FINAL JEE–MAIN EXAMINATION – APRIL, 2024

(Held On Thursday 04th April, 2024) TIME : 3 : 00 PM to 6 : 00 PM

MATHEMATICS TEST PAPER WITH SOLUTION

SECTION-A 3. Let C be a circle with radius 10 units and centre
 72  9  8  1
x x x
at the origin. Let the line x + y = 2 intersects the
 , x0
1. If the function f  x    2  1  cos x
 a log 2 log 3 circle C at the points P and Q. Let MN be a chord
 e e , x 0
of C of length 2 unit and slope –1. Then, a distance
is continuous at x = 0, then the value of a2 is equal
(in units) between the chord PQ and the chord MN
to
is
(1) 968 (2) 1152
(3) 746 (4) 1250 (1) 2  3 (2) 3  2
Ans. (2) (3) 2 1 (4) 2 1
Sol. lim f  x   a n2 n3 Ans. (2)
x 0

lim
72x  9x  8x  1
 lim
8 x

 1 9x  1 
n 0 2  1  cosx x 0 2  1  cosx
M
 8x  1  9x  1  x 2 
lim 
n 0
 
 x  x  1  cos x 
  2  1  cos x 
A
 n8  n9  2  2 2  24 2 n2 n3
O N
 a = 24 2 , a2 = 576 × 2 = 1152 10
2. If  > 0, let  be the angle between the vectors
a  ˆi  ˆj  3kˆ and b  3iˆ  ˆj  2kˆ . If the vectors
a  b and a  b are mutually perpendicular, then
the value of (14 cos )2 is equal to C : x2 + y2 = 10
(1) 25 (2) 20
MN
(3) 50 (4) 40 AN = 1
2
Ans. (1)
 In OAN  (ON)2 = (OA)2 + (AN)2
Sol.  a  b  . a  b   0 ,  0 10 = (OA)2 + 1 OA = 3
2 2
a  b  0  1 + 2 + 9 = 9 + 1 + 4 Perpendicular distance of center from
002
ab 36 PQ   2
  = 2, cos    2
a.b 14. 14
Perpendicular distance between MN and
14cos = 3 – 8 = –5
 (14 cos)2 = 25 PQ  OA  2 or OA  2

 3  2 or 3  2
4. Let a relation R on  be defined as : 1 2  2
6. Let A    and B = I + adj(A) + (adj A) +…+
(x1,y1) R(x2,y2) if and only if x1 < x2 or y1 < y2  0 1 
Consider the two statements : (adj A)10. Then, the sum of all the elements of the
matrix B is :
(I) R is reflexive but not symmetric. (1) –110 (2) 22
(II) R is transitive (3) –88 (4) –124
Ans. (3)
Then which one of the following is true ? 1 2 
Sol. Adj(A) =  
(1) Only (II) is correct. 0 1 
(2) Only (I) is correct. 1 4 
(AdjA)2 =  
(3) Both (I) and (II) are correct. 0 1 
|
(4) Neither (I) nor (II) is correct.
|
Ans. (2) 1 20 
 AdjA   
10

Sol. All ((x1y1), (x1,y1)) are in R where 0 1 
x1, y1  N  R is reflexive 1 0  1 2  1 4  1 20 
B        ...   
((1,1), (2,3))  R but ((2,3), (1,1))  R 0 1  0 1  0 1  0 1 
11 110 
 R is not symmetric B  sum of elements of B
0 11 
((2,4), (3,3))  R and ((3,3), (1,3))  R but ((2,4), = –88
1  22  2  32  ...  100  101
2
(1,3))  R
7. The value of is
 R is not transitive 12  2  22  3  ...  1002  101
306 305
5. Let three real numbers a,b,c be in arithmetic (1) (2)
305 301
progression and a + 1, b, c + 3 be in geometric 32 31
(3) (4)
progression. If a > 10 and the arithmetic mean of 31 30
Ans. (2)
a,b and c is 8, then the cube of the geometric mean 100
 r  r  1
2
1  2  2  3  ...  100  101
of a,b and c is 2 2 2
r 1
Sol.  100
(1) 120 (2) 312 12  2  22  3  ...  100 2  101
 r 2  r  1
(3) 316 (4) 128 r 1
 n  n  1 2  2.n  n  1 2n  1 n  n  1
Ans. (1) 100
 3 2
r  2r  r 


 2



6

2
Sol. 2b = a + c, b2 = (a + 1) (c + 3),
r 1
 
 n  n  1  n  n  1 2n  1
100 2
  r3  r2    
abc r 1
 2  6
 8  b  8,a  c  16
3 n  n  1  n  n  1 2 
2   .  2n  1  1
64 = (a + 1) (19 – a) = 19 + 18a – a 2  2 3 
 ;Put n = 100
a2 – 18a – 45 = 0  (a – 15) (a + 3) = 0, (a > 10) n  n  1  n  n  1  2n  1 
  
2  2 3 
a = 15, c = 1, b = 8
100 101 2
((abc)1/3)3 = abc = 120   201  1
2 3 5185 305
  
100  101 201 5117 301

2 3
 x 1
8. 
Let f  x    t  sin 1  e t dt, x 
0
  . Shaded area  1  x Right  x Left  dy

2
f x
Then lim is equal to
x 0 x3 y 2  2x
1 1 y  4x  1 Solve
(1) (2) 
6 6 1
y  1, y  
2
2 2
(3)  (4) 1
 y  1 y2 
3 3 Shaded area  1  4  2  dy

