A 000 989 88 03 11 Servolenkungsöl/ Lenkgetriebeöl MB 236.3

Safety Data Sheet according to Regulation (EC) No.
1907/2006 (REACH)
A 000 989 88 03 11
Servolenkungsöl/ Lenkgetriebeöl MB 236.3
Print date 20.04.2023
Revision date 01.01.2023
Version 4.0 (en)
replaces version of 05.11.2021 (3.0)
SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Trade name/designation Servolenkungsöl/ Lenkgetriebeöl MB 236.3
MB-Freigabe-Nr 236.3
Product category PC-TEC-OTH Other products for chemical or technical processes
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
lubricant
Uses advised against

This product should not be used for other purposes than those specified without the advice of an expert.
1.3 Details of the supplier of the safety data sheet

Supplier
Mercedes-Benz AG
70546 Stuttgart
Germany
+49 (0)711 17-0
Telefon + 49 (0)711 17-97390
Telefax + 49 (0)711 17-94831
E-Mail (fachkundige Person) mercedes-benz-sdb@mercedes-benz.com
Manufacturer
Mercedes-Benz AG
70546 Stuttgart
Germany
Telephone +49 711 17-0
E-mail (competent person):
mercedes-benz-sdb@mercedes-benz.com
1.4 Emergency telephone number

+49 711 17-0
gms.aftersales.mercedes-benz.com
Giftnotruf der Charité – Universitätsmedizin Berlin +49 (0)30 30686700
SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Classification procedure
Regulation (EC) No 1272/2008
[CLP]
Aquatic Chronic 3, H412
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hazard statements for environmental hazards

H412 Harmful to aquatic life with long lasting effects.
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard statements
H412 Harmful to aquatic life with long lasting effects.
Precautionary statements
P102 Keep out of reach of children.
P273 Avoid release to the environment.
P501 Dispose of contents/container in accordance with regional regulations.
2.3 Other hazards
Adverse human health effects and symptoms
Prolonged or repeated skin contact may cause removal of natural fat from the skin resulting in dermatitis (skin
inflammation).
Other adverse effects

Special danger of slipping by leaking/spilling product.
Results of PBT and vPvB assessment

The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.
SECTION 3: Composition / information on ingredients

3.1 Substances
not applicable
3.2 Mixtures
Description
Highly refined mineral oil with additives.
Hazardous ingredients
CAS No. EC No. Substance name Concentration Classification SCL/ M/ ATE
according to
Regulation (EC) No
1272/2008 [CLP]
64742-54-7 265-157-1 Distillates (petroleum), 50 < 100 % Asp. Tox. 1; H304 ATE(oral): ≥ 5001
hydrotreated heavy paraffinic mg/kg
ATE(dermal): ≥
3001 mg/kg
ATE(inhalation
vapour): 5.53
mg/L
AFT019 PMA 1<5% Eye Irrit. 2; H319 Eye Irrit. 2;H319:
>=75%
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CAS No. EC No. Substance name Concentration Classification SCL/ M/ ATE

according to
Regulation (EC) No
1272/2008 [CLP]
67124-09-8 266-582-5 1-(tert-dodecylthio)propan-2-ol 0.25 < 1 % Skin Sens. 1; H317 Skin Sens.
Aquatic Acute 1; 1;H317: >=14,2%
H400 M=1 (Aquatic
Aquatic Chronic 1; Acute 1)
H410 M=1 (Aquatic
Chronic 1)
ATE(oral): > 5000
mg/kg
ATE(dermal): >
2001 mg/kg
1218787-32- 620-540-6 2,2'-(C16-18 (evennumbered, 0.25 < 1 % Acute Tox. 4; H302 M=10 (Aquatic
6 C18 unsaturated) alkyl imino) Skin Corr. 1C; H314 Acute 1)
diethanol Eye Dam. 1; H318 M=1 (Aquatic
Aquatic Acute 1; Chronic 1)
H400 ATE(oral): 1350
Aquatic Chronic 1; mg/kg
H410
REACH No. Substance name
01-2119484627-25 Distillates (petroleum), hydrotreated heavy paraffinic
01-2119510877-33 2,2'-(C16-18 (evennumbered, C18 unsaturated) alkyl imino) diethanol
01-2119953277-30 1-(tert-dodecylthio)propan-2-ol
Remark
The highly refined mineral oil contains <3% (w/w) DMSO-extract, according to IP346.
SECTION 4: First aid measures

