bC~L Aa8 cl /\jl!

tJCcO AaBbC AaBbCcl • :: ~ •

1• "J, • • lmpl,a S1rong W.W. 1llo , t Sim, , s..-n •
Oi,t,c..d
I I )
,, .. ,
,,,., ........... ., ... . It

Tahel I. Pemi!ahan molekul pada tumhukan

Molcaalc Comuound ,A
A ~k
He
Kr
~t".. +
~lon
3542"{'
USl i
'"
10.ZZ
Ne 34" 111.,
Neo• U20 JU
Xe ·Xcao.
Air Air
4Jm 206.9
Brz 3.711 '18.6
Broawac 4.296 m.,
ca. Cvboa lclncbloridc
cr, Carboa tctraRuoridc
S.947
4.662
m.1
CH<ll CbJorof'orm 131.0
~
.S.319 340.2
Mcshlcac chloride 4.198 3.S6.3
ObBr Mcshly bromcidc 4.118
CffJ(] 449.2
MctbJy cbloride 4.182 m.o
ClbOH Mcllwol 3.626
0'4 Methane 481.1
co 3.7S8 148.6
Carbon monoxide 3.690 9L7
I
-- 7 G - - -1 • 1~

·'·· ..
 . . . 0,.0 Q ,...... - ,...... 1.,<1,,

Ti '" «,,,,II.• 11 • A," A• M • '; :

•DI.Cc! IY!!bC<O. AaBbC AaBbCd •
,(( Fomwt ~
1
8 / U • o l l' ~ • /J,. • irn,,,g W: I ti Spg 1

~
I t I
'-
I I • I I 41 I I i I I tl11ll1U1U•
""" '"
Tahcl l. Pcmisahnn molckul pada tumhuknn

Molecule Comoound rA ¾k
A Al~n 3.542 '-J.3'('
He Uc ·um+ 2.SSl 10.22
1Ct Krypton 3.655 178.9
Ne Neon 2.820 32.8
X:. •Xenon 4.082 206.9
A°Jr AJr 3.711 78.6
Bri BrOOWlc 4.296 501.9
CCl4 Cvboo tetrachloride S.947 m1
CF, Carbon tetrafluoride ◄IJ62 134.0
CHCb Chloroform S.389 3402
CHlCli Mcthlcac chloride ◄.898 3S6.3
ClbBr Methly bTomcide 4.118 449.l
ObO Mcthly chloride '-182 310.0
ClbOH Mtlhanol 3.616 481.8
014 Mctlwie 3.758 148.6
co Cl.rboa monoxide 3.690 9L7
 Tln-..,IU,ol\• u . bC,l Aa8 11.oC<I twSbCd), AaBbC A.ilibCd
:tfOIIN\,..._ • ' u . ,1. )( )( "'I'· A · 1 • ~_,, l
Clf,lx,sd ,_ r.s
I I I I ' I ,. II II

Tabcl 2. Fun1:,si tumbukan

-,
kt .. Oo -kTt Oo -kT£ QD
t
0.30 2.662 1.65 1.153 4.0 0.8836
0.35 2.416 1.70 1.140 4.1 0.8788
0.40 2.318 1.15 1.128 4.2 0.8740
0.4S 2.184 1.80 1.116 43 0.8694
050 2.066 1.8S 1.105 4.4 0.8652
055 1966 1.90 1.094 45 0.8610
0.60 1.877 1.95 1.084 4.6 0.8S68

Q S. rth
 \a(}I.C,1 twSbCtO. AaSbC AaBbCd •
t • ~. l]ho I

I • • \ I •
• • • • • 11 U • II

Tabe \ 3. Volu me atom dan ,·olum e moleku\

Atomic volume , Mo\tc11.l:a.r vo\umt

Cvbon 14.8 lb 14.3
Hiydrogen
Ollorine
3.1 <n 25.6
24.6 Ni 31.2
Bromine 27.0 Air
Lodinc 29.9
Sulfur
37.0 co 30.7
25.6 CO2 34.0
Niuogcn 15.6 SC>i
Nitt"Ogea in prim.try amines 44.8
Nitrogen in secondary amines
10.S NO 23.6
12.0 N10 36.4
Oxygen 7.4
Oxygen in methyl esters Nlb 25.8
9.1 lhO 18.9 I
Oxygen in higher csle.rs
"'---·----- :_ - ~~- ...
11.0
~
lhS
~
32.9
r 4 r . '

Q ""'
 I <Pl

fme\lt....,I\• 12 • I\ 0
A ~• ~ : PIN.
ilnBbC,L Aa8bC AnBbCd AaUhCd Aa8bC<O AaBbC AnllbCcl ... • ~
' <fonn41J'.m., a ' u · •· )( x '7 ·A· l • t1 • • f p!\t llf.jng 1 H il 111~ SJ.Ult ldt mo Ip~ , St!oa •
~
I ' I 4 t l I , I I o I I , 1 10 I II I II I II ,,
T11bcl 4. ,·olume difusi atom dam molckul
A. Atomic and struc:tunl diffusion volume increments.,
\

C 16.S (Cl) 19.5

H 1.98 (S) 17.0
0 5.48 Aromatic rin& -20l
(N) 5.69 HeterocycUc ring -20l
B. Dill'uslon volumes ror simple molecules, Iv

