1721903259phpsmmiWg

JEE-MAIN-2024 (29th January-First Shift)-MPC-2
PART – A (MATHEMATICS)
SECTION - A
(One Options Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (1), (2), (3) and
(4), out of which ONLY ONE option is correct.
1. A fair die is thrown until 2 appears. Then the probability, that 2 appears in even number of throws,
is
6 1
(1) (2)
11 6
5 5
(3) (4)
11 6
Ans. (3)
5 1 5 5 5 1
Sol. Required Probability =       .........
6 6 6 6 6 6
2 4
5  5 5  5 1 5
= 1        ......... =  
36   6   6   36 25 11
1
36
*2. If in a G.P. of 64 terms, the sum of all the terms is 7 times the sum of the odd terms of the G.P.
then the common ratio of the G.P. is equal to
(1) 4 (2) 7
(3) 6 (4) 5
Ans. (3)
Sol. Let the G.P. is a, ar, ar2, ………
a  r 64  1 a  r 64  1
  7
r 1 r2  1
 r+1=7 r=6
2  2x, 1  x  0
  x, 3  x  0
3. If f  x    x ; g x    , then range of (fog)(x) is
 1  , 0  x  3  x, 0  x 1
3
(1) [0, 3) (2) [0, 1]
(3) [0, 1) (4) (0, 1]
Ans. (2)
2  2x, 1  x  0
   x, 3  x  0
Sol.  
f x  x and g  x   
 1  3 , 0  x  3  x, 0  x 1
 x
1  3 , 3  x  0
 f g x   
 
1  x , 0  x  1
 3
 Range of f(g(x)) is [0, 1].
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*4. In an A.P., the sixth term a6 = 2. If the product a1a4a5 is the greatest, then the common difference
of the A.P. is equal to
2 8
(1) (2)
3 5
5 3
(3) (4)
8 2
Ans. (2)*
Sol. Let the A.P. is a, a + d, a + 2d, ……..
 a + 5d = 2
a1.a4.a5 = a(a + 3d) (a + 4d)
 a1.a4.a5 = (2  5d) (2  2d) (2  d) = f(d)
3 2
f(d) = 10d + 34d  32d + 8
2
 f'(d) = 30d + 68d  32
2 8
f'(d) = 0  d = and
3 5
8 2
f"(d) < 0 for d = and f"(d) > 0 for d =
5 3
8
* Note : f(d) attains local maximum at d = and not the absolute maximum value.
5
1 
5. Consider the function f :  ,1  R defined by f(x) = 4 2x3  3 2x  1 . Consider the statements
2 
:
(I) The curve y = f(x) intersects the x-axis is exactly at one point.

(II) The curve y = f(x) intersects the x-axis at x = cos
12
Then
(1) Both (I) and (II) are correct (2) Both (I) and (II) are incorrect
(3) Only (I) is correct (4) Only (II) is correct
Ans. (1)
1 
Sol. f :  ,1  R , f  x   4 2x 3  3 2x  1
2 
1 
f   x   3 2  2x  1 2x  1  0  x   ,1
2 
1 
 f(x) is strictly increasing in  ,1
2 
 1
f    0 , f(1) > 0
 2
1 
 f(x) = 0 has exactly one solution in  ,1
2 
3 1
Also f(x) = 0  4x  3x =
2
1
Now put x = cos  cos3 =
2

 x = cos .
12
1  2 2
A  A  A T    A  A T   is equal to
T
6. Let A be a square matrix such that AA = I. Then
2
(1) A2 + I (2) A2 + AT
(3) A3 + I (4) A3 + AT
Ans. (4)
Sol. A.AT = I  (A + AT)2 = A2 + (AT)2 + 2I
(A  AT)2 = A2 + (AT)2  2I
1  2 2
A  A  A T    A  A T   = A + A
3 T

2
7. Let R be a relation on Z  Z defined by (a, b) R (c, d) if and only if ad  bc is divisible by 5. Then

R is
(1) Reflexive and transitive but not symmetric
(2) Reflexive, symmetric and transitive
(3) Reflexive and symmetric but not transitive
(4) Reflexive but neither symmetric nor transitive
Ans. (3)
Sol.  (a, b)  I  I, ab  ba = 0  (a, b) R(a, b)  R is reflexive
(a, b) R(c, d)  ad  bc is divisible by 5  cb  da is divisible by 5
 (c, d) R(a, b)  R is symmetric
If (a, b) R(c, d) and (c, d) R (e, f)  ad  bc = 5 and cf  de = 5
 af  be is not necessarily a multiple of 5  R is not transitive.
 2x  2 x  tan x tan1  x2  x  1
8. Suppose f  x   . Then the value of f'(0) is equal to
 7x2  3x  13

(1)  (2)
2
(3) 0 (4) 
Ans. (4)
 2x  2 x  tan x tan1  x2  x  1
Sol. f x 
 7x2  3x  13
1
ln  tan1  x 2  x  1   3ln  7x 2  3x  1
ln f  x   ln  2x  2 x   ln  tan x  
2
f   x   2 x  2 x  ln 2 sec 2 x  2x  1 3 14x  3 
     2
f x  x
2 2 x
tan x 
2  tan1  x2  x  1  1   x 2  x  1
2

