FINAL JEE–MAIN EXAMINATION – JANUARY, 2024

(Held On Monday 29th January, 2024) TIME : 9 : 00 AM to 12 : 00 NOON

MATHEMATICS TEST PAPER WITH SOLUTION

SECTION-A 2  2x ,  1  x  0
 x ,  3  x  0
3. If f  x    x ; g x   ,
1. If in a G.P. of 64 terms, the sum of all the terms is 1 , 0  x  3 x, 0  x  1
 3
7 times the sum of the odd terms of the G.P, then then range of (fog(x)) is
the common ratio of the G.P. is equal to (1) (0, 1] (2) [0, 3)
(1) 7 (2) 4 (3) [0, 1] (4) [0, 1)
Ans. (3)
(3) 5 (4) 6
2  2g(x) , 1  g(x)  0 .....(1)
Ans. (4) 
Sol. f(g(x))   g(x)
 1  3 , 0  g(x)  3 .....(2)
Sol. a  ar  ar2  ar3  ....  ar63
By (1) x  
= 7(a  ar 2  ar 4 .....  ar 62 )
And by (2) x  [ 3,0] and x  [0,1]
64 64
a(1  r ) 7a(1  r ) y=f(x)
  (–3,3)
1 r 1  r2
(1,1)
r=6
2. In an A.P., the sixth terms a6 = 2. If the a1a 4a 5 is

the greatest, then the common difference of the 1

y=f(g(x))
A.P., is equal to 2/3

3 8 2 5 –3 O 1
(1) (2) (3) (4)
2 5 3 8 Range of f(g(x)) is [0, 1]
Ans. (2) 4. A fair die is thrown until 2 appears. Then the
probability, that 2 appears in even number of
Sol. a6  2  a  5d  2
throws , is
a1a 4a5  a(a  3d)(a  4d) 5 1 5 6
(1) (2) (3) (4)
6 6 11 11
= (2  5d)(2  2d)(2  d)
Ans. (3)
2 2 3
f(d)  8  32d  34d  20d  30d  10d Sol. Required probability =
3 5
f '(d)  2(5d  8)(3d  2) 5 1 5 1 5 1
      .....
6 6  6  6  6  6
– + –
2/3 8/5 5
1 5
8 =  6 =
d 6 1 25 11
5
36
5.
1
If z   2i , is such that 7. In a ABC, suppose y = x is the equation of the
2
bisector of the angle B and the equation of the side
| z  1|  z  1  i  ,i  1 and ,   R , then
AC is 2x –y =2. If 2AB = BC and the point A and
   is equal to B are respectively (4, 6) and  , , then   2 is
(1) –4 (2) 3
equal to
(3) 2 (4) –1
(1) 42 (2) 39
Ans. (2)
(3) 48 (4) 45
1
Sol. z   2i Ans. (1)
2
Sol.
z  1  z  (1  i) A(4,6)

3 
 2i   2i    i D
y=x
2 2
(2,2)
3  
 2i          2  i B(,) A’(6,4) C(–2,–6)
2 2 
AD : DC = 1 : 2
 9
  2 and    4 4   10
2 4 
6 8
   3
=
 
 
3
   14 and  = 14
 2  cos 
1 1 
lim 
 
6. 2  x3   is equal to
dt
x    t   8. Let a, b and c be three non-zero vectors such that
3
2
 x   
 2 
b and c are non-collinear .if a  5b is collinear
3 32
(1) (2) with c,b  6c is collinear with a and
8 4
32 a  b c  0 , then    is equal to
3
(3) (4)
8 4 (1) 35 (2) 30
Ans. (3) (3) – 30 (4)–25
Sol. Using L’hopital rule Ans. (1)
0  cos x  3x 2 Sol. a  5b  c
= lim
   
x 2x   b  6c  a
2  2
Eliminating a
 
sin  x   6 1
 2  3 2 c  5b  c b
= lim   
   4
x 2x  
2  2 1
  ,   30
3 2 5
=
8   5,   30
  a  
9. Let  5,  , be the circumcenter of a triangle with 11. If ,     is the solution of 4cos  5sin   1 ,
 4 2 2

  a then the value of tan  is

vertices A a, 2 , Ba, 6 and C  , –2  . Let 
4  10  10 10  10
(1) (2)
denote the circumradius,  denote the area and  6 12
denote the perimeter of the triangle. Then      is 10  10 10  10
(3) (4)
(1) 60 (2) 53 12 6

(3) 62 (4) 30 Ans. (3)

Ans. (2) Sol. 4  5 tan   sec 
a   a Squaring : 24tan 2   40tan   15  0
Sol. A(a, –2), B(a, 6), C  , 2  , O  5, 
4   4
10  10
AO = BO tan  
12
2 2
a  a 
(a  5)2    2   (a  5)2    6   10  10 
4  4  and tan      is Rejected.
 12 
a=8
(3) is correct.
AB = 8, AC = 6, BC = 10
12. A function y = f(x) satisfies
  5,   24,   24
f  x  sin 2x  sin x  1  cos2 x  f '  x   0 with condition
  
10. For x    ,  , if
 2 2   
f(0) = 0 . Then f   is equal to
cosec x  sin x 2
y x   dx and
cosec x sec x  tan x sin 2 x (1) 1 (2) 0 (3) –1 (4) 2
 Ans. (1)
lim  y  x   0 then y   is equal to

x   4 dy  sin 2x 
2
Sol.   y  sin x
 1  1  1  dx  1  cos 2 x 
(1) tan 1   (2) tan 1  
 2 2  2 I.F. = 1 + cos2x

