SAFETY DATA SHEET

Pilot II
Section 1. Identification
GHS product identifier : Pilot II
Product code : 635
Product description : Paint.
Other means of : Not available.
identification
Product type : Liquid.

Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Uses in Coatings - Industrial use
Uses in Coatings - Professional use

Supplier's details : Jotun Paints, Inc.

9203 Highway 23
Belle Chasse, LA 70037
Telephone: (800) 229-3538 or
+1 504-394-3538
SDSJotun@jotun.com

Emergency telephone : 1-800-424-9300

number (with hours of (Staffed 24/7)
operation)
635;637 1,2 635 alkyd ^(ValidationDate) 1

Approved

Section 2. Hazards identification

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : FLAMMABLE LIQUIDS - Category 3
substance or mixture SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 2
TOXIC TO REPRODUCTION (Fertility) - Category 2
TOXIC TO REPRODUCTION (Unborn child) - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1
AQUATIC HAZARD (LONG-TERM) - Category 2

GHS label elements

Hazard pictograms :

Signal word : Danger.

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Section 2. Hazards identification

Hazard statements : Flammable liquid and vapor.
May cause an allergic skin reaction.
Suspected of damaging fertility or the unborn child.
Suspected of causing cancer.
May cause drowsiness and dizziness.
Causes damage to organs through prolonged or repeated exposure.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting
and all material-handling equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Keep container tightly closed. Use only outdoors or
in a well-ventilated area. Avoid release to the environment. Do not breathe vapor or
spray. Do not eat, drink or smoke when using this product. Wash hands thoroughly
after handling. Contaminated work clothing must not be allowed out of the workplace.
Response : Collect spillage. Get medical attention if you feel unwell. IF exposed or concerned: Get
medical attention. IF INHALED: Remove person to fresh air and keep comfortable for
breathing. Call a POISON CENTER or physician if you feel unwell. IF ON SKIN (or
hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
IF ON SKIN: Wash with plenty of soap and water. Wash contaminated clothing before
reuse. If skin irritation or rash occurs: Get medical attention. In case of fire Use dry
chemical, CO2, water spray or foam to extinguish.
Storage : Store locked up. Store in a well-ventilated place. Keep cool.
Disposal : Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise : None known.
classified

Section 3. Composition/information on ingredients

Substance/mixture : Mixture
Other means of : Not available.
identification

CAS number/other identifiers

CAS number : Not applicable.
Product code : 635
Ingredient name % CAS number
Hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, aromatics (2-25%), ≥25 - <50 64742-82-1
(<0,1% Benzene)
xylene ≥1 - <3 1330-20-7
Hydrocarbons, C9, aromatics, (<0,1% Benzene) ≥1 - <3 64742-95-6
hexanoic acid, 2-ethyl-, cobalt(2+) salt ≥0.1 - <0.3 136-52-7
2-Propenoic acid, 2-methyl-, 2-(dimethylamino)ethyl ester, polymer with butyl ≥0.1 - <0.3 1259547-09-5
2-propenoate, comps. with polyethylene glycol hydrogen maleate
C9-11-alkyl ethers
2-butanone oxime; ethyl methyl ketone oxime ≥0.1 - <0.3 96-29-7
hexanoic acid, 2-ethyl-, zirconium salt ≥0.1 - <0.3 22464-99-9
Hexanoic acid, 2-ethyl-, zinc salt, basic ≥0.1 - <0.3 85203-81-2
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.

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Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of
inhalation of decomposition products in a fire, symptoms may be delayed. The exposed
person may need to be kept under medical surveillance for 48 hours.
Skin contact : Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
Ingestion : Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. If necessary,
call a poison center or physician. Never give anything by mouth to an unconscious
person. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt
or waistband.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : No known significant effects or critical hazards.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness and
dizziness.
Skin contact : May cause an allergic skin reaction.
Ingestion : Can cause central nervous system (CNS) depression.
Over-exposure signs/symptoms
Eye contact : No specific data.
Inhalation : Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Skin contact : Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Ingestion : Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations

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Section 4. First aid measures

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam.
media
Unsuitable extinguishing : Do not use water jet.
media

Specific hazards arising : Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and
from the chemical the container may burst, with the risk of a subsequent explosion. Runoff to sewer may
create fire or explosion hazard. This material is toxic to aquatic life with long lasting
effects. Fire water contaminated with this material must be contained and prevented
from being discharged to any waterway, sewer or drain.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
nitrogen oxides
metal oxide/oxides

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information
in Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to
the environment if released in large quantities. Collect spillage.

