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Sl No.Question Correct Answer

The packing efficiency of the two-dimensional square unit cell shown below is

(A) 39.27%
(B) 68.02%
(C) 74.05%
(D) 78.54%
D

The incorrect statement(s) for the packing of identical spheres in two dimension is

(A) For square close packing, coordination number is 4

2 (B) For hexagonal close packing, coordination number is 6
(C) There is only one void per atom in both, square and hexagonal close packing
(D) Hexagonal close packing is more efficiently packed than square close packing
C

˚
A solid element (monoatomic) exist as cubic crystal. If its atomic radius is 1.0A and the ratio of
packing fraction and density is 0.1cm3 /gm , then the atomic mass of the element is (NA = 6 × 10
23
)

(A) 8π
3
(B) 16π

(C) 80π

(D) 4π

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A metal crystallizes in such a lattice that only 70% of the total space crystal is occupied by the atoms.
If the atomic mass of metal is 32π gm mol−1 and atomic radius is 0.2nm, the density of the metal is

(A) 7.0gm/cm
3

4
(B) 3.5gm/cm
3

(C) 10.5gm/cm
3

(D) 14.0gm/cm
3

A compound has cubical unit cell in which X atoms are found at 6 corners and Y atoms are present at
remaining corners and at face centre which are not opposite to each other and Z-atoms are present at
˚ 3
body centre and remaining face center. Calculate density in amu/(A ) , if atomic mass of X, Y and Z

˚
are 20, 40 and 60 amu respectively and side of unit cell (2A )

235
5 (A)
8
940
(B)
8
470
(C)
8
235
(D)
16

In a compound , the atoms ‘A’ are present at three fourth of the corners and the atoms ‘B’ are present
only at two pairs of diagonally opposite edge centres. If the ‘C’ atoms are present at the vacant corners
and the edges. Find the simplest formula of the compound

6 (A) A 6 B 8 C18

(B) A 4 B 8 C10

(C) A 3 B 4 C9

(D) A 2 B 8 C18

In a hydrogen like species, an electron jumps from an orbital having two radial and two angular nodes
to the orbital having same sign of wave function in all direction and having zero radial node at any
distance. If the energy of emitted photon is 326.4 eV, the atom or ion is

7 (A) H

(B) Li
2+

(C) He
+

(D) B
4+

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An electron revolving around H-nucleus in ground state absorbs 10.2eV energy. Its angular
momentum increase by

h
(A)
2π
h
8 (B)
π
2h
(C)
π
h
(D)
4π

The given diagram shows points P1 , P2 , P3 and P4 in 1s orbital

Correct order of radial probability density at these point

are

(A) P1 = P2 = P4 > P3

(B) P1 = P3 < P2 = P4

(C) P1 = P3 > P2 = P4

(D) P1 = P2 = P4 < P3

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PV
The given graph represents the variation of Z (compressibility factor = ) versus P, for three real
nRT

gases A, B and C. Identify the only INCORRECT statement.

10

(A) For the gas A, a = 0 and its dependence on P is linear at all pressure
(B) For the gas B, b = 0 and its dependence on P is linear at all pressure
(C) For the gas C, which is typical real gas for which neither a nor b = 0. By knowing the minima and
the point of intersection, with Z = 1, a and b can be calculated.
(D) At high pressure, the slope is positive for all real gases A, B and C
D

If the number of molecules of S O2 (M = 64) effusing through an orifice of unit area of cross section
in unit at 0°C and 1 atm pressure is ‘n’. The number of He molecules (M = 24) effusing in unit time
similar conditions at 273°C and 0.25atm is

n
(A)
11 –
√2
n
(B)
2

(C) 2n
–
(D) √2n

An open vessel at 27°C heated until 3/8th of air in it has been expelled. Assuming that the volume
remain constant, find the temperature at which the vessel was heated

(A) 307°C
12
(B) 107°C
(C) 480°C
(D) 207°C
D

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The density of a gaseous substance at 1 atm pressure and 773K is 0.4g/L. If the molecular weight of
the substance is 30, then dominant forces existing among gas molecules is

