Physical Sciences p2 Grade 11 Nov 2015 Eng
Physical Sciences p2 Grade 11 Nov 2015 Eng
Physical Sciences p2 Grade 11 Nov 2015 Eng
SENIOR CERTIFICATE
GRADE 11
NOVEMBER 2015
MARKS: 150
TIME: 3 hours
Copyright reserved
Please turn over
Physical Sciences/P2 2 DBE/November 2015
CAPS – Grade 11
1. Write your name and class (for example 11A) in the appropriate spaces on
the ANSWER BOOK.
2. This question paper consists of TEN questions. Answer QUESTION 4.2 and
QUESTION 4.3 on the attached ANSWER SHEET. Answer ALL the other
questions in the ANSWER BOOK.
4. Number the answers correctly according to the numbering system used in this
question paper.
10. Round off your final numerical answers to a minimum of TWO decimal places.
Copyright reserved
Please turn over
Physical Sciences/P2 3 DBE/November 2015
NSC – Grade 11
Four options are provided as possible answers to the following questions. Each
question has only ONE correct answer. Choose the answer and write only the
letter (A–D) next to the question number (1.1–1.10) in the ANSWER BOOK, for
example 1.11 E.
A 5
B 7
C 8
D 15 (2)
1.3 Which ONE of the following has the strongest forces between its molecules?
A F2
B Cℓ2
C Br2
D I2 (2)
C CO2
D AℓCℓ3 (2)
Copyright reserved
Please turn over
Physical Sciences/P2 4 DBE/November 2015
NSC – Grade 11
A 2 dm3
B 11,2 dm3
C 22,4 dm3
A ΔH is positive and the products have less potential energy than the
reactants.
B ΔH is positive and the products have more potential energy than the
reactants.
C ΔH is negative and the products have less potential energy than the
reactants.
D ΔH is negative and the products have more potential energy than the
reactants. (2)
1.7 Which ONE of the following balanced equations represents a redox reaction?
1.8 During the extraction of gold, zinc powder is added to a solution of gold
cyanide to produce gold according to the following balanced equation:
A Au+
Zn
B
Na+
C
D (2)
Copyright reserved
Please turn over
Physical Sciences/P2 5 DBE/November 2015
NSC – Grade 11
If the temperature is doubled and the pressure is halved, the volume of the
gas will be …
A 4V
B 2V
C V
D ½V (2)
1.10 Two identical containers, M and N, are shown below. Container M contains
H2(g) and container N contains CO2(g). Both gases are at a temperature of
25 °C and a pressure of 101,3 kPa.
M N
H2(g) CO2(g)
25 °C 25 °C
101,3 kPa 101,3 kPa
(i) The average kinetic energy of the molecules is the same in both
containers.
(ii) Container M contains more gas molecules than container N.
(iii) The mass of the gas in container N is greater than the mass of the gas
in container M.
A (i) only
B (iii) only
Copyright reserved
Please turn over
Physical Sciences/P2 6 DBE/November 2015
NSC – Grade 11
Molecules such as CO2 and H2O are formed through covalent bonding.
2.2 ONE of the above molecules has lone pairs of electrons on the central atom.
Draw the Lewis diagram for this molecule. (2)
2.3 H3O+ is formed when H2O forms a dative covalent bond with an H+ ion.
2.3.2 State TWO conditions for the formation of such a bond. (2)
2.4.3 Explain the difference in polarity between CO2 and H2O by referring
to the polarity of the bonds and the shape of the molecules. (6)
[17]
Copyright reserved
Please turn over
Physical Sciences/P2 7 DBE/November 2015
NSC – Grade 11
3.1 The boiling point of compounds A to E are given in the table below.
3.1.5 Explain why the boiling point increases from compound A to E. (3)
3.2 Consider the boiling points of the compounds in the table below.
3.2.1 Which ONE of the substances in the table above has the weakest
forces between its molecules? (1)
Copyright reserved
Please turn over
Physical Sciences/P2 8 DBE/November 2015
NSC – Grade 11
PRESSURE VOLUME
(cm-3)
(kPa) (cm3)
40 43 0,02
80 27 0,04
100 22 (a)
120 18 (b)
4.1 Write down the name of the gas law being investigated. (1)
Answer QUESTION 4.2 and QUESTION 4.3 on the attached ANSWER SHEET.
Two values in the table, (a) and (b), have not been calculated.
4.2
Calculate these values. (1)
4.3 Draw a graph of pressure versus on the attached ANSWER SHEET. (4)
4.4 Use the graph to determine the volume of the gas at 68 kPa. (2)
4.5.1 Use the conditions at a pressure of 100 kPa and calculate the molar
mass of the enclosed gas. (6)
4.5.2 Write down the molecular formula of the enclosed gas. (1)
4.6 The sketch graph below shows the relationship between volume and
temperature for an ideal gas.
