44-261 Ammonium Chloride

Revision date: 30/01/2020 Version number: 2.
004 Supersedes date: 16/10/2018
SAFETY DATA SHEET

AMMONIUM CHLORIDE
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier

Product name AMMONIUM CHLORIDE
Product number 261
Synonyms; trade names AMMONIUM CHLORATUM, AMMONIUM CHLORIDE RWS FOOD GRADE, AMMONIUM
CHLORIDE MIN 99.5%, AMMONIUM CHLORIDE TECHNICAL GRADE, NON FOOD
GRADE, AMM CHLORIDE NO AC, AMM CHLORIDE U, AMM CHLORIDE FINE WHITE
RWN, AMMONIUM CHLORIDE S FG/PH, AMMONIUM CHLORIDE 99/100%, AMMONIUM
CHLORIDE AC (RWN) TECH, AMM CHLORIDE RWN BSF, AMMONIUM CHLORIDE RWT
REACH registration number 01-2119487950-27-XXXX
REACH registration notes 01-2119489385-24-XXXX
CAS number 12125-02-9
EU index number 017-014-00-8
EC number 235-186-4
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Food / Feed additive Chemical Intermediate
1.3. Details of the supplier of the safety data sheet

Supplier Univar Solutions UK Ltd
Aquarius House
6 Mid Point Business Park
Bradford
BD3 7AY
+44 1274 267300
+44 1274 267306
SDS.EMEA@univarsolutions.com
1.4. Emergency telephone number

Emergency telephone SGS - +32 (0)3 575 55 55 (24h)
Sds No. 261
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Not Classified
Health hazards Acute Tox. 4 - H302 Eye Irrit. 2 - H319
Environmental hazards Not Classified
2.2. Label elements
1/31
Revision date: 30/01/2020 Version number: 2.004 Supersedes date: 16/10/2018
AMMONIUM CHLORIDE
EC number 235-186-4
Hazard pictograms
Signal word Warning
Hazard statements H302 Harmful if swallowed.

H319 Causes serious eye irritation.
Precautionary statements P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301+P312 IF SWALLOWED: Call a POISON CENTRE/doctor if you feel unwell.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/ container in accordance with national regulations.
2.3. Other hazards

This substance is not classified as PBT or vPvB according to current EU criteria.
SECTION 3: Composition/information on ingredients
3.1. Substances
REACH registration notes 01-2119489385-24-XXXX
EU index number 017-014-00-8
EC number 235-186-4
Composition comments The data shown are in accordance with the latest EC Directives.
SECTION 4: First aid measures
4.1. Description of first aid measures

Inhalation Move affected person to fresh air and keep warm and at rest in a position comfortable for
breathing. Get medical attention if any discomfort continues.
Ingestion Rinse mouth thoroughly with water. Do not induce vomiting. If vomiting occurs, the head
should be kept low so that stomach vomit doesn't enter the lungs. Give plenty of water to
drink. Get medical attention.
Skin contact Remove contaminated clothing immediately and wash skin with soap and water. Get medical
attention if any discomfort continues.
Eye contact Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wide
apart. Continue to rinse for at least 15 minutes. Get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
General information Overexposure may cause the following adverse effects: Nausea, vomiting. Headache.
Ingestion Harmful if swallowed.
Eye contact Causes serious eye irritation.
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AMMONIUM CHLORIDE
4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media

Suitable extinguishing media Water spray.
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
5.2. Special hazards arising from the substance or mixture

Hazardous combustion When heated, vapours/gases hazardous to health may be formed. Ammonia. Hydrogen
products chloride (HCl).
5.3. Advice for firefighters

Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet. Avoid inhalation
of dust and contact with skin and eyes. Provide adequate ventilation.
6.2. Environmental precautions

Environmental precautions Avoid discharge into water courses or onto the ground. Spillages or uncontrolled discharges
into watercourses must be reported immediately to the Environmental Agency or other
appropriate regulatory body.
6.3. Methods and material for containment and cleaning up