(A) repulsive
13
(B) attractive
(C) both
(D) none of these
A

0.5 mol of a diatomic gas present in 10L vessel at certain temperature exert a pressure of 0.96atm.
Under similar conditions an ideal gas exerted 1.0 atm pressure. If volume of gas molecules is negligible
then, the value of vander waals constant “a” (in atm L2 /mol2 ) is

14 (A) 4
(B) 16
(C) 32
(D) 8
B

Assume, as Dalton did, that the atomic mass of oxygen is 7. A sample of 11 g of a Uranium oxide
contains 10 grams Uranium. Which of the following statements is compatible with this data?

(A) Uranium oxide is UO and the atomic mass of U is 70

15
(B) Uranium oxide is U3 O8 and the atomic mass of U is 240
(C) Uranium oxide is U O3 and the atomic mass of U is 105
(D) Uranium oxide is U2 O3 and the atomic mass of U is 105.
D

Zinc sulphate contains 22.65% of Zinc and 43.9% of water of crystallization. If the law of constant
proportions is true, then the weight of zinc required to produce 20g of the crystals will be (atomic weight
zinc = 66)

16 (A) 45.3g
(B) 4.53g
(C) 0.453g
(D) 453g
B

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Two elements X and Y have atomic weights of 14 and 16. They form a series of compounds A, B, C,
D and E in which the same amount of element X, Y is present in the ratio 1 : 2 : 3 : 4 : 5. If the
compound A has 28 parts by weight of X and 16 parts by weight of Y, then the compound of C will have
28 parts weight of X and

17
(A) 32 parts by weight of Y
(B) 48 parts by weight of Y
(C) 64 parts by weight of Y
(D) 16 parts by weight of Y
B

The mass of P4 O10 produced if 440gm of P4 S3 is mixed with 384gm of O2 is

P 4 S3 + O2 → P 4 O10 + S O2

(A) 568gm
18
(B) 426gm
(C) 284gm
(D) 396gm
A

In Br 3 O8 , oxidation numbers of three bromines are

(A) +6, +4, +6

19 (B) +7, +2, 7
(C) +8, 0, +8
(D) +4, +4, +8
A

20 (A) -2
(B) -3
(C) -1
(D) -4
B

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Reaction between magnesium dilute H N O3 is given below

M g + H N O3 → M g(N O3 ) 2 + N H4 N O3 + H3 O . In this reaction equivalent weight of H N O3 is
(M – M. W. of H N O3 )

M
(A)
21 8
M
(B)
4

(C) M

5M
(D)
4

A sample of F eS O4 and F eC2 O4 is dissolved in H2 S O4 . The complete oxidation of sample

required 8/3 equivalents of K M nO4 . After oxidation the reaction mixture was reduced by zinc. On
again oxidation by K M nO4 required 5/3 equivalents. The mole ratio of F eS O4 and F eC2 O4 is

22 (A) 3/4
(B) 7/3
(C) 5/7
(D) 7/5
B

Which of the following statements are correct?

(A) Ferrimagnetic substances lose ferrimagnetism on heating and become paramagnetic.

(B) Ferrimagnetic substances do not lose ferrimagnetism on heating and remain ferrimagnetic.
23 (C) Antiferromagnetic substances have domain structures similar to ferromagnetic substances and
their magnetic moments are not cancelled by each other.
(D) In ferromagnetic substances all the domains get oriented in the direction of magnetic field and
remain as such even after removing magnetic field.
A;D

Which of the following is incorrect about NaCl structure?