H2 7.07
co 18.9
CO2 26.9
D2 6.70 N20 35.9
He 2.88 NHJ 14.9 I
i
N2 17.9 H20 12.7
16.6 11A R

o Q Search
 Aa8bC Aa8bC'd

Tabel 5. Koer1Sien difusl gas pada tekanan l atm

Sysleai Temp.oC Datmul'flly, 1q aa/HC

H2-CH4 0 0.62S
02-N2 0 . 0.181
CO-Oz 0 0.185
COz-Oz 0 0.139
Air-NHJ 0 0.198
Air-Hz<) 25.9 0.258
59.0 0.305
Air-ethanol 0
Air-n-butanol 0.102
25.9 0.087
59.0 0.104
Air-Ethyl acetate 25.9 0.087
59.0 0.106
Air-anilcnc 25.9 0074
hU ••- •
•
• Q Sa di

~·
un ,
 • vt•t• ~ t.o. J ( c , n ~ ~l 'tltro1 d

lf~'\.... t Iv-.,,;• .,, "' ~ .. ......,W"I \.l..,.;,4p .,_.__,. v ...... ~'-Ip ..,:t,oPt> Qlrlr,,.._,....,1"._.41 ,k - v..,,.
r. ,.,_A.. 11 • A r,,' Aa• ~ : luBbCd AaBbC Ai, l}l_,{"d AaSbCct), AaBbC AillbCd • !.. R,¢o<o

(ffomuHv,ur B / V • •• ,c X
CJ:i:t,ca,o,I J....
II II
I 4 .. I
"

Solute Solvent Temp. C Solute conn Oltrusivhy + (J

.
g moles liter sq cm/see (101)
Cb \Voter 16 0.12 1.26
HCI \Vater 0 9 2.7
~
2 1.8
10 9 3.3
2.5 2.5
16 0.5 2.44
NHJ \Vater 5 3.5 1.24
15 1.0 1.n
CO2 \Vater 10 0 1.46
20 0 i.n
NaCl \Vater 18 0.05 1.26
0.2 1.21
,n 1 ..,..,

,6 .,_ . ~~-

C Q rch
 •

1!1\•1 Cn..-.J""

NNII• 1l
(11 >v1

• A
0
A
...,.~•-in . \_. . . ., ~..,._ \...
A..• ~ i · • · t.
JJ•I,;, &. I ~ loo,i.;~t, M..,J...

4
H9\) ,..,,.

A,,BbCcL
v,(.

AaBbC
""'-... d

Q ,,.. ,. • .,~,) 'I.; ••d I d.,

-
...... -
.... -
.
.... \>,...

'°fouN1 ,.._ II I U • ,._ II X "/ • /:. I • ~. 1t

O;Da9d
I I J J ' • \ , • t I , I t I t ll I II I U t IJ t

Tabet 7. Sifat-sifat ~fl jcnuh

SuhuT Tck:in:i.a Volume Spesifak_ ft3/lb Eolalp~ Btu/lb

°F uap ·'.,
PAlbC/m Llteairv,. Up:11.i.r v1 Pcngu.apao UapJcouh
Zat Cair H• A H.c
32 0,08854 0,01602 3J06 0,00 1075,8
35 1075,8
0,09995 0,01602 2.9-$7 3,02 1074,l 1077,1
40 0,Ul70 0,01602 2.444 8,05 1071,3
45 1079,3
0,14752 0,01602 2.036,4 13,06 1068,4 1081,S
so 0,17811 0,01603 1.703,2 18,06 1065,6 1083,7
55 0,2141 0,01<,0J 1.430,7 23,01 1062,7 1085,8
60 0,2563 0,01604 1.206,7 28,06 1059,9 1088,0
65 0,3056 0,01605 1.021,4 33,05 1057,1 1090,2
70 0,3631 0,01606 867,9 38,04 1054,3 1092,3
75
AA
0,4298
n c.t\<O
0,01607
Ol'ltiC/10
740,0
4:-,,., •
43,03
.,, -- !~~~ !Q'.14,S

= Q Sc,lrch
 • : I ' !, I • : I

.(! Jo,IM'I Puiur B IU ••-,:X,x '? · A · : . ~. (mph,"' tlN~rt;I I $1,oe,g S.J,ul. r.i. INoSp.o.:. •
,_ ,..~..,, ,..
~d

'-'-"'
l . J
• '
\.,.UUVQ u:U •1.WVUUC
I
• I I I
• .>.'NI
I I
•• I
!,)lo,
u .
,u.., u I II I II ..
14"'9

cr. Carbon lctralluoridc ◄.662 134.0

CH01 Chloroform S.389 340.2
CH2Cli MethJcoc chloride 4.898 356.J
Ohllr McthJy bromcidc 4.118 ~9.2
CHJO MclhJy chloride 4.182 3.SO.D
CH)OH Mctlwiol 3.626 481.8
CJ:14 Mctwe 3.758 148.6
co Ouboo monODdc 3.690 9L7
cos Carbon sulfide -4.130 l36.0
COi Carbo11 dioxide 3.941 19S.2
CS1 Carbon disulfide 4.483 461JJ
C2.Hl Accteoe 4.033 ZJU
OH4 Elhye11c 4.163 224.7
C2H4 Etuac 4.40 215.7
Ol{sC Ethyl chloride 4.898 300.0
ClH$0H Ethanol 4.SJO , 362.6
~ ◄.361 ·r 348.6
QIJOCl{J
CHlOIC3
OiJCOI
~:thcr
P cac
M ybcctylcne
007
◄.G78
4.761
39S.0
298.9
251.8
,

41111 1.48.9 - -
~ t -
9'dopropan c
-
~

i,o .,_ u• l¢-'>(UQdsi- I G - - -• - • I

,. I

~ Q &.; ,Ji l:J lid w e c;· r2J ffiG

U5
QC,, :.