7x  3x  1
 f'(0) = 
   cosecx  sin x 

9. For x    ,  , if y(x) =  cosecx sec x  tan x sin2 x dx and lim  y  x   0 then y   is equal
 2 2 x
  4
 
 2
to
1  1   1 
(1)  tan1   (2) tan1  
2  2  2
1  1 1  1 
(3) tan1    (4) tan1  
2  2 2  2
Ans. (3)
cosecx  sin x
Sol. yx   dx
cosecx sec x  tan x  sin 2 x
1  sin2 x  cos x
 yx   dx
1  sin4 x
Put sinx = t  cosx dx = dt
 1
1  t2  dt 1 1
t t 
   tan  c
1 t4 2  2 
1  cos2 x 
 yx  tan1   c
2  2 sin x 
lim y  x   0  c = 0

x
2
1  cos2 x   1  1
 yx  tan1     y   tan1   
2  2 sin x  4 2  2
10. A function y = f(x) satisfies f(x) sin2x + sinx  (1 + cos2x) f'(x) = 0 with condition f(0) = 0. Then,
 
f   is equal to
2
(1) 1 (2) 2
(3) 0 (4) 1
Ans. (1)
Sol. f(x) . sin2x + sinx  (1 + cos2x) f'(x) = 0
 (1 + cos2x) f'(x)  (sin2x) f(x) = sinx
d
 (f(x) (1 + cos2x)) = sinx
dx
 f(x) (1 + cos2x) = cosx + c, As f(0) = 0  c = 1
1  cos x 
 f x  2
 f  1
1  cos x 2
*11. In a ABC, suppose y = x is the equation of the bisector of the angle B and the equation of the
side AC is 2x  y = 2. If 2AB = BC and the points A and B are respectively (4, 6) and (, ), then
 + 2 is equal to
(1) 42 (2) 45
(3) 39 (4) 48
Ans. (1)
Sol. Let BD is angle bisector of B A(4, 6)
 D is (2, 2) 1
AD 1 D(2,2)
Also  
CD 2 y=x 2
 C is (2, 6) 2xy=2
Also (slope of AB) (slope of BC) = 1 

   6    6 
    1 B(,) 2 C(2,6)
   4    2 
Also  =    =  = 14
  + 2 = 42
 
*12. If ,     is the solution of 4cos + 5sin = 1, then the value of tan is
2 2
10  10 10  10
(1) (2)
6 12
10  10 10  10
(3) (4)
12 6
Ans. (2)
  
Sol. 4cos  5sin = 1 has a solution  = ,     , 
 2 2
 4 + 5tan = sec
2 2
 16 + 25tan  + 40tan = sec 
2
 24tan  + 40tan + 15 = 0
10  10 10  10
 tan = ,
12 12
 10  10
tan = is rejected.
12
3
  
 

 1 2 
13. lim  2  cos  t
1/3  dt  is equal to
 
x 
2 x 
 x 3
  
 2 
3 3 2
(1) (2)
8 4
3 32
(3) (4)
4 8
Ans. (4)
  /2 3
 cos  t1/3  dt
x3
Sol. Let lim 2
L

x  
2 x  
 2
Applying L-Hospital's Rule
 
sin  x   3x 2
 cos  x  3x 2  2
 L  lim  lim
x
   x
  
2 2 x   2 2 x  
 2  2
32
 L=
8
 a a 
*14. Let  5,  be the circumcenter of a triangle with vertices A(a, 2), B(a, 6) and C  , 2  . Let 
 4 4 
denote the circumradius,  denote the area and  denote the perimeter of the triangle. Then
 +  +  is
(1) 30 (2) 53
(3) 62 (4) 60
Ans. (2) A(a, 2) a 

Sol. As AB  AC C  , 2 
4 
 circum-centre is mid-point of BC
a
a
 4 5 a=8
2
 vertices are A(8, 2), B(8, 6), C(2, 2)
  = 5,  = 24,  = 24
B(a, 6)
  +  +  = 53
1 0 0
15. Let A = 0    and |2A|3 = 221 where ,   Z. Then a value of  is
0   
(1) 5 (2) 9
(3) 3 (4) 17
Ans. (1)
1 0 0
Sol. A = 0     |2A| = 23|A|
0   
 |2A|3 = 29.|A|3 = 221
 |A| = 16  2  2 = 16
  can be 5 for  =  3.
16. Let PQR be a triangle with R (1, 4, 2). Suppose M (2, 1, 2) is the mid point of PQ. The distance
x2 y z3
of the centroid of PQR from the point of intersection of the lines   and
0 2 1
x 1 y  3 z 1
  is
1 3 1
(1) 99 (2) 9
(3) 69 (4) 69
Ans. (3)
Sol. G is centroid of PQR l1
 2  2  1 2  1 4 2  2  2  P
G  , , 
 3 3 3 
(2,1,2)
G  (1, 2, 2)
Let x is the point of intersection of lines M 1
x2 y z3 G l2
l1 :   2
0 2 1
x 1 y  3 z 1 Q R
l2 :   , then x  (2, 6, 0) (1,4,2)
1 3 1
 distance between G and x = 69
     
17. Let a,b and c be three non-zero vectors such that b and c are non-collinear. If a  5b is collinear
       
with c,b  6c is collinear with a and a  b  c  0 , then  +  is equal to
(1) 25 (2) 35
(3) 30 (4) 30
Ans. (2)
  
Sol.  2  a  5b  1c  …(1)
  
b  6c   2a …(2)
Add (1) and (2)
 
