTRY (043)
MARKING SCHEME

SECTION A
1. a 1
2. d 1
3. b 1
4. d 1
5. d 1
6. b 1

7. a 1
8. a 1
9. b 1
10. a 1
11. d 1
12. a 1
13. c 1
14. a 1
15. e 1
16. d 1
17. d 1
18. d 1
19. Nitrite ion is an ambident nucleophile. KONO IS predominantly ionic. So 2
attack occurs through oxygen atom as electron density on oxygen is more,
hence nitrites is formed. Whereas AgONO is Covalent and O is already
involved in formation of bond with Ag and attack occurs through Nitrogen
 1
20. (a)Diamminechloridonitroplatinum(II) 1
(b) Potassium trioxalatochromate(III)
1
21. (a) They form azeotropic mixture at 78.20 C which is lower than boiling 1
point of either of its constituents.
(b) If intravenous injection is Hypertonic to blood, RBC will shrivel ,
whereas if it is hypotonic to blood ,RBC will swell and burst. 1
Or
Definition
Condition 1
application
½
1/2
22. T99=2.303/k X log a-x/a = 464/k = Eqn(i) 1/2
2nd case = t90= 2.303/k log 100/10 = 2.303/k Eqn (2) 1/2
Div eqn (2) by (1) 1/2
T (99%)/t (90%) =463/k X k/2.303= 2. 1/2
23. 1/2
Log =
1/2
T2=273+37= 310 K
1/2
Log8 X 102 /4 X 102 = Ea/2.303 X 8.314(310-300/300 X 310)
1/2
Log 2= Ea./2.303 X 8.314 X 10/300 X 310= 53598J mol -1 = 53.598k J mol-1S
24. In [Ni(H2O)6 ] 2+ , H2O is a weak field ligand. Therefore, there are unpaired 1/2
2+
electrons in Ni . In this complex, the d electrons from the lower energy
1/2
level can be excited to the higher energy level i.e. the possibility of d-d
transition is present. In[Ni(CN)4] 2– ,the electrons are all paired as CN– is a
strong field ligand. Therefore, d - d transition is not possible.Hence, it is
colourless. As there are no unpaired electrons, it is diamagnetic.
1
OR
no. of ions resulting from dissociation increases
[Co(NH3)3Cl3]<[Co(NH3) 4Cl2]Cl <[Co(NH3)5Cl]Cl2 < [Co(NH3)6]Cl3 ,
1
 1
25. CH3Cl 1
Correct explanation 1
26. a) Correct equations 1
b) Correct equations
1
c) Correct equations
1

OR
(i) All amino acids have a similar structure. There is a central carbon atom,
called the alpha-carbon and this is bonded to an amino group on one side
and a carboxyl group on the other by loss of a molecule of water.
(ii) The specific sequence in which the alpha amino acids are linked to one
another is called primary structure.
(iii) When a native protein is subjected to change in temperature, pH, and 1
other changes the hydrogen bonds are broken and as a result coagulation
of protein takes place .This coagulated protein loses its specific biological
activity. This is called denaturation of proteins. Example- Coagulated 1
proteins are denatured proteins.

1
27. Anode: Zn (s) → Zn2+ (aq) + 2 e- 1/2
Cathode: O2(g) + 2H2O(l) + 4e– → 4OH– (aq).
1/2
Overall: 2 Zn (s) + O2(g) + 2H2O(l) → 2Zn2+(aq) + 4OH–
2 Zn (s) + O2(g) + 2H2O(l) → 2 Zn(OH)2 (ppt)
a) Quantity of electricity passed= Ixt =5X20X60s=6000C
The electrode reaction is: Ni2++ 2e--- Ni 1
2x96500 C deposit Ni =58.7g
6000Cwill deposit Ni = 58.7x6000/2x96500 =1.825g

1
28. a) 1st order reaction 1
b) Slope represents -k ; intercept is ln [R0]
1
c) s -1
1
29. 1
Correct order
1
Correct order
1
Correct order

30. (a)(i) In aniline due to resonance the lone pair of electrons on the nitrogen 1
atom are delocalized over the benzene ring. As a result, the electron
density on the nitrogen decreases. On the other hand, in methyl amine +I
effect of CH3 increases the electron density on the nitrogen atom.
Therefore aniline is a weaker base than methyl amine and hence its pKb
value is higher than that of methyl amine.
(ii) CH3 NH2 + H2O → CH3 NH3+ + OH-
Due to alkaline nature of solution of methylamine precipitation of Fe(OH) 3
occurs.
FeCl3 + 3OH–→ Fe (OH)3 Ferric hydroxide(Brown ppt) + 3Cl- 1

(b)

OR
(i) Correct chemical equation.
(ii) Correct chemical equation.
(iii) Correct chemical equation.