(3) 
1  1 
tan 1  (4)
1  1
tan 1    y  1  cos2 x     sin x  dx

2  2 2  2
= – cosx + C
Ans. (4)
x = 0, C = 1
(1  sin2 x)cos x
Sol. y(x)   dx  
1  sin 4 x y   1
2
Put sinx = t
13. Let O be the origin and the position vector of A
 1
1 t 2
1 t  t  and B be 2iˆ  2jˆ  kˆ and 2iˆ  4jˆ  4kˆ respectively. If
1   C
=  dt = tan
4 the internal bisector of AOB meets the line AB
t 1 2 2
 at C, then the length of OC is
x  ,t 1 C=0
2 (1)
2
31 (2)
2
34
3 3
 1  1
y   tan 1    3 3
4 2  2 (3) 34 (4) 31
4 2
Ans. (2) 1 0 0 
Sol. 15. Let A  0    and | 2A |3  2 21 where  , Z ,
O 0  

3 6 Then a value of  is
A B (1) 3 (2) 5
(2, 2, 1) C (2, 4, 4)
1 :2
(3) 17 (4) 9
136 2 34
length of OC   Ans. (2)
3 3
1  Sol. A  2 2
14. Consider the function f :  ,1  R defined by
2  3
2A  221  A  24
f  x   4 2x  3 2x  1 . Consider the statements
3

(I) The curve y = f(x) intersects the x-axis exactly 2  2  16

at one point           16    4 or 5
(II) The curve y = f(x) intersects the x-axis at
16. Let PQR be a triangle with R  1,4, 2 . Suppose

x  cos
12 M(2, 1, 2) is the mid point of PQ. The distance of
Then the centroid of PQR from the point of
(1) Only (II) is correct
intersection of the line
(2) Both (I) and (II) are incorrect
x2 y z3 x 1 y  3 z 1
(3) Only (I) is correct   and   is
0 2 1 1 3 1
(4) Both (I) and (II) are correct (1) 69 (2) 9
Ans. (4)
(3) 69 (4) 99
f '  x   12 2x  3 2  0 for  ,1
2 1
Sol. Ans. (3)
2 
Sol. Centroid G divides MR in 1 : 2
1
f 0 G(1, 2, 2)
2
Point of intersection A of given lines is (2,–6, 0)
f(1) > 0  (A) is correct.

f  x   2  4x3  3x   1  0 AG  69
17. Let R be a relation on Z × Z defined by
Let cos = x,
(a, b)R(c, d) if and only if ad – bc is divisible by 5.
 
cos 3 = cos  = Then R is
4 12
 (1) Reflexive and symmetric but not transitive
x  cos
12 (2) Reflexive but neither symmetric not transitive
(4) is correct. (3) Reflexive, symmetric and transitive
(4) Reflexive and transitive but not symmetric
Ans. (1)
Sol. (a, b)R(a, b) as ab – ab = 0 f(h)  f(0)
Sol. f '(0)  lim
Therefore reflexive h0 h
Let (a,b)R(c,d)ad – bc is divisible by 5
(2h  2 h ) tan h tan 1(h 2  h  1)  0
= lim
 bc – ad is divisible by 5 (c,d)R(a,b) h0 (7h 2  3h  1)3 h
Therefore symmetric
= 
Relation not transitive as (3,1)R(10,5) and
20. Let A be a square matrix such that AAT  I . Then
(10,5)R(1,1) but (3,1) is not related to (1,1)
A  A  AT    A  AT   is equal to
1  2 2
18. If the value of the integral
2  

2
 x 2 cos x 1  sin 2 x   (1) A2  I (2) A3  I
    dx     a   2 ,
 1  1  esin x
2023
(3) A2  AT (4) A3  AT
x

  4
2
Ans. (4)
then the value of a is
3 3
Sol. AAT  I  ATA
(1) 3 (2)  (3) 2 (4)
2 2 On solving given expression, we get
Ans. (1) 1  2
A A  (AT )2  2AAT  A2  (AT )2  2AAT 
2  
 /2  x 2 cos x 1  sin 2 x 
Sol. I   1  x  sin x2023  dx
 = A[A2  (A T )2 ] = A3  AT
 /2  1 e 
SECTION-B
/2  x cos x 2 2 
1  sin x 21. Equation of two diameters of a circle are
I  
 x
 2023  dx

/2  1   1  esin(  x)  2x  3y  5 and 3x  4y  7 . The line joining the

On Adding, we get  22   1
points   ,  4  and   ,3  intersects the circle
/2  7   7 
2I    x2 cos x  1  sin2 x  dx at only one point P  , . Then 17   is equal to
/2
Ans. (2)
On solving
Sol. Centre of circle is (1, 1)
 2 3
I  2 C(1,–1)
4 4
a=3
19. Suppose A(–22/7,–4) P( ,) B(–1/7,3)

f x 
2 x
 2  x  tan x tan 1  x 2  x  1 Equation of AB is 7x – 3y + 10 = 0 …(i)
,
 7x  3x  1
3
2
Equation of CP is 3x + 7y + 4 = 0 …(ii)
Solving (i) and (ii)
Then the value of f '(0) is equal to
41 1
(1)  (2) 0  ,   17    2
29 29