Ans. (2) 
2
f x 1
Sol. lim  1  y2  y3  9
x 0 x 3     y   
4 2 
   6   1 32
Using L Hopital Rule. 2

10. The area (in sq. units) of the region

lim
f 'x
 lim

x  sin 1  e x  (Again L Hopital) S  z  ; z  1  2;  z  z   i  z  z   2, lm  z   0
x 0 3x 2 x 0 3x 2
is
Using L.H. Rule 7 3
(1) (2)
 sin 1  e
 lim 
 x
 e .e
x x

 cos 1  e .e x
 x

3 2
17 7
x 0 6 (3) (4)
8 4
1
 Ans. (2)
6
Sol. Put z = x + iy
9. The area (in sq. units) of the region described by
z  1  2   x  1  y2  4
2
2
…(1)
{(x,y) : y < 2x, and y > 4x –1} is
 z  z   i z  z   2  2x  i 2iy   2
11 8
(1) (2)  x  y 1 …(2)
32 9
Im(z) > 0  y > 0 …(3)
11 9
(3) (4)
12 32
Ans. (4) x–y=1

y /4
P (–3,0) (1,0) (5,0)
1

x' 0 x
Sol. (1/4,0
–1/2
Required area
(0,–1) Q
= Area of semi-circle – area of sector A
y' 1 
2 
2

2 2
3

2
 cos x
1
2 13. If the coefficients of x4, x5 and x6 in the expansion
11. If the value of the integral  dx is .
1 1  3
x
 of (1 + x)n are in the arithmetic progression, then
Then, a value of  is the maximum value of n is :
  (1) 14 (2) 21
(1) (2)
6 2
(3) 28 (4) 7
 
(3) (4)
3 4 Ans. (1)
Ans. (2) Sol. Coeff. of x4 = nC4
1
cos x Coeff. of x5 = nC5
Sol. Let I   1  3x dx …(I)
1
Coeff. of x6 = nC6
1
cos x n
C4, nC5, nC6 …. AP
I  1  3 x dx
1
2.nC5 = nC4 + nC6
 b b

 using  f  x  dx   f  a  b  x  dx  …(II) n
C4 n
C6  n
 Cr n  r  1

 a a  2 n
 n n  
C5 C5  Cr 1
 r 

Add (1) and (II)
1 1 5 n5
2I   cos  x  dx  2  cos  x  dx 2 
n4 6
1 0

sin  2 12(n – 4) = 30 + n2 – 9n + 20
I   given 
  n2 – 21n + 98 = 0
 (n – 14) (n – 7) = 0
 
2
nmax = 14 nmin = 7
12. Let f  x   3 x  2  4  x be a real valued
14. Consider a hyperbola H having centre at the origin
function. If  and  are respectively the minimum
and the maximum values of f, then 2 + 22 is and foci and the x-axis. Let C1 be the circle
equal to touching the hyperbola H and having the centre at
(1) 44 (2) 42
the origin. Let C2 be the circle touching the
(3) 24 (4) 38
Ans. (2) hyperbola H at its vertex and having the centre at
Sol. f(x) = 3 x  2  4  x one of its foci. If areas (in sq. units) of C1 and C2
x–20 & 4–x0 are 36 and 4, respectively, then the length (in
 x  [2, 4]
units) of latus rectum of H is
Let x = 2sin2 + 4cos2
 f(x) = 3 2 cos   2 sin  28 14
(1) (2)
3 3
 2  3 2 cos   2 sin   9  2  2
10 11
2  3 2 cos   2 sin   20 (3) (4)
3 3
= 2 = 20 Ans. (1)
2 2
 + 2 = 2 + 40 = 42
 x2 y2 46 46
Sol. Let H :  1 (b2 = a2(e2 – 1))  Pi X i  9
 4a + 4a + 4b + 12b + 24b =
9
a 2 b2
46
 eqn of C1 = x2 + y2 = a2 8a + 40b =
9
Ar. = 36 23
a2 = 36 4a + 20b = …. (II)
9
a=6 Subtract (I) from (II) we get
Now radius of C2 can be a(e – 1) or a(e + 1) 1 1
b= &a=
for r = a(e – 1) for r = a(e + 1) 9 12
Variance = E(xi2) – E(xi)2
Ar. = 4 r2 = 4 E(xi2) = 02 × 92 + 22 × 2a + 42(a + b) + 62(2b) + 82(3b)
a2(e – 1)2 = 4 a2(e + 1)2 = 4 = 24a + 280b
1 1
36(e – 1)2 = 4 36(e + 1)2 = 4 Put a = b=
12 9
1 1
e–1= e+1= 2 280 298
3 3 E(xi ) = 2 + 
9 9
4 2 2 = E(xi2) – E(xi)2
e= 
3 3 298  46 
2
 