  5 2  1 b   1 2  6  c
 
 b and c are non-collinear
1
 2 =  and 1 = 30
5
  
 a  5b  30c  0   = 5,  = 30   +  = 35
1
*18. If z =  2i is such that |z + 1| = z + (1 + i), i = 1 and ,   R, then  +  is equal to
2
(1) 1 (2) 4
(3) 2 (4) 3
Ans. (4)
1
Sol. z =  2i , |z + 1| = z + (1 + i) ; ,   R
2
 (2) +  = 0 …(i)
2
2  
and z  1     
2 
2 2
3 2  5 
    2       1
2  2 
  = 1 and  = 2   +  = 3.
19. Let O be the origin and the position vectors of A and B be 2iˆ  2jˆ  kˆ and 2iˆ  4ˆj  4kˆ
respectively. If the internal bisector of AOB meets the line AB at C, then the length of OC is
3 3
(1) 34 (2) 31
2 2
2 2
(3) 34 (4) 31
3 3
Ans. (3)
Sol.  OC bisects AOB B(2,4,4)
 C divides AB in the ratio of 1 : 2 2
C
 2  2  2 4  2  2 4  2 1
 C , ,  6 1
 3 3 3  A(2,2,1)
 8 
C   2, ,2  3
 3 
2 O
OC = 34
3
 /2
 x 2 cos x 1  sin2 x  
20. If the value of the integral   1  x  1  esin x2023  dx  4    a   2 , then the value of a is
 /2
3
(1) 2 (2) 
2
3
(3) (4) 3
2
Ans. (4)
 /2
 x 2 cos x 1  sin2 x  
Sol. Let I =   1  x  1  esin x2023  dx  4    a   2
 /2
 /2  /2
x 2 cos xdx   1 sin x  dx
2
 I= 
0 0
2
 3 
I= 2    3  2  a  3
4 4 4
SECTION - B
(Numerical Answer Type)
This section contains 10 Numerical based questions. The answer to each question is rounded off to the
nearest integer value.
21. A line with direction ratio 2, 1, 2 meets the lines x = y + 2 = z and x + 2 = 2y = 2z respectively at
the points P and Q. If the length of the perpendicular from the point (1, 2, 12) to the line PQ is l,
then l2 is _____ .
Ans. 65
Sol. L1 : x = y + 2 = z
L2 : x + 2 = 2y = 2z
P  (,   2, )
   P
Q     2, , 
 2 2 Q
   + 2 = 2k
 (2,1,2)
   2 = k   = 6,  = 4
2
L1
 L2
 = 2k
2
x6 y4 z6
Equation of PQ is  
2 1 2
Now length of perpendicular from the point (1, 2, 12) to the line PQ = 52  22  62  65 = l
 l2 = 65
22. The area (in sq. units) of the part of the circle x2 + y2 = 169 which is below the line 5x  y = 13 is
 65  1  12 
  sin   , where ,  are coprime number. Then  +  is equal to ____ .
2 2   13 
Ans. 171
Sol. Area of shaded region = Area of sector AOB  
2 2
x +y =169 B(5,12)
area of AOB
13 2    13 
2
 
=     sin     O 
2 2  2 2 
169 65 169  12   12  (0,0)
=   sin1    sin   
2 2 2 2  13   13 
  = 169,  = 2   +  = 171
A
5x  y=13
23. If the solution curve y = y(x) of the differential equation (1 + y2) (1 + logex) dx + x
3
  tan  
dy = 0, x > 0 passes through the point (1, 1) and y(e) =  2  , then  + 2 is _____ .
3
  tan  
2
Ans. 3
2
Sol. (1 + y ) (1 + lnx) dx + x dy = 0
1  ln x  dx dy
   
x 1 y2
1  ln x  2
  tan1  y   c
2
 curve passes through (1, 1)
1 
 c= 
2 4
2
 1 1  ln x 
 tan1 y   
4 2 2
1  tan  3 / 2 
y e  ==1
1  tan  3 / 2 
 + 2 = 3.
*24. If the mean and variance of the data 65, 68, 58, 44, 48, 45, 60, , , 60 where  >  are 56 and
66.2 respectively, then 2 + 2 is equal to ______ .
Ans. 6344
Sol. Mean of 10 observations (65, 68, 58, 44, 48, 45, 60, , , 60) is 56
i.e. x  56
xi2
variance (2) =  x2
n
 a2 + b2 = 6344
11 11 11
C1 C2 C9 n
*25. If   ......   with gcd(n, m) = 1, then n + m is equal to _____ .
2 3 10 m
Ans. 2041
11 11 11
C1 C2 C9 n
Sol.   .....   , gcd(n, m) = 1
2 3 10 m
n n 1
Cr Cr 1
 
 r  1  n  1
9  11C  1 9
 212  26 2035 n
   r  1r   12   12 Cr 1   12

6

m
r 1  r 1 
n + m = 2041
x2 y 2
*26. If the points of intersection of two distinct conics x 2 + y2 = 4b and   1 lie on the curve
16 b2
2 2
y = 3x , then 3 3 times the area of the rectangle formed by the intersection points is _____ .
Ans. 432
Sol. x2 + y2 = 4b …(1)
x2 y 2
 1 …(2)
16 b2
and y2 = 3x2 …(3)
Solving equation (1), (2), (3)
for point of intersection, we get
2 2
x = b and b  16b + 48 = 0
b = 4 or 12
 b = 4 is rejected as conics are distinct
x =  2 3 , y =  6 (vertices of rectangle)
 Area(A) = 4 3  12
now 3 3  A  48  9  432
*27. Let ,  be the roots of the equation x 2  x + 2 = 0 with Im() > Im(). Then 6 + 4 + 4  52 is
equal to _______ .
Ans. 13
Sol. x2  x + 2 = 0, Im() > Im()
now, 2   + 2 = 0  2 = 2   and 2 = 2   …(1)
and  +  = 1,  = 2 …(2)
 6 + 4 + 4  52 = 3( + ) + 16 (using equation (1) and (2))
= 16  3 = 13
*28. Equations of two diameters of a circle are 2x  3y = 5 and 3x  4y = 7. The line joining the points
 22   1 
  , 4  and   ,3  intersects the circle at only one point P(, ). Then, 17   is equal
 7   7 
to _______ .
Ans. 2
Sol. Given L1 : 2x  3y = 5
L2 : 3x  4y = 7
 c (1, 1) P(,) L1
Equation of line L passing through
 22   1 
  , 4  and   ,3  is 3y  7x = 10
 7   7 
L
Now point P(, ) is the point of contact C
 3  7 = 10 …(1) (1,1)
L2
  1 3
and      7 + 3 = 4 …(2)
   1 7
Equation (1) + 2  Equation (2)
 17   = 2  4 + 10
17   = 2
*29. All the letters of the word "GTWENTY" are written in all possible ways with or without meaning
and these words are written as in a dictionary. The serial number of the word "GTWENTY"
is______ .
Ans. 553
Sol. Rank of GTWENTY
6! 5!
=   1  1  4!  1  1  1  1  553
2! 2!
30. Let f(x) = 2x  x2, x  R. If m and n are respectively the number the number of points at which the
curves y = f(x) and y = f'(x) intersect the x-axis, then the value of m + n is ______ .
Ans. 5
x 2
Sol. f(x) = 2  x , x  R
y = f(x) cuts x-axis at 3 points  m = 3
x
and y = f'(x) = 2 ln2  2x cuts x-axis at 2 points
n=2 m+n=5
PART – B (PHYSICS)
SECTION - A
31. The de-Broglie wavelength of an electron is the same as that of a photon. If velocity of electron is
25% of the velocity of light, then the ratio of K.E. of electron and K.E. of photon will be:
1 1
(1) (2)
4 1
8 1
(3) (4)
1 8
Ans. (4)
Sol. Given that (ve = 0.25c)