Methods for cleaning up Avoid generation and spreading of dust. Collect and place in suitable waste disposal
containers and seal securely. Label the containers containing waste and contaminated
materials and remove from the area as soon as possible. Avoid the spillage or runoff entering
drains, sewers or watercourses.
6.4. Reference to other sections

Reference to other sections For personal protection, see Section 8. For waste disposal, see Section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling

Usage precautions Avoid generation and spreading of dust. Avoid inhalation of dust and contact with skin and
eyes. Provide adequate ventilation.
7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store in tightly-closed, original container in a well-ventilated place. Avoid contact with the
following materials: Alkalis. Oxidising agents. Nitrites Sodium nitrate Protect from moisture.
7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.
SECTION 8: Exposure controls/Personal protection
8.1. Control parameters

Occupational exposure limits
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AMMONIUM CHLORIDE
Long-term exposure limit (8-hour TWA): WEL 10 mg/m³ fume

Short-term exposure limit (15-minute): WEL 20 mg/m³ fume
WEL = Workplace Exposure Limit
DNEL Industry - Inhalation; Long term systemic effects: 43.97 mg/m³

Industry - Dermal; Long term systemic effects: 128.9 mg/kg/day
Consumer - Inhalation; Long term systemic effects: 9.4 mg/m³
Consumer - Dermal; Long term systemic effects: 55.2 mg/kg/day
Consumer - Oral; Long term systemic effects: 55.2 mg/m³
PNEC - Fresh water; 0.25 mg/l

- marine water; 0.025 mg/l
- Sediment (Freshwater); 0.9 mg/kg
- Soil; 50.7 mg/kg
- STP; 13.1 mg/l
- Sediment (Marinewater); 0.09 mg/kg
- Intermittent release; 0.43 mg/l
8.2. Exposure controls
Protective equipment
Appropriate engineering Provide adequate ventilation. Observe occupational exposure limits and minimize the risk of
controls inhalation of dust. Provide eyewash station and safety shower.
Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicates
eye contact is possible. Unless the assessment indicates a higher degree of protection is
required, the following protection should be worn: Wear chemical splash goggles. Personal
protective equipment for eye and face protection should comply with European Standard
EN166.
Hand protection The most suitable glove should be chosen in consultation with the glove
supplier/manufacturer, who can provide information about the breakthrough time of the glove
material. Chemical-resistant, impervious gloves complying with an approved standard should
be worn if a risk assessment indicates skin contact is possible. The selected gloves should
have a breakthrough time of at least 8 hours. Chloroprene rubber. Protective gloves should
have a minimum thickness of 0.5 mm. Butyl rubber. Viton rubber (fluoro rubber). Polyvinyl
chloride (PVC). Protective gloves should have a minimum thickness of 0.7 mm. Nitrile rubber.
Protective gloves should have a minimum thickness of 0.4 mm. To protect hands from
chemicals, gloves should comply with European Standard EN374.
Hygiene measures Wash at the end of each work shift and before eating, smoking and using the toilet. When
using do not eat, drink or smoke. Take off contaminated clothing and wash it before reuse.
Respiratory protection Respiratory protection must be used if the airborne contamination exceeds the recommended
occupational exposure limit. Particulate filter, type P1. EN 136/140/141/145/143/149
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties

Appearance Crystalline powder.
Colour White.
Odour Almost odourless.
Odour threshold No information available.
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AMMONIUM CHLORIDE
pH pH (diluted solution): 4.7 @ 0.2%
Melting point 338°C
Initial boiling point and range No information available.
Flash point No information available.
Evaporation rate No information available.
Evaporation factor No information available.
Flammability (solid, gas) No information available.
Upper/lower flammability or No information available.

explosive limits
Other flammability No information available.
Vapour pressure 66 mbar @ 250°C
Vapour density No information available.
Relative density 1.53 @ 25°C
Bulk density 600-900 kg/m³
Solubility(ies) 372 g/l water @ 20°C
Partition coefficient No information available.
Auto-ignition temperature No information available.
Decomposition Temperature No information available.
Viscosity No information available.
Explosive properties Not considered to be explosive.
Explosive under the influence No information available.

of a flame
Oxidising properties Does not meet the criteria for classification as oxidising.
9.2. Other information

