SAFETY DATA SHEET

Date of issue 19 December 2023

Version 10.06

Section 1. Product and company identification

Product name : 9008C2 REDUCER COMPONENT
Product code : 9008C2 REDUCER COMPONENT
Other means of identification : Not available.
Product type : Liquid.

Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Coating. Paints. Painting-related materials.

Uses advised against Reason

Not applicable.

Supplier's details:
Supplier : PPG Industrial do Brasil – Tintas e Vernizes Ltda
Via Anhanguera KM 106, Bairro Sao Judas Tadeu
Sumare / SP, Brasil
55 19 2103-6000 (Recepção e Portaria)

Email address: : HazComLatam@ppg.com

Emergency telephone number :

0800 707 1767 / 0800 707 7022 – Empresa Suatrans Cotec
0800 14 8110 – CEATOX - Centro de Assistência Toxicológica

Section 2. Hazards identification

Classification of the : FLAMMABLE LIQUIDS - Category 2
substance or mixture ACUTE TOXICITY (oral) - Category 4
ACUTE TOXICITY (dermal) - Category 4
ACUTE TOXICITY (inhalation) - Category 4
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
Target organs : Contains material which causes damage to the following organs: mucous
membranes, brain, .
Contains material which may cause damage to the following organs: kidneys, the
nervous system, peripheral nervous system, upper respiratory tract, skin, eyes,
central nervous system (CNS).

Percentage of the mixture consisting of ingredient(s) of unknown hazards to the

aquatic environment: 99.7%

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Section 2. Hazards identification

GHS label elements
Hazard pictograms :

Signal word : Danger

Hazard statements : Highly flammable liquid and vapor.
Harmful if swallowed, in contact with skin or if inhaled.
Causes serious eye irritation.
May cause drowsiness or dizziness.
Precautionary statements
Prevention : Wear protective gloves and protective clothing. Wear eye or face protection. Keep
away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking. Use explosion-proof electrical, ventilating or lighting equipment. Use non-
sparking tools. Take action to prevent static discharges. Avoid breathing vapor. Do
not eat, drink or smoke when using this product. Wash thoroughly after handling.
Response : IF INHALED: Call a POISON CENTER or doctor if you feel unwell. IF ON SKIN:
Call a POISON CENTER or doctor if you feel unwell. IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical advice or attention.
Storage : Store in a well-ventilated place. Keep container tightly closed. Keep cool.
Disposal : Dispose of contents and container in accordance with all local, regional, national
and international regulations.

Other hazards which do not : Prolonged or repeated contact may dry skin and cause irritation.
result in classification

Section 3. Composition/information on ingredients

Substance/mixture : Mixture
Other means of : Not available.
identification

CAS number/other identifiers

CAS number : Not applicable.
Ingredient name % CAS number
butanone 30 - <60 78-93-3
pentane-2,4-dione 30 - <60 123-54-6
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.

SUB codes represent substances without registered CAS Numbers.

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Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Remove contact lenses, irrigate copiously with clean, fresh water, holding the
eyelids apart for at least 10 minutes and seek immediate medical advice.
Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel.
Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and
water or use recognized skin cleanser. Do NOT use solvents or thinners.
Ingestion : If swallowed, seek medical advice immediately and show this container or label.
Keep person warm and at rest. Do NOT induce vomiting.

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
Specific treatments : quantities have been ingested or inhaled.
No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it
is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing
thoroughly with water before removing it, or wear gloves.
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Harmful if inhaled. Can cause central nervous system (CNS) depression. May
cause drowsiness or dizziness.
Skin contact : Harmful in contact with skin. Defatting to the skin. May cause skin dryness and
irritation.
Ingestion : Harmful if swallowed. Can cause central nervous system (CNS) depression.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam.
media
Unsuitable extinguishing : Do not use water jet.
media

Specific hazards arising : Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion
from the chemical hazard. In a fire or if heated, a pressure increase will occur and the container may
burst, with the risk of a subsequent explosion.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon oxides

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training. Move containers from fire area if this can be done without risk.
Use water spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.

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Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers. Inform the relevant authorities if the product has caused
environmental pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools
and explosion-proof equipment. Dilute with water and mop up if water-soluble.
Alternatively, or if water-insoluble, absorb with an inert dry material and place in an
appropriate waste disposal container. Dispose of via a licensed waste disposal
contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools
and explosion-proof equipment. Approach release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Wash spillages into an
effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations (see Section 13).
Dispose of via a licensed waste disposal contractor. Contaminated absorbent
material may pose the same hazard as the spilled product. Note: see Section 1 for
emergency contact information and Section 13 for waste disposal.

Section 7. Handling and storage

Precautions for safe : Put on appropriate personal protective equipment (see Section 8). Do not ingest.
handling Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Use only
with adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Do not enter storage areas and confined spaces unless adequately
ventilated. Keep in the original container or an approved alternative made from a
compatible material, kept tightly closed when not in use. Store and use away from
heat, sparks, open flame or any other ignition source. Use explosion-proof
electrical (ventilating, lighting and material handling) equipment. Use only non-
sparking tools. Take precautionary measures against electrostatic discharges.
Empty containers retain product residue and can be hazardous. Do not reuse
container.