(3)  (4)
2
Ans. (3)
22. All the letters of the word "GTWENTY" are Ans. (5)
written in all possible ways with or without Sol.
meaning and these words are written as in a
dictionary. The serial number of the word
"GTWENTY" IS y=x2
y=2x

Ans. (553)  2 4
Sol. Words starting with E = 360
m=3
Words starting with GE = 60
f '(x)  2 x ln 2  2x  0
Words starting with GN = 60
Words starting with GTE = 24 2x ln 2  2x
Words starting with GTN = 24
Words starting with GTT = 24
GTWENTY = 1
y=2xln2
Total = 553 1
y=2x
23. Let ,  be the roots of the equation x 2  x  2  0

with Im    Im   . Then 6  4   4  52 is

n=2
equal to m+n=5
Ans. (13)
25. If the points of intersection of two distinct conics
6 4 4 2
Sol.       5 x 2 y2
x 2  y 2  4b and   1 lie on the curve
16 b2
=  4 (  2)   4  5 2  (  2)2
y 2  3x 2 , then 3 3 times the area of the rectangle
= 5   4  5 2  2  4  4
formed by the intersection points is __
3 4 2
=  (  2)    5    2  4  4
Ans. (432)
3 2
= 2  5  3  2
Sol. Putting y 2  3x 2 in both the conics
= 2(  2)  5 2  3  2 b 3
We get x2  b and  1
= 72  4  3  2 16 b
 b  4,12 (b = 4 is rejected because curves
= 7(  2)  4  3  2
coincide)
= 3  3  16  3(1)  16  13
 b = 12
24. Let f  x   2  x ,x  R .
x 2
If m and n are
Hence points of intersection are
respectively the number of points at which the
curves y = f(x) and y = f '(x) intersects the x-axis,
 
12, 6  area of rectangle = 432

then the value of m + n is

26. If the solution curve y  y x of the differential 28. The area (in sq. units) of the part of circle

equation 1  y  1  log x  dx  x dy
2
e = 0, x > 0 x 2  y 2  169 which is below the line 5x  y  13 is

passes through the point (1, 1) and  65  1  12 

  sin   where ,  are coprime
2 2   13 
 3
  tan  
y e   2  , then   2 is numbers. Then    is equal to
 3
  tan  
2 Ans. (171)
Ans. (3)
Sol.
1 ln x  dy
Sol.   x  x   dx  
1  y2
0
(5,12)
2
(ln x)
ln x   tan 1 y  C
2
(0,–13)
Put x = y = 1
 12
C  1
4 Area =  169  y 2 dy   25  5
2
13
(ln x)2 
 ln x   tan 1 y 
2 4  169 65 169 1 12
=    sin
Put x = e 2 2 2 2 13

3      171
1  tan
 3 2
 y  tan    
 1  tan 3
11
 4 2 C1 11 C2 11
C n
29. If   .....  9  with gcd(n, m) = 1,
2 2 3 10 m

   1,   1 then n +m is equal to

  + 2 = 3 Ans. (2041)
27. If the mean and variance of the data 65, 68, 58, 44,
9 11
C
48, 45, 60, , ,60 where    are 56 and 66.2 Sol.  r  1r
r 1
respectively, then  2   2 is equal to
1 9 12
Ans. (6344) =  Cr 1
12 r 1
Sol. x  56

2  66.2 1  12 2035
= 2  26 
12   6
 2    25678
  (56)2  66.2
10  m + n = 2041

 2  2  6344
30. A line with direction ratios 2, 1, 2 meets the lines
x = y +2 = z and x + 2 = 2y = 2z respectively at
the point P and Q. if the length of the
perpendicular from the point (1, 2, 12) to the line
PQ is l, then l2 is

Ans. (65)
Sol. Let P(t, t  2, t) and Q(2s  2,s,s)

D.R’s of PQ are 2, 1, 2
2s  2  t s  t  2 s  t
 
2 1 2
 t  6 and s  2

 P(6, 4,6) and Q(2,2,2)

x 2 y 2 z 2
PQ :   
2 1 2
Let F(2  2,   2,2  2)

A(1, 2,12)

AF·PQ  0

  2

So F(6,4, 6) and AF  65
A

P F Q
 PHYSICS TEST PAPER WITH SOLUTION
SECTION-A Sol. Given that
31. In the given circuit, the breakdown voltage of the Current I = I0 + t
Zener diode is 3.0 V. What is the value of Iz? I 0  20A
  3A/s
I = 20 + 3t
dq
 20  3t
dt
q 20