Other information Not determined.
Refractive index No information available.
Particle size No information available.
Molecular weight No information available.
Volatility No information available.
Saturation concentration No information available.
Critical temperature No information available.
Volatile organic compound No information available.
SECTION 10: Stability and reactivity
10.1. Reactivity
Reactivity Stable at normal ambient temperatures and when used as recommended.
10.2. Chemical stability
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AMMONIUM CHLORIDE
Stability Stable at normal ambient temperatures.
10.3. Possibility of hazardous reactions

Possibility of hazardous The following materials may react violently with the product: Oxidising agents. The following
reactions materials may react with the product: Inorganic nitrites. Organic nitrites.
10.4. Conditions to avoid

Conditions to avoid Avoid excessive heat for prolonged periods of time. Water, moisture.
10.5. Incompatible materials

Materials to avoid Organic nitrites. Inorganic nitrites. Inorganic nitrates. Strong oxidising agents. Strong alkalis.
10.6. Hazardous decomposition products

Hazardous decomposition When heated, vapours/gases hazardous to health may be formed. Ammonia or amines.
products Hydrogen chloride (HCl).
SECTION 11: Toxicological information
11.1. Information on toxicological effects

Acute toxicity - oral
Acute toxicity oral (LD₅₀ 1,410.0
mg/kg)
Species Rat
ATE oral (mg/kg) 500.0
Acute toxicity - dermal

Notes (dermal LD₅₀) LD₅₀ >2000 mg/kg, Dermal, Rat
Skin corrosion/irritation
Animal data Not irritating.
Serious eye damage/irritation

Serious eye damage/irritation Irritating. Rabbit
Respiratory sensitisation
Respiratory sensitisation No information available.
Skin sensitisation
Skin sensitisation Not sensitising. Guinea pig maximization test (GPMT)
Germ cell mutagenicity

Genotoxicity - in vitro Based on available data the classification criteria are not met.
Carcinogenicity
Carcinogenicity Based on available data the classification criteria are not met.
Reproductive toxicity
Reproductive toxicity - Based on available data the classification criteria are not met.
development
Specific target organ toxicity - single exposure

STOT - single exposure Based on available data the classification criteria are not met.
Specific target organ toxicity - repeated exposure

STOT - repeated exposure Based on available data the classification criteria are not met.
Aspiration hazard
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AMMONIUM CHLORIDE
Aspiration hazard No information available.
Inhalation Dust in high concentrations may irritate the respiratory system.
Ingestion Harmful if swallowed. The product irritates mucous membranes and may cause abdominal
discomfort if swallowed.
Skin contact Prolonged skin contact may cause temporary irritation.
Eye contact Causes serious eye irritation.
SECTION 12: Ecological information
Ecotoxicity The product components are not classified as environmentally hazardous. However, large or
frequent spills may have hazardous effects on the environment.
12.1. Toxicity
Toxicity Not considered toxic to fish.
Acute aquatic toxicity

Acute toxicity - fish LC₅₀, 96 hours: 42.91 mg/l, Oncorhynchus mykiss (Rainbow trout)
Acute toxicity - aquatic EC₅₀, 48 hours: 136.6 mg/l, Daphnia magna

invertebrates
Acute toxicity - aquatic plants EC₅₀, 5 days: 1300 mg/l, Algae

This information is based on test data from similar products
Acute toxicity - EC₂₀, 0.5 hour: 850 mg/l, Activated sludge

microorganisms OECD 209
Chronic aquatic toxicity

Chronic toxicity - fish early life EC10, 30 days: 4.28 mg/l, Lepomis macrochirus (Bluegill)
stage
Chronic toxicity - aquatic EC10, 70 days: 2.52 mg/l, Freshwater invertebrates

invertebrates
12.2. Persistence and degradability

Persistence and degradability The product contains only inorganic substances which are not biodegradable.
12.3. Bioaccumulative potential

Bioaccumulative potential The product does not contain any substances expected to be bioaccumulating.
Partition coefficient No information available.
12.4. Mobility in soil

