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Material Safety Data Sheet

Sulfuric Acid 50% (w/w) Solution MSDS

Section 1: Chemical Product and Company Identification

Product Name: Sulfuric Acid 50% (w/w) Solution Contact Information:

Catalog Codes: SLS1573 Sciencelab.com, Inc.
14025 Smith Rd.
CAS#: Mixture. Houston, Texas 77396
RTECS: Not applicable. US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
TSCA: TSCA 8(b) inventory: Sulfuric acid; Water
Order Online: ScienceLab.com
CI#: Not applicable.
CHEMTREC (24HR Emergency Telephone), call:
Synonym: Sulfuric Acid, 50% (w/w) Solution 1-800-424-9300
Chemical Name: Not applicable. International CHEMTREC, call: 1-703-527-3887
Chemical Formula: Not applicable. For non-emergency assistance, call: 1-281-441-4400

Section 2: Composition and Information on Ingredients

Composition:

Name CAS # % by Weight

Sulfuric acid 7664-93-9 50
Water 7732-18-5 50

Toxicological Data on Ingredients: Sulfuric acid: ORAL (LD50): Acute: 2140 mg/kg [Rat.]. VAPOR (LC50): Acute: 510 mg/m
2 hours [Rat]. 320 mg/m 2 hours [Mouse].

Section 3: Hazards Identification

Potential Acute Health Effects:

Very hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, . Hazardous in case of skin contact
(corrosive, permeator), of eye contact (corrosive). Slightly hazardous in case of inhalation (lung sensitizer). Non-corrosive for
lungs. Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory
tract. Skin contact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratory tract,
characterized by coughing, choking, or shortness of breath. Severe over-exposure can result in death. Inflammation of the
eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or,
occasionally, blistering.
Potential Chronic Health Effects:
Non-corrosive for skin. Non-irritant for skin. Non-sensitizer for skin. Non-permeator by skin. Non-irritating to the eyes.
Non-hazardous in case of ingestion. Non-hazardous in case of inhalation. Non-irritant for lungs. Non-sensitizer for lungs.

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CARCINOGENIC EFFECTS: Classified 1 (Proven for human.) by IARC, + (Proven.) by OSHA [Sulfuric acid]. Classified A2
(Suspected for human.) by ACGIH [Sulfuric acid]. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not
available. DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/female, Reproductive system/toxin/male
[SUSPECTED] [Sulfuric Acid 50% (w/w) Solution]. The substance may be toxic to the reproductive system, teeth. Repeated
or prolonged exposure to the substance can produce target organs damage. Repeated or prolonged contact with spray mist
may produce chronic eye irritation and severe skin irritation. Repeated or prolonged exposure to spray mist may produce
respiratory tract irritation leading to frequent attacks of bronchial infection. Repeated exposure to a highly toxic material may
produce general deterioration of health by an accumulation in one or many human organs.

Section 4: First Aid Measures

Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention immediately.
Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing
and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly clean
shoes before reuse. Get medical attention immediately.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical
attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention immediately.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If
breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may
be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or
corrosive. Seek immediate medical attention.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.

Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Not available.
Fire Hazards in Presence of Various Substances: Not applicable.
Explosion Hazards in Presence of Various Substances:
Slightly explosive in presence of oxidizing materials. Non-explosive in presence of open flames and sparks, of shocks.
Fire Fighting Media and Instructions: Not applicable.
Special Remarks on Fire Hazards: Not available.
Special Remarks on Explosion Hazards:

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Mixturesofsulfuricacidandanyofthefollowingcanexplode:p-nitrotoluene,pentasi
l v e r trihydroxydiaminophosphate, perchlorates, alcohols with strong hydrogen peroxide, ammonium tetraperoxychromate,
mercuric nitrite, potassium chlorate, potassium permanganate with potassium chloride. Nitramide decomposes explosively
on contact with concentrated sulfuric acid. 1,3,5-Trinitrosohexahydro-1,3,5-triazine + sulfuric acid causes explosive
decompositon. (Sulfuric acid)

Section 6: Accidental Release Measures

Small Spill:
Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. If
necessary: Neutralize the residue with a dilute solution of sodium carbonate.
Large Spill:
Corrosive liquid. Poisonous liquid. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material.
Do not get water inside container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Use water spray
to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal.
Neutralize the residue with a dilute solution of sodium carbonate. Be careful that the product is not present at a concentration
level above TLV. Check TLV on the MSDS and with local authorities.

Section 7: Handling and Storage

Precautions:
Keep locked up.. Keep container dry. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Never add water to this product.
In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and
show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents,
combustible materials, organic materials, metals, acids, alkalis, moisture. May corrode metallic surfaces. Store in a metallic or
coated fiberboard drum using a strong polyethylene inner package.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 23°C (73.4°F).