(A) Nearest neighbours of N a+ ion is six C l− ion

24 (B) Na
+
ion make bcc lattice
(C) Cl
−
ions are packed in cubic close packed arrangement
(D) There are eight next nearest neighbours of N a+ ion
B;D

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If observed density of crystal is less than ideal density, then the defect may be

(A) Schottky defect

25 (B) Frenkel defect
(C) Substitutional impurity
(D) metal deficiency defect
A;C;D

The co-ordination number of FCC structure for metals is 12, since

(A) each atom touches 4 others in same layer, 3 in layer above and 3 in layer below
26 (B) each atom touches 4 others in same layer, 4 in layer above and 4 in layer below
(C) each atom touches 6 others in same layer, 3 in layer above and 3 in layer below
(D) each atom touches 3 others in same layer, 6 in layer above and 6 in layer below
B;C

Select the correct information(s) regarding truncated tetrahedron

(A) 12 vertices
27 (B) 8 faces
(C) 18 edges
(D) 3 hexagonal faces
A;B;C

When photons of energy 4.25eV strike the surface of a metal ‘A’, the ejected photo electrons
maximum kinetic energy have wavelength λA . The maximum kinetic energy of photoelectrons liberated
from another metal ‘B’ by photons of energy 4.7eV is 1.5eV less than that of photo electrons of metal A.
If wavelength of photo electrons of metal B is twice than that of photoelectron of ‘A’ then

28
(A) Work function of A = 2.25eV
(B) Work function of B = 4.2eV
(C) Maximum (K.E.) of photoelectrons of ‘A’ = 2eV
(D) Maximum (K.E.) of photoelectrons of ‘B’ = 2.75eV
A;B;C

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–h
The orbital angular momentum of an electron in a single electron system is √3 . Which of the
π

following angular momentum value(s) are not possible for this electron in Bohr orbit.

3h
(A)
2π
29 h
(B)
π
3h
(C)
π
2h
(D)
π

A;B

A gas described by Van der Waals’ equation

(A) behaves similar to an ideal gas in the limit of large molar volumes
(B) behaves similar to an ideal gas in the limit of large pressures
30
(C) is characterized by van der Waal’s coefficients that are dependent on the identify of the gas but
are independent of the temperature
(D) has the pressure that is lower than the pressure exerted by the same gas behaving ideally
A;C;D

A closed container of volume 4.92 litre contains N H3 gas at 27°C as shown.

H2 S gas is passed inside the container at a

31 rate of 0.01 mole/sec, such that no gas is coming out from the container. The reaction take place in the
100%

container is 2N H3 (g) + H2 S (g) −−−→ (N H4 ) 2 S (s)

(Assume that there is no time lag in between H2 S gas passed and (N H4 ) 2 S formed).
The time at which the difference in Hg column is equal to 38 cm

(A) 0sec
(B) 20sec
(C) 10sec
(D) 25sec
A;C;D

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Comprehension
The hydrogen-like species Li2+ is in a spherically symmetric state S1 with one radial node. Upon
absorbing light the ion undergoes transition to a state S2 . The state S2 has one radial node and its
energy is equal to the ground state energy of the hydrogen atom
-- * --
Question :
The state S1 is
32

(A) 1s
(B) 2s
(C) 2p
(D) 3s
B

Question :
For H e+ ion, select incorrect option(s)

(A) Difference between radius of II and III Bohr’s orbit is greater than that of III and IV Bohr orbit
33 (B) Ratio of velocity of electron in III and IV Bohr’s orbit is less than one
(C) Energy difference between consecutive energy levels decreases continuously
(D) Ratio of wavelength of least energetic and most energetic photon of lyman series is (3/4)
C

Question :
The orbital angular momentum quantum number of the state S2 is

(A) 0
34 (B) 1
(C) 2
(D) 3
B

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Comprehension
The location of electron inside the atom can be predicted by wave mechanical model which gives
wave function of orbitals represented as ψn,ℓ,m where n, ℓ, m represents quantum numbers
sometimes. ϕ can be analysed as two separate components, radial and angular, represented as
ψ(r) and ψ(θ,ϕ) respectively for H, the following expressions of ψn,ℓ,m are known
2r
[where a0 is constant and σ is ]
na0
3/2
2 1 1 −σ/2
−a/2 2 e
ψ1,0,0 = e ψ3,0,0 = ( ) (6 − 6σ + σ )e
3/2 –
9√ 3 a0
a
0

3/2 3/2
1 1 1 1
−σ/2 −σ/2
psi 2,0,0 = ( ) (2 − σ)e ψ3,1,0 = ( ) (4 − σ)σe
35 –
a0
–
a0
2√ 2 9√ 3

