Limiting Reagents and POAC

Mixing and Dilution

Concentration Terms
Rearrange the following (I to IV) in the order of increasing
masses:
(I) 0.5 mole of O3 (II) 0.5 gm atom
of oxygen
(III) 3.011 x 1023 molecules of O2 (IV) 5.6 litre of CO2 at STP

A II < IV < III < I

B II < I < IV < III

C IV < II < III < I

D I < II < III < IV

Rearrange the following (I to IV) in the order of increasing
masses:
(I) 0.5 mole of O3 (II) 0.5 gm atom
of oxygen
(III) 3.011 x 1023 molecules of O2 (IV) 5.6 litre of CO2 at STP

A II < IV < III < I

B II < I < IV < III

C IV < II < III < I

D I < II < III < IV

Solution :
Q- If Avogadro’s number is A0, the number of sulphur atoms
present in 200 mL of 1 N H2SO4 is

A A0/5

B A0/2

C A0/10

D A0
Q- If Avogadro’s number is A0, the number of sulphur atoms
present in 200 mL of 1 N H2SO4 is

A A0/5

B A0/2

C A0/10

D A0
Solution:
A metal M forms the sulphate M2(SO4)3. A 0.596 gram sample of the
sulphate reacts with excess BaCl2 to give 1.220 g BaSO4. What is the atomic
weight of M ?
(Atomic weights : S = 32, Ba = 137.3)

A 26.9

B 69.7

C 55.8

D 23
A metal M forms the sulphate M2(SO4)3. A 0.596 gram sample of the
sulphate reacts with excess BaCl2 to give 1.220 g BaSO4. What is the atomic
weight of M ?
(Atomic weights : S = 32, Ba = 137.3)

A 26.9

B 69.7

C 55.8

D 23
Solution:
1.0 g of magnesium is burnt with 0.56 g O2 in a closed vessel.
Which reactant is left in excess and how much? (At. wt. Mg =
24, O = 16)

A Mg, 0.16 g

B O2, 0.16 g

C Mg, 0.44 g

D O2, 0.28 g
1.0 g of magnesium is burnt with 0.56 g O2 in a closed vessel.
Which reactant is left in excess and how much? (At. wt. Mg =
24, O = 16)

A Mg, 0.16 g

B O2, 0.16 g

C Mg, 0.44 g

D O2, 0.28 g
Solution:
Equal weight of ‘X’ (At. wt. = 36) and ‘Y’ (At. wt = 24) are
reacted to form the compound X2Y3. Then:

A X is the limiting reagent

B Y is the limiting reagent

C No reactant is left over and mass of X2Y3 formed

is double the mass of ‘X’ taken
D None of these
Equal weight of ‘X’ (At. wt. = 36) and ‘Y’ (At. wt = 24) are
reacted to form the compound X2Y3. Then:

A X is the limiting reagent

B Y is the limiting reagent

C No reactant is left over and mass of X2Y3 formed

is double the mass of ‘X’ taken
D None of these
Solution:
Suppose two elements X and Y combine to form two
compounds XY2 and X2Y3 when 0.05 mole of XY2 weighs 5g
while 3.011 x 1023 molecules of X2Y3 weighs 85 g. The atomic
masses of X and Y are respectively :

A 20, 30

B 30, 40

C 40, 30

D 80, 60
Suppose two elements X and Y combine to form two
compounds XY2 and X2Y3 when 0.05 mole of XY2 weighs 5g
while 3.011 x 1023 molecules of X2Y3 weighs 85 g. The atomic
masses of X and Y are respectively :

A 20, 30

B 30, 40

C 40, 30

D 80, 60
Solution :
The moles of methane required to produce 81 g of water after complete

combustion is____ × 10-2 mol. [Nearest integer]

Solution:
For preparation of H2SO4 from iron pyrite [FeS2] involves
following set of reaction:

Calculate the weight of H2SO4 which can be obtained when

240 kg of FeS2 is used.

A 410 kg

B 330 kg

C 240 kg

D 392 kg
For preparation of H2SO4 from iron pyrite [FeS2] involves
following set of reaction:

Calculate the weight of H2SO4 which can be obtained when

240 kg of FeS2 is used.