Section 8: Exposure Controls/Personal Protection

Engineering Controls:
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective
threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.
Personal Protection:
Face shield. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Boots.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits:
Sulfuric acid TWA: 1 STEL: 3 (mg/m3) [Australia] Inhalation TWA: 1 (mg/m3) from OSHA (PEL) [United States] Inhalation
TWA: 1 STEL: 3 (mg/m3) from ACGIH (TLV) [United States] [1999] Inhalation TWA: 1 (mg/m3) from NIOSH [United States]
Inhalation TWA: 1 (mg/m3) [United Kingdom (UK)]3 Consult local authorities for acceptable exposure limits.

Section 9: Physical and Chemical Properties

Physical state and appearance: Liquid.

Odor: Odorless.
Taste: Not available.

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Molecular Weight: Not applicable.
Color: Colorless. Clear
pH (1% soln/water): Acidic.
Boiling Point: The lowest known value is 100°C (212°F) (Water). Weighted average: 195°C (383°F)
Melting Point: May start to solidify at 10.36°C (50.6°F) based on data for: Sulfuric acid.
Critical Temperature: Not available.
Specific Gravity: Weighted average: 1.3 (Water = 1)
Vapor Pressure: The highest known value is 2.3 kPa (@ 20°C) (Water).
Vapor Density: The highest known value is 3.4 (Air = 1) (Sulfuric acid). Weighted average: 2.01 (Air = 1)
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water.
Solubility: Easily soluble in cold water, hot water.

Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.
Conditions of Instability: Incompatible materials
Incompatibility with various substances: Reactive with oxidizing agents, combustible materials, organic materials, metals,
acids, alkalis.
Corrosivity:
Extremely corrosive in presence of aluminum, of stainless steel(304), of stainless steel(316). Non-corrosive in presence of
glass.
Special Remarks on Reactivity:
Incompatible with the following materials: potassium chlorate, potassium perchlorate, potassium permanganate, sodium,
lithium, bases, organic material, halogens, metal acetylides, oxides and hydrides, metals as non powders(yields hydrogen
gas), metal compounds, metals as powders, strong oxidizing and reducing agents. Concentrated solutions react violently with
water, spattering and liberating heat.
Special Remarks on Corrosivity:
Concentrated acid is non-corrosive to lead and mild steel, but diluted acid attacks most metals. Attacks and corrodes many
metals releasing hydrogen. Minor corrosive on bronze. No data for copper, zinc or brass.
Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Absorbed through skin. Dermal contact. Eye contact.

Toxicity to Animals: Acute oral toxicity (LD50): 4280 mg/kg (Rat.) (Calculated value for the mixture).
Chronic Effects on Humans:
CARCINOGENIC EFFECTS: Classified 1 (Proven for human.) by IARC, + (Proven.) by OSHA [Sulfuric acid]. Classified A2
(Suspected for human.) by ACGIH [Sulfuric acid]. DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/

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female, Reproductive system/toxin/male [SUSPECTED] [Sulfuric Acid 50% (w/w) Solution]. May cause damage to the
following organs: the reproductive system, teeth.
Other Toxic Effects on Humans:
Extremely hazardous in case of inhalation (lung corrosive). Very hazardous in case of skin contact (irritant), of ingestion, .
Hazardous in case of skin contact (corrosive, permeator), of eye contact (corrosive).
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans: May cause adverse reproductive effects and Cancer.
Special Remarks on other Toxic Effects on Humans:

Section 12: Ecological Information

Ecotoxicity: Not available.

BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: Class 8: Corrosive material

Identification: : Sulfuric Acid, Solution (Sulfuric acid) UNNA: 2796 PG: II
Special Provisions for Transport: Not available.

Section 15: Other Regulatory Information

Federal and State Regulations:

Illinois toxic substances disclosure to employee act: Sulfuric acid New York release reporting list: Sulfuric acid Rhode Island
RTK hazardous substances: Sulfuric acid Pennsylvania RTK: Sulfuric acid Minnesota: Sulfuric acid Massachusetts RTK:
Sulfuric acid New Jersey: Sulfuric acid TSCA 8(b) inventory: Sulfuric acid; Water SARA 302/304/311/312 extremely hazardous
substances: Sulfuric acid SARA 313 toxic chemical notification and release reporting: Sulfuric acid 50% CERCLA: Hazardous
substances.: Sulfuric acid: 1000 lbs. (453.6 kg);
Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
Other Classifications:
WHMIS (Canada):
CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC). CLASS E: Corrosive liquid.
DSCL (EEC):
R35- Causes severe burns. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S30- Never add water to this product. S45- In case of accident or if you feel unwell, seek medical advice immediately (show
the label where possible).

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HMIS (U.S.A.):
Health Hazard: 3
Fire Hazard: 0
Reactivity: 0
Personal Protection:
National Fire Protection Association (U.S.A.):
Health: 3
Flammability: 0
Reactivity: 2
Specific hazard:
Protective Equipment:
Gloves. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator
when ventilation is inadequate. Face shield.

Section 16: Other Information

References: Not available.

Other Special Considerations: Not available.
Created: 10/09/2005 11:59 PM
Last Updated: 05/21/2013 12:00 PM

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