Methods and materials for containment and cleaning up

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Section 6. Accidental release measures

Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Avoid exposure - obtain special instructions before use. Avoid
exposure during pregnancy. Do not handle until all safety precautions have been read
and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist.
Do not ingest. Avoid release to the environment. Use only with adequate ventilation.
Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas
and confined spaces unless adequately ventilated. Keep in the original container or an
approved alternative made from a compatible material, kept tightly closed when not in
use. Store and use away from heat, sparks, open flame or any other ignition source.
Use explosion-proof electrical (ventilating, lighting and material handling) equipment.
Use only non-sparking tools. Take precautionary measures against electrostatic
discharges. Empty containers retain product residue and can be hazardous. Do not
reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved area.
including any Store in original container protected from direct sunlight in a dry, cool and well-ventilated
incompatibilities area, away from incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, aromatics ACGIH TLV (United States, 1/2005). Notes:
(2-25%), (<0,1% Benzene) Substances for which the TLV is higher
than the OSHA Permissible Exposure Limit
(PEL) and/or the NIOSH Recommended
Exposure Limit (REL). See CFR 58(124) :
36338-33351, June 30, 1993, for revised
OSHA PEL.
TWA: 525 mg/m³ 8 hours. Form: All forms
TWA: 100 ppm 8 hours. Form: All forms
NIOSH REL (United States, 12/2001).

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Section 8. Exposure controls/personal protection

CEIL: 1800 mg/m³ 15 minutes. Form: All
forms
TWA: 350 mg/m³ 10 hours. Form: All forms
OSHA PEL (United States, 8/1997).
TWA: 2900 mg/m³ 8 hours. Form: All forms
TWA: 500 ppm 8 hours. Form: All forms
OSHA PEL 1989 (United States, 3/1989).
TWA: 525 mg/m³ 8 hours. Form: All forms
TWA: 100 ppm 8 hours. Form: All forms
xylene ACGIH TLV (United States, 3/2015).
STEL: 651 mg/m³ 15 minutes.
STEL: 150 ppm 15 minutes.
TWA: 434 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
OSHA PEL (United States, 2/2013).
TWA: 435 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
OSHA PEL 1989 (United States, 3/1989).
STEL: 655 mg/m³ 15 minutes.
STEL: 150 ppm 15 minutes.
TWA: 435 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
Hydrocarbons, C9, aromatics, (<0,1% Benzene) NIOSH REL (United States, 6/2001).
TWA: 125 mg/m³ 10 hours. Form: All forms
TWA: 25 ppm 10 hours. Form: All forms
ACGIH TLV (United States, 1/2005).
TWA: 123 mg/m³ 8 hours. Form: All forms
TWA: 25 ppm 8 hours. Form: All forms
OSHA PEL 1989 (United States, 3/1989).
TWA: 125 mg/m³ 8 hours. Form: All forms
TWA: 25 ppm 8 hours. Form: All forms
hexanoic acid, 2-ethyl-, cobalt(2+) salt ACGIH TLV (United States, 3/2015).
TWA: 0,02 mg/m³, (as Co) 8 hours.
2-Propenoic acid, 2-methyl-, 2-(dimethylamino)ethyl ester, polymer with None
butyl 2-propenoate, comps. with polyethylene glycol hydrogen maleate
C9-11-alkyl ethers
2-butanone oxime; ethyl methyl ketone oxime AIHA WEEL (United States, 10/2011). Skin
sensitizer.
TWA: 10 ppm 8 hours.
hexanoic acid, 2-ethyl-, zirconium salt ACGIH TLV (United States, 3/2015). Notes:
as Zr
STEL: 10 mg/m³, (as Zr) 15 minutes.
TWA: 5 mg/m³, (as Zr) 8 hours.
NIOSH REL (United States, 10/2013). Notes:
as Zr
STEL: 10 mg/m³, (as Zr) 15 minutes.
TWA: 5 mg/m³, (as Zr) 10 hours.
OSHA PEL (United States, 2/2013). Notes:
as Zr
TWA: 5 mg/m³, (as Zr) 8 hours.
OSHA PEL 1989 (United States, 3/1989).
Notes: as Zr
STEL: 10 mg/m³, (as Zr) 15 minutes.
TWA: 5 mg/m³, (as Zr) 8 hours.
Hexanoic acid, 2-ethyl-, zinc salt, basic None

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.