(1) 3.3 mA (2) 5.5 mA  dq    20  3t  dt

0 0
(3) 10 mA (4) 7 mA 20 20
Ans. (2) q   20dt   3tdt
0 0

20
 3t 2 
q  20t    1000 C
 2 0
33. Given below are two statements:
Sol. Statement I : If a capillary tube is immersed first
Vz = 3V in cold water and then in hot water, the height of
Let potential at B = 0 V capillary rise will be smaller in hot water.
Potential at E(VE) = 10 V Statement II : If a capillary tube is immersed first
VC = VA = 3 V in cold water and then in hot water, the height of
Iz + I1 = I capillary rise will be smaller in cold water.
10 – 3 7 In the light of the above statements, choose the
I  A most appropriate from the options given below
1000 1000
(1) Both Statement I and Statement II are true
3
I1  A (2) Both Statement I and Statement II are false
2000
(3) Statement I is true but Statement II is false
7 –1.5
Therefore I z   5.5mA (4) Statement I is false but Statement II is true
1000
Ans. (3)
32. The electric current through a wire varies with time
Sol. Surface tension will be less as temperature
as I = I0 + t. where I0 = 20 A and  = 3 A/s. The
increases
amount of electric charge crossed through a section
2T cos 
of the wire in 20 s is : h
gr
(1) 80 C (2) 1000 C
Height of capillary rise will be smaller in hot water
(3) 800 C (4) 1600 C
and larger in cold water.
Ans. (2)
34. A convex mirror of radius of curvature 30 cm 36. A body starts moving from rest with constant
forms an image that is half the size of the object.
acceleration covers displacement S1 in first (p – 1)
The object distance is :
(1) –15 cm (2) 45 cm seconds and S2 in first p seconds. The displacement
(3) –45cm (4) 15 cm S1 + S2 will be made in time :
Ans. (1)
Sol. (1)  2p  1 s

(2)  2p 2
 2p  1 s
(3)  2p  1 s


(4) 2p2  2p  1 s 
Given R = 30 cm
Ans. (2)
f = R/2 = +15 cm
1 Sol. S1 in first (p – 1) sec
Magnification (m) = 
2 S2 in first p sec
For convex mirror, virtual image is formed for real
1
S1  a  p  1
2
object.
Therefore, m is +ve 2
1 f 1
 S2  a  p 
2

2 f u 2
u = – 15 cm
35. Two charges of 5Q and –2Q are situated at the 1
S1  S2  at 2
points (3a, 0) and (–5a, 0) respectively. The 2
electric flux through a sphere of radius '4a' having (p – 1)2 + p2 = t2
center at origin is :
2Q 5Q t  2p2  1  2p
(1) (2)
0 0
37. The potential energy function (in J) of a particle in
7Q 3Q
(3) (4) a region of space is given as U = (2x2 + 3y3+ 2z).
0 0
Here x, y and z are in meter. The magnitude of
Ans. (2)
Sol. x - component of force (in N) acting on the particle
at point P (1, 2, 3) m is :
(1) 2 (2) 6
(3) 4 (4) 8
Ans. (3)
Sol. Given U = 2x2 + 3y3 + 2z
U
Fx    4x
5Q charge is inside the spherical region x
5Q
flux through sphere = At x = 1 magnitude of Fx is 4N
0
 V 40. Match List I with List II
38. The resistance R  where V   200  5  V and
I List I List II

I   20  0.2  A , the percentage error in the A. dE I. Gauss’

 B.dl   i 0 c  0 0
dt law for
measurement of R is :
electricity
(1) 3.5% B. II. Gauss'
dB
(2) 7%  E.dl  dt law for
(3) 3% magnetism
(4) 5.5% C. Q III. Faraday
Ans. (1)  E.dA   0
law
V D. IV. Ampere –
Sol. R
l
 B.dA  0 Maxwell
According to error analysis law
dR dV dI
  Chose the correct answer from the options given
R V I
below
dR 5 0.2
  (1) A-IV, B-I, C-III, D-II
R 200 20
(2) A-II, B-III, C-I, D-IV
dR 7
 (3) A-IV, B-III, C-I, D-II
R 200 (4) A-I, B-II, C-III, D-IV
dR 7 Ans. (3)
% error 100  100  3.5%
R 200 Sol. Ampere – Maxwell law
39. A block of mass 100 kg slides over a distance of dE
10 m on a horizontal surface. If the co-efficient of
  B.dl   i
0 c  0 0
dt
friction between the surfaces is 0.4, then the work dB
done against friction (in J) is :
Faraday law   E.dl  dt
(1) 4200 Q
Gauss’ law for electricity   E.dA 
(2) 3900 0
(3) 4000
(4) 4500
Gauss ‘ law for magnetism   B.dA  0
Ans. (3) 41. If the radius of curvature of the path of two
Sol. Given m = 100 kg particles of same mass are in the ratio 3:4, then in
s = 10 m order to have constant centripetal force, their
 = 0.4 velocities will be in the ratio of:

As f = mg = 0.4 × 100 × 10 = 400 N (1) 3 : 2 (2) 1: 3

Now W = f.s = 400 ×10 = 4000 J (3) 3 :1 (4) 2 : 3
Ans. (1)
Sol. Given m1 = m2 Sol. For photon
r1 3 hc hc
and  EP   p 
r2 4 p EP
mv2
As centripetal force F  For electron
r
In order to have constant (same in this question) h hv
centripetal force
e   e
me ve 2K e
F1 = F2
Given ve = 0.25 c
m1v12 m 2 v22

r1 r2 h  0.25c hc
e  
2K e 8K e
v1 r 3
  1 
v2 r2 2 Also  p   e
42. A galvanometer having coil resistance 10 shows
hc hc
a full scale deflection for a current of 3mA. For it 
to measure a current of 8A, the value of the shunt E p 8K e
should be:
Ke 1
(1) 3 × 10–3 (2) 4.85 × 10–3 
Ep 8
(3) 3.75 × 10–3 (4) 2.75 × 10–3
Ans. (3) 44. The deflection in moving coil galvanometer falls
Sol. Given G = 10 
Ig = 3mA from 25 divisions to 5 division when a shunt of
I = 8A 24 is applied. The resistance of galvanometer
In case of conversion of galvanometer into
coil will be :
ammeter.
(1) 12 (2) 96
(3) 48 (4) 100
Ans. (2)
We have IgG = (I – Ig)S
Sol. Let x = current/division
IgG
S
I  Ig