Not possible 9  9 
 16  298 2116
 b2 = 36   1  = 28 2  
 9  9 81
566
2b2 2  28 28 
 LR =   81
a 6 3 16. Let PQ be a chord of the parabola y2 = 12x and the
15. If the mean of the following probability midpoint of PQ be at (4,1). Then, which of the
following point lies on the line passing through the
distribution of a random variable X;
points P and Q ?
X 0 2 4 6 8 3 
(1) (3,–3) (2)  , 16 
P  X  a 2a a  b 2b 3b 2 
1 
(3) (2, 9) (4)  , 20 
46 2 
is , then the variance of the distribution is
9 Ans. (4)
581 566 P
(1) (2)
81 81 (4,1
Sol.
173 151
(3) (4)
27 27 Q
Ans. (2)
T = S1
Sol.  Pi  1 y – 6(x + 4)
= 1 – 48
a + 2a + a + b + 2b + 3b = 1 6x – y = 23
4a + 6b = 1 …. (I) 1 
Option 4  , 20  will satisfy
46 2 
E(x) = mean =
9
17. Given the inverse trigonometric function assumes  3 
dy  2x  8x  2
principal values only. Let x, y be any two real Sol.  y  2
   
2 2
dx  x2  4  x 4
numbers in [–1,1] such that  

cos–1x – sin–1 y = ,    . dy  2x  2
2  y 2  
 
2
2 2
dx  x  4  x2  4
Then, the minimum value of x + y + 2xy sin is
(1) –1 (2) 0 2x
 x2  4 dx
1 1 IF = e
(3) (4)
2 2
IF = x2 + 4
Ans. (2)
 
Sol. cos–1x –   cos 1 y  =  y × (x2 + 4) = 
2

 x2  4 
x 
2
2  2
4

cos–1x + cos–1y = 
2 dx
y(x2 + 4) = 2 
     3 
2
x  22
    ,   ,    0, 
 2  2  2
  2 x
cos 1
 xy  1 x 2
1 y 2
 
 
2
y x2  4 
2
tan 1    c
2

xy  1  x 2 1  y 2   sin  0=0+c=c=0

(xy + sin) = (1 – x2)(1 – y2) x

2 2 2 2 2 2 2 y(x2 + 4) = tan–1  
x y + 2xysina + sin a = 1 – x – y + x y 2
x2 + y2 + 2xy sin = 1 – sin2
y at x = 2
x2 + y2 + 2xysin = cos2
Min. value of cos2 = 0 y(4 + 4) = tan–1(1)

At   
2 y 2 
32
Option (2) is correct
18. Let y = y(x) be the solution of the differential Option (4) is correct
equation
(x2 + 4)2dy + (2x3y + 8xy – 2)dx = 0. If y(0) = 0, 19. Let a  ˆi  ˆj  k,
ˆ b  2iˆ  4ˆj  5kˆ and

then y(2) is equal to c  xiˆ  2ˆj  3k,x

ˆ  . If d is the unit vector in the
 
(1)
8
(2)
16
direction of b  c such that a.d  1 , then a  b .c  
 is equal to
(3) 2 (4)
32 (1) 9 (2) 6
Ans. (4)
(3) 3 (4) 11
Ans. (4)
Sol. 
d  bc  L1 L2
P

a.d   b.a  c.a  Q
L3
1 = (1 + x + 5)
1 = (x + 6) ….(1) x2 y4 z2
L1    
1 1 5 1
d =1 x6
 P    2,5  4,   2 


 b  c 1  L2 
x 3 y 2 z 3
 
2 3 2

  x  2  ˆi  6ˆj  2kˆ  1  P  2  3,3  2,2  3
2((x + 2)2 + 62 + 22) = 1  + 2 = 2 + 3 3 + 2 = 5 + 4
x2 + 4x + 4 + 36 + 4 = (x + 6)2  = 2 + 1 3 = 5 + 2
x2 + 4x + 44 = x2 + 12x + 36 3 = 5(2 + 1) + 2
8x = 8, x = 1 3 = 10 + 7
1 1 1  = –1  = –1
2 4 5  a  b .c   Both satisfies (P)
x 2 3
P(1,–1,1)
0 1 0 x y z
L3   
2 4 = 2 – 9(x – 2)
9 1/ 4 1/ 2 1
x  2 1 3 x y z
L3    k
= 20 – 9x 1 2 4
at x = 1 Coordinates of Q(k,2k,4k)
20 – 9 = 11 DR’s of PQ = <k–1, 2k + 1, 4k – 1>
Option 4 is correct PQ  to L3
20. Let P the point of intersection of the lines (k – 1) + 2(2k + 1) + 4(4k – 1) = 0
k – 1 + 4k + 2 + 16k – 4 = 0
x2 y4 z2 x 3 y 2 z 3
  and   . 1
1 5 1 2 3 2 k
7
Then, the shortest distance of P from the line
1 2 4
4x = 2y = z is Q , , 
7 7 7
5 14 14
(1) (2)  1 
2
2  4
2 2
7 7 PQ   1     1     1  
 7  7  7
3 14 6 14
(3) (4) 36 81 9 126
7 7    
49 49 49 7
Ans. (3)
3 14
PQ 
7
Option-3 will satisfy
 SECTION-B x
2I1  –cosecx cotx + n tan
21. 2 4
Let S = {sin 2 : (sin  + cos )x + (sin2)x + 4 2 2

(sin6 + cos6) = 0 has real roots}. If  and  be 1 1 x

I1  – cosecx cot x  n tan
2 2 2
the smallest and largest elements of the set S,
3 3 x
respectively, then 3(( – 2)2 + ( – 1)2) equals….. 4I  – cot xcosec 3x – cosecx cot x  n tan  4c
2 2 2
Ans. (4)
1  3 3 x
 sin 2 2   3 2  I  – cosecx cot x  cosec 2 x    n tan  c
D   sin 2  – 4 1 –
2 4  2 8 2
Sol. 1 – sin 2 
 2  4  1 3
  ,    8       1
 5 3  4 8
  sin 2  – 4  1 – sin 2 2  sin 4 2 
2