For photon,
hc
P 
EP
For electron,
h hv e
e  
me v e 2K e
As P = e
hc hv e
 
EP 2K e
hc h(0.25c)

EP 2K e
Ke 1

EP 8
*32. If the radius of curvature of the path of two particles of same mass are in the ratio 3 : 4, then in
order to have constant centripetal force, their velocities will be in the ratio of:
(1) 1: 3 (2) 3 : 1
(3) 3 : 2 (4) 2 : 3
Ans. (3)
Sol. Given that,

mv 2
 constant and m 1 = m2 = m
r
mv12 mv 22
 
r1 r2
v1 r1 3
  =
v2 r2 4
*33. A thermodynamic system is taken from an original state A to 8000 A

an intermediate state B by a linear process as shown in the
Pressure (Dyne/cm2)
figure. It’s volume is then reduced to the original value from B
to C by an isobaric process. The total work done by the gas 4000 B
from A to B and B to C would be: C
(1) 2200 J (2) 1200 J
(3) 33800 J (4) 600 J
3 7
3
Volume (m )
Ans. 800 J (No option is matching)
Sol. Work done by the gas from A to B and B to C = Area of triangle ABC
1
W  (800  400)  (7  3)  800 J
2
*34. A body starts moving from rest with constant acceleration covers displacement S1 in first (p – 1)
seconds and S2 in first p seconds. The displacement S1 + S2 will be made in time.
(1)  2p 2

 2p  1 s (2)  2p2  2p  1 s
(3)  2p  1 s (4)  2p  1 s
Ans. (1)
1
Sol. S1  a(p  1)2 …(i)
2
1
S2  ap2 …(ii)
2
1 2
and S1 + S2 = at …(iii)
2
Putting S1 and S2 in equation (iii), we get
t  2p2  2p  1
*35. Given below are two statements:

Statement (I): If a capillary tube is immersed first in cold water and then in hot water, the height
of capillary rise will be smaller in hot water.
Statement (II): If a capillary tube is immersed first in cold water and then in hot water, the height
of capillary rise will be smaller in cold water.
In the light of the above statements, choose the most appropriate from the options given below:
(1) Statement I is false but Statement II is true
(2) Both Statement I and Statement II are false
(3) Statement I is true but Statement II is false
(4) Both Statement I and Statement II are true
Ans. (3)
2T cos 
Sol. h
gr
and surface tension decreases with the increase of temperature
36. Match List I with List II

List-I List-II
(A)   d (I) Gauss’ law for electricity
 B.dl  0ic  0 0 dtE
(B)   d (II) Gauss law for magnetism
 E.dl  dtB
(C)   Q (III) Faraday law
 E.dA  0
 
(D) (IV) Ampere – Maxwell law

B.dA  0
Choose the correct answer from the options given below:
(1) (A) – (II), (B) – (III), (C) – (I), (D) – (IV) (2) (A) – (IV), (B) – (I), (C) – (III), (D) – (II)
(3) (A) – (IV), (B) – (III), (C) – (I), (D) – (II) (4) (A) – (I), (B) – (II), (C) – (III), (D) – (IV)
Ans. (3)
Sol. Maxwell’s equations of electromagnetism
37. The explosive in a Hydrogen bomb is a mixture of 1H2 , 1H3 and 3Li6 in some condensed form. The
chain reaction is given by:
6 1 4 3
3 Li  0 n  2He  1H
1H2  1H3  2He 4  0n1

During the explosion the energy released is approximately
[Given: M (Li) = 6.01690 amu, M (1H2 ) = 2.01471 amu, M ( 2 He 4 ) = 4.00388 amu, and 1 amu =
931.5 MeV]
(1) 28.12 MeV (2) 16.48 MeV
(3) 12.64 MeV (4) 22.22 MeV
Ans. (4)
Sol. Q = (M)c2
Q = [M(Li) + M(1H2 )  2M(2 H4 )]  931.5 MeV
*38. Two vessels A and B are of the same size and are at same temperature. A contains 1g of
hydrogen and B contains 1g of oxygen. PA and PB are the pressures of the gases in A and B
P
respectively, then A is:
PB
(1) 8 (2) 16
(3) 32 (4) 4
Ans. (2)
Sol. Given that
VA = VB and TA = TB
PV = nRT
P
  cons tant
n
PA nA 1/ 2
   16
PB nB 1/ 32
39. A galvanometer having coil resistance 10 shows a full scale deflection for a current of 3mA. For
it to measure a current of 8A, the value of the shunt should be:
(1) 4.85  103  (2) 3  103 
3
(3) 3.75  10  (4) 2.75  10 3 
Ans. (3)
Sol. Given that i ig
G = 10  G
ig = 3mA
i = 8A
igG = (i  ig)S
 S = 3.75  103  i  ig
S
40. A convex mirror of radius of curvature 30 cm forms an image that is half the size of the object.
The object distance is:
(1) –15 cm (2) – 45 cm
(3) 45 cm (4) 15 cm
Ans. (1)
Sol. Given that
R
f = + 15 cm
2
v
m = + 1/2  
u
u
v
2
using mirror formula
1 1 1
 
f v u
1 1 1
 
15 u u / 2
 u =  15 cm
41. A biconvex lens of refractive index 1.5 has a focal length of 20 cm in air. Its focal length when
immersed in a liquid of refractive index 1.6 will be:
(1) – 16 cm (2) + 16 cm
(3) + 160 cm (4) – 160 cm
Ans. (4)
1  1 1  1
Sol.  (1.5  1)   
fa R
 1 R 2  20
1 1 1
 