4.1 Description of first aid measures
General information
Remove victim out of the danger area.
Remove contaminated, saturated clothing immediately.
Following inhalation
Provide fresh air.
In the event of symptoms refer for medical treatment.
Following skin contact

After contact with skin, wash immediately with plenty of water and soap.
In case of skin irritation, consult a physician.
After eye contact

In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart and
consult an ophthalmologist.
Remove contact lens
Following ingestion
Do NOT induce vomiting.
Call a physician immediately.
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4.2 Most important symptoms and effects, both acute and delayed
Symptoms
May cause irritation of the skin and eyes.
4.3 Indication of any immediate medical attention and special treatment needed
Notes for the doctor
Treat symptomatically.
SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing media
alcohol resistant foam
Extinguishing powder
Carbon dioxide (CO2)
Water spray jet
Unsuitable extinguishing media

Full water jet
5.2 Special hazards arising from the substance or mixture

Hazardous combustion products
Fire gas of organic material has to be classed invariably as respiratory poison.
In case of fire formation of dangerous gases possible.
5.3 Advice for firefighters

Special protective equipment for firefighters
In case of fire: Wear self-contained breathing apparatus.
Additional information
Co-ordinate fire-fighting measures to the fire surroundings.
Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water.
Cool endangered containers with water spray and possibly remove them from fire site.
Fire residues and contaminated firefighting water must be disposed of in accordance with the local regulations.
SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
Avoid skin and eye contact.
Use personal protection equipment.
For emergency responders

Personal protection equipment
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6.2 Environmental precautions

Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter into surface water or drains.
Prevent spread over a wide area (e.g. by containment or oil barriers).
Do not allow to enter into soil/subsoil.
6.3 Methods and material for containment and cleaning up

For containment
Collect with spongy material (all-purpose gelation agent) and dispose of in compliance with the regulations.
6.4 Reference to other sections

Safe handling: see section 7
Personal protection equipment: see section 8
Disposal: see section 13
SECTION 7: Handling and storage

7.1 Precautions for safe handling
Protective measures
Avoid:
generation/formation of aerosols
Provide for appropriate ventilation/aspiration at the work station
Do not heat up to temperatures close to the flash point.
All work processes must always be designed so that the following is as low as possible:
Skin contact
Avoid:
Eye contact
Do not put any product-impregnated cleaning rags into your trouser pockets.
Advices on general occupational hygiene

Thorough skin-cleansing after handling the product.
Apply skin care products after work.
When using do not eat, drink, smoke, sniff.
Keep away from food and drink.
Use protective skin cream before handling the product.
7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage rooms and vessels
Keep/Store only in original container.
Storage class
10 Combustible liquids that cannot be assigned to any of the above storage classes
Materials to avoid
Do not store together with:
Food and feedingstuffs
Further information on storage conditions

Keep container tightly closed and protected against effects of weather in a cool, appropriately aerated area.
Protect against:
Heat
UV-radiation/sunlight
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7.3 Specific end use(s)

Recommendation
See section 1.2
SECTION 8: Exposure controls/personal protection

8.1 Control parameters
DNEL worker
CAS No. Substance name DNEL value DNEL type Remark
64742-54-7 Distillates (petroleum), 5.4 mg/m³ long-term inhalative (local)
hydrotreated heavy paraffinic
1218787-32- 2,2'-(C16-18 (evennumbered, C18 0.3 mg/kg bw/day long-term dermal
6 unsaturated) alkyl imino) diethanol (systemic)
1218787-32- 2,2'-(C16-18 (evennumbered, C18 2.112 mg/m³ long-term inhalative
DNEL Consumer
CAS No. Substance name DNEL value DNEL type Remark
64742-54-7 Distillates (petroleum), 1.2 mg/m³ long-term inhalative (local)
1218787-32- 2,2'-(C16-18 (evennumbered, C18 0.214 mg/kg long-term oral (repeated)
6 unsaturated) alkyl imino) diethanol bw/day
1218787-32- 2,2'-(C16-18 (evennumbered, C18 0.214 mg/kg long-term dermal
6 unsaturated) alkyl imino) diethanol bw/day (systemic)
1218787-32- 2,2'-(C16-18 (evennumbered, C18 0.214 mg/kg long-term dermal
6 unsaturated) alkyl imino) diethanol bw/day (systemic)
1218787-32- 2,2'-(C16-18 (evennumbered, C18 0.745 mg/m³ long-term inhalative
PNEC
CAS No. Substance name PNEC Value PNEC type Remark
64742-54-7 Distillates (petroleum), 9.33 mg/kg Secondary Poisoning , Nahrung
1218787-32- 2,2'-(C16-18 (evennumbered, C18 0.000214 mg/L aquatic, freshwater
6 unsaturated) alkyl imino) diethanol
1218787-32- 2,2'-(C16-18 (evennumbered, C18 2.14e-005 mg/L aquatic, marine water
1218787-32- 2,2'-(C16-18 (evennumbered, C18 1.692 mg/kg sediment, freshwater
1218787-32- 2,2'-(C16-18 (evennumbered, C18 0.1692 mg/kg sediment, marine water
1218787-32- 2,2'-(C16-18 (evennumbered, C18 5 mg/L soil
1218787-32- 2,2'-(C16-18 (evennumbered, C18 1.5 mg/L sewage treatment plant
6 unsaturated) alkyl imino) diethanol (STP)
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8.2 Exposure controls