A 410 kg

B 330 kg

C 240 kg

D 392 kg
Solution:
Q- X g of Ca [atomic mass = 40] dissolves completely in
concentrated HCl solution to produce 5.04 L of H2 gas at STP. The
value of X is closest to

A 4.5

B 8.1

C 9.0

D 16.2
Q- X g of Ca [atomic mass = 40] dissolves completely in
concentrated HCl solution to produce 5.04 L of H2 gas at STP. The
value of X is closest to

A 4.5

B 8.1

C 9.0

D 16.2
Solution:
Q- Calculate the volume of Cl2 gas (in mL) liberated at 1 atm
and 273 K when 1.74 g MnO2 reacts with 2.19 g HCl according to
the following reaction with % yield 40:
MnO2 + HCl ⟶ MnCl2 + Cl2 + H2O

A 336 mL

B 112 mL

C 134.4 mL

D 44.8 mL
Q- Calculate the volume of Cl2 gas (in mL) liberated at 1 atm
and 273 K when 1.74 g MnO2 reacts with 2.19 g HCl according to
the following reaction with % yield 40:
MnO2 + HCl ⟶ MnCl2 + Cl2 + H2O

A 336 mL

B 112 mL

C 134.4 mL

D 44.8 mL
Solution:
Solution:
 Concentration Terms

❏ Mass percentage (w/w)

❏ Volume percentage (v/v)

❏ Mass by volume percentage (w/v)

❏ Parts per million (ppm)

 Concentration Terms

❏ Mole fraction (x)

❏ Molarity (M)

❏ Molality (m)
Dilution and Mixing of two solutions

If a particular solution having volume V1 and molarity = M1 is diluted upto

volume V2 mL than
M1V1 = M2V2 (M2 : Resultant molarity)

If a solution having volume V1 and molarity M1 is mixed with another

solution of same solute having volume V2 mL & molarity M2
The density of a solution prepared by dissolving 120 g of urea (M.M =60 u) in
1000 g of water is 1.15 g/mL. The molarity of this solution is

A 0.50 M

B 1.78 M

C 1.02 M

D 2.05 M
The density of a solution prepared by dissolving 120 g of urea (M.M =60 u) in
1000 g of water is 1.15 g/mL. The molarity of this solution is

A 0.50 M

B 1.78 M

C 1.02 M

D 2.05 M
Solution:
The mole fraction of a solute in a solution is 0.1. At 298 K, molarity of this
solution is the same as its molality. Density of this solution at 298 K is 2.0 g
cm–3 . The ratio of the molecular weights of the solute and solvent,

A 9

B 4:3

C 1:2

D None of these
The mole fraction of a solute in a solution is 0.1. At 298 K, molarity of this
solution is the same as its molality. Density of this solution at 298 K is 2.0 g
cm–3 . The ratio of the molecular weights of the solute and solvent,

A 9

B 4:3

C 1:2

D None of these
Solution:
Q- 200 mL of 1 M HCl solution is mixed with 800 mL of 2 M HCl
solution. Calculate the molarity of final solution.

A 1.8 M

B 5.6 M

C 2.90 M

D 4.0 M
Q- 200 mL of 1 M HCl solution is mixed with 800 mL of 2 M HCl
solution. Calculate the molarity of final solution.

A 1.8 M

B 5.6 M

C 2.90 M

D 4.0 M
Solution:
The molarity of Cl¯ in an aqueous solution which was (w/V) 2% NaCl, 4%
CaCl2 and 6% NH4Cl will be

A 0.342

B 0.721

C 1.12

D 2.18
The molarity of Cl¯ in an aqueous solution which was (w/V) 2% NaCl, 4%
CaCl2 and 6% NH4Cl will be

A 0.342

B 0.721

C 1.12

D 2.18
Solution:
What is the molarity of SO42- ion in aqueous solution that
contain 34.2 ppm of Al2(SO4)3? (Assume complete dissociation
and density of solution 1 g/mL)