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Section 8. Exposure controls/personal protection

Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with side-
shields.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
There is no one glove material or combination of materials that will give unlimited
resistance to any individual or combination of chemicals.
The breakthrough time must be greater than the end use time of the product.
The instructions and information provided by the glove manufacturer on use,
storage, maintenance and replacement must be followed.
Gloves should be replaced regularly and if there is any sign of damage to the glove
material.
Always ensure that gloves are free from defects and that they are stored and used
correctly.
The performance or effectiveness of the glove may be reduced by physical/chemical
damage and poor maintenance.
Barrier creams may help to protect the exposed areas of the skin but should not be
applied once exposure has occurred.
Wear suitable gloves tested to EN374.
Recommended, gloves(breakthrough time) > 8 hours: nitrile rubber, 4H, Teflon
Not recommended, gloves(breakthrough time) < 1 hour: neoprene, butyl rubber,
PVC

Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard (NIOSH-approved P95) if a risk assessment indicates this is necessary.
Respirator selection must be based on known or anticipated exposure levels, the
hazards of the product and the safe working limits of the selected respirator.

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Section 9. Physical and chemical properties

Appearance
Physical state : Liquid.
Color : Various colors.
Odor : Characteristic.
Odor threshold : Not available.
pH : Not available.
Melting point : Not available.
Boiling point : Not available.
Flash point : Closed cup: 26°C (78.8°F)
Evaporation rate : Not available.
Flammability (solid, gas) : Not available.
Lower and upper explosive : Not available.
(flammable) limits
Vapor pressure : Not available.
Vapor density : Not available.
Relative density : 0.95 to 1.15 g/cm³ 7.93 to 9.6 pounds/gallon
Solubility : Insoluble in the following materials: cold water and hot water.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Kinematic (40°C (104°F)): >0.225 cm2/s (>22.5 mm2/s)

Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.

Incompatible materials : Reactive or incompatible with the following materials:

oxidizing materials

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
xylene LC50 Inhalation Gas. Rat 6700 ppm 4 hours
LD50 Oral Rat 4300 mg/kg -
2-butanone oxime; ethyl LD50 Oral Rat 930 mg/kg -
methyl ketone oxime
Irritation/Corrosion

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Section 11. Toxicological information

Product/ingredient name Result Species Score Exposure Observation
2-butanone oxime; ethyl Eyes - Severe irritant Rabbit - 100 -
methyl ketone oxime microliters
Sensitization
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.
Classification
Product/ingredient name OSHA IARC NTP
xylene - 3 -
hexanoic acid, 2-ethyl-, cobalt - 2B -
(2+) salt
Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Name Category Route of Target organs
exposure
Hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, Category 3 Not applicable. Narcotic effects
aromatics (2-25%), (<0,1% Benzene)
Hydrocarbons, C9, aromatics, (<0,1% Benzene) Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Specific target organ toxicity (repeated exposure)
Name Category Route of Target organs
exposure
Hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, Category 1 Not determined Not determined
aromatics (2-25%), (<0,1% Benzene)
Aspiration hazard
Name Result
Hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, aromatics ASPIRATION HAZARD - Category 1
(2-25%), (<0,1% Benzene)
Hydrocarbons, C9, aromatics, (<0,1% Benzene) ASPIRATION HAZARD - Category 1

Information on the likely : Not available.

routes of exposure
Potential acute health effects
Eye contact : No known significant effects or critical hazards.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness and
dizziness.
Skin contact : May cause an allergic skin reaction.
Ingestion : Can cause central nervous system (CNS) depression.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : No specific data.

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Section 11. Toxicological information

Inhalation : Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Skin contact : Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Ingestion : Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.
General : Causes damage to organs through prolonged or repeated exposure. Once sensitized, a
severe allergic reaction may occur when subsequently exposed to very low levels.
Carcinogenicity : Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : Suspected of damaging the unborn child.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : Suspected of damaging fertility.