 4 8  23. Let f :    be a thrice differentiable function

3
D  – sin 4 2  6sin 2 2 – 4  0 such that f(0) = 0, f(1) = 1, f(2) = –1, f(3) = 2 and
2
3sin 4 2 –12sin2 2  8  0 f(4) = –2. Then, the minimum number of zeros of
(3f' f'' + ff"') (x) is …..
12  122 – 12.8 12  4 3 6  2 3
sin 2 2   
6 6 3 Ans. (5)

sin 2 2  2 
2
3
, but sin2 2 [0, 1] Sol. 
 3f 'f '' ff '''   x   ff ''  f ' 2 (x) '  
2 4  ff ''  f ' 2  (x)    ff '  x   '
,  = 1    – 2   ,  – 1  0 
2 2
 2–
3 3   3f 'f '' f '''  (x)   f(x)  f '(x)  ''
3   – 2    – 1  4
2 2


22. If  3 x
 cosec xdx   cot x cosecx  cosec x  2    loge tan 2
5 2
C

where    and C is constant of integration , 1 2 3 4

then the value of 8( + ) equals …..

Ans. (1) min. roots of f(x)  4
 cosec x  cosec xdx  I
3 2
Sol. min. roots of f '(x)  3
By applying integration by parts min. roots of  f(x)  f '(x)   7

I  – cot xcosec3 x   cot x  –3cosec 2 x cot xcosecx dx  min . roots of  f(x)  f '(x)  ''  5

I  – cot xcosec3 x – 3 cosec3 x  cosec 2 x – 1 dx 24. Consider the function f :    defined by

I  – cot xcosec3 x – 3I  3 cosec3xdx 2x

f(x) = . If the composition of
let 1  9x 2
I1   cosec3 xdx  –cosecx cot x –  cot 2 xcosecxdx 210 x
f,  f o f o f o...o f  x   , then the
1  9x 2
I1  –cosecxcotx–   cosec 2 x – 1cosecxdx
10 times

value of 3  1 is equal to …..

 Ans. (1024)
Sol.
2f(x) 4x
Sol. f  f  x   
1  9f  x 
2 2
1  9x  9.22 x 2 From From Ways of selection
Group A Group B
23 x / 1  9x 2 23 x
f  f  f(x)    
4M 4W 4
C4 4C4  1
1  9x 2 1  2 2  2 4 
2 2
2 x
1  9 1  2 2 
1  9x 2 3M 1W 1M 3W 4
C3 5C1 5C1 4C3  400
 By observation
2M 2W 2M 2W 4
C2 5C2 5C2 4C2  3600
  22 10 – 1  220 – 1
  1  2  2  ....  2  1 2
2 4 18   1M 3W 3M 1W 4
C1 5C3 5C3 4C1  1600
 2 –1  3
3  1  220  3  1  210  1024 4W 4M 5
C4 5C4  25

25. Let A be a 2 × 2 symmetric matrix such that Total 5626

Ans. 5626
1 3 
A      and the determinant of A be 1. 27. In a tournament, a team plays 10 matches with
1  7 
probabilities of winning and losing each match as
If A–1 = A + I, where I is an identity matrix of
1 2
order 2 × 2, then  +  equals ….. and respectively. Let x be the number of
3 3
Ans. (5) matches that the team wins, and y be the number of
matches that team loses. If the probability
a b P(|x – y| < 2) is p, then 39p equals……
Sol. Let A   
b d  Ans. (8288)
 a b  1  3  2 1 2
 b d  1   7  ,ad – b  1 Sol. P(W)  P(L) 
     3 3
a + b = 3, b + d = 7, (3 – b) (7 – b) –b2 = 1 x = number of matches that team wins
21 – 10b = 1  b = 2, a = 1, d = 5 y = number of matches that team loses
1 2   5 –2  x – y  2 and x + y = 10
A  , A –1   
2 5   –2 1  x – y  0,1,2 x, y  N
A–1  A  I Case-I : x – y  0  x  y
 5 –2     2  x  y  10  x  5  y
 –2 1    2 5   
    5 5
1 
P  x – y  0   10 C 5    
 = –1,  = 6      5 3  3

26. There are 4 men and 5 women in Group A, and 5 Case-II : x – y  1  x – y  1

men and 4 women in Group B. If 4 persons are x=y+1 x = y –1
selected from each group, then the number of ways x  y  10  x  y  10

of selecting 4 men and 4 women is ….. 2y = 9 2y = 11

Ans. (5626) Not possible Not possible
Case-III : x – y  2  x – y  2 4 3 4 3
2 2
2 2
     
x–y2 OR x  y  –2  1 3   1 3 
x  y  10 x  y  10 2   2  14
x  6, y  4 x  4, y  6
29. Consider a line L passing through the points
6 4 4 6
1 2 1 2
P  x – y  2   10 C 6     10 C 4     P(1,2,1) and Q(2,1,–1). If the mirror image of the
   
3 3 3  3
point A(2,2,2) in the line L is (), then
5 4 6
2 2 2
p  10 C 5 10
 10C 6 10  10C 4 10  +  + 6 is equal to …..
3 3 3
Ans. (6)
1
3 p   10 C5 25  10 C 6 2 4  10 C 4 26 
9
3
= 8288
28. Consider a triangle ABC having the vertices