A 3 🇽 10-4 M

B 2 🇽 10-4 M

C 10-4 M

D None of these
What is the molarity of SO42- ion in aqueous solution that
contain 34.2 ppm of Al2(SO4)3? (Assume complete dissociation
and density of solution 1 g/mL)

A 3 🇽 10-4 M

B 2 🇽 10-4 M

C 10-4 M

D None of these
Solution :
 Equivalent weight

Molecular Weight
Equivalent Weight =
Valency Factor

Unit of Equivalent Weight : g/eq

 n-factor /Valency Factor

Type Valency factor / n factor

Acids No. of replaceable H+ ions per acid molecule

Bases No. of replaceable OH– ions per base molecule

Salts total cationic/anionic charge present in 1 mole of the salt

Cation / Anion Charge on ion

Equivalent or Gram equivalent
 Normality

This is defined as the number of equivalent or gram equivalent of any

substances dissolved in one litre of solution.
 Titrations

1 equivalent of a reactant (Titre) reacts with 1 equivalent of the counter-reactant (Titrant)

Equivalents of Titre = Equivalents of Titrant

In terms of Normality (N) and Volume (V):

N1V1 = N2V2

Using relationship between Normality (N), Molarity(M) and Valency Factor(z): N = z × M

z1M1V1 = z2M2V2
Q- Find the Equivalent weight of K2SO4.Al2(SO4)3.24H2O
(Mol. Mass = M)
Solution:
Q- The equivalent weight of HCl in the given reaction is :
K2Cr2O7 + 14HCl → 2KCl + 2CrCl3 + 3Cl2 + H2O

A 16.25

36.5
B

C 73

D 85.1
Q- The equivalent weight of HCl in the given reaction is :
K2Cr2O7 + 14HCl → 2KCl + 2CrCl3 + 3Cl2 + H2O

A 16.25

36.5
B

C 73

D 85.1
Solution:
Q- Calculate the normality of a solution containing 15.8 g of KMnO 4 in 50 mL acidic
solution.

A 8

6
B

C 1

D 10
Q- Calculate the normality of a solution containing 15.8 g of KMnO 4 in 50 mL acidic
solution.

A 8

6
B

C 1

D 10
Solution:
Q- If the weight of metal oxide is x g containing y g of oxygen, the equivalent weight
of metal will be

D
Q- If the weight of metal oxide is x g containing y g of oxygen, the equivalent weight
of metal will be

D
Solution:
JEE Main PYQ’s
25 g of an unknown hydrocarbon upon burning produces 88 g of CO2 and 9
g of H2O . This unknown hydrocarbon contains
JEE Main 2019

A 20 g of C and 5 g of H

B 22 g of C and 3 g of H

C 24 g of C and 1 g of H

D 18 g of C and 7 g of H
25 g of an unknown hydrocarbon upon burning produces 88 g of CO2 and 9
g of H2O . This unknown hydrocarbon contains
JEE Main 2019

A 20 g of C and 5 g of H

B 22 g of C and 3 g of H

C 24 g of C and 1 g of H

D 18 g of C and 7 g of H
Solution:
Compound A contains 8.7% Hydrogen, 74% Carbon and 17.3% Nitrogen.

The molecular formula of the compound is,

Given: Atomic masses of C, H and N are 12, 1 and 14 amu respectively.

The molar mass of the compound A is 162 g mol-1.

JEE Main 2022

A C4H6N2

B C2H3N

C C5H7N

D C10H14N2
Compound A contains 8.7% Hydrogen, 74% Carbon and 17.3% Nitrogen.

The molecular formula of the compound is,

Given: Atomic masses of C, H and N are 12, 1 and 14 amu respectively.

The molar mass of the compound A is 162 g mol-1.

