CHEMISTRY QUESTION PAPER

CLASS-XII

Time : 3.00 Hours] [Maximum Marks : 100

Instructions :
1. This question paper has total 60 questions and all are compulsory.
2. Write your answer to the point and as instructed in the question.
3. Begin new section from new page and maintain the order of questions.
4. Use log-table or simple calculator for calculations.
5. Draw a neat and clean diagram with necessary labellings, wherever
required.

Atomic weights
H = 1, 0= 16, K = 39, Mn= 55 gms / mole

SECTION-A
Question Nos. from 1 to 16 are multiple choice type. 16
Each carries ONE mark. Select the correct option from the following.

1. For which of the following sets of 4 quantum numbers an electron

will have the highest energy?
n l m s
(A) 3 2 1 ½
(B) 4 2 -1 ½
(C) 4 1 0 -½
(D) 5 0 0 -½

2. The number ofNa + ions filling all octahedral voids in NaCl structure
are:
(A) 6 (B) 12 (C) 13 (D) 14

3. What is the normality of lM KMnO 4 solution?

(A) 0.lN (B) 2N (C) 0.5N (D) 5N
4. Zn gives H2 gas with H2S04 and HCl, but not with HN03 because
(A) N03- is reduced before reduction of hydronium ion.
(B) HN03 is weaker acid than H2S04 and HCI.
(C) In electrochemical series Zn is above hydrogen.
(D) Zn acts as an oxidizing agent when reacts with HN03.

5. The second order rate constant is usually expressed as

(A) mole liter sec-1 (B) mole-1 liter -1 sec-1
(C) mole liter l sec-1 (D) mole-1 liter sec-1

6. ZSM-5 converts
(A) Benzene to Toluene (B) Alcohol to Petrol.
(C) Toluene to Benzene (D) Heptane to Toluene

7. An element (X) forms compounds of the formula XC1 3, X205 and

Ca3X2, but does not form XC15. Which of the following is the element
X?
(A) B (B) Al
(C) N (D) P

8. What is responsible for the stability of +3 oxidation state in inner

transition elements?
(A) Ionization energy.
(B) Hydration energy.
(C) Ionization energy and Hydration energy.
(D) Electronic configuration.

9. The nuclear reaction accompanied with the emission of Neutrons is

(A) 6C 12 + 1H 1 ., 7N 13

(B) 13Al21 + 2He4 _, 15p30

(C) 15p30 14Si + le

30 o

(D) 96Am241 + 2He4 97Bk 41 + le o

2
10. Which of the following pairs of compounds are enantiomers?

CH3
(A)
H iOH and HO H
=i=
HO H H OH
CH3 CH3
CH3 CH3
(B)
H OH HO H
=i=- and =F
HO H HO H
CH3 CH3
(C)
H iOH and H OH
HO H H OH
i
CH3 CH3

HOiH HOiH
(D)

and
H OH HO H
CH3 CH3
11. Which of the following alcohol will not be easily oxidized by K2 Cr2O 7
in dil. H2SO4?
(A) CH3 OH (B) CH3 .CH2 .OH
(C) (CH3 ) 3 .C.OH (D) CH3 CH.OH.CH3
12. Identify the wrong statement from the following.
(A) Salicylic acid is monobasic acid.
(B) Methyl sa1icylate is an ester.
(C) Salicylic acid gives violet colour with neutral FeC13 as well as
brisk effervescence with NaHCO3 •
(D) Methyl salicylate does not occur in natural oils.

13. Dimethylterephtha1ate and ethylene glycol react to form ......

(A) Nylon 6 (B) Nylon 66
(C) Decron (D) Neoprene
14. Two vitamins absorbed from the intestine along with fats are
(A) A, D (B) A, B

@-
(C) A, C (D) D, B
OCOCH3
15. The compound COOH is used as ....

(A) antiseptic (B) antibiotic

(C) analgesic (D) pesticide

16. A 16 year old boy came to the doctor with main complaints of
frequent sneezing, watering from nose and eyes, intense itching in
eyes, and cold. He has past history of allergy to dust. The doctor
prescribes most probably which of the following drugs.
(A) Norethindrone (B) Lansoprazole
(C) Reserpine (D) Chlorpheniramine

SECTION -B
Question Nos. from 17 to 32 are very short answer type questions. 16
Each question carries ONE mark.
17. State the relationship of cartesian co-ordinates x, y and z to spherical
polar co-ordinates r, 0 and�-

18. Give examples, one of each, of ferromagnetic and anti-ferromagnetic

substances.

19. How many atoms are needed for the formation of one unit cell of bcc
configuration? Why?

20. For which reaction, the Enthalpy will be zero?

2 I. In the flue cell, the electroenergy produced during the formation of

1 mol H2 0 (l) is equal to 50 K.cal. and standard free energy of water
is 68.32 K. cal./mol. Find out the efficiency of the Flue cell.
22. Give the structural formula of 0-hydroxy amino ethyl benzoate.
23. What is Tyndall effect?
24. Give the equation of obtaining Sodium salt of triphosphoric acid.
25. Write the theoretical and practical electron configuration of Cerium
(Z = 58).