1
1
 1
31. (i)b 1
(ii)d
1
(iii)d
(iv)a 1
1
32. (i)b 1
(ii)d
1
(iii)a
(iv)c 1
1
33. (a) due to the availability of vaccant d-orbitals and high ionic charges 1
(b) Due to Lanthanoid contraction.
1
(c) in acidic medium it changes to dichromate ions.
1
(d)Due to Lanthanoid contraction
(e) Transition elements have generally high melting points. This is attributed 1
to the involvement of greater number of electrons from (n-1)d in addition 1
to the ns electrons in the interatomic metallic bonding.
OR

a) Due to presence of unpaired electrons in d-orbitals/d-d transitions.

b) Because they have larger number of unpaired electrons in their atoms.
This results in stronger interatomic interaction and stronger bonding
between atoms.
c) For lanthanoids +3 is most stable oxidation state.
d) Energy difference between 5f,6d and 7s orbitals is less and all of them
take part in bond formation.
e) Absence of unpaired electrons.

1
1
1
1
1
34. (a) Zn(s)|Zn2+(aq) || Ag+ (aq) | Ag (s) 1
(i)Zn- electrode
1/2
(ii) electron flows from anode to cathode
(iii) Anode Reaction: Zn (s)  Zn 2+(aq) + 2e- 1/2
Cathode: Ag+ (aq) + e Ag(S
(b) E°celll = E°(cathod) - E° (anode) =0.80-0.77=0.03 volt
Δ rG°= -nFE° = -1 x 96500 x 0.03 = -2895J/mol or 1
-2.895KJ/mol
Log Kc = nE /0.059 = 1 x 0.03/0.059=0.508
Kc =(anti) 0.508 = 3.22 1
OR

a) The cell can be written as Mg/Mg2+(0.130M)|| Ag+(0.0001M)/ Ag

E cell = Eocell ----0.0591/n log[Mg2+]/[Ag+]2      
= 3.17 V – 0 059/2. log ( 0.130/(0.0001)2
= 3.17 V – 0.21V = 2.96 V.

b) The conductivity of a solution at any given concentration is the 1

conductance of one unit volume of solution kept between two platinum
1/2
electrodes with unit area of cross section and at a distance of unit
length.Molar conductivity of a solution at a given concentration is the 1/2
conductance of the volume V of solution containing one mole of
electrolyte kept between two electrodes with area of cross section A 1(1/2
and distance of unit length. for
c) Correct statement unit)

1
35. (a)
(i)Propanone will form yellow ppt in Iodoform test
1
(ii)On treatment with Fehling solution only propanal will form reddish
brown ppt. (Or any other correct suitable test) 1
(b) o-ethyl benzaldehyde  2.4DNP (o-CH2CH3)-C6H4-CH=N-NH-C6H4(p-
NO2)
o-ethyl benzaldehyde  KMnO4,KOH Benzene 1,2- 3
dicarboxylic acid

OR
(a)
(i) Acetophenone will give yellow ppt in Iodoform test
(ii) Benzoic acid will give brisk effervescence on treatment with
Sodium carbonate.
(b) The carbon atom of the carbonyl group of benzaldehyde is
less electrophilic than carbon atom of the carbonyl group
present in propanal. The polarity of the carbonyl group is
reduced in benzaldehyde due to resonance as shown below
and hence it is less reactive than propanal. 1+1
(c) correct equation

1
 KENDRIYA VIDYALAYA SANGATHAN,GURUGRAM REGION
FIRST PRE BOARD SUMMER STATION KVs
CLASS XII SUBJECT-CHEMISTRY (043)
Session 2022--2023
BLUE PRINT

VSA SA LA-I LA-II LA-III

Unit Name of Chapter Total
(1) (2) (3) (4) (5)

1 Solution 4 (1)
1(1) 2(1) -- -- 7 (6)

2 Electrochemistry 1 (1) -- 3(1) 5 (1) 9 (3)

3 Chemical Kinetics -- 4(2) 3(1) -- 7(3)
4 d- & f- Block Elements 2 (2) -- -- 5(1) 7 (3)
5 Coordination Compound 3 (3) 4(2) 7 (4)
6 Haloalkanes & haloarenes 2(2) 4(2) 6 (3)
7 Alcohols, Phenols &Ethers 2 (2) 4 (1) 6 (3)
8 Aldehydes, Ketones &
3(1) 5 (1) 8 (2)
carboxylic acid
9 Compounds containing
3 (3) -- 3 (1) 6 (4)
Nitrogen
10 Bio-molecules 4(4) 3(1) 7 (4)
*Total Marks (Total NO. Of
Question) 18(18) 14(7) 15(5) 15(3) 70(35)
8(2)