A C4H6N2

B C2H3N

C C5H7N

D C10H14N2
Solution:
Q- In the reaction of oxalate with permanganate in acidic medium, the number of
electrons involved in producing one molecule of CO 2 is

JEE Mains 2019

A 1

B 10

C 2

D 5
Q- In the reaction of oxalate with permanganate in acidic medium, the number of
electrons involved in producing one molecule of CO 2 is

JEE Mains 2019

A 1

B 10

C 2

D 5
Solution:
8 g of NaOH is dissolved in 18 g of H2O. Mole fraction of NaOH in solution and
molality (in mol kg-1) of the solution respectively are
JEE Main 2019

A 0.2, 11.11

B 0.167, 22.20

C 0.2, 22.20

D 0.167, 11.11
8 g of NaOH is dissolved in 18 g of H2O. Mole fraction of NaOH in solution and
molality (in mol kg-1) of the solution respectively are
JEE Main 2019

A 0.2, 11.11

B 0.167, 22.20

C 0.2, 22.20

D 0.167, 11.11
Solution:
Which of the following oxoacids of sulphur contains “S” in two different

oxidation states?
JEE Main 2022

A H2S2O3

B H2S2O6

C H2S2O7

D H2S2O8
Which of the following oxoacids of sulphur contains “S” in two different

oxidation states?

A H2S2O3

B H2S2O6

C H2S2O7

D H2S2O8
Solution:
Q- 4.5 g of compound A (MW = 90) was used to make 250 mL of its aqueous
solution. The molarity of the solution in M is x × 10–1. The value of x is ________.
(Rounded off to the nearest integer)
JEE Mains 2021
Q- 4.5 g of compound A (MW = 90) was used to make 250 mL of its aqueous
solution. The molarity of the solution in M is x × 10–1. The value of x is ________.
(Rounded off to the nearest integer)

Ans 2
Solution:
Q- The NaNO3 weighed out to make 50 mL of an aqueous solution containing 70.0
mg Na+ per mL is ______g. (Rounded off to the nearest integer)
[Given : Atomic weight in g mol–1 – Na : 23 ; N : 14 ; O : 16]

JEE Mains 2021

Q- The NaNO3 weighed out to make 50 mL of an aqueous solution containing 70.0
mg Na+ per mL is ______g. (Rounded off to the nearest integer)
[Given : Atomic weight in g mol–1 – Na : 23 ; N : 14 ; O : 16]

Ans 13
Solution:
Q- The number of chlorine atoms in 20 mL of chlorine gas at STP is_____1021.
(Round off to the Nearest Integer).
[Assume chlorine is an ideal gas at STP
R = 0.083 L bar mol–1 K–1, NA = 6.023 ×1023]
JEE Mains 2021
Q- The number of chlorine atoms in 20 mL of chlorine gas at STP is_____1021.
(Round off to the Nearest Integer).
[Assume chlorine is an ideal gas at STP
R = 0.083 L bar mol–1 K–1, NA = 6.023 ×1023]

Ans 1
Solution:
Q- Complete combustion of 3 g of ethane gives x × 1022 molecules of water. The
value of x is ______. (Round off to the Nearest Integer).
[Use : NA = 6.023 × 1023; Atomic masses in u : C : 12.0 ; O : 16.0 ; H : 1.0]

JEE Mains 2021

Q- Complete combustion of 3 g of ethane gives x × 1022 molecules of water. The
value of x is ______. (Round off to the Nearest Integer).
[Use : NA = 6.023 × 1023; Atomic masses in u : C : 12.0 ; O : 16.0 ; H : 1.0]

Ans 18
Solution:
Q- 250 mL of 0.5 M NaOH was added to 500 mL of 1 M HCl. The number of unreacted
HCl molecules in the solution after complete reaction is _______ ×1021. (Nearest
integer)
(NA = 6.022 × 1023)
JEE Mains 2021
Q- 250 mL of 0.5 M NaOH was added to 500 mL of 1 M HCl. The number of unreacted
HCl molecules in the solution after complete reaction is _______ ×1021. (Nearest
integer)
(NA = 6.022 × 1023)

Ans 226
Solution:
Q- If the concentration of glucose (C6H12O6) in blood is 0.72 g L–1, the molarity of
glucose in blood is ______ × 10–3M. (Nearest integer)
[Given : Atomic mass of C = 12, H = 1, O = 16 u]