S
 3 10 10 –3

= 3.75 ×10–3
8 – 0.003 After applying shunt
43. The de-Broglie wavelength of an electron is the
same as that of a photon. If velocity of electron is
25% of the velocity of light, then the ratio of K.E.
of electron and K.E. of photon will be:
1 1
(1) (2)
1 8
8 1 Now 5x × G = 20x × 24
(3) (4)
1 4 G = 4 × 24
Ans. (2)
G = 96
45. A biconvex lens of refractive index 1.5 has a focal 1
Work done AB = (8000 + 6000) Dyne/cm2 ×
length of 20 cm in air. Its focal length when 2
immersed in a liquid of refractive index 1.6 will 4m3 = (6000Dyne/cm2) × 4m3
be: 2
Work done BC = –(4000 Dyne/cm ) × 4m
3

(1) – 16 cm Total work done = 2000 Dyne/cm2 × 4m3

(2) – 160 cm 1 N
(3) + 160 cm  2 103  5 2
 4m3
10 cm
(4) + 16 cm
N
Ans. (2)  2 102  –4 2  4m3
10 m
Sol. l = 1.5 2
= 2 × 10 × 4 Nm = 800 J
m = 1.6 47. At what distance above and below the surface of
fa = 20 cm the earth a body will have same weight, (take
fm   l  1  m radius of earth as R.)
As 
fa  l  m  3R  R
(1) 5R  R (2)
fm 1.5  11.6 2

20 1.5  1.6  (3)
R
(4)
5R  R
fm = –160 cm
2 2
46. A thermodynamic system is taken from an original Ans. (4)
state A to an intermediate state B by a linear gR 2
Sol. gp 
R  h 
2
process as shown in the figure. It's volume is then
reduced to the original value from B to C by an
 h
isobaric process. The total work done by the gas gq  g 1  
 R
from A to B and B to C would be :
gp = g q
g  h
 g 1  
2
 h  R
1  R 
 
 h2   h
 1  2 
1   1
 R  R 
(1) 33800 J (2) 2200 J
(3) 600 J (4) 1200 J h
Take x
Ans. (BONUS) R
Sol.
So
x3 – x + x 2 = 0
5 1
x
2

h
R
2
 5 1 
48. A capacitor of capacitance 100 F is charged to a 50. Two vessels A and B are of the same size and are
potential of 12 V and connected to a 6.4 mH at same temperature. A contains 1g of hydrogen
inductor to produce oscillations. The maximum and B contains 1g of oxygen. PA and PB are the
current in the circuit would be : pressures of the gases in A and B respectively, then
(1) 3.2 A (2) 1.5 A PA
is :
(3) 2.0 A (4) 1.2 A PB
Ans. (2) (1) 16 (2) 8 (3) 4 (4) 32
Sol. By energy conservation Ans. (1)
1 1 2
CV2  LImax PA VA n A RTA
2 2 Sol. 
PBVB n BRTB
C Given VA =VB
I max  V
L And TA = TB
100  10 –6 PA n A
  12 
6.4  10 –3 PB n B
12 3 PA 1 / 2
   1.5 A   16
8 2 PB 1 / 32
49. The explosive in a Hydrogen bomb is a mixture of
2 3 6 SECTION-B
1
H , 1H and 3Li in some condensed form. The
chain reaction is given by 51. When a hydrogen atom going from n = 2 to n = 1
Li6 + 0n12He4 + 1H3 x
3 emits a photon, its recoil speed is m/s. Where
H + 1H 2He + 0n
2 3 4 1 5
1

During the explosion the energy released is x = ______ . (Use : mass of hydrogen atom
approximately = 1.6 × 10–27 kg)
2
[Given : M(Li) = 6.01690 amu. M (1H ) = 2.01471 Ans. (17)
amu. M (2He4) = 4.00388amu, and 1 amu = 931.5 n =2
–3.4 eV
MeV]
(1) 28.12 MeV (2) 12.64 MeV
(3) 16.48 MeV (4) 22.22 MeV n =1
Sol. –13.6 eV
Ans. (4)
E = 10.2 eV
Sol. Li6 + 0n12He4 + 1H3
3
E
H + 1H 2He + 0n
2 3 4 1
Recoil speed(v) =
1
mc