R1 R2 10
1  L  1 1 
  1  
fm  m  R1 R2 
1  1.5  1.6  1
 
fm  1.6  10
fm  160 cm
42. The electric current through a wire varies with time as I  I0  t, where I0  20A and   3A / s.
The amount of electric charge crossed through a section of the wire in 20 s is:
(1) 1600 C (2) 800 C
(3) 80 C (4) 1000 C
Ans. (4)
dQ
Sol. I
dt
Given that
I = I0 + t = (20 + 3t)
Q 20

 dQ 
0
 (20  3t)dt
0
20
20  3t 2 
Q  20t 0   
 2  0
 3  20  20 
Q  (20  20)   
 2 
Q = 1000 C
43. The deflection in moving coil galvanometer falls from 25 divisions to 5 division when a shunt of
24 is applied. The resistance of galvanometer coil will be:
(1) 100 (2) 48
(3) 12 (4) 96
Ans. (4)
Ig 5 1 1 I Ig
Sol.    Ig  I G
I 25 5 5
In case of shunted galvanometer (S = 24 )
(I  Ig)S = Ig G
 1  1
 I  5 I   24  5 I  G I  Ig
S
 
 5  1 1
 5   24  5  G
 
G = 96 
*44. A block of mass 100 kg slides over a distance of 10 m on a horizontal surface. If the co-efficient
of friction between the surfaces is 0.4, then the work done against friction (in J) is:
(1) 4000 (2) 3900
(3) 4200 (4) 4500
Ans. (1)
Sol. F = N N
N = mg
W=Fx
= 0.4  100  10  10
W = 4000 J
Mg
45. Two charges of 5Q and –2Q are situated at the points (3a, 0) and (–5a, 0) respectively. The
electric flux through a sphere of radius ‘4a’ having center at origin is:
3Q 5Q
(1) (2)
0 0
7Q 2Q
(3) (4)
0 0
Ans. (2)
qenclosed
Sol. 
0
2Q 5Q
5Q
  (5a, 0) (3a,0) (4a,0)
0
46. A capacitor of capacitance 100 F is charged to a potential of 12 V and connected to a 6.4 mH

inductor to produce oscillations. The maximum current in the circuit would be:
(1) 1.2 A (2) 1.5 A
(3) 3.2 A (4) 2.0 A
Ans. (2)
1 2 1
Sol. Limax  CV 2
2 2
C
imax  V
L
imax = 1.5 A
47. In the given circuit, the breakdown voltage of the Zener 1k
A C
diode is 3.0 V. What is the value of Iz ?
Iz
(1) 7 mA (2) 5.5 mA 2k
V 10V
(3) 10 mA (4) 3.3 mA
B D
Ans. (2)
10  3
Sol. Ibattery   7 mA
1000
3
I2k   1.5mA
2000
Iz  (7  1.5) mA
Iz = 5.5 mA
*48. At what distance above and below the surface of the earth a body will have same weight. (take
radius of earth as R.)
R
(1) (2) 5 R  R
2
3R R 5R R
(3) (4)
2 2
Ans. (4)
Sol. Given, d = h
g  d
2
 g 1  
 h  R 
1  R 
 
g  h
2
 g 1  
 h  R 
1  R 
 
 h2  Rh  R2  0
5R  R
h
2
V
49. The resistance R  where V  (200  5) V and I  (20  0.2) A, the percentage error in the
I
measurement of R is:
(1) 3.5 % (2) 5.5%
(3) 7% (4) 3%
Ans. (1)
Sol. R = V/I
R V I
 100   100   100
R V I
5 0.2
 100   100
= 200 20
 3.5%
*50. The potential energy function (in J) of a particle in a region of space is given as
U  (2x 2  3y 3  2z) . Here x, y and z are in meter. The magnitude of x-component of force (in N)
acting on the particle at point P(1, 2, 3) m is:
(1) 6 (2) 2
(3) 8 (4) 4
Ans. (4)
Sol. U  (2x 2  3y 3  2z)
U
Fx   = 4x
x
at x = 1
|Fx| = 4 N
SECTION - B
*51. When the displacement of a simple harmonic oscillator is one third of its amplitude, the ratio of
x
total energy to the kinetic energy is , where x = __________ .
8
Ans. 9
1
Sol. x A
3
1
m2 A 2
T.E. 2 A2 A2 9
  2 2
 2

K.E. 1 8
m2 (A 2  x 2 ) A  x A2 
A
2 9
52. A square loop of side 10 cm and resistance 0.7 is placed vertically in east-west plane. A
uniform magnetic field of 0.20 T is set up across the plane in north east direction. The magnetic
field is decreased to zero in 1 s at a steady rate. Then, magnitude of induced emf is x  103 V.
The value of x is __________ .
Ans. 2
Sol. 1  BA cos 
2
 10  3
 0.20    cos 45  2  10 Wb
 100 
2 = 0

e  2  103 V , x = 2
t
*53. In a test experiment on a model aeroplane in wind tunnel, the flow speeds on the upper and lower
surfaces of the wings are 70 ms–1 and 65 ms–1 respectively. If the wing area is 2 m2, the lift of the
wing is _______ N.
(Given density of air = 1.2 kg m –3)
Ans. 810
Sol. Using Bernoulli’s equation

1 1
P1  1v12  P2  2 v22
2 2
1
 P2  P1 =  v12  v 22
2
 
Lift on wing = (P2  P1)A
1 1
 
=  v12  v 22 A   1.2  (702  652 )2  810N
2 2
54. A 16 wire is bend to form a square loop. A 9V battery with internal resistance 1 is connected
across one of its sides. If a 4F capacitor is connected across one of its diagonals, the energy
x
stored by the capacitor will be J, where x = _________ .
2
Ans. 81
V 9 9 9V
Sol. i   A 1
Req 12  4 4
1
12  4
4i2 = 12i1 …(i) i I2 4
A
9 i1
and i1 + i2 = …(ii) 4F
4
Solving (i) and (ii) 4 4
9 4
i1  A
16 B
9
VA  VB  i1  8  V
2
1
U  CV 2
2
2
1 9 81
U   4   J
2 2 2
55. The magnetic potential due to a magnetic dipole at a point on its axis situated at a distance of
–5 2
20 cm from its center is 1.5 × 10 T m. The magnetic moment of the dipole is ______ Am