A(1,2), B() and C() and angles ABC  C
6
2
and BAC  . If the points B and C lie on the B(,,)
3
line y = x + 4, then 2 + 2 is equal to …..
DR's of Line L –1 : 1 : 2
Ans. (14)
DR's of AB  – 2 : – 2 :  – 2
Sol.
ABar L 2 –  +  – 2 + 2  – 4 = 0
C(,)
2 +  –  = 4 ...(1)
/6 y=x+4
Let C is mid-point of AB
m=1
2/3 2 2 2
/6 C , , 
A(1,2) B(,)  2 2 2 
 2 
Equation of line passes through point A(1, 2) DR's of PC = : :
2 2 2

which makes angle from y = x + 4 is    2 
6 line L | | PC     K(let)
2 2 4

1  tan
6 (x  1)  = – 2K
y2 

1 tan  = 2K + 2
6
 = 4K
3 1
y2  (x  1)
3 1 1
use in (1)  K 
6
 Θ
y  2  (2  3)(x  1) y  2  (2  3)(x  1) value of  +  + 6 = 24K + 2 = 6
solve with y  x  4 solve with y  x  4
x  2  (2  3)x  2  3 x  2  (2  3)x  2  3
4 3 4 3
x x
1 3 1 3
30. Let y = y(x) be the solution of the differential dy
Sol.  (x  y  2)2 ...(1), y(0) = –2
2
equation (x + y + 2) dx = dy, y(0) = –2. Let the dx
maximum and minimum values of the function Let x + y + 2 = v
dy dv
  1 
y = y(x) in  0,  be  and , respectively. If dx dx
 3
dv
from (1)  1  v2
3  
2 2
      3, ,  , then  +  equals dx
dv
…..  1  v2   dx
Ans. (31)
tan–1(v) = x + C
tan–1(x + y + 2) = x + C
at x = 0 y = – 2 C = 0
 tan–1(x + y + 2) = x
y = tanx – x – 2
 
f(x) = tanx – x – 2, x  0,  
 3
 f '(x) = sec2x – 1 > 0 f(x)
fmin = f(0) = –2 = 
 
fmax = f    3   2  
3 3
now (3 + )2 +  2 = +  3
(3 + )2 + 2 = (3 3 –6)2 + 4
  3 = 67 – 36 3 
 = 67 and  = –36 = 31 
 PHYSICS TEST PAPER WITH SOLUTION
SECTION-A 33. The magnetic moment of a bar magnet is 0.5 Am2.
31. The translational degrees of freedom (ft) and It is suspended in a uniform magnetic field of
rotational degrees of freedom (fr) of CH4 molecule 8 × 10–2 T. The work done in rotating it from its
are : most stable to most unstable position is :
(1) ft = 2 and fr = 2 (2) ft = 3 and fr = 3 (1) 16 × 10–2 J (2) 8 × 10–2 J
(3) ft = 3 and fr = 2 (4) ft = 2 and fr = 3 (3) 4 × 10–2 J (4) Zero
Ans. (2) Ans. (2)
Sol. Since CH4 is polyatomic Non-Linear
Sol. At stable equilibrium
D.O.F of CH4
U = –mB cos 0° = –mB
T. DOF = 3
R DOF = 3 At unstable equilibrium
32. A cyclist starts from the point P of a circular U = –mB cos 180° = + mB
ground of radius 2 km and travels along its W = U
circumference to the point S. The displacement of W.D. = 2 mB
a cyclist is : = 2 (0.5) 8 × 10–2 = 8 × 10–2 J
34. Which of the diode circuit shows correct biasing
P
used for the measurement of dynamic resistance of
p-n junction diode :

(1) D4 R
S Q
0

R
R
D2
(1) 6 km (2) 8 km (2) 5V
(3) 4 km (4) 8 km
Ans. (2)
R
P Displacement
D3
(3)
R
Sol.
S Q
R
R
D1
(4) 5V

 Displacement = R 2 = 2 2  8 km
Ans. (2)
Sol. Diode should be in forward biased to calculate 38. Correct formula for height of a satellite from earths
dynamic resistance
surface is :
Hence correct answer would be 2.
35. Arrange the following in the ascending order of  T2 R 2g 
1/2
 T2 R2g 
1/3

wavelength : (1)   R (2)  2 

R
 4   4 
(A) Gamma rays (1) (B) x-ray (2)
1/3
(C) Infrared waves (3) (D) Microwaves (4)  T2 R2 
1/3
 T2 R2 
Choose the most appropriate answer from the (3)  2 
R (4)  2 
R
 4 g   4 
options given below :
(1) 4 < 3 < 1 < 2 (2) 4 < 3 < 2 < 1 Ans. (2)
(3)  < 2 <  < 4 (4) 2 < 1 < 4 < 3
Ans. (3)
R h m
Sol.  < 2 <  < 4 Sol. M
36. Identify the logic gate given in the circuit :
A
Y GMm mv2
 
