Ferro Zine

SAFETY DATA SHEET
Issue Date 22-11-2019 Revision Date Version 5.4 Page 1 / 16

10-Aug-2021
1. IDENTIFICATION
Product identifier
Product Name FerroZineÒ Iron Reagent
Other means of identification

Product Code(s) 230149
Safety data sheet number M00186
UN/ID no UN2922
Recommended use of the chemical and restrictions on use

Recommended Use Water Analysis. Indicator for iron.
Uses advised against Consumer use.
Restrictions on use For Laboratory Use Only.
Details of the supplier of the safety data sheet
Manufacturer Address
Hach Company P.O.Box 389 Loveland, CO 80539 USA +1(970) 669-3050
Emergency telephone number

+1(303) 623-5716 - 24 Hour Service
2. HAZARDS IDENTIFICATION
Classification
Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Acute toxicity - Oral Category 3

Acute toxicity - Inhalation (Vapors) Category 4
Acute toxicity - Inhalation (Dusts/Mists) Category 4
Skin corrosion/irritation Category 1 Sub-category B
Serious eye damage/eye irritation Category 1
Respiratory sensitization Category 1
Skin sensitization Category 1
Chronic aquatic toxicity Category 3
Hazards not otherwise classified (HNOC)

Not applicable
Label elements
Signal word
Danger
EN / AGHS Page 1 / 16
Product Code(s) 230149 Product Name FerroZineÒ Iron Reagent
Issue Date 22-11-2019 Revision Date 10-Aug-2021
Version 5.4 Page 2 / 16
Hazard statements
H301 - Toxic if swallowed
H314 - Causes severe skin burns and eye damage
H317 - May cause an allergic skin reaction
H332 - Harmful if inhaled
H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled
H412 - Harmful to aquatic life with long lasting effects
Precautionary statements
P271 - Use only outdoors or in a well-ventilated area
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P260 - Do not breathe dust/fume/gas/mist/vapors/spray
P280 - Wear protective gloves, protective clothing, eye protection, and face protection
P301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting
P303 + P361 + P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing
P310 - Immediately call a POISON CENTER or doctor/physician
P363 - Wash contaminated clothing before reuse
P405 - Store locked up
P501 - Dispose of contents/ container to an approved waste disposal plant
P285 - In case of inadequate ventilation wear respiratory protection
P304 + P341 - IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for
breathing
P342 + P311 - If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician
P272 - Contaminated work clothing should not be allowed out of the workplace
P273 - Avoid release to the environment
P270 - Do not eat, drink or smoke when using this product
P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
Other Hazards Known

May be harmful in contact with skin
Harmful to aquatic life
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance
Not applicable
Mixture
Chemical Family Mixture.

Chemical nature Mixture of organic compounds.
Percent ranges are used where confidential product information is applicable.
Chemical name CAS No Percent HMRIC #

Range
Acetic acid, mercapto-, monoammonium salt 5421-46-5 40 - 50% -
Thioglycolic acid 68-11-1 20 - 30% -
Benzenesulfonic acid, 4,4-[3-(2-pyridinyl)-1,2,4-triazine-5,6-diyl]bis-, 69898-45-9 <1% -