(Given: 0  107 T m A 1 )
4
Ans. 6
 Mcos 
Sol. V 0
4 r 2
10 7  M  cos0
1.5  10 5 
(0.2)2
2
M = 6 Am
*56. A ball rolls off the top of a stairway with horizontal velocity u. The steps are 0.1 m high and 0.1 m
wide. The minimum velocity u with which that ball just hits the step 5 of the stairway will be
x ms1 where x = ________ [use g = 10 m/s2]
Ans. 2
Sol. For minimum velocity ball needs to just cross 4th step u
to just hit 5th step 0
In vertical 1
1 2
0.4  gt …(i) 2
2
In horizontal 3
0.4 = ut …(ii) 4
Solving (i) and (ii)
u  2 m/s 5
57. An electron is moving under the influence of the electric field of a uniformly charged infinite plane
sheet S having surface charge density  . The electron at t = 0 is at a distance of 1 m from S
and has a speed of 1 m/s. The maximum value of  if the electron strikes S at t = 1 s is
 m 0  C
  2 , the value of  is ________ .
 e m
Ans. 8
 e
Sol. E , a
20 2m 0
given u = 1 m/s and t = 1 sec
using
1
S  ut  at 2
2
1  e  2
 1  1(1)   1
2  2m0 
 m 0  2
   8  C/m
 e 
*58. A cylinder is rolling down on an inclined plane of inclination 60°. It’s acceleration during rolling
x 2
down will be m/s2 , where x = _________ (use g = 10 m/s )
3
Ans. 10
g sin 
Sol. a
I
1  cm 2 a
mR
 = 60
2 10
a  gsin60  m/s2
3 3
59. In a double slit experiment shown in figure, when light of S1

wavelength 400 nm is used, dark fringe is observed at P. If D = 0.2
m, the minimum distance between the slits S1 and S2 is ______
mm.
d
S2
*
Source D D P
Ans. 0.2 (Not matching with answer key)
Sol. 2 (D2  d2 )1/2  D  x

 
  1/2 
d2 
2 D  1  2   D   x
  D  
 
 d2 
2D 1  2
 1  x
 2D 
For dark fringe
d2 
 x  (2n  1)
D 2
For minimum distance n = 0
d2 

D 2
D 0.2  400  10 9
d2   d  0.2 mm
2 2
x
60. When a hydrogen atom going from n = 2 to n = 1 emits a photon, its recoil speed is m/s . Where
5
x = __________ . (Use, mass of hydrogen atom  1.6  10 27 kg )
Ans. 17
Sol.  E = 10.2 eV n=2

Recoil speed  3.4 eV
E 10.2  1.6  10 19
v 
mc 1.6  1027  3  108 n=1
17  13.6 eV
v m/s
5
 x = 17
PART – C (CHEMISTRY)
SECTION - A
*61. Given below are two statements: One is labeled as Assertion A and the other is labeled as
Reason R.
Assertion A: The first ionization enthalpy decreases across a period
Reason R : The increasing nuclear charge outweighs the shielding across the period.
(1) A is false but R is true
(2) A is true but R is false
(3) Both A and R are true and R is the correct explanation of A
(4) Both A and R are true but R is NOT the correct explanation of A
Ans. (1)
Sol. Assertion (A) is false
The first ionization enthalpy increases across a period.
Reason is correct.
*62. The difference in energy between the actual structure and the lowest energy resonance structure
for the given compound is
(1) electromeric energy (2) ionization energy
(3) hyperconjugation energy (4) resonance energy
Ans. (4)
Sol. Resonance Energy: A compound with delocalized electron is more stable than if it would be if all
its electron were localized. The extra stability of compound gains from having delocalized
electrons is called Resonance Energy.
*63. The arenium ion which is not involved in the bromination of Aniline is _______.
NH2
NH 2
(1) H (2)
Br
H Br
NH 2
NH2 H
(3) (4) Br
Br
Ans. (3)
Sol. NH2 group being ortho and para directing. Bromination is not possible at meta position.
64. In chromyl chloride test for confirmation of Cl– ion, a yellow solution is obtained. Acidification of
the solution and addition of amyl alcohol and 10% H2O2 turns organic layer blue indicating
formation of chromium pentoxide. The oxidation state of chromium in that is
(1) +5 (2) +3
(3) +10 (4) +6
Ans. (4)
 1 O O  1
(+6)
Cr
Sol. O  1
 1 O O
 2 
65. Match List I with List II
LIST I (Substances ) LIST II ( Element Present )

A. Ziegler catalyst I. Rhodium
B. Blood Pigment II. Cobalt
C. Wilkinson catalyst III. Iron
D. Vitamin B12 IV. Titanium
Choose the correct answer from the options given below
(1) A-II, B-IV, C-I, D-III (2) A-IV, B-III, C-I, D-II
(3) A-II, B-III, C-IV, D-I (4) A-III, B-II, C-IV, D-I
Ans. (2)
Sol. Ziegler catalyst - TiCl4  Al  C2H5 3
Blood pigment – Haemoglobin contains Fe2 
Ph3P PPh 3
Wilkinson’s catalyst Rh
Ph3P Cl
Vitamin B12 – contain Co2 
66. Type of amino acids obtained by hydrolysis of proteins is :