Appropriate engineering controls
Technical measures to prevent exposure
Sufficient ventilation and exhaustion.
Personal protection equipment

Eye/face protection
Safety glasses recommended during transfer
EN 166
Hand protection
Glove materials data [type, thickness, breakthrough time/duration of use, permeation rate]: Nitrile rubber (protection index
6, >480 min, 0.4 mm)
For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above
together with the supplier of these gloves.
The protective gloves to be used must comply with the specifications of EC directive 89/686/EEC and. the resultant
standard EN374.
Body protection:
Protective clothing
Respiratory protection
Respiratory protection necessary at:
insufficient exhaust
prolonged exposure
Suitable respiratory protection apparatus:
Filtering device (full mask or mouthpiece) with filter:
AX
SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state
liquid
Colour
light brown
Odour
characteristic
Safety relevant basis data

Value Method Source, Remark
Odour threshold: not determined
Melting point/freezing point not determined
Boiling point or initial boiling point not determined
and boiling range
flammability not determined
Lower and upper explosion limit not determined
Flash point 190 °C
Auto-ignition temperature not determined
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Decomposition temperature not determined
pH in delivery state not applicable
Viscosity kinematic
33.5 mm²/s (40°C)
Solubility(ies) Water solubility practically insoluble
Partition coefficient n- not determined

octanol/water (log value)
Vapour pressure not determined
Density and/or relative density 0.86 g/mL (15°C)
Relative vapour density not determined
particle characteristics not determined
9.2 Other information
Other safety characteristics
Explosive properties: The product is not explosive
Other information
none
SECTION 10: Stability and reactivity

10.1 Reactivity
No hazardous reactions known.
10.2 Chemical stability

The product is chemically stable under recommended conditions of storage, use and temperature.
10.3 Possibility of hazardous reactions

No hazardous reactions known.
10.4 Conditions to avoid

Heat
High temperatures
10.5 Incompatible materials

Oxidising agent, strong
Strong acids
Strong bases
10.6 Hazardous decomposition products

No decomposition products will result from proper storage and handling.
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SECTION 11: Toxicological information

11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008
Acute toxicity
Animal data
Effective dose Method,Evaluation Source, Remark
Acute oral toxicity CAS No.64742-54-7 OECD 423
Distillates (petroleum),
hydrotreated heavy
paraffinic
LD50: ≥ 5001 mg/kg
Species Rat
CAS No.67124-09-8 1-(tert-
dodecylthio)propan-2-ol
LD50: > 5000 mg/kg
Species Rat
CAS No.1218787-32-6 2,2'- OECD 401
(C16-18 (evennumbered,
C18 unsaturated) alkyl
imino) diethanol
LD50: 1350 mg/kg Species
Rat
Acute dermal toxicity CAS No.67124-09-8 1-(tert-
LD50: > 2001 mg/kg
Species Rabbit
CAS No.64742-54-7 OECD 402
hydrotreated heavy
paraffinic
LD50: ≥ 3001 mg/kg
Species Rabbit
Acute inhalation toxicity CAS No.64742-54-7
hydrotreated heavy
paraffinic
Acute inhalation toxicity
(vapour)
LC50: 5.53 mg/L Species
Rat
Assessment/classification
Based on available data, the classification criteria are not met.
Skin corrosion/irritation
Practical experience/human evidence
Frequent and prolonged contact with the skin may cause skin irritation.
Serious eye damage/irritation
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Animal data
Result / Evaluation Method Source, Remark
CAS No.AFT019 PMA CAS No.AFT019 PMA
Causes serious eye irritation.1Specific
Concentration Limit (SCL) Eye Irrit. 2;
H319: C ≤ 75%
Sensitisation to the respiratory tract