-- * --
Question :
For 1s orbital H-atom, the radial probability will be maximum at what radial distance from nucleus

(A) r = 0 (at the nucleus)

(B) r = ∞

(C) r = a0

(D) r = 2a0

Question :
The distance from the nucleus (in terms of a0 ) where the second radial node is found for 3s (for
hydrogen) is

(A) 1.9
36
(B) 7.09

(C) 3.1

(D) 6.8

Question :
Which of the following statements are incorrect w.r.t. ψ(r) v/s r graph for H-atom

(A) For 1s orbital the graph will not intersect x-axis at finite distance
37 (B) For 2s orbital, the graph will have one ‘local minima’ only
(C) For 3s orbital, the graph will intersect x-axis at two distinct points
(D) For 3p orbital, the graph will intersect x-axis at two non-zero distinct points
D

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Comprehension
Recent communications with the inhabitants of Neptune have revealed that they have a Celsius type
temperature scale, but based on the melting point (0°N) and boiling point (100°N) of their most common
substance, hydrogen. Further communications have revealed that the Neptunians know about perfect
gas behaviour and that they find in the limit of zero pressure, the value of P Vm is 28L –atm at 0°N and
40L – atm at 100°N
-- * --
Question :
38
What is the value of the absolute zero of temperature on their temperature scale?

(A) 233.33°C
(B) -233.33°C
(C) -233.33°N
(D) 233.33°N
B

Question :
What is the value of universal gas constant?

(A) 0.082L – atm/K – mol

39 (B) 0.12L – atum/K – mol
(C) 0.4L – atm/K – mol
(D) Infinite
A

Question :
What is the volume occupied by 2 mole of a perfect gas at 2atm and 66.67°N?

(A) 36L
40 (B) 24.6L
(C) 20.0L
(D) 8.0L
B

If truncated octahedron has x corners y square faces and z hexagon then z – x/y = ?
41
4

If NaCl is dropped with 10−3 mol % S rC l2 , and the numbers of cation vacancies per mole of N aC l
is x × 1018 , the value of ‘x’ is (NA = 6 × 10
23

42

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If 4 times the most probable distance of electron of a 1s orbital in a unielectronic atom/ion is given by
˚
0.529A then the atomic number of the unielectronic species will be
−−−− − −−

 Z
3

43 [Given: wave function of 1s orbital, ψ = ( )e

−Zx/a0
Where a0 = radius of first Bohr’s orbital
3
⎷ πa
0

in $H – atom \eqiuv (52.pm) and Z is atomic number of unielectronic species]

4

Find the number of spectral lines in Paschen series emitted by atomic H, when electron is excited
44 from ground state to 7 energy level returns back.
th

The figure shows a sample of H-atoms having electron revolving in higher orbit ‘n’.

If this electron makes transition from orbit ‘n’ to ground state, No. of
45

Paschen lines emitted are .

3

500ml of a vessel contains an ideal gas saturated with water vapours at 3.2atm and 47°C. Now the
entire mass is transferred into vessel of 1800ml capacity maintained at 87°C. The final pressure (in atm)
46
becomes (vapour pressure of water at 47° and 87° C are 0.2atm and 0.6atm, respectively)
1

COLUMN - I COLUMN - II

(A) ℓ (P) Indicates the distance from nucleus

(B) s (Q) It can have only two possible values

47 (C) m (R) Indicates the possible

(D) n (S) Indicates the possible orientations in space

(T) Possible values are +ℓ to − ℓ including ‘Zero’

R;Q;ST;P

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COLUMN - I COLUMN - II

(A) Hydrogen gas (P = 200atm, T = 273K) (P) Compressibility factor ≠ 1

(B) Hydrogen gas (P ∼ 0, T = 273K ) (Q) Attractive forces are dominant

48
(C) C O2 (P = 1atm, T = 273K ) (R) PV = nRT

(D) Real gas with very large molar volume (S) P(V – nb) = nRT

PS;R;PQ;R

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