(1)  (2) 
(3)  (4) 
Ans. (4)
Hydrolysis Hydrolysis
Sol. Proteins   Peptides     amino acids
*67. The interaction between  bond and lone pair of electrons present on an adjacent atom is
responsible for
(1) Resonance effect (2) Electromeric effect
(3) Inductive effect (4) Hyperconjugation
Ans. (1)
Sol. Resonance – The delocalization of electrons is known as resonance. For a compound to show
resonance, compound with unsaturated system would be in conjugation with   bond, –ve
charge, positive charge, lone pair or odd electron.
68. In which one of the following metal carbonyls, CO forms a bridge between metal atoms?
(1) Os3  CO 12  (2) Ru3  CO 12 
(3)  Co 2  CO 8  (4) Mn2  CO 10 
Ans. (3)
O
C
OC CO
Sol. OC Co Co CO
OC CO
C
69. Given below are two statements: One is labelled as Assertion A and the other is labelled as
Reason R.
Assertion A: Aryl halides cannot be prepared by replacement of hydroxyl group of phenol by
halogen atom.
Reason R : Phenols react with halogen acids violently.
(1) A is false but R is true
(2) Both A and R are true and R is the correct explanation of A
(3) A is true but R is false
(4) Both A and R are true but R is NOT the correct explanation of A
Ans. (3)
Sol. Aryl halides cannot be prepared by replacement of hydroxyl group of phenol by halogen atom.
*70. The correct set of four quantum numbers for the valence electron of rubidium atom (Z = 37) is:
1 1
(1) 5, 1, 0,  (2) 5, 1, 1, 
2 2
1 1
(3) 5, 0, 1,  (4) 5, 0, 0, 
2 2
Ans. (4)
Sol. Rubidium  Kr  5s1
[At. No. = 37]
1
n  5,   0, m  0, s  
2
71. Identify the incorrect pair from the following:

(1) Carnallite- KCl.MgCl2.6H2O (2) Cryolite –Na3AlF6
(3) Fluoroapatite-3 Ca3(PO4).CaF2 (4) Fluorspar –BF3
Ans. (4)
*72. Appearance of blood red colour, on treatment of the sodium fusion extract of an organic
compound with FeSO4 in presence of concentrated H2SO4 indicates the presence of element/s
(1) N and S (2) N
(3) S (4) Br
Ans. (1)
Sol. Lassaigne’s filtrate (sodium extract) consist of NaCN and NaOH and when organic compound
contains both ‘N’ and ‘S’. Sodium thiocyanate is formed, which gives red coloration (of ferric
sulphocyanide) with ferric ion.
3NaCNS  FeCl3  Fe  CNS 3  3NaCl
Blood red
73. In alkaline medium, MnO 4 oxidizes I to

(1) IO  (2) IO 4
(3) I2 (4) IO 3
Ans. (4)
Sol. In alkaline medium KMnO4 oxidises I to IO3
6MnO4  I  6OH  IO3  6MnO42   3H2 O
*74. Which of the following is not correct?

(1) G is zero for a reversible reaction
(2) G is negative for a spontaneous reaction
(3) G is positive for a spontaneous reaction
(4) G is positive for a non-spontaneous reaction
Ans. (3)
Sol. At constant temperature and pressure
G   ve for spontaneous process
G  0 for process at equilibrium
G   ve for non-spontaneous process.
*75. Identify product A and product B :

hv
 Pr oduct A
 Cl 2
CCl4
  Pr oduct B
Cl Cl Cl
Cl
(1) A : B: (2) A : B:
Cl
Cl Cl Cl
Cl
Cl Cl
Cl
(3) A : (4) A : B:
B:
Cl Cl
Cl
Cl
Ans. (2)
h
 Product  A 
Sol.  Cl2
h
 Product B 
Cl
h
 Cl2 
free radical mechanism

Cl
Cl
CCl4 Cl
 Cl Cl 
 Cl
 Cl 
Cl
76. The major product (P) in the following reaction is

OCH 2CH3
 
conc. HBr excess

Heat P 
major product
CH=CH 2
Br OH
(1) (2)
CH2CH2Br CH 2CH2Br
Br OH
(3) (4)
Br CH CH3 Br CH CH3
Ans. (4)
OCH2CH3
conc. HBr  excess 
Sol. 
Heat P 
major product
CH=CH2
H
OCH2CH3
O CH2 CH3
 HBr 

CH=CH2
CH=CH2
Br
Major 
OH
OH OH
  
Br HBr  CH2  CH2  Br
HC CH3
HC CH3 CH=CH2
Br
*77. Chlorine undergoes disproportionation in alkaline medium as shown below :

a Cl2g  b OH aq  c ClO  aq  d Claq  e H2O l
The values of a, b, c and d in a balanced redox reaction are respectively:
(1) 2, 2, 1 and 3 (2) 1, 2, 1 and 1
(3) 2, 4, 1 and 3 (4) 3, 4, 4 and 2
Ans. (2)
lost
Sol.
0  1


 c ClO  aq   dCl  aq   eH2O   
a Cl2  g  b OH  aq   
gain
Lost part
0
2Cl  2Cl  2e … (1)
Gain part
0
2e  2Cl  2Cl … (2)
Add Eqn. (1) and (2)
0
2Cl  2Cl  2Cl
4OH  2Cl2  2ClO  2Cl  2H2 O
2OH  Cl2  ClO  Cl  H2 O
Hence, a = 1, b = 2, c = 1, d = 1, e = 1
78. The final product A formed in the following multistep reaction sequence is
 i H2 O, H
 ii CrO3
 iii H2NNH2 ,KOH  A

Heating
N NH2
OH
(1) (2)
O
N
NH2
(3) (4)
Ans. (4)
CH CH3
 H2O / H 

H2 O
OH
O
CH CH3
Sol. CH2 CH3 C CH3
CrO3
   
NH2  NH2 /KOH,
*79. Given below are two statements:

Statement I: The electronegativity of group 14 elements from Si to Pb gradually decreases.
Statement II: Group 14 contains non-metallic, metallic, as well as metalloid elements.
(1) Statement I is true but Statement II is false
(2) Statement I is false but Statement II is true
(3) Both Statement I and Statement II are false
(4) Both Statement I and Statement II are true
Ans. (2)
Sol. Order of E. N.
C > Pb > Ge > Si  Sn
80. KMnO4 decomposes on heating at 513 K to form O2 along with

(1) Mn & KO2 (2) K2MnO4 & MnO2
(3) K2MnO4 & Mn (4) MnO2 & K2O2
Ans. (2)

Sol. KMnO 4 
513 K
 K 2MnO 4  MnO2  O 2
SECTION - B
*81. Number of compounds among the following which contains sulphur as heteroatom is________ .
Furan, Thiophene, Pyridine, Pyrrole, Cysteine, Tyrosine
Ans. 2
O
Thiophene  , Cysteine  HS OH
Sol.
S NH2
and furan, pyridine, pyrrole and tyrosine does not contain sulphur (heteroatom).
82. The osmotic pressure of a dilute solution is 7  105 Pa at 273 K. Osmotic pressure of the same
solution at 283 K is __________  104 Nm 2
Ans. 73
Sol. Osmotic pressure  7  105 Pa, T  273 K