R  h
2
R  h
B

(1) NAND - gate (2) OR - gate GM

  v2 ….(1)
(3) AND gate (4) NOR gate  R  h 
Ans. (2)
Sol. Y  A.B  v = (R + h)
By De-Morgan Law
2
 v =  R  h  …….(2)
Y  AB T
Y=A+B
Hence OR gate GM
 g
37. The width of one of the two slits in a Young's R2
double slit experiment is 4 times that of the other
slit. The ratio of the maximum of the minimum  GM = gR2 ……..(3)
intensity in the interference pattern is :
Put value from (2) & (3) in eq. (1)
(1) 9 :1 (2) 16 : 1
(3) 1 : 1 (4) 4 : 1 2
gR 2 2  2 
Ans. (1)   R  h  
Sol. Since, Intensity  width of slit () R  h  T
so, I1 = I, I2 = 4I
T2 R2g
   R  h
2 3
Imin = I1  I 2 I 
 2 
2

 
2
I max  I1  I 2  9I 1/3
 T2 R2g 
I max 9I 9    R  h
    2  
2
I min I 1
39. Match List I with List II 40. Given below are two statements :
Statement I : The contact angle between a solid
List–I List–II and a liquid is a property of the material of the
A. Purely I. I solid and liquid as well.
capacitive Statement II : The rise of a liquid in a capillary
circuit tube does not depend on the inner radius of the
90° tube.
V
In the light of the above statements, choose the
B. Purely II.
correct answer from the options given below :
inductive (1) Both Statement I and Statement II are false
circuit I V (2) Statement I is false but Statement II is true.
(3) Statement I is true but Statement II is false.
C. LCR III. (4) Both Statement I and Statement II are true.
series at V Ans. (3)
resonance Sol. Statement I is correct as we know contact angle

I depends on cohesine and adhesive forces.
Statement II is incorrect because height of liquid is
D. LCR IV.
V 2T cos C
series given by h =  where r is radius of
circuit gr
90° Tube (assuming length of capillary is sufficient)
I
Hence option (3) is correct.
41. A body of m kg slides from rest along the curve of
Choose the correct answer from the options given vertical circle from point A to B in friction less
below : path. The velocity of the body at B is :
(1) A-I, B-IV, C-III, D-II
(2) A-IV, B-I, C-III, D-II A

(3) A-IV, B-I, C-II, D-III

(4) A-I, B-IV, C-II, D-III 45°
(Vertical Circle)
Ans. (4)
Sol. A – V lags by 90° from I hence option (I) is
correct. B
B – V lead by 90° from I hence option (IV) is
correct (given, R = 14 m, g = 10 m/s2 and 2 = 1.4)
(1) 19.8 m/s (2) 21.9 m/s
C – In LCR resonance XL = XC. Hence circuit is
(3) 16.7 m/s (4) 10.6 m/s
purely resistive so option (II) is correct Ans. (2)
D – In LCR series V is at some angle from I hence
(III) is correct
Hence option (4) is correct.
 43. A 2 kg brick begins to slide over a surface which is
inclined at an angle of 45° with respect to
horizontal axis. The co-efficient of static friction
between their surfaces is :
Sol.
1
R (1) 1 (2)
3
(3) 0.5 (4) 1.7
Ans. (1)
Apply W.E.T. from A to B
 Wmg = KB – KA N
fL
Sol. mgsin45
 R  1
 mg ×   R  = mv2B  0 v A  0 rest mgcos45
 2  2 45°

 mgR
 2 1   1 mv 2 mg sin 45 = fL
B
2 2 mg cos 45 = N
fL = µsN

 gR
2  2 1  v µs = tan 45 = 1
2
B or
tan  = µs ( is angle of repose)
10  14  2  2.4  tan 45 = µs = 1
  vB
1.4 correct option (1)
 21.9 = vB 44. In simple harmonic motion, the total mechanical
energy of given system is E. If mass of oscillating
Hence option (2) is correct
particle P is doubled then the new energy of the
42. An electric bulb rated 50 W – 200 V is connected
system for same amplitude is :
across a 100 V supply. The power dissipation of
the bulb is :
(1) 12.5 W (2) 25 W
(3) 50 W (4) 100 W K
Ans. (1)
Sol. Rated power & voltage gives resistance
m P
V 2  200 
2
40000
R   E
P 50 50 (1) (2) E
2
R = 800
(3) E 2 (4) 2E
V   100 
2 2
applied Ans. (2)
P
R 800 1
Sol. T.E. = kA 2
P = 12.5 watt 2
Hence option 1 is correct. since A is same T.E. will be same
correct option (2)
45. Given below are two statements : one is labelled as 47. A sample of gas at temperature T is adiabatically
Assertion A and the other is labelled as Reason R. expanded to double its volume. Adiabatic constant
Assertion A : Number of photons increases with for the gas is  = 3/2. The work done by the gas in
increase in frequency of light. the process is : (µ = 1 mole)
Reason R : Maximum kinetic energy of emitted
(1) RT  2  2 (2) RT 1  2 2 
electrons increases with the frequency of incident    
radiation.
(3) RT 2 2  1 (4) RT 2  2 
In the light of the above statements, choose the    
most appropriate answer from the options given Ans. (4)
below : nRT
Sol. W
(1) Both A and R are correct and R is NOT the 1 
correct explanation of A.
TV 1  cons tan t  Tf  2V 
1

(2) A is correct but R is not correct.