Mobility The product is soluble in water.
12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB This substance is not classified as PBT or vPvB according to current EU criteria.
assessment
12.6. Other adverse effects

Other adverse effects Not determined.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
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AMMONIUM CHLORIDE
General information Waste is classified as hazardous waste. Do not puncture or incinerate, even when empty.
Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority.
SECTION 14: Transport information
General The product is not covered by international regulations on the transport of dangerous goods
(IMDG, IATA, ADR/RID).
14.1. UN number
Not applicable.
14.2. UN proper shipping name

Not applicable.
14.3. Transport hazard class(es)

No transport warning sign required.
14.4. Packing group

Not applicable.
14.5. Environmental hazards
Environmentally hazardous substance/marine pollutant

No.
14.6. Special precautions for user

Not applicable.
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).
Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures (as
amended).
Commission Regulation (EU) No 2015/830 of 28 May 2015.
15.2. Chemical safety assessment

A chemical safety assessment has been carried out.
Inventories
EU - EINECS/ELINCS
All the ingredients are listed or exempt.
SECTION 16: Other information
8/31
AMMONIUM CHLORIDE
Abbreviations and acronyms ATE: Acute Toxicity Estimate.

used in the safety data sheet ADR: European Agreement concerning the International Carriage of Dangerous Goods by
Road.
ADN: European Agreement concerning the International Carriage of Dangerous Goods by
Inland Waterways.
CAS: Chemical Abstracts Service.
DNEL: Derived No Effect Level.
IATA: International Air Transport Association.
IMDG: International Maritime Dangerous Goods.
Kow: Octanol-water partition coefficient.
LC₅₀: Lethal Concentration to 50 % of a test population.
LD₅₀: Lethal Dose to 50% of a test population (Median Lethal Dose).
PBT: Persistent, Bioaccumulative and Toxic substance.
PNEC: Predicted No Effect Concentration.
REACH: Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation
(EC) No 1907/2006.
RID: European Agreement concerning the International Carriage of Dangerous Goods by
Rail.
vPvB: Very Persistent and Very Bioaccumulative.
IARC: International Agency for Research on Cancer.
MARPOL 73/78: International Convention for the Prevention of Pollution From Ships, 1973 as
modified by the Protocol of 1978.
cATpE: Converted Acute Toxicity Point Estimate.
BCF: Bioconcentration Factor.
BOD: Biochemical Oxygen Demand.
EC₅₀: 50% of maximal Effective Concentration.
LOAEC: Lowest Observed Adverse Effect Concentration.
LOAEL: Lowest Observed Adverse Effect Level.
NOAEC: No Observed Adverse Effect Concentration.
NOAEL: No Observed Adverse Effect Level.
NOEC: No Observed Effect Concentration.
LOEC: Lowest Observed Effect Concentration.
DMEL: Derived Minimal Effect Level.
EL50: Exposure Limit 50
hPa: Hectopascal
LL50: Lethal Loading fifty
OECD: Organisation for Economic Co-operation and Development
POW: Octanol-water partition coefficient
SCBA: self-contained breathing apparatus
STP: Sewage Treatment Plant
VOC: Volatile Organic Compounds
Classification abbreviations Acute Tox. = Acute toxicity

and acronyms Aquatic Acute = Hazardous to the aquatic environment (acute)
Aquatic Chronic = Hazardous to the aquatic environment (chronic)
Revision comments NOTE: Lines within the margin indicate significant changes from the previous revision.
Revision date 30/01/2020
Version number 2.004
Supersedes date 16/10/2018
SDS number 261
SDS status Approved.
9/31
AMMONIUM CHLORIDE
Hazard statements in full H302 Harmful if swallowed.