JEE Mains 2021

Q- If the concentration of glucose (C6H12O6) in blood is 0.72 g L–1, the molarity of
glucose in blood is ______ × 10–3M. (Nearest integer)
[Given : Atomic mass of C = 12, H = 1, O = 16 u]

Ans 4
Solution:
Q- The reaction of sulphur in alkaline medium is the below:

The values of 'a' is _______. (Integer answer)

JEE Mains 2021
Q- The reaction of sulphur in alkaline medium is the below:

The values of 'a' is _______. (Integer answer)

Ans 12
Solution:
Q- The oxidation states of nitrogen in NO, NO2, N2O and NO3– are in the order of :

JEE Mains 2021

A NO3- > NO2 > NO > N2O

B NO2 > NO3- > NO > N2O

C N2O > NO2 > NO > NO3-

D NO > NO2 > N2O > NO3-

Q- The oxidation states of nitrogen in NO, NO2, N2O and NO3– are in the order of :

A NO3- > NO2 > NO > N2O

B NO2 > NO3- > NO > N2O

C N2O > NO2 > NO > NO3-

D NO > NO2 > N2O > NO3-

Solution:
Q- 25 ml of the given HCl solution requires 30 mL of 0.1 M sodium carbonate
solution. What is the volume of this HCl solution required to titrate 30 mL of 0.2 M
aqueous NaOH solution

[JEE (Main) - 2019]

A 25 mL

12.5 mL
B

C 50 mL

D 75 mL
Q- 25 ml of the given HCl solution requires 30 mL of 0.1 M sodium carbonate
solution. What is the volume of this HCl solution required to titrate 30 mL of 0.2 M
aqueous NaOH solution

[JEE (Main) - 2019]

A 25 mL

12.5 mL
B

C 50 mL

D 75 mL
Solution:
Q- The volume, in mL, of 0.02 M K2Cr2O7 solution required to react with 0.288 g of
ferrous oxalate in acidic medium is _______.
(Molar mass of Fe = 56 g mol–1)
[JEE (Main) - 2020]
Solution:
Q- The oxidation states of ‘P’ in H4P2O7 , H4P2O5 and H4P2O6 , respectively are

[JEE (Main) - 2021]

A 5, 4 and 3

7, 5 and 6
B

C 6, 4 and 5

D 5, 3 and 4
Q- The oxidation states of ‘P’ in H4P2O7 , H4P2O5 and H4P2O6 , respectively are

[JEE (Main) - 2021]

A 5, 4 and 3

7, 5 and 6
B

C 6, 4 and 5

D 5, 3 and 4
Solution:
Q- Identify the process in which change in the oxidation state is five :

[JEE (Main) - 2021]

A C2O42- → 2CO2

MnO4- → Mn2+
B

C Cr2O72- → 2Cr3+

D CrO42- → Cr3+
Q- Identify the process in which change in the oxidation state is five :

[JEE (Main) - 2021]

A C2O42- → 2CO2

MnO4- → Mn2+
B

C Cr2O72- → 2Cr3+

D CrO42- → Cr3+
Solution:
A solution of sodium sulphate contains 92 g of Na+ ions per kg of water. The
molality of Na+ ions in that solution in mol kg-1 is
JEE Main 2019

A 16

B 4

C 132

D 8
A solution of sodium sulphate contains 92 g of Na+ ions per kg of water. The
molality of Na+ ions in that solution in mol kg-1 is
JEE Main 2019

A 16

B 4

C 132

D 8
Solution:
In order to oxidise a mixture of one mole of each of FeC2O4, Fe2(C2O4)3, FeSO4
and Fe2(SO4)3 in acidic medium, the number of moles of KMnO4 required is
JEE Main 2019

A 2

B 1

C 3

D 1.5
In order to oxidise a mixture of one mole of each of FeC2O4, Fe2(C2O4)3, FeSO4
and Fe2(SO4)3 in acidic medium, the number of moles of KMnO4 required is

A 2

B 1

C 3

D 1.5
Solution:
Q- An example of a disproportionation reaction is:

[JEE (Main) - 2019]