  CRT   CR  constant
T
7  105 req
 
273 283
7  105
req   283  72.56
273
*83. The number of species from the following which are paramagnetic and with bond order equal to
one is __________ .
H2 , He2 , O2 , N22  , O22  , F2 ,Ne 2 , B2
Ans. 1
2
Sol. H2  1s2 , Bond order   1, M. B.  Diamagnetic
2
1 1
He2  1s2  * 1s2 2s1, Bond order  3  2  2  0.5, M. B.  P. M.
2
O 2  Bond order  2.5, M. B.  P. M.
N22   Bond order  2.0, M. B.  P. M.
1 4
Bond order 
2
10  6    2
2
O 22   Bond order  1, M. B.  Diamagnetic
F2  Bond order  1.0, M. B.  Diamagnetic
Ne2  Bond order  0.5,M. B.  Paramagnetic
1 2
B2  Bond order 
2
 6  4  2  1, M. B.  P. M.
Hence, the number of species from the following which are paramagnetic and with bond order
equal to one = 1.
84. From the compounds given below, number of compounds which give positive Fehling’s test
is _____ .
Benzaldehyde, Acetaldehyde, Acetone, Acetophenone, Methanal, 4-nitrobenzaldehyde,
cyclohexane carbaldehyde.
Ans. 3
Sol. Number of compound which gives Fehling test

O
O O C H
H3C C H, H C H ,
*85. Number of compounds with one lone pair of electron on central atom amongst following
is ________ .
O3 , H2 O, SF4 , ClF3 , NH3 , BrF5 , XeF4
Ans. 4
Sol. O
O3 
O O
F
F
SF4  S
F
F
O
H2 O 
H H
F
ClF3  Cl F
F
N
NH3 
H H
H
F F
BrF5  Br
F F
F
F F
XeF4  Xe
F F
 Number of compound with one lone pair of electron on central atom = 4 (which are O3, NH3,
BrF5 and SF4)
*86. For the reaction N2 O4 g  2NO2g , K P  0.492atm at 300 K. KC for the reaction at same
temperature is _________  10 2 .
(Given : R = 0.082 L atom mol–1 K–1)
Ans. 2
Sol. 

N2 O 4  g  
 2NO 2  g , K P  0.492 atm, T  300 K
ng  2  1  1
ng 1
 K P  K c   RT   0.492  K c   0.082  300 
0.492 0.492
Kc    2  102
300  0.082 24.6
H3C H
*87.  i O
ii Zn  H2 O   P 
 3
Pr oduct
H CH3
Consider the given reaction. The total number of oxygen atom/s present per molecule of the
product (P) __________ .
Ans. 1
O O
H3C H
Sol.  3
1 O

 2 Zn/H2 O
 H3C C H  H3C C H
H CH3
*88. A solution of H2SO4 is 31.4 % H2SO4 by mass and has a density of 1.25 g/mL.
The molarity of the H2SO4 solution is __________ M (nearest integer)
[Given molar mass of H2SO4 = 98 g mol–1]
Ans. 4
Sol. 31.4% by mass of H2SO4, dsoln = 1.25 g/mL
MH SO  ?
2 4
Let mass of solution = 100 g

Mass of H2 SO4  31.4
100
 Vso ln   80 mL
1.25
31.4
 mole H2SO4   0.32
98
mole
MH2SO4   1000  4
Vso ln in mL
89. The mass of zinc produced by the electrolysis of zinc sulphate solution with a steady current of
0.015 A for 15 minutes is __________  10 4 g.
(Atomic mass of zinc = 65.4 amu)
Ans. 46
Sol. Zn2   2e   Zn
W Q
W  zit
5.4 882.9
  0.015  15  60   45.75  10 4 g
2  96500 193000
K 1K 2
*90. For a reaction taking place in three steps at same temperature, overall rate constant K  . If
K3
Ea1. Ea2 and Ea3 are 40, 50 and 60 kJ/ mol respectively, the overall Ea is _____ kJ/mole
Ans. 30
Sol. Ea1  40, Ea2  50 and Ea3  60
k 1k 2
k eff 
k3
E1 E2
 
E RT RT
 A1  e  A 2e
*A eff. e RT  E3

A 3  e RT
On differentiating w. r. t. to temperature,
E  Ea1  Ea2  Ea3
= 40 + 50 – 60 = 30

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JEE-MAIN-2024 (29th January-First Shift)-MPC-2

7. Let R be a relation on Z  Z defined by (a, b) R (c, d) if and only if ad  bc is divisible by 5. Then

   cosecx  sin x 

Ans. (2) A(a, 2) a 

Sol. Given that (ve = 0.25c)

Sol. Given that,

*33. A thermodynamic system is taken from an original state A to 8000 A

Ans. 800 J (No option is matching)

*35. Given below are two statements:

36. Match List I with List II

1H2  1H3  2He 4  0n1

46. A capacitor of capacitance 100 F is charged to a potential of 12 V and connected to a 6.4 mH

Sol. Using Bernoulli’s equation

59. In a double slit experiment shown in figure, when light of S1

Ans. 0.2 (Not matching with answer key)

Sol. 2 (D2  d2 )1/2  D  x

Sol.  E = 10.2 eV n=2

LIST I (Substances ) LIST II ( Element Present )

66. Type of amino acids obtained by hydrolysis of proteins is :

71. Identify the incorrect pair from the following:

73. In alkaline medium, MnO 4 oxidizes I to

*74. Which of the following is not correct?

*75. Identify product A and product B :

76. The major product (P) in the following reaction is

*77. Chlorine undergoes disproportionation in alkaline medium as shown below :

*79. Given below are two statements:

80. KMnO4 decomposes on heating at 513 K to form O2 along with

Sol. Number of compound which gives Fehling test

Let mass of solution = 100 g

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