monosodium salt
4. FIRST AID MEASURES

Description of first aid measures
General advice Show this safety data sheet to the doctor in attendance. Immediate medical attention is
required.
Inhalation Remove to fresh air. If breathing has stopped, give artificial respiration. Get medical
attention immediately. Do not use mouth-to-mouth method if victim ingested or inhaled the
substance; give artificial respiration with the aid of a pocket mask equipped with a one-way
valve or other proper respiratory medical device. If breathing is difficult, (trained personnel
should) give oxygen. Delayed pulmonary edema may occur. Get immediate medical
advice/attention. May cause allergic respiratory reaction. Avoid direct contact with skin. Use
barrier to give mouth-to-mouth resuscitation.
Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep
eye wide open while rinsing. Do not rub affected area. Remove contact lenses, if present
and easy to do. Continue rinsing. Get immediate medical advice/attention.
Skin contact Wash off immediately with soap and plenty of water while removing all contaminated
clothes and shoes. Get immediate medical advice/attention. May cause an allergic skin
reaction.
Ingestion Do NOT induce vomiting. Clean mouth with water and drink afterwards plenty of water.
Never give anything by mouth to an unconscious person. Get immediate medical
advice/attention. May produce an allergic reaction.
Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved, take precautions to
protect themselves and prevent spread of contamination. Avoid contact with skin, eyes or
clothing. Avoid direct contact with skin. Use barrier to give mouth-to-mouth resuscitation.
Avoid breathing vapors or mists.
Most important symptoms and effects, both acute and delayed
Symptoms Burning sensation. May cause allergy or asthma symptoms or breathing difficulties if
inhaled. Coughing and/ or wheezing. Itching. Rashes. Hives. Difficulty in breathing.
Indication of any immediate medical attention and special treatment needed
Note to physicians Product is a corrosive material. Use of gastric lavage or emesis is contraindicated.
Possible perforation of stomach or esophagus should be investigated. Do not give
chemical antidotes. Asphyxia from glottal edema may occur. Marked decrease in blood
pressure may occur with moist rales, frothy sputum, and high pulse pressure. May cause
sensitization in susceptible persons. Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
Unsuitable Extinguishing Media Caution: Use of water spray when fighting fire may be inefficient.
Specific hazards arising from the The product causes burns of eyes, skin and mucous membranes. Thermal decomposition
chemical can lead to release of irritating gases and vapors. Product is or contains a sensitizer. May
cause sensitization by inhalation and skin contact. May cause sensitization by skin contact.
Hazardous combustion products Carbon monoxide, Carbon dioxide. Nitrogen oxides. Sulfur oxides. Ammonia.
Special protective equipment for Firefighters should wear self-contained breathing apparatus and full firefighting turnout
fire-fighters gear. Use personal protection equipment.
6. ACCIDENTAL RELEASE MEASURES

U.S. Notice Only persons properly qualified to respond to an emergency involving hazardous
substances may respond to a spill according to federal regulations (OSHA 29 CFR
1910.120(a)(v)) and per your company's emergency response plan and
guidelines/procedures. See Section 13, Special Instructions for disposal assistance.
Outside of the US, only persons properly qualified according to state or local regulations
should respond to a spill involving chemicals.
Personal precautions, protective equipment and emergency procedures
Personal precautions Attention! Corrosive material. Avoid contact with skin, eyes or clothing. Ensure adequate
ventilation. Use personal protective equipment as required. Evacuate personnel to safe
areas. Keep people away from and upwind of spill/leak. Avoid breathing vapors or mists.
Other Information Refer to protective measures listed in Sections 7 and 8.
Environmental precautions
Environmental precautions Prevent further leakage or spillage if safe to do so. Should not be released into the
environment. Do not allow to enter into soil/subsoil. Prevent product from entering drains.
Methods and material for containment and cleaning up
Methods for containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Pick up and transfer to properly labeled containers.
Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.
Reference to other sections See section 8 for more information. See section 13 for more information.
7. HANDLING AND STORAGE

Precautions for safe handling
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes or clothing. In case of insufficient ventilation, wear suitable respiratory
equipment. Handle product only in closed system or provide appropriate exhaust
ventilation. Do not eat, drink or smoke when using this product. Take off contaminated
clothing and wash before reuse. Provide extract ventilation to points where emissions
occur. Remove contaminated clothing and shoes. Avoid breathing vapors or mists.
Conditions for safe storage, including any incompatibilities
Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Keep out of the reach
of children. Protect from moisture. Store locked up. Store away from other materials.
Flammability class Not applicable
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
Chemical name ACGIH TLV OSHA PEL NIOSH

Acetic acid, mercapto-, TWA: 1 ppm NDF NDF
monoammonium salt S*
CAS#: 5421-46-5
Thioglycolic acid TWA: 1 ppm (vacated) TWA: 1 ppm TWA: 1 ppm
CAS#: 68-11-1 S* (vacated) TWA: 4 mg/m3 TWA: 4 mg/m3
(vacated) SKN*
Appropriate engineering controls

Engineering Controls Showers
Eyewash stations
Ventilation systems.
Individual protection measures, such as personal protective equipment

Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are
exceeded or irritation is experienced, ventilation and evacuation may be required. Wear
breathing apparatus if exposed to vapors/dusts/aerosols.
Hand Protection Wear suitable gloves. Impervious gloves. Gloves must be inspected prior to use. The
selected protective gloves have to satisfy the specifications of EU Directive 2016/425 and
the standard EN 374 derived from it. Chemical resistant gloves made of butyl rubber or
nitrile rubber category III according to EN 374-1:2016.
Eye/face protection Face protection shield.
Skin and body protection Wear suitable protective clothing. Long sleeved clothing. Chemical resistant apron.
General Hygiene Considerations Avoid contact with skin, eyes or clothing. Wear suitable gloves and eye/face protection. Do
not eat, drink or smoke when using this product. Remove and wash contaminated clothing
and gloves, including the inside, before re-use. Contaminated work clothing should not be
allowed out of the workplace. Regular cleaning of equipment, work area and clothing is
recommended. Wash hands before breaks and immediately after handling the product.
Environmental exposure controls Local authorities should be advised if significant spillages cannot be contained. Do not
allow into any sewer, on the ground or into any body of water.
Thermal hazards None under normal processing.
9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Physical state Liquid

Appearance aqueous solution Color yellow
Odor Strong, skunk-like Odor threshold No data available
Property Values Remarks • Method
Molecular weight Not applicable
pH 3.5 @ 20 °C
Melting point/freezing point ~ -9 °C / 15.8 °F
Boiling point / boiling range ~ 102 °C / 215.6 °F

Evaporation rate 0.21 (water = 1)
Vapor pressure 2.325 mm Hg / 0.31 kPa at 20 °C / 68 °F
Relative vapor density 0.62
Specific gravity (water = 1 / air = 1) 1.310
Partition Coefficient (n-octanol/water) No data available
Soil Organic Carbon-Water Partition No data available

Coefficient
Autoignition temperature No data available
Decomposition temperature No data available
Dynamic viscosity No data available
Kinematic viscosity No data available
Solubility(ies)
Water solubility
Water solubility classification Water solubility Water Solubility Temperature

Soluble > 1000 mg/L 25 °C / 77 °F
Solubility in other solvents
Chemical Name Solubility classification Solubility Solubility Temperature

Acid Soluble > 1000 mg/L 25 °C / 77 °F
Other information
Metal Corrosivity
Steel Corrosion Rate 0.56 mm/yr / 0.02 in/yr

Aluminum Corrosion Rate 0.1 mm/yr / 0 in/yr
Volatile Organic Compounds (VOC) Content

See ingredients information below
Chemical name CAS No Volatile organic CAA (Clean Air Act)

compounds (VOC) content
Acetic acid, mercapto-, 5421-46-5 Not applicable -
monoammonium salt
Thioglycolic acid 68-11-1 No data available -
Benzenesulfonic acid, 69898-45-9 Not applicable -
4,4-[3-(2-pyridinyl)-1,2,4-triazine-5,6-di
yl]bis-, monosodium salt
Explosive properties
Upper explosion limit No data available

Lower explosion limit No data available
Flammable properties
Flash point No data available
Flammability Limit in Air

Upper flammability limit: No data available
Lower flammability limit: No data available
Oxidizing properties No data available.
Bulk density Not applicable
10. STABILITY AND REACTIVITY

Reactivity
Not applicable.
Chemical stability
Stable under normal conditions.
Explosion data
Sensitivity to Mechanical Impact None.
Sensitivity to Static Discharge None.
Possibility of hazardous reactions

None under normal processing.
Hazardous polymerization
Hazardous polymerization does not occur.
Conditions to avoid
Exposure to air or moisture over prolonged periods. Excessive heat.
Incompatible materials
Acids. Bases. Oxidizing agent.
Hazardous decomposition products