H319 Causes serious eye irritation.
Signature Jitendra Panchal
10/31
Exposure scenario
Manufacture of substance, Distribution of substance
Identification

Aquarius House
Bradford
BD3 7AY
+44 1274 267300
+44 1274 267306
1. Title of exposure scenario
Main title Manufacture of substance, Distribution of substance
Process scope Manufacture of the substance or use as a process chemical or extraction agent. Includes
recycling/recovery, material transfers, storage, maintenance and loading (including marine
vessel/barge, road/rail car and bulk container), sampling and associated laboratory activities.
Main sector SU3 Industrial uses
Environment
Environmental release ERC1 Manufacture of the substance
category
Worker
Process category PROC2 Chemical production or refinery in closed continuous process with occasional
controlled exposure or processes with equivalent containment conditions
PROC9 Transfer of substance or mixture into small containers (dedicated filling line, including
weighing)
2. Conditions of use affecting exposure (Industrial - Environment 1)
Control of environmental exposure

Not regarded as dangerous for the environment. As no environmental hazard was identified,
no environmental-related exposure assessment and risk characterisation was performed.
2. Conditions of use affecting exposure (Workers - Health 1)
Control of workers exposure

Process category PROC2 Chemical production or refinery in closed continuous process with occasional
controlled exposure or processes with equivalent containment conditions
weighing)
11/31
Manufacture of substance, Distribution of substance
Product characteristics
Physical state Solid, medium dustiness
Concentration details Covers concentrations up to 100 %.
Frequency and duration of use

Covers daily exposures up to 8 hours (unless stated differently).
Human factors not influenced by risk management

Potentially exposed body Palm of both hands. Covers skin contact area up to 480 cm².
parts
Other given operational conditions affecting workers exposure

Setting Indoor.
Risk management measures

Use suitable eye protection.
Risk Management Measures are based on qualitative risk characterisation.
3. Exposure estimation (Health 1)
Assessment method ECETOC TRA v2.0 Worker; modified version
Exposure PROC2, Worker - inhalation, long-term - systemic: Exposure 0.5 mg/m³, DNEL 43.97 mg/m³,
RCR 0.01
Worker - dermal, long-term - systemic: Exposure 1.4 mg/kg/day, DNEL 128.9 mg/kg, RCR
0.01
PROC9, Worker - inhalation, long-term - systemic: Exposure 5 mg/m³, DNEL 43.97 mg/m³,
RCR 0.11
0.05
4. Guidance to check compliance with the exposure scenario (Health 1)
For scaling see http://www.ecetoc.org/tra
12/31
Exposure scenario
Formulation & (re)packing of substances and mixtures, Industrial applications
Identification

Aquarius House
Bradford
BD3 7AY
+44 1274 267300
+44 1274 267306
Main title Formulation & (re)packing of substances and mixtures, Industrial applications

SU10 Formulation [mixing] of preparations and/or re-packaging
SU16 Manufacture of computer, electronic and optical products, electrical equipment
Environment
Environmental release ERC2 Formulation into mixture
category ERC5 Use at industrial site leading to inclusion into/onto article
ERC7 Use of functional fluid at industrial site
ERC8a Widespread use of non-reactive processing aid (no inclusion into or onto article,
indoor)
ERC9a Widespread use of functional fluid (indoor)
ERC9b Widespread use of functional fluid (outdoor)
Worker
Process category PROC4 Chemical production where opportunity for exposure arises
PROC5 Mixing or blending in batch processes
PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities
weighing)
PROC15 Use as laboratory reagent.
PROC19 Manual activities involving hand contact

13/31



parts

Setting Indoor.


Process category PROC19 Manual activities involving hand contact


Potentially exposed body Both hands and main part of the arms. Covers skin contact area up to 1980 cm².
parts

Setting Indoor.

Wear suitable gloves (tested to EN374) and eye protection.
14/31
Exposure PROC4 Chemical production where opportunity for exposure arises

Worker - inhalation, long-term - systemic: Exposure 5 mg/m³, DNEL 43.97 mg/m³, RCR 0.11
0.05

0.11

0.05

Worker - inhalation, long-term - systemic: Exposure 0.05 mg/m³, DNEL 43.97 mg/m³, RCR
0.01
0.003
Exposure Worker - inhalation, long-term - systemic: Exposure 5 mg/m³, DNEL 43.97 mg/m³, RCR 0.11
0.22
15/31
Exposure scenario
Formulation & (re)packing of substances and mixtures, Professional applications
Identification