Volume (cm3)
Temperature (K)
4.6.1 Redraw the above graph in the ANSWER BOOK. On the same set
of axes, use a BROKEN LINE to sketch the graph that will be
obtained for the diatomic gas above. (1)
Copyright reserved
Please turn over
Physical Sciences/P2 9 DBE/November 2015
NSC – Grade 11
4.6.2 Fully explain why this diatomic gas deviates from ideal behaviour. (3)
[19]
Copyright reserved
Please turn over
Physical Sciences/P2 10 DBE/November 2015
NSC – Grade 11
The fizz produced when an antacid dissolves in water is caused by the reaction
between sodium hydrogen carbonate (NaHCO 3) and citric acid (H3C6H5O7). The
balanced equation for the reaction is:
5.1 Write down the FORMULA of the substance that causes the fizz when the
antacid dissolves in water. (1)
A certain antacid contains 1,8 g of H 3C6H5O7 and 3,36 g of NaHCO3. The antacid is
dissolved in 100 cm3 distilled water in a beaker.
5.4 Determine, using calculations, which substance is the limiting reagent. (4)
6.1 Sodium thiosulphate, Na2S2O3(s), reacts with 200 cm3 of a hydrochloric acid
solution, HCℓ(aq), of concentration 0,2 mol·dm-3 according to the following
balanced equation:
6.1.3 Calculate the volume of SO 2(g) that will be formed if the reaction
takes place at STP. (3)
Copyright reserved
Please turn over
Physical Sciences/P2 11 DBE/November 2015
NSC – Grade 11
6.2.3 The molar mass of menthol is 156 g·mol -1. Determine the molecular
formula of menthol. (2)
[21]
A barium hydroxide solution, Ba(OH)2(aq), reacts with a nitric acid solution, HNO 3(aq),
according to the following balanced equation:
The potential energy graph below shows the change in potential energy for this
reaction.
Potential energy
(kJ⋅mol-1)
B
116 kJ⋅mol-1
C
Course of reaction
7.2 Use energy values A, B and C indicated on the graph and write down an
expression for each of the following:
Copyright reserved
Please turn over
Physical Sciences/P2 12 DBE/November 2015
NSC – Grade 11
7.2.1 The energy of the activated complex (1)
7.3 Calculate the amount of energy released during the reaction if 0,18 moles of
Ba(OH)2(aq) reacts completely with the acid. (3)
[8]
When sulphuric acid reacts with water, it ionises in two steps, as shown in the two
balanced equations below.
8.3.2 Balanced equation for the reaction that takes place (3)
Copyright reserved
Please turn over
Physical Sciences/P2 13 DBE/November 2015
NSC – Grade 11
9.1.1 Define the term oxidation with reference to oxidation numbers. (2)
9.2.1 Define the term reducing agent with reference to electron transfer. (2)
Copyright reserved
Please turn over
Physical Sciences/P2 14 DBE/November 2015
CAPS – Grade 11
The simplified diagram below shows a blast furnace used for the extraction of iron from
iron ore. P represents a reactant added to the blast furnace. Q and R represent
products that leave the blast furnace.
Raw materials
Iron ore
Limestone
Coke
Waste Waste gases
gases out out
R
Q
Limestone and coke are added to the blast furnace, as shown in the diagram
above. Write down the function of:
10.2.1 P (1)
10.2.2 Q (1)
10.2.3 R (1)
10.3 Write down the NAME or FORMULA of ONE waste gas formed during the
extraction of iron from iron ore. (1)
