Scribd Logo
Upload

Welcome to Scribd!

  • 6 views

    Coordination WS Key

    Uploaded by

    Deena chemist
    1. This document provides information about various coordination complexes including their structures, oxidation states, isomerism, magnetic properties, and reactions. 2. Key complexes discussed include [Cu(NH3)4]SO4, [Cr(H2O)4Cl2]+, [MnO4]-, [Co(C2O4)3]3-, [Co(NH3)6]3+, and reactions of complexes like [Co(NH3)5SO4]+ and [Co(NH3)5Br]+ with AgNO3 and BaCl2 respectively. 3. The document also discusses topics like crystal field splitting energy, spectrochemical series, ambidentate ligands,

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd

    Coordination WS Key

    Uploaded by

    Deena chemist
    6 views2 pages
    1. This document provides information about various coordination complexes including their structures, oxidation states, isomerism, magnetic properties, and reactions. 2. Key complexes discussed include [Cu(NH3)4]SO4, [Cr(H2O)4Cl2]+, [MnO4]-, [Co(C2O4)3]3-, [Co(NH3)6]3+, and reactions of complexes like [Co(NH3)5SO4]+ and [Co(NH3)5Br]+ with AgNO3 and BaCl2 respectively. 3. The document also discusses topics like crystal field splitting energy, spectrochemical series, ambidentate ligands,

    Original Title

    COORDINATION WS KEY

    Copyright

    © © All Rights Reserved

    Available Formats

    DOCX, PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    1. This document provides information about various coordination complexes including their structures, oxidation states, isomerism, magnetic properties, and reactions. 2. Key complexes discussed include [Cu(NH3)4]SO4, [Cr(H2O)4Cl2]+, [MnO4]-, [Co(C2O4)3]3-, [Co(NH3)6]3+, and reactions of complexes like [Co(NH3)5SO4]+ and [Co(NH3)5Br]+ with AgNO3 and BaCl2 respectively. 3. The document also discusses topics like crystal field splitting energy, spectrochemical series, ambidentate ligands,

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    6 views2 pages

    Coordination WS Key

    Uploaded by

    Deena chemist
    1. This document provides information about various coordination complexes including their structures, oxidation states, isomerism, magnetic properties, and reactions. 2. Key complexes discussed include [Cu(NH3)4]SO4, [Cr(H2O)4Cl2]+, [MnO4]-, [Co(C2O4)3]3-, [Co(NH3)6]3+, and reactions of complexes like [Co(NH3)5SO4]+ and [Co(NH3)5Br]+ with AgNO3 and BaCl2 respectively. 3. The document also discusses topics like crystal field splitting energy, spectrochemical series, ambidentate ligands,

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    You are on page 1of 2

    PINNAACLE CLASSES

    1. (b)
    CuSO 4 +4 NH 3 →[Cu( NH 3 )4 ]SO 4
    10. (c) It gives precipitate with
    AgNO
    3 it means it given Cl
    −

    2. (b) Oxalate is a bidentate ligand hence forms a chelate. ion in the solutions. Since conductivity corresponds to two
    −
    ions, it shows one Cl is outside the coordination sphere. The
    structure will be
    [Cr ( H 2 O )4 Cl 2 ]Cl→[Cr ( H 2 O)4 Cl 2 ]+ +Cl−
    −
    3. (a) Oxidations state of Mn in
    [ MnO 4 ] = +7, hence it does AgNO 3 +Cl− → AgCl +NO −3
    not have any d-electron present in it. White ppt
    0 0
    Mn7 + (Z = 25) : [ Ar ]4 s 3d
    [Co( NH 3 )5 SO 4 ]Br →[Co( NH 3 )5 SO4 ]+ +Br −
    (d) In the complex linkage, geometrical and optical isomerism 11.
    X
    4.
    are possible. AgNO 3 +Br− → AgBr +NO−3
    pale yellow