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Section 7. Handling and storage

Conditions for safe storage, : Do not store above the following temperature: 50°C (122°F). Store in accordance
including any with local regulations. Store in a segregated and approved area. Store in original
incompatibilities container protected from direct sunlight in a dry, cool and well-ventilated area, away
from incompatible materials (see Section 10) and food and drink. Store locked up.
Eliminate all ignition sources. Separate from oxidizing materials. Keep container
tightly closed and sealed until ready for use. Containers that have been opened
must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination. See Section 10 for incompatible materials before handling or use.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Ingredient name Exposure limits
butanone Ministry of Labor and Employment (Brazil,
11/2001).
TWA: 460 mg/m³ 8 hours.
TWA: 155 ppm 8 hours.
pentane-2,4-dione ACGIH TLV (United States, 1/2023).
Absorbed through skin.
TWA: 25 ppm 8 hours.
Recommended monitoring : Reference should be made to appropriate monitoring standards. Reference to
procedures national guidance documents for methods for the determination of hazardous
substances will also be required.

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust
controls ventilation or other engineering controls to keep worker exposure to airborne
contaminants below any recommended or statutory limits. The engineering controls
also need to keep gas, vapor or dust concentrations below any lower explosive
limits. Use explosion-proof ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products,
before eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
Eye protection : Chemical splash goggles.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary. Considering the parameters specified by the glove manufacturer,
check during use that the gloves are still retaining their protective properties. It
should be noted that the time to breakthrough for any glove material may be
different for different glove manufacturers. In the case of mixtures, consisting of
several substances, the protection time of the gloves cannot be accurately

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Section 8. Exposure controls/personal protection

estimated.
Gloves : For prolonged or repeated handling, use the following type of gloves:

May be used: butyl rubber

Body protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product. When there is a risk of ignition from static electricity,
wear anti-static protective clothing. For the greatest protection from static
discharges, clothing should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection : Respirator selection must be based on known or anticipated exposure levels, the
hazards of the product and the safe working limits of the selected respirator. If
workers are exposed to concentrations above the exposure limit, they must use
appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed
respirator complying with an approved standard if a risk assessment indicates this is
necessary.

Section 9. Physical and chemical properties

Appearance
Physical state : Liquid.
Color : Clear.
Odor : Not available.
pH : Not applicable.
Melting point : Not available.
Boiling point : >37.78°C (>100°F)
Flash point : Closed cup: -1.11°C (30°F)
Evaporation rate : Not available.
Flammability (solid, gas) : Not available.
Lower and upper explosive : Not available.
(flammable) limits
Vapor pressure : Not available.
Vapor density : Not available.
Relative density : 0.87
Media Result
Solubility(ies) :
cold water Partially soluble

Partition coefficient: n- : Not applicable.

octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Kinematic (40°C (104°F)): >21 mm2/s (>21 cSt)

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Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : When exposed to high temperatures may produce hazardous decomposition
products.

Incompatible materials : Keep away from the following materials to prevent strong exothermic reactions:
oxidizing agents, strong alkalis, strong acids.

Hazardous decomposition : Depending on conditions, decomposition products may include the following materials:
products carbon oxides

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
butanone LD50 Dermal Rabbit 6480 mg/kg -
LD50 Oral Rat 2737 mg/kg -
pentane-2,4-dione LC50 Inhalation Vapor Rat 5.1 mg/l 4 hours
LD50 Dermal Rat 790 mg/kg -
LD50 Oral Rat 570 mg/kg -
Conclusion/Summary : There are no data available on the mixture itself.
Irritation/Corrosion
Not available.
Conclusion/Summary
Skin : There are no data available on the mixture itself.
Eyes : There are no data available on the mixture itself.
Respiratory : There are no data available on the mixture itself.
Sensitization
Not available.
Conclusion/Summary
Skin : There are no data available on the mixture itself.
Respiratory : There are no data available on the mixture itself.
Mutagenicity
Not available.
Conclusion/Summary : There are no data available on the mixture itself.
Carcinogenicity
Not available.

Conclusion/Summary : There are no data available on the mixture itself.

Reproductive toxicity

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Section 11. Toxicological information

Not available.

Conclusion/Summary : There are no data available on the mixture itself.

Teratogenicity
Not available.
Conclusion/Summary : There are no data available on the mixture itself.
Specific target organ toxicity (single exposure)
Name Category Route of Target organs
exposure
butanone Category 3 - Narcotic effects

Specific target organ toxicity (repeated exposure)

Not available.

Target organs : Contains material which causes damage to the following organs: mucous
membranes, brain, .
Contains material which may cause damage to the following organs: kidneys, the
nervous system, peripheral nervous system, upper respiratory tract, skin, eyes,
central nervous system (CNS).