Numerical measures of toxicity

Acute toxicity estimates
Route ATE value
Oral 325249,3 mg/kg
Dermal 83203,3 mg/kg
Inhalation (vapors) 832 mg/l

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Section 12. Ecological information

Toxicity
Product/ingredient name Result Species Exposure
Hydrocarbons, C9-C12, n- Acute EC50 <10 mg/l Daphnia 48 hours
alkanes, isoalkanes, cyclics,
aromatics (2-25%), (<0,1%
Benzene)
Acute IC50 <10 mg/l Algae 72 hours
Acute LC50 <10 mg/l Fish 96 hours
Hydrocarbons, C9, aromatics, Acute EC50 <10 mg/l Daphnia 48 hours
(<0,1% Benzene)
Acute IC50 <10 mg/l Algae 72 hours
Acute LC50 <10 mg/l Fish 96 hours
hexanoic acid, 2-ethyl-, cobalt Acute LC50 1.5 mg/l Fish 96 hours
(2+) salt
Hexanoic acid, 2-ethyl-, zinc Acute LC50 12.8 mg/l Fish 96 hours
salt, basic

Persistence and degradability

Product/ingredient name Aquatic half-life Photolysis Biodegradability
Hydrocarbons, C9-C12, n- - - Not readily
alkanes, isoalkanes, cyclics,
aromatics (2-25%), (<0,1%
Benzene)
xylene - - Readily
Hydrocarbons, C9, aromatics, - - Not readily
(<0,1% Benzene)

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
Hydrocarbons, C9-C12, n- - 10 to 2500 high
alkanes, isoalkanes, cyclics,
aromatics (2-25%), (<0,1%
Benzene)
xylene 3,12 8.1 to 25.9 low
Hydrocarbons, C9, aromatics, - 10 to 2500 high
(<0,1% Benzene)
hexanoic acid, 2-ethyl-, cobalt - 15600 high
(2+) salt
2-butanone oxime; ethyl 0,63 2.5 to 5.8 low
methyl ketone oxime
hexanoic acid, 2-ethyl-, - 2,96 low
zirconium salt
Hexanoic acid, 2-ethyl-, zinc - 60960 high
salt, basic

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

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Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
United States - RCRA Toxic hazardous waste "U" List
Ingredient CAS # Status Reference
number
Xylene 1330-20-7 Listed U239

Section 14. Transport information

DOT TDG Mexico ADR/RID IMDG IATA
Classification Classification Classification
UN number 1263 1263 1263 1263 1263 1263

UN proper Paint. Paint. Paint. Paint. Paint. Paint.

shipping name
Transport 3 3 3 3 3 3
hazard class(es)

Packing group III III III III III III

Environmental Yes. Yes. No. Yes. Yes. No.
hazards

Additional information
DOT Classification : This product is not regulated as a marine pollutant when transported on inland
waterways in sizes of ≤5 L or ≤5 kg or by road, rail, or inland air in non-bulk sizes,
provided the packagings meet the general provisions of §§ 173.24 and 173.24a.

Reportable quantity
7522 lbs / 3415 kg [859.18 gal / 3252.4 L]
Package sizes shipped in quantities less than the product reportable quantity are not
subject to the RQ (reportable quantity) transportation requirements.
TDG Classification : Product classified as per the following sections of the Transportation of Dangerous
Goods Regulations: 2.18-2.19 (Class 3), 2.7 (Marine pollutant mark).

The marine pollutant mark is not required when transported by road or rail.
Mexico Classification : -
ADR/RID : Tunnel restriction code: (D/E)
Hazard identification number: 30
Special provisions: 640E

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Section 14. Transport information

IMDG : Emergency schedules (EmS): F-E, S-E
Marine pollutant: Yes.
IATA : The environmentally hazardous substance mark may appear if required by other
transportation regulations.

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.

Transport in bulk according : Not available.

to Annex II of MARPOL
73/78 and the IBC Code

Section 15. Regulatory information

U.S. Federal regulations : TSCA 8(a) PAIR: 2-methoxy-1-methylethyl acetate; dipropylene glycol methyl ether
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
United States inventory (TSCA 8b): Not determined.
Clean Water Act (CWA) 307: ethylbenzene; Hexanoic acid, 2-ethyl-, zinc salt, basic
Clean Water Act (CWA) 311: ethylbenzene; xylene; maleic anhydride
Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs)
Ingredient name CAS number %
xylene 1330-20-7 1.3294

Clean Air Act Section 602 : Not listed

Class I Substances
Clean Air Act Section 602 : Not listed
Class II Substances
DEA List I Chemicals : Not listed
(Precursor Chemicals)
DEA List II Chemicals : Not listed
(Essential Chemicals)
SARA 302/304
Composition/information on ingredients
No products were found.