A 2MnO4- + 10I– + 16H+ → 2Mn2+ + 5I2 + 8H2O

B 2CuBr → CuBr2 + Cu

C 2KMnO4 → K2MnO4 + MnO2 + O2

D 2NaBr + Cl2 → 2NaCl + Br2

Q- An example of a disproportionation reaction is:

[JEE (Main) - 2019]

A 2MnO4- + 10I– + 16H+ → 2Mn2+ + 5I2 + 8H2O

B 2CuBr → CuBr2 + Cu

C 2KMnO4 → K2MnO4 + MnO2 + O2

D 2NaBr + Cl2 → 2NaCl + Br2

Solution:

It is an example of disproportionation reaction.

50 mL of 0.5 M oxalic acid is needed to neutralise 25 mL of sodium
hydroxide solution. The amount of NaOH in 50 mL of the given sodium
hydroxide solution is JEE Main 2019

A 4g

B 80 g

C 20 g

D 10 g
50 mL of 0.5 M oxalic acid is needed to neutralise 25 mL of sodium
hydroxide solution. The amount of NaOH in 50 mL of the given sodium
hydroxide solution is

A 4g

B 80 g

C 20 g

D 10 g
Solution:
Q- 4g equimolar mixture of NaOH and Na2CO3 contains x g of NaOH and y g of
Na2CO3. The value of x is ______ g. (Nearest integer)
[JEE (Main) - 2021]
Q- 4g equimolar mixture of NaOH and Na2CO3 contains x g of NaOH and y g of
Na2CO3. The value of x is ______ g. (Nearest integer)

Ans 1
Solution:
Q- Consider the following reaction :

The values of x, y and z in the reaction are, respectively

[JEE (Main) - 2013]

A 5, 2 and 16

B 2, 5 and 8

C 2, 5 and 16

D 5, 2 and 8
Q- Consider the following reaction :

The values of x, y and z in the reaction are, respectively

[JEE (Main) - 2013]

A 5, 2 and 16

B 2, 5 and 8

C 2, 5 and 16

D 5, 2 and 8
Solution:

2MnO4- + 5C2O42- + 16 H+ → 2Mn2+ → 10 CO2 + 8H2O

Which of the following is an example of disproportionation reaction?

JEE Main 2022

A 3MnO42- + 4H+ → 2MnO4- + MnO2 + 2H2O

B MnO42- + 4H+ + 4e- → MnO2 + 2H2O

C 10I- + 2MnO4- + 16H+ → 2Mn2+ + 8H2O + 5I2

D 8MnO4- + 3S2O32- + H2O → 8MnO2 + 6SO42- + 2OH-

Which of the following is an example of disproportionation reaction?

A 3MnO42- + 4H+ → 2MnO4- + MnO2 + 2H2O

B MnO42- + 4H+ + 4e- → MnO2 + 2H2O

C 10I- + 2MnO4- + 16H+ → 2Mn2+ + 8H2O + 5I2

D 8MnO4- + 3S2O32- + H2O → 8MnO2 + 6SO42- + 2OH-

Solution:
A commercially sold conc. HCl is 35% HCl by mass. If the density of this

commercial acid is 1.46 g/mL, the molarity of this solution is:

Atomic mass: Cl = 35.5 amu, H = 1 amu)

JEE Main 2022

A 10.2 M

B 12.5 M

C 14.0 M

D 18.2 M
A commercially sold conc. HCl is 35% HCl by mass. If the density of this

commercial acid is 1.46 g/mL, the molarity of this solution is:

Atomic mass: Cl = 35.5 amu, H = 1 amu)

A 10.2 M

B 12.5 M

C 14.0 M

D 18.2 M
Solution:
The number of N atoms in 681 g of C7H5N3O6 is x × 1021. The value of x is___

(NA = 6.02 × 1023 mol-1) (Nearest Integer) JEE Main 2022

Solution:
The complete combustion of 0.492 g of an organic compound containing

‘C’, ‘H’ and ‘O’ gives 0.793g of CO2 and 0.442 g of H2O. The percentage of

oxygen composition in the organic compound is___(nearest integer)