Thermal decomposition can lead to release of irritating and toxic gases and vapors.
11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure
Product Information
Inhalation Corrosive by inhalation. Inhalation of corrosive fumes/gases may cause coughing, choking,
headache, dizziness, and weakness for several hours. Pulmonary edema may occur with
tightness in the chest, shortness of breath, bluish skin, decreased blood pressure, and
increased heart rate. Inhaled corrosive substances can lead to a toxic edema of the lungs.
Pulmonary edema can be fatal. May cause sensitization in susceptible persons. Harmful by
inhalation.
Eye contact Causes burns. Corrosive to the eyes and may cause severe damage including blindness.
Causes serious eye damage. May cause irreversible damage to eyes.
Skin contact Repeated or prolonged skin contact may cause allergic reactions with susceptible persons.
May cause sensitization by skin contact. Corrosive. Causes severe burns. Avoid contact
with skin and clothing.
Ingestion Causes burns. Ingestion causes burns of the upper digestive and respiratory tracts. May
cause severe burning pain in the mouth and stomach with vomiting and diarrhea of dark
blood. Blood pressure may decrease. Brownish or yellowish stains may be seen around the
mouth. Swelling of the throat may cause shortness of breath and choking. May cause lung
damage if swallowed. May be fatal if swallowed and enters airways. May cause additional
affects as listed under "Inhalation".
Symptoms Redness. Burning. May cause blindness. Coughing and/ or wheezing. Symptoms of allergic
reaction may include rash, itching, swelling, trouble breathing, tingling of the hands and
feet, dizziness, lightheadedness, chest pain, muscle pain, or flushing. Itching. Rashes.
Hives.
Acute toxicity
Toxic if swallowed
Harmful if inhaled
Product Acute Toxicity Data

Test data reported below.
Oral Exposure Route
Endpoint type Reported dose Exposure time Toxicological effects

Rat 190 mg/kg Single generation Abnormalities of the lungs
Abnormalities of the liver
Abnormalities of the kidneys
Abnormalities of the spleen
Abnormalities of the gastrointestinal tract
Inhalation (Gas) Exposure Route
Ingredient Acute Toxicity Data

Oral Exposure Route
Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Acetic acid, Rat 3500 mg/kg None None reported RTECS (Registry of Toxic
mercapto-, LD50 reported Effects of Chemical
monoammonium salt Substances)
(40 - 50%)
CAS#: 5421-46-5
Thioglycolic acid Rat 73 mg/kg None None reported RTECS (Registry of Toxic
(20 - 30%) LD50 reported Effects of Chemical
CAS#: 68-11-1 Substances)
Dermal Exposure Route
Thioglycolic acid Rat 848 mg/kg None None reported RTECS (Registry of Toxic
(20 - 30%) LD50 reported Effects of Chemical
CAS#: 68-11-1 Substances)
Thioglycolic acid None None None None reported No information available
(20 - 30%) reported reported reported
CAS#: 68-11-1
Thioglycolic acid None None None None reported No information available

(20 - 30%) reported reported reported
CAS#: 68-11-1
Unknown Acute Toxicity
0% of the mixture consists of ingredient(s) of unknown toxicity.
Acute Toxicity Estimations (ATE)
The following values are calculated based on chapter 3.1 of the GHS document
ATEmix (oral) No information available

ATEmix (dermal) 2,868.70 mg/kg
ATEmix (inhalation-dust/mist) 1.70 mg/l
ATEmix (inhalation-vapor) 10.10 mg/l
ATEmix (inhalation-gas) No information available
Skin corrosion/irritation
Causes severe burns.
Product Skin Corrosion/Irritation Data

No data available.
Ingredient Skin Corrosion/Irritation Data

Chemical name Test method Species Reported Exposure Results Key literature
dose time references and
sources for data
Acetic acid, Existing human Human None None Skin irritant HSDB (Hazardous
mercapto-, experience reported reported Substances Data
monoammonium salt Bank)
(40 - 50%)
CAS#: 5421-46-5
Thioglycolic acid EpiDerm Skin synthetic 990 mg 3 minutes Corrosive to skin ECHA (The European
(20 - 30%) Model (Directive bio-barrier Chemicals Agency)
CAS#: 68-11-1 2000/33/EC, B.27) membrane
Benzenesulfonic QSAR None None None Not corrosive or Toxtree (Ideaconsult,
acid, (Quantitative reported reported reported irritating to skin Ltd)
4,4-[3-(2-pyridinyl)-1, Structure Activity
2,4-triazine-5,6-diyl]bi Relationship
s-, monosodium salt Models)
(<1%)
CAS#: 69898-45-9
Serious eye damage/irritation

Classification based on data available for ingredients. Causes burns. Risk of serious damage to eyes.
Product Serious Eye Damage/Eye Irritation Data