SARA 304 RQ : Not applicable.

SARA 311/312
Classification : Fire hazard
Immediate (acute) health hazard
Delayed (chronic) health hazard
Composition/information on ingredients
Name % Fire Sudden Reactive Immediate Delayed
hazard release of (acute) (chronic)
pressure health health
hazard hazard
Hydrocarbons, C9-C12, n- ≥25 - <50 Yes. No. No. Yes. Yes.
alkanes, isoalkanes, cyclics,
aromatics (2-25%), (<0,1%
Benzene)
xylene ≥1 - <3 Yes. No. No. Yes. No.
Hydrocarbons, C9, aromatics, ≥1 - <3 Yes. No. No. Yes. No.
(<0,1% Benzene)
hexanoic acid, 2-ethyl-, cobalt ≥0.1 - <0.3 No. No. No. Yes. Yes.

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Section 15. Regulatory information

(2+) salt
2-Propenoic acid, 2-methyl-, 2- ≥0.1 - <0.3 No. No. No. Yes. No.
(dimethylamino)ethyl ester,
polymer with butyl 2-propenoate,
comps. with polyethylene glycol
hydrogen maleate C9-11-alkyl
ethers
2-butanone oxime; ethyl methyl ≥0.1 - <0.3 No. No. No. Yes. Yes.
ketone oxime
hexanoic acid, 2-ethyl-, ≥0.1 - <0.3 No. No. No. No. Yes.
zirconium salt
Hexanoic acid, 2-ethyl-, zinc salt, ≥0.1 - <0.3 No. No. No. Yes. Yes.
basic
SARA 313
Product name CAS number %
Form R - Reporting xylene 1330-20-7 ≥1 - <3
requirements ethylbenzene 100-41-4 ≥0.3 - <1
hexanoic acid, 2-ethyl-, cobalt(2+) salt 136-52-7 ≥0.1 - <0.3
Supplier notification xylene 1330-20-7 ≥1 - <3
ethylbenzene 100-41-4 ≥0.3 - <1
hexanoic acid, 2-ethyl-, cobalt(2+) salt 136-52-7 ≥0.1 - <0.3
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
State regulations
Massachusetts : The following components are listed: XYLENE
New York : The following components are listed: Xylene (mixed)
New Jersey : The following components are listed: XYLENES; BENZENE, DIMETHYL-; COBALT
compounds; ETHYL ALCOHOL; ALCOHOL
Pennsylvania : The following components are listed: BENZENE, DIMETHYL-; COBALT COMPOUNDS;
DENATURED ALCOHOL
California Prop. 65
WARNING: This product contains a chemical known to the State of California to cause cancer.
WARNING: This product contains less than 1% of a chemical known to the State of California to cause birth defects or
other reproductive harm.
Ingredient name Cancer Reproductive No significant risk Maximum
level acceptable dosage
level
titanium dioxide Yes. No. No. No.
ethylbenzene Yes. No. 41 µg/day (ingestion) No.
54 µg/day
(inhalation)
ethanol Yes. No. No. No.
2-ethylhexanoic acid No. Yes. No. No.
talc (non-asbestos form) Yes. No. No. No.
silica, crystalline - quartz Yes. No. No. No.
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
Montreal Protocol (Annexes A, B, C, E)
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Inform Consent (PIC)

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Section 15. Regulatory information

Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
International lists
National inventory
Australia : Not determined.
Canada : Not determined.
China : Not determined.
Europe : Not determined.
Japan : Not determined.
Malaysia : Not determined.
New Zealand : Not determined.
Philippines : Not determined.
Republic of Korea : Not determined.
Taiwan : Not determined.

Section 16. Other information

Procedure used to derive the classification
Classification Justification
Flam. Liq. 3, H226 On basis of test data
Skin Sens. 1, H317 Calculation method
Carc. 2, H351 Calculation method
Repr. 2, H361 (Fertility) Calculation method
Repr. 2, H361 (Unborn child) Calculation method
STOT SE 3, H336 Calculation method
STOT RE 1, H372 Calculation method
Aquatic Chronic 2, H411 Calculation method
History
Date of printing : 03.06.2016
Date of issue/Date of : 03.06.2016
revision
Date of previous issue : 25.05.2016
Version : 1.01
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
References : Not available.
Indicates information that has changed from previously issued version.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.

Date of issue : 03.06.2016 15/15