3 Li6 1 H2  2  2 He 4  =
10.2eV
1.6 10–27  3 108
Energy released in process
10.2  1.6  10 –19
Q = mc 2

1.6  10 –27  3  108
Q = [M(Li)+ M (1H2) –2 × M(2He4)] × 931.5 MeV
17
Q = [6.01690+2.01471–2 × 4.00388] × 931.5 MeV v = 3.4 m/s = m/s
5
Q = 22.216 MeV
Therefore, x = 17
Q = 22.22 MeV
52. A ball rolls off the top of a stairway with Sol.
horizontal velocity u. The steps are 0.1 m high and
0.1 m wide. The minimum velocity u with which
that ball just hits the step 5 of the stairway will be
x ms–l where x = ___________[use g = 10 m/s2].
Ans. (2)
Sol.
0
1
A   0.1 ˆj
2
2
3 Just miss
(for minimum speed) 0.2 ˆ 0.2 ˆ
B i j
4 2 2
5 Magnitude of induced emf
 B·A  0
e   2  10 3 V
th
t 1
The ball needs to just cross 4 steps to just hit 5
54. A cylinder is rolling down on an inclined plane of
step
inclination 60°. It's acceleration during rolling
Therefore, horizontal range (R) = 0.4 m
x
R = u.t down will be m/s2, where x = _________.
3
Similarly, in vertical direction 2
(use g = 10 m/s ).
1
h  gt 2 Ans. (10)
2
1
0.4  gt 2
2
2
1  0.4 
0.4  g
2  u 
2
Sol.
u =2
g sin 
For rolling motion, a 
u= 2 m/s I
1  cm 2
Therefore, x = 2 MR
53. A square loop of side 10 cm and resistance 0.7 is gsin 
a
placed vertically in east-west plane. A uniform 1
1
magnetic field of 0.20 T is set up across the plane 2
in north east direction. The magnetic field is 3
2  10 
decreased to zero in 1 s at a steady rate. Then,  2
3
magnitude of induced emf is x × 10 V. The
–3

10
value of x is ________. 
3
Ans. (2) Therefore x = 10
55. The magnetic potential due to a magnetic dipole at 57. A 16 wire is bend to form a square loop. A 9V
a point on its axis situated at a distance of 20 cm battery with internal resistance 1 is connected
from its center is 1.5 × 10–5Tm. The magnetic across one of its sides. If a 4F capacitor is
2
moment of the dipole is__________Am . connected across one of its diagonals, the energy
0 –7 –1 x
(Given : = 10 TmA ) stored by the capacitor will be J. where
4 2
Ans. (6) x = _________.
0 M Ans. (81)
Sol. V
4 r 2
M
 1.5  10 –5  10 –7 
 20 10 
2
–2

1.5  10 –5  20  20  10 –4
M
10 –7
M = 1.5 × 4 = 6 Sol.
56. In a double slit experiment shown in figure, when I
V
I
V

9

9
light of wavelength 400 nm is used, dark fringe is R eq R eq 1  12  4 4
12  4
observed at P. If D = 0.2 m. the minimum distance
9 4 9
between the slits S1 and S2 is ______ mm. I1   
4 16 16
9 9
VA  V B  I1  8   8  V
16 2
1 81
 U   4  J
2 4
81
 U  J
2
 x  81

Ans. (0.20) 58. When the displacement of a simple harmonic

Sol. Path difference for minima at P oscillator is one third of its amplitude, the ratio of
 x
2 D 2  d 2  2D  total energy to the kinetic energy is , where
2 8
 x = _________.
 D2  d 2  D 
4
Ans. (9)

 D2  d 2   D 1
4 Sol. Let total energy = E = KA 2
2
 2 D
 D 2  d 2  D2   2
16 2 1  A  KA2 E
U  K   
D  2 2 3 29 9
 d2  
2 16 E 8E
KE  E  
0.2  400 109 4 1014 9 9
 d2  
2 4 Total E 9
Ratio  =
 d 2  400  1010 KE 8E 8
d  20  105 9

 d  0.20mm x=9
59. An electron is moving under the influence of the 60. In a test experiment on a model aeroplane in wind
electric field of a uniformly charged infinite plane
tunnel, the flow speeds on the upper and lower
sheet S having surface charge density +. The
electron at t = 0 is at a distance of 1 m from S and surfaces of the wings are 70 ms–1 and 65 ms–1
has a speed of 1 m/s. The maximum value of  if respectively. If the wing area is 2 m2 the lift of the
m   C wing is _______ N.
the electron strikes S at t = l s is   0
 2
 e m –3
(Given density of air = 1.2 kg m )
the value of  is
Ans. (8) Ans. (810)
e
Sol. u  1 m / s; a   F    v12  v 22  A
1
2 0 m Sol.
2
t 1 s
 1.2   702  652   2
1
S = –1 m F
2
1
Using S  ut  at 2 = 810 N
2
1 e
1  1  1    1
2

2 20 m
0 m
  8
e
  8
 CHEMISTRY TEST PAPER WITH SOLUTION
SECTION-A 63. In chromyl chloride test for confirmation of Cl–
61. Given below are two statements : one is labelled as ion, a yellow solution is obtained. Acidification of
Assertion A and the other is labelled as Reason R: the solution and addition of amyl alcohol and 10%
Assertion A: The first ionisation enthalpy decreases H2O2 turns organic layer blue indicating formation
across a period. of chromium pentoxide. The oxidation state of
Reason R: The increasing nuclear charge outweighs chromium in that is
the shielding across the period. (1)+6 (2)+5
In the light of the above statements, choose the (3)+10 (4)+3
most appropriate from the options given below: Ans. (1)
Sol. Cl  K Cr O  H SO  CrO Cl   CrO2  Cl
(1) Both A and R are true and R is the correct
Basic medium
2 2 7 2 4 2 2 4
yellow solution