No data available.
Ingredient Eye Damage/Eye Irritation Data

Chemical name Test method Species Reported Exposure Results Key literature
sources for data
Benzenesulfonic QSAR None None None Not corrosive or Toxtree (Ideaconsult,
acid, (Quantitative reported reported reported irritating to eyes Ltd)
4,4-[3-(2-pyridinyl)-1, Structure Activity
2,4-triazine-5,6-diyl]bi Relationship
s-, monosodium salt Models)
(<1%)
CAS#: 69898-45-9
Respiratory or skin sensitization

May cause sensitization by inhalation. May cause sensitization by skin contact.
Product Sensitization Data

No data available.
Ingredient Sensitization Data

Respiratory Sensitization Exposure Route
Chemical name Test method Species Results Key literature references and
sources for data
Acetic acid, Based on human None Confirmed to be a respiratory HSDB (Hazardous Substances Data
mercapto-, experience reported sensitizer Bank)
monoammonium salt
(40 - 50%)
CAS#: 5421-46-5
STOT - single exposure

Based on available data, the classification criteria are not met.
Product Specific Target Organ Toxicity Single Exposure Data

No data available.
Ingredient Specific Target Organ Toxicity Single Exposure Data

No data available.
STOT - repeated exposure

Product Specific Target Organ Toxicity Repeat Dose Data

No data available.
Ingredient Specific Target Organ Toxicity Repeat Exposure Data

No data available.
Carcinogenicity
Product Carcinogenicity Data

No data available.
Ingredient Carcinogenicity Data

No data available.
Chemical name CAS No ACGIH IARC NTP OSHA

Acetic acid, mercapto-, 5421-46-5 - - - -
monoammonium salt
Thioglycolic acid 68-11-1 - - - -
Benzenesulfonic acid, 69898-45-9 - - - -
4,4-[3-(2-pyridinyl)-1,2,4-tri
azine-5,6-diyl]bis-,
monosodium salt
Legend
ACGIH (American Conference of Governmental Industrial Hygienists) Does not apply

IARC (International Agency for Research on Cancer) Does not apply
NTP (National Toxicology Program) Does not apply
OSHA (Occupational Safety and Health Administration of the US Department of Does not apply
Labor)
Benzenesulfonic QSAR None None Not Carcinogenic Toxtree (Ideaconsult, Ltd)
acid, (Quantitative reported reported
4,4-[3-(2-pyridinyl)-1, Structure
2,4-triazine-5,6-diyl]bi Activity
s-, monosodium salt Relationship
(<1%) Models)
CAS#: 69898-45-9
Germ cell mutagenicity
Product Germ Cell Mutagenicity invitro Data

No data available.
Ingredient Germ Cell Mutagenicity invitro Data

Chemical name Test Cell Strain Reported Exposure Results Key literature
sources for data
Thioglycolic acid Mutation in Salmonella None None Negative test result IUCLID (The
(20 - 30%) microorganisms typhimurium reported reported for mutagenicity International
CAS#: 68-11-1 Uniform Chemical
Information
Database)
Product Germ Cell Mutagenicity invivo Data

No data available.
Ingredient Germ Cell Mutagenicity invivo Data

No data available.
Reproductive toxicity
Product Reproductive Toxicity Data

No data available.
Ingredient Reproductive Toxicity Data

No data available.
Aspiration hazard
12. ECOLOGICAL INFORMATION
Ecotoxicity Harmful to aquatic life with long lasting effects.
Unknown aquatic toxicity 0 % of the mixture consists of component(s) of unknown hazards to the aquatic
environment.
Product Ecological Data
Aquatic Acute Toxicity