    [Co(C 2 O4 )3 ] 3− [Co( NH 3 )5 Br ]SO 4 →[Co( NH 3 )5 Br ]2+ +SO 2−


    4
    5. (d) −
    Oxidations state of Co = +3 BaCl 2 + SO2−
    4 →BaSO 4 +2 Cl
    White ppt
    Co 3+ (Z=27 ):3 d 6
    Since
    C 2 O2−
    4 is a strong filed ligand pairing will take place. 2 . 675
    CoCl 3 . 6 NH 3 = =0 . 01
    12. (b) No. of moles of 267 .5
    4 . 78
    = =0. 03
    No. of moles of AgCl 143 . 5

    6. (a) Electronic configurations of Co


    3+
    =3 d 6 0 . 01 moles of the complex CoCl 3 . 6 NH 3 gives 0 . 03
    Since
    [Co(CN )6 ]3− AgNO .
    3 it implies the 3
    moles of AgCl on treatment with
    chloirde ion are ionisable, in the complex. Thus, that formula

    of the complex is
    [Co( NH 3 )6 ]Cl 3 .
    No. of unpaired electrons = 0.
    Hence, shows no paramagnetism. 13. (a) SCN and
    − NO−
    2 are ambidentate ligand since they have
    more than one donor atoms to attach to the central metal
    6 atom.
    7. (c) In d (low spin) electrons get paired up to make two d-

    orbitals empty. Hydridisations is d 2 sp 3 (octahedral) and the 14. (a) Potassium pentacyanonitrosylferrate (II)
    complex is low spin.
    15. (b) The ligand are interchanged in both the cationic and
    8. (c) Cr is in zero oxidations state. anionic entities of different metal ions present in a complex to
    form coordination isomers.

    16. (c) Primary valencies are also known as oxidation state.


    K 2 [ Ni (CN )4 ] , 2+ x−4=0⇒ x =+ 2

    No. of unpaired electrons


    =0 17. (a)
    μ= √0 (0+2)=0 When metal is in low oxidation state then it
    forms complexes when ligands have good -
    accepting character
    9. (a) Higher the number of ions in the solutions, higher is the
    conductivity.
    18. (b) Complexes in which a metal is bound to more than one
    No. of ion :
    [Co( NH 3 )3 Cl 3 ]=0 ;
    [Co( NH 3 ) 4 Cl 2 ]Cl=2 kind of donor groups, e.g., are known
    as heteroleptic. Complexes in which a metal is bound to only
    [Co( NH 3 )5 Cl ]Cl 2 =3 ; [Co( NH 3 )6 ]Cl 3 =4
    Opp. Om Shakti Temple, Beside Naturals, Ramakrishna Road, Salem : 83009 81676 / 98403 37371
    PINNAACLE CLASSES
    27. (c)
    one kind of donor groups, e.g., are known [Co(NH3)6]+3 – d2sp3 diamagnetic
    as homoleptic.
    28. (a)
    [FeF6]3-: Fe3+= 3d5  0<P
    19. (d)

    20. (c) Correct match is, P-(ii),Q-(i),R-(iii),S-(iv)

    21. (d) : Triamminetriaqua Number of unpaired e- = 5    35 BM


    chromium(III) chloride [CoF6]3-:Co3+ = 3d6 (  0<P)

    22. (a) (yellow) gave


    when it is treated with excess silver nitrate solution.

    23. (a)
    Number of unpaired e- = 4    24 BM
    [Co(C2O4)3]3- : Co3+ = 3d6 (  0 > P)

    24. (b) Both and are tetrahedral


    Number of unpaired e- = 0
       0 BM
    geometry

    25. (c) has geometrical isomers, cis and 29. (b)


    trans. The increasing order of field strength of
    ligands (according to spectrochemical
    series)
    S2- < C2O24 < NH3 < en < CO

    30. (b)

    [Co(NH3)5SO4]Br+AgNO3 AgBr
    0.01 mol excess 0.01 Mol
    [Co(NH3)5Br]SO4+BaCl2 BaSO4
    26. (d) 0.01 mol excess 0.01 Mol
    Crystal field theory introduce
    spectrochemical series based upon the
    experimental values of but can't explain
    it's order. While other three points arc
    explained by CFT. Specially when the CFSE
    increases thermodynamic stability of the
    complex increases.

    Opp. Om Shakti Temple, Beside Naturals, Ramakrishna Road, Salem : 83009 81676 / 98403 37371

    You might also like