explanation of A 1.Acidification
(2) A is true but R is false CrO24 
2. Amyl alcohol
3. 10% H2 O2
 CrO5
yellow solution blue compound
(3) A is false but R is true –2
O
(4) Both A and R are true but R is NOT the –1
O +6 O– 1
Cr
correct explanation of A –1
O O– 1
Ans. (3) 64. The difference in energy between the actual
Sol. First ionisation energy increases along the period. structure and the lowest energy resonance structure
Along the period Z increases which outweighs the for the given compound is
shielding effect (1) electromeric energy
62. Match List I with List II (2) resonance energy
LIST-I LIST-II (3) ionization energy
(Substances) (Element Present) (4) hyperconjugation energy
A.Ziegler catalyst I.Rhodium Ans. (2)
B.Blood Pigment II. Cobalt Sol. The difference in energy between the actual structure
C.Wilkinson catalyst III.Iron and the lowest energy resonance structure for the
given compound is known as resonance energy.
D.Vitamin B12 IV.Titanium
65. Given below are two statements :
Choose the correct answer from the options given
Statement I : The electronegativity of group 14
below:
elements from Si to Pb gradually decreases.
(1) A-II, B-IV, C-I, D-III
Statement II : Group 14 contains non-metallic,
(2) A-II, B-III, C-IV, D-I
metallic, as well as metalloid elements.
(3) A-III, B-II, C-IV, D-I In the light of the above statements, choose the
(4) A-IV, B-III, C-I, D-II most appropriate from the options given below :
Ans. (4) (1) Statement I is false but Statement II is true
Sol. Ziegler catalyst  Titanium (2) Statement I is true but Statement II is false
Blood pigment  Iron (3) Both Statement I and Statement II are true
Wilkinson catalyst  Rhodium (4) Both Statement I and Statement II are false
Vitamin B12Cobalt Ans. (1)
Sol. Gr-14 EN OCH2  CH3
Sol. C o n c H B r (ex ces s)
C 2.5 (P )
Si 1.8 C H = CH 2
Ge 1.8
Sn 1.8
Pb 1.9
The electronegativity values for elements from Si
to Pb are almost same. So Statement I is false.
66. The correct set of four quantum numbers for the
valence electron of rubidium atom (Z = 37) is:
68. The arenium ion which is not involved in the
1 1
(1) 5, 0, 0,  (2) 5, 0,1,  bromination of Aniline is .
2 2
1 1
(3) 5,1, 0,  (4) 5,1,1, 
2 2 (1) (2)
Ans. (1)
Sol. Rb = [Kr]5s1
n=5
(3) (4)
l=0
m=0 Ans. (3)

s = +½ or –½ 
Sol. Since  N H 2 group is o/p directing hence arenium
67. The major product(P) in the following reaction is ion will not be formed by attack at meta position
i.e.
NH 2


H
Br
Hence Answer is (3)
69. Appearance of blood red colour, on treatment of
(1) (2) the sodium fusion extract of an organic compound
with FeSO4 in presence of concentrated H2SO4
indicates the presence of element/s
(1) Br (2) N
(3) N and S (4) S
Ans. (3)
(3) (4) Sol. Fe2 H 
Fe3
Conc.H 2SO4

 Fe SCN 3  blood red colour 


Fe3 
SCN

Appearance of blood red colour indicates presence

Ans. (4) of both nitrogen and sulphur.
70. Given below are two statements : one is labelled as Cl

Assertion A and the other is labelled as Reason R : hv (Formed by free radical mechanism)
Assertion A : Aryl halides cannot be prepared by
replacement of hydroxyl group of phenol by Cl
Sol. +Cl 2 (product A )
halogen atom. Cl
CCl
Reason R : Phenols react with halogen acids violently.
4
(Formed by electrophilic
Cl addition reaction on alkene)
In the light of the above statements, choose the
(Product B)
most appropriate from the options given below:
(1) Both A and R are true but R is NOT the Hence correct Ans. (4)
correct explanation of A
72. Identify the incorrect pair from the following :
(2) A is false but R is true
(3) A is true but R is false (1) Fluorspar- BF3
(4) Both A and R are true and R is the correct
explanation of A (2) Cryolite-Na3AlF6
Ans. (3) (3) Fluoroapatite-3Ca3(PO4)2.CaF2
Sol. Assertion (A): Given statement is correct because
in phenol hydroxyl group cannot be replaced by (4) Carnallite-KCl.MgCl2.6H2O
halogen atom.
Ans. (1)
Reason (R) :
OH Sol. (1) Fluorspar is CaF2

HX
N o R eac tio n
73. The interaction between  bond and lone pair of

Given reason is false electrons present on an adjacent atom is

Hence Assertion (A) is correct but Reason (R) is false responsible for
71. Identify product A and product B :
(1) Hyperconjugation
(2) Inductive effect

(3) Electromeric effect

(4) Resonance effect

(1) Ans. (4)

Sol. It is a type of conjugation responsible for resonance.

74. KMnO4 decomposes on heating at 513K to form

(2) O2 along with

(1) MnO2 & K2O2

(2) K2MnO4 & Mn

(3)
(3) Mn & KO2
(4) K2MnO4 & MnO2
(4) Ans. (4)

Sol. KMnO 4   K 2MnO 4  MnO 2  O 2
Ans. (4)
75. In which one of the following metal carbonyls, CO 77. The final product A formed in the following
multistep reaction sequence is
forms a bridge between metal atoms?