Aquarius House
Bradford
BD3 7AY
+44 1274 267300
+44 1274 267306
Main title Formulation & (re)packing of substances and mixtures, Professional applications
Main sector SU22 Professional uses

Environment
category ERC5 Use at industrial site leading to inclusion into/onto article
ERC7 Use of functional fluid at industrial site
indoor)
Worker
weighing)
PROC13 Treatment of articles by dipping and pouring.
PROC19 Manual activities involving hand contact
PROC26 Handling of solid inorganic substances at ambient temperature

16/31

weighing)
PROC26 Handling of solid inorganic substances at ambient temperature

Covered by
weighing)


parts

Setting Indoor.




parts

Setting Indoor.
17/31

0.05

0.11

0.05

Worker - inhalation, long-term - systemic: Exposure 0.05 mg/m³, DNEL 43.97 mg/m³, RCR
0.01
0.003

0.11
Exposure Worker - inhalation, long-term - systemic: Exposure 5 mg/m³, DNEL 43.97 mg/m³, RCR 0.11
0.22
18/31
Exposure scenario
Usa as Cross-linking agent, Use in/as Composite Material based on wood, mineral and natural
fibres, Industrial applications
Identification

Aquarius House
Bradford
BD3 7AY
+44 1274 267300
+44 1274 267306
Main title Usa as Cross-linking agent, Use in/as Composite Material based on wood, mineral and
natural fibres, Industrial applications

SU6a Manufacture of wood and wood products
Environment
category ERC3 Formulation into solid matrix
ERC5 Use at industrial site leading to inclusion into/onto article
ERC6d Use of reactive process regulators in polymerisation processes at industrial site
(inclusion or not into/onto article)
Worker
Process category PROC6 Calendering operations.
PROC14 Tabletting, compression, extrusion, pelletisation, granulation


Process category PROC6 Calendering operations.
PROC14 Tabletting, compression, extrusion, pelletisation, granulation
19/31
Usa as Cross-linking agent, Use in/as Composite Material based on wood, mineral and natural
fibres, Industrial applications


parts

Setting Indoor.

Exposure PROC6, Worker - inhalation, long-term - systemic: Exposure 5 mg/m³, DNEL 43.97 mg/m³,
RCR 0.11
0.21
PROC14, Worker - inhalation, long-term - systemic: Exposure 1 mg/m³, DNEL 43.97 mg/m³,
RCR 0.02
0.03
20/31
Exposure scenario
Use as a Process chemical, Use in Metallurgy, Use in Metal surface treatment, Use in leather
tanning, finishing, impregnation, Use for Electroplating, Use in Textile finishing, Use in
Biotechnology, Industrial applications, (indoor use)
Identification

Aquarius House
Bradford
BD3 7AY
+44 1274 267300
+44 1274 267306
Main title Use as a Process chemical, Use in Metallurgy, Use in Metal surface treatment, Use in leather

SU5 Manufacture of textiles, leather, fur
SU9 Manufacture of fine chemicals
SU14 Manufacture of basic metals, including alloys
SU15 Manufacture of fabricated metal products, except machinery and equipment
SU24 Scientific research and development
Environment
Environmental release ERC4 Use of non-reactive processing aid at industrial site (no inclusion into or onto article)
category ERC6a Use of intermediate
ERC6b Use of reactive processing aid at industrial site (no inclusion into or onto article)
indoor)
Worker
21/31
PROC6 Calendering operations.
PROC10 Roller application or brushing
PROC22 Manufacturing and processing of minerals and/or metals at substantially elevated
temperature
PROC23 Open processing and transfer operations at substantially elevated temperature
PROC25 Other hot work operations with metals




parts

Setting Indoor.


Process category PROC22 Manufacturing and processing of minerals and/or metals at substantially elevated
temperature
22/31


parts

Setting Indoor.