No data available.
Aquatic Chronic Toxicity

No data available.
Ingredient Ecological Data
Aquatic Acute Toxicity

Fish
Chemical name Exposure Species Endpoint Reported Key literature references and
time type dose sources for data
Acetic acid, 96 hours None reported LC50 8596 mg/L Estimation through ECOSARS
mercapto-, v1.11 part of the Estimation
monoammonium salt Programs Interface (EPI) SuiteÔ
(40 - 50%)
CAS#: 5421-46-5
Thioglycolic acid 96 hours Pimephales promelas LC50 30 mg/L IUCLID (The International
(20 - 30%) Uniform Chemical Information
CAS#: 68-11-1 Database)
Benzenesulfonic 96 hours None reported LC50 22900 mg/L Estimation through ECOSARS
acid, v1.11 part of the Estimation
4,4-[3-(2-pyridinyl)-1, Programs Interface (EPI) SuiteÔ
2,4-triazine-5,6-diyl]bi
s-, monosodium salt
(<1%)
CAS#: 69898-45-9
Crustacea
Acetic acid, 48 Hours None reported EC50 41 mg/L Estimation through ECOSARS
(40 - 50%)
CAS#: 5421-46-5
Benzenesulfonic 48 Hours None reported EC50 97900 mg/L Estimation through ECOSARS
s-, monosodium salt
(<1%)
CAS#: 69898-45-9
Algae
Acetic acid, 96 hours None reported EC50 19 mg/L Estimation through ECOSARS
(40 - 50%)
CAS#: 5421-46-5
Benzenesulfonic 96 hours None reported EC50 22400 mg/L Estimation through ECOSARS

s-, monosodium salt
(<1%)
CAS#: 69898-45-9
Aquatic Chronic Toxicity

No data available.
Persistence and degradability
Product Biodegradability Data

No data available.
Product Bioaccumulation Data

No data available.
Partition Coefficient (n-octanol/water) No data available
Mobility
Soil Organic Carbon-Water Partition Coefficient No data available
Other adverse effects

No information available
Endocrine Disruptor Information
Chemical name EU - Endocrine Disrupters EU - Endocrine Disrupters - Endocrine disrupting
Candidate List Evaluated Substances potential
Benzenesulfonic acid, Group III Chemical - -
4,4-[3-(2-pyridinyl)-1,2,4-triazine-5,6-di
yl]bis-, monosodium salt
(<1%)
CAS#: 69898-45-9
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Waste from residues/unused Dispose of in accordance with local regulations. Dispose of waste in accordance with
products environmental legislation.
Contaminated packaging Do not reuse empty containers.
US EPA Waste Number D002
14. TRANSPORT INFORMATION

DOT
UN/ID no UN2922
Proper shipping name Corrosive liquids, toxic, n.o.s.
DOT Technical Name Thioglycolic acid
Transport hazard class(es) 8
Subsidiary class 6.1
Packing Group II
Description UN2922, Corrosive liquids, toxic, n.o.s. (Thioglycolic acid), 8 (6.1), II
Emergency Response Guide 154

Number
TDG
UN/ID no UN2922
Proper shipping name Corrosive Liquid, Toxic, N.O.S.
TDG Technical Name Thioglycolic acid
Subsidiary class 6.1
Packing Group II
Description UN2922, Corrosive liquid, toxic, n.o.s. (Thioglycolic acid), 8 (6.1), II
IATA
UN number or ID number UN2922
Proper shipping name Corrosive liquid, toxic, n.o.s.
IATA Technical Name Thioglycolic acid
Subsidiary hazard class 6.1
Packing group II
ERG Code 8P
Special precautions for user A3, A803
IMDG
UN number or ID number UN2922
Proper shipping name Corrosive liquid, toxic, n.o.s.
IMDG Technical Name Thioglycolic acid
Subsidiary hazard class 6.1
Packing Group II
EmS-No F-A, S-B
Special precautions for user 274
Note: No special precautions necessary.
Additional information
There is a possibility that this product could be contained in a reagent set or kit composed of various compatible dangerous goods.
If the item is not in a reagent set or kit, the classification given above applies.
If the item is part of a reagent set or kit the classification would change to the following:
UN3316 Chemical Kit, Hazard Class 9, Packing Group II or III.
If the item is not regulated, the Chemical Kit classification does not apply.
15. REGULATORY INFORMATION

National Inventories
TSCA Complies
DSL/NDSL Complies
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
International Inventories
EINECS/ELINCS Complies
ENCS Does not comply
IECSC Complies
KECL - Existing substances Complies
PICCS Does not comply
TCSI Complies
AICS Complies
NZIoC Complies
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
TCSI - Taiwan Chemical Substances Inventory
AICS - Australian Inventory of Chemical Substances
NZIoC - New Zealand Inventory of Chemicals
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
SARA 311/312 Hazard Categories

