Practical Chemistry XII

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Evaluation Scheme for Examination Marks

Volumetric Analysis 08
Salt Analysis 08

Content Based Experiment 06

Project Work 04

Class record and viva 04

Total 30

PRACTICAL SYLLABUS 60
Periods Micro-chemical methods are available for several of practical experiments. Wherever
possible, such techniques should b

A. Surface Chemistry
(a) Preparation of one lyophilic and one lyophobic sol Lyophilic sol - starch, egg albumin and gum
Lyophobic sol - aluminium hydroxide, ferric hydroxide, arsenous sulphide.
(b) Dialysis of sol-prepared in (a) above.
(c) Study of the role of emulsifying agents in stabilizing the emulsion of different oils.
B. Chemical Kinetics
(a) Effect of concentration and temperature on the rate of reaction between Sodium Thiosulphate
and Hydrochloric acid. (b) Study of reaction rates of any one of the following: (i) Reaction of Iodide
ion with Hydrogen Peroxide at room temperature using different concentrations of Iodide ion
(ii) Reaction between Potassium Iodate, (KIO3) and Sodium Sulphite: (Na2SO3) using starch solution
as an indicator (clock reaction).
C. Thermochemistry
Any one of the following experiments (a) Enthalpy of dissolution of Copper Sulphate or Potassium
Nitrate. (b) Enthalpy of neutralization of strong acid (HCI) and strong base (NaOH). (c) Determination
of enthaply change during interaction (Hydrogen bond formation) between Acetone and
Chloroform.
D. Electrochemistry
Variation of cell potential in Zn/Zn2+|| Cu2+/Cu with change in concentration of electrolytes (CuSO4
or ZnSO4) at room temperature.
E. Chromatography
(a) Separation of pigments from extracts of leaves and flowers by paper chromatography and
determination of Rf values. (b) Separation of constituents present in an inorganic mixture containing
two cations only (constituents having large difference in Rf values to be provided).
F. Preparation of Inorganic Compounds
Preparation of double salt of Ferrous Ammonium Sulphate or Potash Alum. Preparation of
Potassium Ferric Oxalate.
G. Preparation of Organic Compounds Preparation of any one of the following compounds
i) Acetanilide ii) Di -benzalAcetone iii) p-Nitroacetanilide iv) Aniline yellow or 2 - Naphthol
Anilinedye.

Tests for the functional groups present in organic compounds:


1. Unsaturation,
2. alcoholic,
3. phenolic,
4. aldehydic,
5. ketonic,
6. carboxylic and
7. amino (Primary) groups.
8.
I. Characteristic tests of carbohydrates, fats and proteins in pure samples and their detection in
given foodstuffs.

J. Determination of concentration/ molarity of KMnO4 solution by titrating it


against a standard solution of:
(a) Oxalic acid,
(b) Ferrous Ammonium Sulphate
(Students will be required to prepare standard solutions by weighing themselves).

K. Qualitative analysis Determination of one anion and one cation in a given salt
Cation:
1. Pb2+,
2. Cu2+
3. As3+,
4. Aℓ3+ ,
5. Fe3+,
6. Mn2+,
7. Zn2+,
8. Ni2+,
9. Ca2+,
10. Sr2+,
11. Ba2+,
12. Mg2+,
13. NH4
Anions:
1. (CO3) 2- ,
2. S2- ,
3. (SO3) 2- ,
4. (NO2) - ,
5. (SO4) 2- ,
6. Cℓ- ,
7. Br- ,
8. I- ,
9. (PO4) 3- ,
10. (C2O4) 2- ,
11. CH3COO- ,
12. NO3 –
(Note: Insoluble salts excluded)
INVESTIGATORY PROJECT Scientific investigations involving laboratory testing and
collecting information from other sources A few suggested Projects.
• Study of the presence of oxalate ions in guava fruit at different stages of ripening. • Study the
quantity of casein present in different samples of milk.
1. Preparation of soybean milk and its comparison with natural milk
with respect to curd formation, the effect of temperature, etc.
2. Study of the effect of Potassium Bisulphate as a food preservative
under various conditions (temperature, concentration, time, etc.)
3. Study of digestion of starch by salivary amylase and effect of pH and
temperature on it
4. Comparative study of the rate of fermentation of the following
materials: wheat flour, gram flour, potato juice, carrot juice, etc.
5. Extraction of essential oils present in Saunf (aniseed), Ajwain (carum),
Illaichi (cardamom).
6. Study of common food adulterants in fat, oil, butter, sugar, turmeric
power, chilli powder and pepper.
Note: Any other investigatory project, which involves about 10 periods of work, can be chosen with
the approval of the teacher. Practical Examination for Visually Impaired Students of Classes XI and XII

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