Skin sensitisation
Animal data
Result / Evaluation Dose / Concentration Method Source, Remark
sensitising CAS No.67124-09-8 1-(tert- OECD 406, OECD 429 Specific Concentration Limit
dodecylthio)propan-2-ol (SCL) Skin Sens. 1B; H317:
14.2 % ≤ C ≤ 100 %
not sensitising. CAS No.1218787-32-6 2,2'- OECD 406
imino) diethanol
Species Guinea pig
Germ cell mutagenicity

Carcinogenicity
Reproductive toxicity
Overall Assessment on CMR properties

This product does not meet the criteria for classification in Categories 1A/1B.
STOT-single exposure
STOT SE 1 and 2
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STOT SE 3
Irritation to respiratory tract
Narcotic effects
STOT-repeated exposure
Aspiration hazard
11.2 Information on other hazards

Other information
Risk of eye and respiratory tract irritation due to high temperatures of vapours and oil mist
In case of swallowing, irritations of the gastric mucous membrane, nausea, vomiting and diarrhoea may occur.
SECTION 12: Ecological information

12.1 Toxicity
Aquatic toxicity
Acute (short-term) fish toxicity CAS No.64742-54-7 OECD 203
hydrotreated heavy
paraffinic
LL50 > 100 mg/L Species
Pimephales promelas
(fathead minnow)
Test duration 96 h
CAS No.67124-09-8 1-(tert-
LC50: > 0.75 mg/L
Test duration 96 h
CAS No.1218787-32-6 2,2'- OECD 203
imino) diethanol
LC50: 0.1 mg/L
Test duration 96 h
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Chronic (long-term) fish toxicity CAS No.64742-54-7
hydrotreated heavy
paraffinic
NOEC 1000 mg/L Species
Oncorhynchus mykiss
(Rainbow trout)
Test duration 14 d
Acute (short-term) toxicity to CAS No.67124-09-8 1-(tert-
crustacea dodecylthio)propan-2-ol
EC50 0.58 mg/L Species
Daphnia pulex (water flea)
Test duration 48 h
CAS No.64742-54-7 OECD 202
hydrotreated heavy
paraffinic
EC50 > 10000 mg/L
Species Daphnia pulex
(water flea)
Test duration 48 h
CAS No.1218787-32-6 2,2'- OECD 202
imino) diethanol
EC50 0.043 mg/L Species
Test duration 48 h
Chronic (long-term) toxicity to CAS No.67124-09-8 1-(tert-
aquatic invertebrate dodecylthio)propan-2-ol
NOEC 0.75 mg/L Species
Test duration 21 d
CAS No.1218787-32-6 2,2'- OECD 211
imino) diethanol
EC10 0.279 mg/L
Test duration 21 d
CAS No.1218787-32-6 2,2'- OECD 211
imino) diethanol
EC10 0.0107 mg/L
Test duration 21 d
CAS No.64742-54-7
hydrotreated heavy
paraffinic
NOEC > 1 mg/L Species
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Acute (short-term) toxicity to algae CAS No.64742-54-7
and cyanobacteria Distillates (petroleum),
hydrotreated heavy
paraffinic
EC50 > 100 mg/L Species
Pseudokirchneriella
subcapitata (green alga)
Test duration 72 h
CAS No.67124-09-8 1-(tert-
NOEC 100 mg/L Species
Pseudokirchneriella
subcapitata (green alga)
Test duration 96 h
CAS No.1218787-32-6 2,2'-
imino) diethanol
NOEC 0.0156 mg/L
Test duration 72 h
CAS No.1218787-32-6 2,2'- OECD 201
imino) diethanol
EC50 0.0538 mg/L
Test duration 72 h
Chronic (long-term) toxicity to not determined
aquatic algae and cyanobacteria
Toxicity to other aquatic not determined
plants/organisms
Toxicity to microorganisms not determined
Harmful to aquatic organisms with lasting effect.
12.2 Persistence and degradability

Biodegradation Degradation rate 63 OECD 301D/ EEC CAS No.1218787-32-6 2,2'-
92/69/V, C.4-E (C16-18 (evennumbered,
imino) diethanol
28 d
Easily biodegradable
Biodegradation Degradation rate 5.9 OECD 301F/ ISO 9408/ CAS No.67124-09-8 1-(tert-
EEC 92/69/V, C.4-D dodecylthio)propan-2-ol
28 d
Not easily biodegradable.
12.3 Bioaccumulative potential