1/2
(3) Both A and R are correct and R is the correct 1 T
Tf = T   
explanation of A. 2 2
(4) A is not correct but R is correct.
 T 
Ans. (4) R
W 
2
 T
  2RT  2 1 
nh 3 2
Sol. Intensity of light I = 1
A 2
Here n is no. of photons per unit time.
IA
 RT 2  2 
n so on increasing frequency , n decreases 48. A charge q is placed at the center of one of the
h
taking intensity constant. surface of a cube. The flux linked with the cube
kmax = h –  is :-
So on increasing , kinetic energy increases. q q
(1) (2)
46. According to Bohr's theory, the moment of 4 0 2 0
momentum of an electron revolving in 4th orbit of q
(3) (4) Zero
hydrogen atom is : 8 0
h h Ans. (2)
(1) 8 (2)
 

h h Sol. From
(3) 2 (4)
 2 q
Ans. (3) 
Sol. Moment of momentum is r  P q
2 
L  r  mv 0
nh 4h 2h q
L = mvr =   
2 2  2 0
49. Applying the principle of homogeneity of SECTION-B
dimensions, determine which one is correct. 51. The displacement of a particle executing SHM is

where T is time period, G is gravitational constant,  

given by x = 10 sin  t  m . The time period
 3 
M is mass, r is radius of orbit.
of motion is 3.14 s. The velocity of the particle at
4 2 r t = 0 is ______ m/s.
(1) T 2  (2) T  4  r
2 2 3

GM2 Ans. (10)

4 2 r 3 4 2 r 2 Sol. Given,
(3) T 2  (4) T 2 
GM GM 2
T = 3.14 =
Ans. (3) 
 = 2 rad/s
Sol. According to principle of homogeneity dimension
 
of LHS should be equal to dimensions of RHS so x  10 sin  t  
 3
option (3) is correct.
dx  
v  10 cos  t  
4 2 r 3 dt  3
T2 
GM at t = 0
 L  3
 1
 T 2   v  10 cos   = 10  2  [using  = 2 rad/s]
 M1L3 T 2   M 3 2
v = 10 m/s
(Dimension of G is  M L T  ) 1 3 2
52. A bus moving along a straight highway with speed
of 72 km/h is brought to halt within 4s after
 L3  applying the brakes. The distance travelled by the
 T   3 2   T 2 
2

 L T  bus during this time (Assume the retardation is

uniform) is _______m.
50. A 90 kg body placed at 2R distance from surface
Ans. (40)
of earth experiences gravitational pull of : Sol. Initial velocity = u = 72 km/h = 20 m/s
(R = Radius of earth, g = 10 ms–2) v = u + at
(1) 300 N (2) 225 N  0 = 20 + a × 4
a = –5 m/s2
(3) 120 N (4) 100 N
v2 – u2 = 2as
Ans. (4)
 02 – 202 = 2(–5).s
2 s = 40 m
 h
Sol. Value of g = gs  1 
 R  53. A parallel plate capacitor of capacitance 12.5 pF is
charged by a battery connected between its plates
gs to potential difference of 12.0 V. The battery is
= gs 1  2 
2

9 now disconnected and a dielectric slab (r = 6) is
inserted between the plates. The change in its
Here gs = gravitational acceleration at surface
potential energy after inserting the dielectric slab is
gs _______× 10–12 J.
Force = mg = 90 × = 100 N
9 Ans. (750)
Sol. Before inserting dielectric capacitance is given Ans. (208)
C0 = 12.5 pF and charge on the capacitor Q = C0V Sol.
235
U 140 Ce  94 Zr  n
After inserting dielectric capacitance will become
Disintegration energy
rC0.
Q = (mR – mP).c2
Change in potential energy of the capacitor
mR = 235.0439 u
= Ei – Ef
mP = 139.9054u + 93.9063u + 1.0086 u
Q2 Q2 Q2  1 = 234.8203u
=  = 1  
2Ci 2Cf 2C 0  r  Q = (235.0439u – 234.8203u)c2
C V
2
= 0.2236 c2
 1 1 2  1
 0 1    C0 V 1   = 0.2236 × 931
2C0  r  2  r 
Q = 208.1716
Using C0 = 12.5 pF, V = 12 V, r = 6
56. A light ray is incident on a glass slab of thickness
1  1 1 5
 12.5   12 2 1    12.5 122  4 3 cm and refractive index 2 . The angle of
2  6 2 6
= 750 pJ = 750 × 10–12J incidence is equal to the critical angle for the glass
54. In a system two particles of masses m1 = 3kg and slab with air. The lateral displacement of ray after
m2 = 2kg are placed at certain distance from each passing through glass slab is ____cm.
other. The particle of mass m1 is moved towards (Given sin 15° = 0.25)
the center of mass of the system through a distance Ans. (2)
2cm. In order to keep the center of mass of the
system at the original position, the particle of mass i
m2 should move towards the center of mass by the t
Sol. µ r
distance ____ cm.
Ans. (3)

Sol. m1=3kg m2=2kg i = C
2cm x 1
 i = sin–1  

m1x1  m2 x 2
XC.O.M.   i = 45º
m1  m2
and according to snell's law
3  2  2  x 
 0 1 sin 45° = 2 sin r
32
 r = 30°
 x = 3 cm
55. The disintegration energy Q for the nuclear fission t sin  i  r 
Lateral displacement  
of U  Ce  Zr  n is ____MeV.
235 140 94 cos r
Given atomic masses of 4 3  sin15
 