(1) [Co2(CO)8] (2) [Mn2(CO)10]

(3) [Os3(CO)12] (4) [Ru3(CO)12]

Ans. (1) (1)

OC CO CO
Sol. (1) OC Co Co CO
OC CO CO
(2)
OC CO
OC CO
(2) OC Mn Mn CO
(3)
OC CO
OC CO
CO CO (4)
OC CO
OC Os CO Ans. (1)
(3) OC CO Sol.
Os Os
OC CO
OC CO
CO CO
OC CO
OC Ru CO
(4) OC CO 78. Which of the following is not correct?
Ru Ru
CO (1) G is negative for a spontaneous reaction
OC
OC CO (2) G is positive for a spontaneous reaction
(3) G is zero for a reversible reaction
76. Type of amino acids obtained by hydrolysis of
(4) G is positive for a non-spontaneous reaction
proteins is :
Ans. (2)
(1)  (2)  Sol. (G)P,T     ve for non-spontaneous process
(3)  (4)  79. Chlorine undergoes disproportionation in alkaline
medium as shown below :
Ans. (2)
a Cl2(g) + b OH–(aq)  c ClO–(aq) + d Cl–(aq)
Sol. Proteins are natural polymers composed of -amino + e H2O(l)
acids which are connected by peptide linkages. The values of a, b, c and d in a balanced redox
reaction are respectively :
Hence proteins upon acidic hydrolysis produce
(1) 1, 2, 1 and 1 (2) 2, 2, 1 and 3
-amino acids. (3) 3, 4, 4 and 2 (4) 2, 4, 1 and 3
Ans. (1)
Sol. 83. For a reaction taking place in three steps at same
+e K1K 2
temperature, overall rate constant K  . If
0 1 +1 K3
Cl2 Cl + ClO
e
Ea1, Ea2 and Ea3 are 40, 50 and 60 kJ/mol
respectively, the overall Ea is____kJ/mol.
 Cl   ClO   H 2O
 Cl2  2OH  Ans. (30)
In alkaline medium. MnO 4 oxidises I– to
 Ea  Ea  Ea 
80. K1  K 2 A1  A 2  1 RT2 3
Sol. K   e
(1) IO 4 (2)IO– K3 A3
 E a  E a 2  E a3 
(3) I2 (4) IO 3 AA  1
A  e  Ea /RT  1 2  e RT
A3
Ans. (4)
E a  E a1  E a 2  E a3  40  50  60  30 kJ / mole.
Sol. 2MnO4  H 2O  I  
alkaline medium
 2MnO 2  2OH   IO3
84. For the reaction N 2O4 (g) 2NO2 (g) ,
SECTION-B
Kp= 0.492 atm at 300K. Kc for the reaction at same
81. Number of compounds with one lone pair of temperature is___ × 10–2 .
electrons on central atom amongst following is _ (Given : R = 0.082 L atm mol–1 K–1)
Ans. (2)
O3, H2O, SF4, ClF3, NH3, BrF5, XeF4
Sol. K P  KC   RT 
n g

Ans. (4) ng = 1

KP 0.492
 Kc    2  102
RT 0.082  300
Sol. 85. A solution of H2SO4 is 31.4% H2SO4 by mass and
has a density of 1.25g/mL.The molarity of the
H2SO4 solution is____M (nearest integer)
[Given molar mass of H2SO4 = 98g mol–1]
Ans. (4)
F nsolute
F F Sol. M 1000
N Br V
H H, F F  31.4 
H  98 
   1000
82. The mass of zinc produced by the electrolysis of  100 
 1.25 
zinc sulphate solution with a steady current of  
 4.005  4
0.015 A for 15 minutes is ____ × 10–4 g.
86. The osmotic pressure of a dilute solution is
(Atomic mass of zinc = 65.4 amu) 7 × 105 Pa at 273K. Osmotic pressure of the same
solution at 283K is____× 104 Nm–2.
Ans. (45.75) or (46) Ans. (72.56) or (73)
Sol.  = CRT
Sol. Zn2  2e 
 Zn
 1 T1
W=Z×i×t  
 2 T2
65.4  1T2 7 105  283
  0.015 15  60  2  
2  96500 T1 273
 45  75  10 4 gm  72.56  104 Nm 2
87. Number of compounds among the following which 89. From the compounds given below, number of
contain sulphur as heteroatom is____.
compounds which give positive Fehling's test is____.
Furan,Thiophene, Pyridine, Pyrrole, Cysteine,
Benzaldehyde, Acetaldehyde, Acetone,
Tyrosine
Ans. (2) Acetophenone,Methanal, 4-nitrobenzaldehyde,
SH
Sol. cyclohexane carbaldehyde.
, OH
H2N
S
Ans. (3)
Thiophene O
Cysteine Sol. Acetaldehyde (CH3CHO),Methanal(HCHO), and
88. The number of species from the following which
CHO

are paramagnetic and with bond order equal to one cyclohexane carbaldehyde .
is____.

H 2 , He 2 ,O 2 , N 22 ,O 22 , F2 , Ne 2 , B2 CH3 H

90. C=C (i) O 3
(P)
Ans. (1) H CH3 (ii) Zn/H2O

Sol. Magnetic behaviour Bond order Consider the given reaction. The total number of
H2 Diamagnetic 1
oxygen atoms present per molecule of the product
He 2 Paramagnetic 0.5
(P) is____.

O 2 Paramagnetic 2.5
Ans. (1)
N 22 Paramagnetic 2 CH3 H CH3
Sol. C=C (i) O 3
2 C=O
O22 Diamagnetic 1 H CH3 (ii) Zn/H2O H

F2 Diamagnetic 1 Hence total number of oxygen atom present per


Ne 2 Paramagnetic 0.5 CH3
C=O
B2 Paramagnetic 1 molecule H is 1.