26. Give the formula and IUPAC name of Sodium Nitroprusside.

27. Sodium's stable isotope is 11Na2 3. If we take 11Na24, it shows which

type of radioactivity? Show it by equation.

28. What is causing fermentation of D-glucose? And which glucose is not

fermented by the same?

29. Show the possible isomers of C6H6O2 with their common names. (any
two).

30. Complete the equation.

Cone. H2SO4
CH3.CN + CH3 .CH2 .OH + H2O
�
Acetonitrile Ethenol

31. Give the basic difference between glycylalanine and alanyl glycine.

32. What is Leuco salt?

SECTION- C

Question Nos. from 33 to 48 are short answer type Questions. 32

Each question carries TWO marks.
33. Give molecular electron configuration of 02 molecule and explain its
magnetic properties.
OR
What is Van der Waals' attraction? On which factors do it depend?
34. What is Hybridization? Give hybridization, geometrical shape and
bond angle of Fe(CO)5 .

35. Write a short note on: Frenkel Defects.

36. Find out mole fractions of solute and solvent of 1 molal aqueous
solution.
OR
How many millimoles of CO2 will dissolve in 900 ml water, when
CO2 gas is passed from water at 25°C.
(KH = 6.02 x 10-4 bar and partial pressure of CO2 is 2 xl0-8 bar).
37. Explain the expansion of ideal gas in vacuum and change in Entropy.

38. Write Second Law of Thermo-dynamics and its limitations.

39. Give the structural formulas of Phosphonic acid and Pyrophosphoric

acid.
OR
Give the equation of Aluminium with dil. HCI and cone. alkali.

40. "Although first ionization energy is less than second ionization

energy, M 1 + compounds of transition elements can not be made
easily in comparison to M2 + compounds." Explain.
OR
Mention the uses of Lanthanides. (any four)

41. [Ni F4] 2- IS diamagnetic, whereas [Ni(CN)4] 2- Is paramagnetic.

Explain.

42. Write a note on Breeder Reactor.

43. Calculate the energy released in the following fusion reaction.

2H
1 +13H �24H e+on
1

(Mass: iH = 2.014; �H = 3.016; :He = 4.003, n =l.009 amu)

44. Give the organic conversion of the following.

Isopropyl Alcohol from acetaldehyde.
OR
Acetoxime from Isopropyl Alcohol.

45. Write conversion of

P-hydroxy azobenzene from Aniline.

46. Explain CarbyI test with equation (any one).

47. Mention full names, polymer structure and uses of PTFE and PAN.

48. Write a note on Pheromones.

 SECTION-D
Question Nos. 49 to 60 are long answer type questions. 36

Each question carries THREE marks. Answer the following to the point.

49. What is meant by Molal Elevation constant? Derive formula for

Molal Elevation constant.
OR
What is meant by Molal Depression constant?
Derive formula for Molal Depression constant.

50. The potential of the following given cell is 0.59 volt. Calculate the
ionic product of Water (Kw).
Pt/ H2 (1 atm) I KOH(O.OlM) II HCl(O.OlM) I H2 (1 atm) I Pt
OR
Calculate cell voltage of the following electrochemical cell at 25 °C
and write cell reaction.

Al I Al2 (S04) 3 (aq) /I CuS04 (aq) / Cu

(lM) (0.02 M)

(E0 Al3+ I Al = -1.66 V; E° Cu I Cu2 + = - 0.34 V)

51. The decomposition of N20 5 dissolved in Carbon tetrachloride

decomposes at definite temperature as follows.

N205 (solution) = 2 N02 (solution) + ½ 02rgJ

This reaction is of 1st order and its rate constant is 5.0 xl0-4 sec-1.
For this reaction initial cone. of N20 5 is 0.25 mole/ litre.

(i) What time will be required for completion of 75% of reaction?

(ii) What will be the concentrations of N205 and N02 after

30 minutes from the start of the reaction?
52. Derive formula of Langmuir Absorption Isotherm and express the
equation at low and high pressure situations.

53. Give only equations of production of Chlorine and Iodine.

OR
Mention equations of the formation of XeF 2, XeF 4 and XeF 6 with
their structures.

54. Write points of tendency of transition metal ions to form complex

compounds.

55. Explain hybridization, geometrical shape and magnetic properties of

complex compound KiFe(CN) 6].
OR
Show geometrical isomers in cis-trans and facial meridonial results
of metal ion Fe and Co bearing 6 co-ordination number.

56. Explain steps of R & S nomenclature.

57. Explain and give equations of industrial manufacturing of Salicylic

acid by Kolbe-Schmitt reaction.

58. Explain Wolff-Kishner and Clemmenson reduction reactions.

OR
Give only equations of dehydration reactions of amides and its
Hoffman reaction.

59. Explain Filler, Plasticizer and Anti-oxidants.

60. Explain classification of Lipids.