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    Coordination Compounds Cet-2

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    Amen Raipur
    The document provides a chemistry test on coordination compounds with multiple choice questions, assertion-reason questions, and short answer questions. It tests understanding of topics like isomerism, hybridization, geometry, and magnetic properties of coordination complexes.

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    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd

    Coordination Compounds Cet-2

    Uploaded by

    Amen Raipur
    51 views2 pages
    The document provides a chemistry test on coordination compounds with multiple choice questions, assertion-reason questions, and short answer questions. It tests understanding of topics like isomerism, hybridization, geometry, and magnetic properties of coordination complexes.

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    COORDINATION COMPOUNDS CET-2

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    The document provides a chemistry test on coordination compounds with multiple choice questions, assertion-reason questions, and short answer questions. It tests understanding of topics like isomerism, hybridization, geometry, and magnetic properties of coordination complexes.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    51 views2 pages

    Coordination Compounds Cet-2

    Uploaded by

    Amen Raipur
    The document provides a chemistry test on coordination compounds with multiple choice questions, assertion-reason questions, and short answer questions. It tests understanding of topics like isomerism, hybridization, geometry, and magnetic properties of coordination complexes.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    of 2

    GRADE: 12 CHAPTER END TEST-2 DATE:4/9/23

    SUB: -CHEMISTRY COOORDINATION COMPOUNDS Max Marks:20

    General Instructions:
    Read the following instructions carefully.
    (a) There are 16 questions in this question paper with internal choice.
    (b) SECTION A consists of 9 multiple -choice questions carrying 1 mark each.
    (c) SECTION B consists of 1 case - based questions carrying 4 marks.
    (d) SECTION C consists of 3 short answer questions carrying 2 marks each.

    SECTION-A
    I.Multiple choice questions
    1. How many ions are produced from the complex[Co(NH3)5Cl]Cl2 in solution?
    a)4. b)2. c) 3. d)5
    2. The coordination number of ;Co’ in the complex[Co(en)3]3+
    a)3. b)6. c)4. d)5
    3. The pair [Co(NH3)4Cl2]Br2. and [Co(NH3)4Br2]Cl2 will show
    a)Linkage isomerism. b) hydrate isomerism
    c)ionization isomerism. d) coordinate isomerism
    4. The IUPAC name of [K3Fe(CN)6] is
    a)potassium ferricyanide. b) potassium hexacyanoferrate(I)
    c)potassium hexacyanoferrate(III). d) potassium hexacyanoferrate(II)
    5. The geometry of Ni(CO)4 and Ni(PPh3)2Cl2 are
    a)both square planar. B) tetra hedral and square planar
    c) both tetrahedral. D)square planar and tetrahedral
    II.Assertion-Reason questions
    Directions:- (Q.NoS. 6 to 9) each of these equations contains two
    statements:Assertion and Reason. Each of these questions also has four alternative
    choices, only one of which is the correct answer. You have to select one of the codes
    a,b, c, d given below.
    a) Both Assertion (A) and Reason (R) are correct statements, and Reason® is the
    correct explanation of the Asssertion(A).
    b) Both Assertion(A) and Reason( R) are correct statements, but the Reason(R) is
    not the correct explanation of the Assertion(A).
    c) Assertion (A) is correct, but the Reason (R) is incorrect statement.
    d) Assertion(A) is incorrect, but the Reason ( R) is correct statement.
    6. Assertion (A)- Low spin tetrashedral complexes are rarely observed.
    Reason(R)-Crystal field splitting energy is less than pairing energy for tetrahedral
    complexes.
    7. Assertion(A)- F- ion is a weak ligand and forms outer orbital complex.
    Reason(R)- F- ion cannot force the electrons of dz 2 and dx2-y2 orbitals to occupy
    dxy, dyz and dzx orbitals of the same shell.
    8. Assertion(A)- Geometrical isomerism is also called cis-trans isomerism.
    Reason(R)- Tetrahedral complexes shows geometrical complexes shows
    geometrical isomerism.
    9. Assertion(A)- [Ti(H2O)]3+ is coloured and [Sc(H2O)6]3+ is colorless.
    Reason- [Sc(H2O)6]3+ has d2sp2 type of hybridization.
    SECTION -B
    Case Study
    (Read the passage given below and answer the following questions)
    Case I Valence bond theory decribes the bonding in complexes in terms of
    coordinate covalent bonds resulting from overlap filled ligand orbitals with
    vacant metal hybrid orbitals. This theory explains magnetic behaviour and
    geometrical shape of coordination compounds.
    Magnetic moment of a complex, compound can be determined experimentally
    and theoretically by using spin only formula.
    Magnetic moment √n(n+2) BM (where, n = no. of unpaired electrons)
    10. Write the state of hybridisation, shape and the magnetic behaviour of the
    [Cr(H2O)2(C2O4)2]-.
    11. Why s-orbital does not show preference to any direction?
    12. Why is [CoF6]3-is paramagnetic but [Co(NH3)6]3+ is diamagnetic in nature?
    13. Describe the type of hybridisation, shape and magnetic properites of
    [Co(NH3)4 Cl₂] CI
    {Given: At. no. of Co= 27}
    Or
    Explain the geometry and magnetic character of complex [Cr(NH3)6]3+.
    SECTION-C
    Short answer type questions
    14. a)Draw the geometrical isomers of [Cr (NH3 )2 (CN)4)]- ?
    b)Write formula for the following compounds.
    Hexammineplatinum (VI) Chloride
    15. Explain that the complex [Co (NH3)6]3+ is diamagnetic on the basis of valence
    bond theory
    16. [Ni(CO)4]2+ is square planar whereas [NiBr4]2- is tetrahedral . Explain

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