No data available
12.4 Mobility in soil
No data available
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12.5 Results of PBT and vPvB assessment

The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.
12.6 Endocrine disrupting properties

No data available
12.7 Other adverse effects
Additional ecotoxicological information
Product is not allowed to be discharged into the ground water or aquatic environment.
SECTION 13: Disposal considerations

13.1 Waste treatment methods
Waste codes/waste designations according to EWC/AVV
Waste code product Waste name
130110 * mineral based non-chlorinated hydraulic oils
Appropriate disposal / Product
Dispose of waste according to applicable legislation.
Appropriate disposal / Package

Dispose of waste according to applicable legislation.
Remark
The allocation of waste identity numbers/waste descriptions must be carried out according to the EEC, specific to the
industry and process.
SECTION 14: Transport information

Land transport (ADR/RID) Sea transport (IMDG) Air transport (ICAO-TI / IATA-
DGR)
14.1 UN number or ID number - - -
14.2 UN proper shipping name - - -
14.3 Transport hazard class(es) - - -
14.4 Packing group - - -
14.5 Environmental hazards No No No
14.6 Special precautions for user
No data available
14.7 Maritime transport in bulk according to IMO instruments
not applicable
All transport carriers

No dangerous goods as defined by the transport regulations - ADR/RID, IMDG, ICAO/IATA-DGR.
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SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Other regulations (EU)
Directive 2010/75/EU on industrial emissions [Industrial Emissions Directive] VOC
not applicable
15.2 Chemical Safety Assessment
National regulations
Substance safety analysis was not performed for this mixture.
SECTION 16: Other information

Indication of changes
* Data changed compared with the previous version
Current safety data sheets are available at:
https://gms.aftersales.mercedes-benz.com
Abbreviations and acronyms

See overview table at www.euphrac.eu
Key literature references and sources for data

Safety data sheets of suppliers
Classification for mixtures and used evaluation method according to regulation (EC) No 1272/2008 [CLP]
The mixture is classified according to the available hazard data for the constituents as defined in the classification criteria
for mixtures for each hazard class in Appendix I of Regulation (EC) No 1272/2008.
Adhere to existing national and local rules referring to chemicals.
The above information describes exclusively the safety requirements of the product and is based on our present-day
knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data
sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case
of mixing the product with other products or in the case of processing, the information on this safety data sheet is not
necessarily valid for the new made-up material.
Relevant H- and EUH-phrases (Number and full text)

H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
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Safety Data Sheet according to Regulation (EC) No.

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Uses advised against

1.3 Details of the supplier of the safety data sheet

1.4 Emergency telephone number

SECTION 2: Hazards identification

hazard statements for environmental hazards

Other adverse effects

Results of PBT and vPvB assessment

SECTION 3: Composition / information on ingredients

CAS No. EC No. Substance name Concentration Classification SCL/ M/ ATE

SECTION 4: First aid measures

Following skin contact

After eye contact

SECTION 5: Firefighting measures

Unsuitable extinguishing media

5.2 Special hazards arising from the substance or mixture

5.3 Advice for firefighters

SECTION 6: Accidental release measures

For emergency responders

6.2 Environmental precautions

6.3 Methods and material for containment and cleaning up

6.4 Reference to other sections

SECTION 7: Handling and storage

Advices on general occupational hygiene

7.2 Conditions for safe storage, including any incompatibilities

Further information on storage conditions

7.3 Specific end use(s)

SECTION 8: Exposure controls/personal protection

8.2 Exposure controls

Personal protection equipment

SECTION 9: Physical and chemical properties

Safety relevant basis data

Value Method Source, Remark

Partition coefficient n- not determined

SECTION 10: Stability and reactivity

10.2 Chemical stability

10.3 Possibility of hazardous reactions

10.4 Conditions to avoid

10.5 Incompatible materials

10.6 Hazardous decomposition products

SECTION 11: Toxicological information

Serious eye damage/irritation

Sensitisation to the respiratory tract

Germ cell mutagenicity

Overall Assessment on CMR properties

11.2 Information on other hazards

SECTION 12: Ecological information

Effective dose Method,Evaluation Source, Remark

Effective dose Method,Evaluation Source, Remark

12.2 Persistence and degradability

12.3 Bioaccumulative potential

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

SECTION 13: Disposal considerations

Appropriate disposal / Package

SECTION 14: Transport information

All transport carriers