JEE Main 2022

Solution:
0.01 M KMnO4 solution was added to 20.0 mL of 0.05 M Mohr’s salt solution

through a burette. The initial reading of 50 mL burette is zero. The volume

of KMnO4 solution left in the burette after the end point is___

mL. (nearest integer)

JEE Main 2022

Solution:
15 mL of aqueous solution of Fe2+ in acidic medium completely reacted with
20 mL of 0.03 M aqueous Cr2O72-. The molarity of the Fe2+ solution is ___
x 10-2 M. (Round off) JEE Main 2021
15 mL of aqueous solution of Fe2+ in acidic medium completely reacted with
20 mL of 0.03 M aqueous Cr2O72-. The molarity of the Fe2+ solution is ___
x 10-2 M. (Round off)

Answer : (24)
Solution:
Test Yourself
The chief ore of Zn is the sulphide, ZnS. The ore is concentrated by froth
floatation process and then heated in air to convert ZnS to ZnO.

The number of moles of ZnS required for producing 2 moles of Zn will be :

A 3.125

B 2

C 2.125

D 4
The chief ore of Zn is the sulphide, ZnS. The ore is concentrated by froth
floatation process and then heated in air to convert ZnS to ZnO.

The number of moles of ZnS required for producing 2 moles of Zn will be :

A 3.125

B 2

C 2.125

D 4
Solution:
9 moles of “D” and 14 moles of E are allowed to react in a closed vessel
according to given reactions. Calculate number of moles of B formed in
the end of reaction, if 4 moles of G are present in reaction vessel.
(Percentage yield of reaction is mentioned in the reaction)

A 2.4

B 30

C 4.8

D 1
9 moles of “D” and 14 moles of E are allowed to react in a closed vessel
according to given reactions. Calculate number of moles of B formed in
the end of reaction, if 4 moles of G are present in reaction vessel.
(Percentage yield of reaction is mentioned in the reaction)

A 2.4

B 30

C 4.8

D 1
Solution:
Excess NaOH (aq) was added to 100mL of FeCI3, (aq) resulting into
2.14 g of Fe(OH)3-.The molarity of FeCI3 (aq) is:
(Given molar mass of Fe= 56 g mol+1 and molar mass of CI = 35.5 g
mol-1)

A 0.2 M

B 0.3 M

C 0.6 M

D 1.8 M
Excess NaOH (aq) was added to 100mL of FeCI3, (aq) resulting into
2.14 g of Fe(OH)3-.The molarity of FeCI3 (aq) is:
(Given molar mass of Fe= 56 g mol+1 and molar mass of CI = 35.5 g
mol-1)

A 0.2 M

B 0.3 M

C 0.6 M

D 1.8 M
Solution:
What weights of P4O6 and P4O10 will be produced by the combustion of 31g of
P4 in 32 g of oxygen leaving no P4 and O2.

A 2.75 g, 219.5 g

B 27.5 g, 35.5 g

C 55 g, 71 g

D 17.5 g, 190.5 g
What weights of P4O6 and P4O10 will be produced by the combustion of 31g of
P4 in 32 g of oxygen leaving no P4 and O2.

A 2.75 g, 219.5 g

B 27.5 g, 35.5 g

C 55 g, 71 g

D 17.5 g, 190.5 g
Solution:
A sample of chalk contains clay as impurity. The clay impurity loses 11% of
its weight as moisture on prolong heating. 5 gram sample of chalk on
heating shows a loss in weight (due to evolution of CO2 and water) by 1.1 g.
Calculate % of chalk (CaCO3) in the sample. [Hint : Chalk (CaCO3) releases
CO2 on heating]

A 50%

B 80%

C 33.33%

D 43.78%
A sample of chalk contains clay as impurity. The clay impurity loses 11% of
its weight as moisture on prolong heating. 5 gram sample of chalk on
heating shows a loss in weight (due to evolution of CO2 and water) by 1.1 g.
Calculate % of chalk (CaCO3) in the sample. [Hint : Chalk (CaCO3) releases
CO2 on heating]

A 50%

B 80%

C 33.33%

D 43.78%
Solution:
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