Acute health hazard Yes
Chronic Health Hazard Yes
Fire hazard No
Sudden release of pressure hazard No
Reactive Hazard No
CWA (Clean Water Act)

This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals
IMERC: Not applicable
U.S. State Right-to-Know Regulations
This product may contain substances regulated by state right-to-know regulations.
Chemical name New Jersey Massachusetts Pennsylvania

Thioglycolic acid X X X
68-11-1
U.S. EPA Label Information
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION

Special Comments
None
Additional information
Global Automotive Declarable Substance List (GADSL)

Not applicable
NFPA and HMIS Classifications
NFPA Health hazards - 3 Flammability - 0 Instability - 0 Physical and chemical

properties -
HMIS Health hazards - 2 Flammability - 0 Physical hazards - 0 Personal protection -
-* X
-I
Key or legend to abbreviations and acronyms used in the safety data sheet
NIOSH IDLH Immediately Dangerous to Life or Health

ACGIH ACGIH (American Conference of Governmental Industrial Hygienists)
NDF no data
Legend - Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit)
MAC Maximum Allowable Concentration Ceiling Ceiling Limit Value
X Listed Vacated These values have no official status. The only

binding levels of contaminants are those
listed in the final OSHA PEL. These lists are
for reference purposes only. Please note that
some reference state regulations of these
"liberated" exposure limits in their state
regulations.
SKN* Skin designation SKN+ Skin sensitization

RSP+ Respiratory sensitization ** Hazard Designation
C Carcinogen R Reproductive toxicant
M mutagen
Prepared By Hach Product Compliance Department
Issue Date 22-11-2019
Revision Date 10-Aug-2021
Revision Note SDS sections updated

2
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End of Safety Data Sheet

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SAFETY DATA SHEET

Issue Date 22-11-2019 Revision Date Version 5.4 Page 1 / 16

Other means of identification

Safety data sheet number M00186

Recommended use of the chemical and restrictions on use

Details of the supplier of the safety data sheet

Emergency telephone number

Acute toxicity - Oral Category 3

Hazards not otherwise classified (HNOC)

Other Hazards Known

Chemical Family Mixture.

Percent ranges are used where confidential product information is applicable.

Chemical name CAS No Percent HMRIC #

Benzenesulfonic acid, 4,4-[3-(2-pyridinyl)-1,2,4-triazine-5,6-diyl]bis-, 69898-45-9 <1% -

4. FIRST AID MEASURES

Most important symptoms and effects, both acute and delayed

Indication of any immediate medical attention and special treatment needed

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Other Information Refer to protective measures listed in Sections 7 and 8.

Methods and material for containment and cleaning up

Methods for containment Prevent further leakage or spillage if safe to do so.

Methods for cleaning up Pick up and transfer to properly labeled containers.

7. HANDLING AND STORAGE

Conditions for safe storage, including any incompatibilities

Flammability class Not applicable

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Chemical name ACGIH TLV OSHA PEL NIOSH

Appropriate engineering controls

Individual protection measures, such as personal protective equipment

Eye/face protection Face protection shield.

Thermal hazards None under normal processing.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state Liquid

Property Values Remarks • Method

Molecular weight Not applicable

Melting point/freezing point ~ -9 °C / 15.8 °F

Boiling point / boiling range ~ 102 °C / 215.6 °F

Vapor pressure 2.325 mm Hg / 0.31 kPa at 20 °C / 68 °F

Relative vapor density 0.62

Specific gravity (water = 1 / air = 1) 1.310

Partition Coefficient (n-octanol/water) No data available

Soil Organic Carbon-Water Partition No data available

Decomposition temperature No data available

Dynamic viscosity No data available

Kinematic viscosity No data available

Water solubility classification Water solubility Water Solubility Temperature

Solubility in other solvents

Chemical Name Solubility classification Solubility Solubility Temperature

Steel Corrosion Rate 0.56 mm/yr / 0.02 in/yr

Volatile Organic Compounds (VOC) Content

Chemical name CAS No Volatile organic CAA (Clean Air Act)

Upper explosion limit No data available

Flash point No data available

Flammability Limit in Air

Oxidizing properties No data available.

Bulk density Not applicable

10. STABILITY AND REACTIVITY

Possibility of hazardous reactions