0.05

0.11

0.21

0.11
temperature
23/31
Exposure PROC22 Manufacturing and processing of minerals and/or metals at substantially elevated
temperature
0.02

0.01

0.002
24/31
Exposure scenario
Use as a Process chemical, Use in Metallurgy, Use in leather tanning, finishing, impregnation,
Use in Metal surface treatment, Use for Electroplating, Use in Textile finishing, Use in
Biotechnology, Industrial applications, (outdoor use)
Identification

Aquarius House
Bradford
BD3 7AY
+44 1274 267300
+44 1274 267306
Main title Use as a Process chemical, Use in Metallurgy, Use in leather tanning, finishing, impregnation,

SU5 Manufacture of textiles, leather, fur
SU9 Manufacture of fine chemicals
SU22 Professional uses
SU24 Scientific research and development
Environment
Environmental release ERC8d Widespread use of non-reactive processing aid (no inclusion into or onto article,
category outdoor)
Worker
PROC22 Manufacturing and processing of minerals and/or metals at substantially elevated
temperature
25/31




parts

Setting Outdoor use.


temperature


parts
26/31
Setting Covers outdoor use.


Worker - inhalation, long-term - systemic: Exposure 3.5 mg/m³, DNEL 43.97 mg/m³, RCR 0.08
0.05

0.11

0.21

0.11
temperature
27/31
Exposure PROC22 Manufacturing and processing of minerals and/or metals at substantially elevated
temperature
0.02

0.01

0.002
28/31
Exposure scenario
Biotechnology, Professional applications, (indoor use)
Identification

Aquarius House
Bradford
BD3 7AY
+44 1274 267300
+44 1274 267306
Main title Use as a Process chemical, Use in Metallurgy, Use in Metal surface treatment, Use in leather
Main sector SU5 Manufacture of textiles, leather, fur

SU22 Professional uses
Environment
Environmental release ERC4 Use of non-reactive processing aid at industrial site (no inclusion into or onto article)
category ERC6b Use of reactive processing aid at industrial site (no inclusion into or onto article)
indoor)
Worker
29/31



parts

Setting Indoor.


Process category PROC23 Open processing and transfer operations at substantially elevated temperature


parts

Setting Indoor.

30/31

0.05

0.11

0.21

0.11
Process category PROC23 Open processing and transfer operations at substantially elevated temperature
Exposure PROC23 Open processing and transfer operations at substantially elevated temperature
0.01

0.002
31/31

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Revision date: 30/01/2020 Version number: 2.

004 Supersedes date: 16/10/2018

SAFETY DATA SHEET

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product number 261

REACH registration number 01-2119487950-27-XXXX

REACH registration notes 01-2119489385-24-XXXX

CAS number 12125-02-9

EU index number 017-014-00-8

1.3. Details of the supplier of the safety data sheet

1.4. Emergency telephone number

Sds No. 261

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Health hazards Acute Tox. 4 - H302 Eye Irrit. 2 - H319

Environmental hazards Not Classified

2.2. Label elements

Signal word Warning

Hazard statements H302 Harmful if swallowed.

2.3. Other hazards

SECTION 3: Composition/information on ingredients

REACH registration number 01-2119487950-27-XXXX

REACH registration notes 01-2119489385-24-XXXX

EU index number 017-014-00-8

CAS number 12125-02-9

SECTION 4: First aid measures

4.1. Description of first aid measures

Ingestion Harmful if swallowed.

Eye contact Causes serious eye irritation.

SECTION 5: Firefighting measures

5.1. Extinguishing media

5.2. Special hazards arising from the substance or mixture

5.3. Advice for firefighters

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.2. Environmental precautions

6.3. Methods and material for containment and cleaning up

6.4. Reference to other sections

SECTION 7: Handling and storage

7.1. Precautions for safe handling

7.2. Conditions for safe storage, including any incompatibilities

7.3. Specific end use(s)

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

Long-term exposure limit (8-hour TWA): WEL 10 mg/m³ fume

DNEL Industry - Inhalation; Long term systemic effects: 43.97 mg/m³

PNEC - Fresh water; 0.25 mg/l

8.2. Exposure controls

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Odour Almost odourless.

Odour threshold No information available.

pH pH (diluted solution): 4.7 @ 0.2%

Melting point 338°C

Initial boiling point and range No information available.

Flash point No information available.

Evaporation rate No information available.