Aspiration hazard
Name Result
butanone ASPIRATION HAZARD - Category 2

Information on the likely : Not available.

routes of exposure
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Harmful if inhaled. Can cause central nervous system (CNS) depression. May
cause drowsiness or dizziness.
Skin contact : Harmful in contact with skin. Defatting to the skin. May cause skin dryness and
irritation.
Ingestion : Harmful if swallowed. Can cause central nervous system (CNS) depression.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness

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Section 11. Toxicological information

Skin contact : Adverse symptoms may include the following:
irritation
dryness
cracking
Ingestion : No specific data.

Delayed and immediate effects and also chronic effects from short and long term exposure
Conclusion/Summary : There are no data available on the mixture itself. Exposure to component solvent
vapor concentrations in excess of the stated occupational exposure limit may result
in adverse health effects such as mucous membrane and respiratory system
irritation and adverse effects on the kidneys, liver and central nervous system.
Symptoms and signs include headache, dizziness, fatigue, muscular weakness,
drowsiness and, in extreme cases, loss of consciousness. Solvents may cause
some of the above effects by absorption through the skin. There is some evidence
that repeated exposure to organic solvent vapors in combination with constant loud
noise can cause greater hearing loss than expected from exposure to noise alone.
If splashed in the eyes, the liquid may cause irritation and reversible damage.
Ingestion may cause nausea, diarrhea and vomiting. This takes into account, where
known, delayed and immediate effects and also chronic effects of components from
short-term and long-term exposure by oral, inhalation and dermal routes of
exposure and eye contact.
Short term exposure
Potential immediate : There are no data available on the mixture itself.
effects
Potential delayed effects : There are no data available on the mixture itself.
Long term exposure
Potential immediate : There are no data available on the mixture itself.
effects
Potential delayed effects : There are no data available on the mixture itself.
Potential chronic health effects
Not available.

General : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/
or dermatitis.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Reproductive toxicity : No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates
Product/ingredient name Oral (mg/ Dermal Inhalation Inhalation Inhalation
kg) (mg/kg) (gases) (vapors) (dusts
(ppm) (mg/l) and mists)
(mg/l)
9008C2 REDUCER COMPONENT 1041.8 1841.8 N/A 11.9 N/A
butanone 2737 6480 N/A N/A N/A
pentane-2,4-dione 570 790 N/A 5.1 N/A

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Section 11. Toxicological information

Other information : Not available.

Section 12. Ecological information

Ecotoxicity
Not available.

Persistence/degradability
Not available.

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
butanone 0.3 - Low
pentane-2,4-dione 0.68 - Low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimized wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements. Dispose of surplus and non-
recyclable products via a licensed waste disposal contractor. Waste should not be
disposed of untreated to the sewer unless fully compliant with the requirements of
all authorities with jurisdiction. Waste packaging should be recycled. Incineration
or landfill should only be considered when recycling is not feasible. This material
and its container must be disposed of in a safe way. Care should be taken when
handling emptied containers that have not been cleaned or rinsed out. Empty
containers or liners may retain some product residues. Vapor from product
residues may create a highly flammable or explosive atmosphere inside the
container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and
contact with soil, waterways, drains and sewers.

Section 14. Transport information

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Section 14. Transport information

Brazil (ANTT) IMDG IATA
UN number UN1263 UN1263 UN1263
UN proper PAINT RELATED MATERIAL PAINT RELATED MATERIAL PAINT RELATED MATERIAL
shipping name
Transport hazard 3 3 3
class(es)
Packing group II II II
Environmental No. No. No.
hazards
Marine pollutant Not applicable. Not applicable. Not applicable.
substances

Additional information
Brazil : None identified.
Risk number : 33
IMDG : None identified.
IATA : None identified.

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.

Transport in bulk according : Not applicable.

to IMO instruments

Section 15. Regulatory information

Safety, health and : No known specific national and/or regional regulations applicable to this product
environmental regulations (including its ingredients).
specific for the product

Section 16. Other information

History
Date of previous issue : 8/23/2023
Version : 10.06
Prepared by : EHS
Key to abbreviations : ADN = European Provisions concerning the International Carriage of Dangerous
Goods by Inland Waterway
ADR = The European Agreement concerning the International Carriage of
Dangerous Goods by Road
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IMDG = International Maritime Dangerous Goods

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Section 16. Other information

LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
RID = The Regulations concerning the International Carriage of Dangerous Goods
by Rail
UN = United Nations
References : ABNT NBR 14725-4: 2014
ANTT - National Land Transportation Agency

Indicates information that has changed from previously issued version.

Disclaimer
The information contained in this data sheet is based on present scientific and technical knowledge. The
purpose of this information is to draw attention to the health and safety aspects concerning the products
supplied by PPG, and to recommend precautionary measures for the storage and handling of the products.
No warranty or guarantee is given in respect of the properties of the products. No liability can be accepted
for any failure to observe the precautionary measures described in this data sheet or for any misuse of the
products.

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