10.4 The balanced equation for the extraction of iron from iron ore is:
TOTAL: 150
Copyright reserved
Physical Sciences/P2 DBE/November 2015
CAPS – Grade 11
OR/OF
Copyright reserved
Physical Sciences/P2 DBE/November 2015
CAPS – Grade 11
1 2 3 4 5 6 Atomic
8 number
9 10 11 12 13 14 15 16 17 18
KEY/SLEUTEL 7
(I) (II) Atoomgetal (III) (IV) (V) (VI) (VII) (VIII)
1 2
1,9
29
H He
2,1
Electronegativity Symbol
1 Elektronegatiwiteit
Cu Simbool 4
3 4 63,5 5 6 7 8 9 10
Li Be B C N O F Ne
1,0
1,5
2,0
2,5
3,0
3,5
4,0
7 9 Approximate relative atomic mass 11 12 14 16 19 20
11 12 Benaderde relatiewe atoommassa 13 14 15 16 17 18
Na Mg Aℓ Si P S Cℓ Ar
0,9
1,2
1,5
1,8
2,1
2,5
3,0
23 24 27 28 31 32 35,5 40
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
0,8
1,0
1,3
1,5
1,6
1,6
1,5
1,8
1,8
1,8
1,9
1,6
1,6
1,8
2,0
2,4
2,8
39 40 45 48 51 52 55 56 59 59 63,5 65 70 73 75 79 80 84
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
0,8
1,0
1,2
1,4
1,8
1,9
2,2
2,2
2,2
1,9
1,7
1,7
1,8
1,9
2,1
2,5
86 88 89 91 92 96 101 103 106 108 112 115 119 122 128 127 131
55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tℓ Pb Bi Po At Rn
0,7
0,9
1,6
1,8
1,8
1,9
2,0
2,5
133 137 139 179 181 184 186 190 192 195 197 201 204 207 209
87 88 89
Fr Ra Ac
0,7
0,9
58 59 60 61 62 63 64 65 66 67 68 69 70 71
226
Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
140 141 144 150 152 157 159 163 165 167 169 173 175
90 91 92 93 94 95 96 97 98 99 100 101 102 103
Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
232 238
Copyright reserved
Physical Sciences/P2 DBE/November 2015
CAPS – Grade 11
TABLE 3: THE PERIODIC TABLE OF ELEMENTS/TABEL 3: DIE PERIODIEKE TABEL VAN ELEMENTE
Copyright reserved
Physical Sciences/P2 DBE/November 2015
CAPS – Grade 11
Copyright reserved
Increasing oxidising ability/Toenemende oksiderende vermoë
Half-reactions/Halfreaksies
(V)
Li+ + e ⇌ Li 3,05
K+ + e ⇌ K 2,93
Cs+ + e ⇌ Cs 2,92
Ba2+ + 2e ⇌ Ba 2,90
Sr2+ + 2e ⇌ Sr 2,89
Ca2+ + 2e ⇌ Ca 2,87
Na+ + e ⇌ Na 2,71
Mg2+ + 2e ⇌ Mg 2,36
Aℓ3+ + 3e ⇌ Aℓ 1,66
Mn2+ + 2e ⇌ Mn 1,18
Cr2+ + 2e ⇌ Cr 0,91
2H2O + 2e ⇌ H2(g) + 2OH 0,83
Zn2+ + 2e ⇌ Zn 0,76
Cr3+ + 3e ⇌ Cr 0,74
Fe2+ + 2e ⇌ Fe 0,44
Cr3+ + e ⇌ Cr2+ 0,41
Cd2+ + 2e ⇌ Cd 0,40
Co2+ + 2e ⇌ Co 0,28
Ni2+ + 2e ⇌ Ni 0,27
Sn2+ + 2e ⇌ Sn 0,14
Pb2+ + 2e ⇌ Pb 0,13
Fe3+ + 3e ⇌ Fe 0,06
2H+ + 2e ⇌ H2(g) 0,00
S + 2H+ + 2e ⇌ H2S(g) + 0,14
Sn4+ + 2e ⇌ Sn2+ + 0,15
Cu2+ + e ⇌ Cu+ + 0,16
SO + 4H+ + 2e ⇌ SO2(g) + 2H2O + 0,17
Cu + 2e
2+
⇌ Cu + 0,34
2H2O + O2 + 4e ⇌ 4OH + 0,40
SO2 + 4H+ + 4e ⇌ S + 2H2O + 0,45
Cu+ + e ⇌ Cu + 0,52
I2 + 2e ⇌ 2I + 0,54
O2(g) + 2H+ + 2e ⇌ H2 O 2 + 0,68
Fe3+ + e ⇌ Fe2+ + 0,77
NO + 2H+ + e ⇌ NO2(g) + H2O + 0,80
Ag+ + e ⇌ Ag + 0,80
Hg2+ + 2e ⇌ Hg(ℓ) + 0,85
NO + 4H+ + 3e ⇌ NO(g) + 2H2O + 0,96
Br2(ℓ) + 2e ⇌ 2Br + 1,07
Pt2+ + 2 e ⇌ Pt + 1,20
MnO2 + 4H+ + 2e ⇌ Mn2+ + 2H2O + 1,23
O2(g) + 4H+ + 4e ⇌ 2H2O + 1,23
Cr2O + 14H+ +
⇌ 2Cr3+ + 7H2O + 1,33
6e
Cℓ2(g) + 2e ⇌ 2Cℓ + 1,36
MnO + 8H + 5e
+
⇌ Mn2+ + 4H2O + 1,51
H2O2 + 2H +2 e
+
⇌ 2H2O +1,77
Co3+ + e ⇌ Co2+ + 1,81
F2(g) + 2e ⇌ 2F + 2,87
Copyright reserved
Physical Sciences/P2 DBE/November 2015
CAPS – Grade 11
NAME:
CLASS:
PRESSURE VOLUME
(cm-3)
(kPa) (cm3)
50 43 0,02
80 27 0,04
100 22
120 18
100
Pressure (kPa)
80
60
40
20
Copyright reserved