235
U : 235.0439u; 140
Ce;139.9054u , cos30
94
Zr : 93.9063u;n :1.0086u ,  = 2cm 
Value of c2 = 931 MeV/u.
57. A rod of length 60 cm rotates with a uniform 59. Two parallel long current carrying wire separated
by a distance 2r are shown in the figure. The ratio
angular velocity 20 rad s–1 about its perpendicular
of magnetic field at A to the magnetic field
bisector, in a uniform magnetic field 0.5 T. The x
produced at C is . The value of x is ___.
direction of magnetic field is parallel to the axis of 7

rotation. The potential difference between the two

I 2I
ends of the rod is ____V.
O
Ans. (0) A C
r r r r
B

Sol. 2r

B A
O
Ans. (5)
B  0 i  0  2i  5 0 i
2
V0  VA   Sol. BA   
2 2 r 2   3r  6 r

B 2
 0  2i  0 i 7 i
V0  VB  BC    0
2 2 r 2   3r  6 r

 VA  VB  VA  VB  0 BA 5
 
BC 7
58. Two wires A and B are made up of the same
x=5
material and have the same mass. Wire A has 60. Mercury is filled in a tube of radius 2 cm up to a
height of 30 cm. The force exerted by mercury on
radius of 2.0 mm and wire B has radius of 4.0 mm.
the bottom of the tube is ___N.
The resistance of wire B is 2. The resistance of (Given, atmospheric pressure = 105 Nm–2, density
of mercury = 1.36 × 104 kg m–3, g = 10 ms–2,
wire A is _____.
22
= )
Ans. (32) 7
Ans. (177)
 V
Sol. R  2 Sol. F  P0 A  m ghA
A A
22
 
2

R A2 r 4 = 105 ×  2 102
 A  2B  B4 7
R B A A rA
 22 
   
2
1.36  10 4  10  30  10 2   2  10 2 
4  7 
R  4  10 3 
 A  3 
F = 51.29 + 125.71 = 177 N
2  2  10 

 RA = 32 .
 CHEMISTRY TEST PAPER WITH SOLUTION
SECTION-A Sol. Br Br Me2.NH
.
Br NMe
.. 2
61. The equilibrium constant for the reaction SN2
+
1 –H
SO3  g  SO 2  g   O 2  g 
2
.. ..
is KC = 4.9 × 10–2. The value of KC for the reaction NMe2 Me2NH 
Me
 N
given below is NMe2 SN2
Me
2SO2  g   O2  g  2SO3  g  is H
–H+
(1) 4.9 (2) 41.6
NMe2
(3) 49 (4) 416
Ans. (4) NMe2

 1  
2
1 
2
The above mechanism valid for both cis and trans
Sol. K 'C     2  isomers. So the products are same for both cis and
 KC   4.9 10 
trans isomers.
K'C = 416.49 63. When MnO2 and H2SO4 is added to a salt (A), the
62. Find out the major product formed from the greenish yellow gas liberated as salt (A) is :
(1) NaBr (2) CaI2
following reaction. [Me: –CH3] (3) KNO3 (4) NH4Cl
Br Br Ans. (4)

Sol. 2NH 4Cl  MnO2  2H 2SO4   MnSO 4
(NH 4 )2 SO4  2H 2O  Cl2 
greenish
NMe2 NMe2 yellow
solution
(1) 64. The correct statement/s about Hydrogen bonding
is/are :
NMe2 A. Hydrogen bonding exists when H is covalently
(2) bonded to the highly electro negative atom.
B. Intermolecular H bonding is present in o-nitro
NMe2 phenol
NMe2 C. Intramolecular H bonding is present in HF.
NMe2
(3) D. The magnitude of H bonding depends on the
physical state of the compound.
E. H-bonding has powerful effect on the structure
NMe2 and properties of compounds.
(4) Choose the correct answer from the options given
below :
NMe2 (1) A only (2) A, D, E only
Ans. (2) (3) A, B, D only (4) A, B, C only
Ans. (2)
 Sol. (A) Generally hydrogen bonding exists when H is 67. CH3 – CH2 – CH2 – Br + NaOH 
2 5
 Product 'A'
C H OH

covalently bonded to the highly

H2O
electronegative atom like F, O, N. Product "B"
H+
(B) Intramolecular H bonding is present in Product A
O O Diborane
Product "C"
N H H2O/H2O2/–OH
O
Consider the above reactions, identify product B
and product C.

(C) Intermolecular Hydrogen bonding is present (1) B = C = 2-Propanol

in HF (2) B = 2-Propanol C = 1-Propanol
(D) The magnitude has Hydrogen bonding in solid (3) B = 1-Propanol C = 2-Propanol
state is greater than liquid state. (4) B = C = 1-Propanol
(E) Hydrogen bonding has powerfull effect on the
Ans. (2)
structure & properties of compound like
OH
melting point, boiling point, density etc. Sol. H2O
CH3–CH–CH3
H+
O–Na+ 2-Propanol
[B]
“A” “B” C2H5OH
65. O O CH3–CH2–CH2–Br + NaOH CH3–CH=CH2
O Product
O
H H [A]
B2H6
H2O/H2O2/OH
CH3–CH2–CH2–OH
In the above chemical reaction sequence “A’’ 1-Propanol
and “B” respectively are : [C]

(1) O3, Zn/H2O and NaOH(alc.) / I2 68. The adsorbent used in adsorption chromatography
(2) H2O, H+ and NaOH(alc.) / I2 is/are
(3) H2O, H+ and KMnO4 A. silica gel B. alumina
(4) O3, Zn/H2O and KMnO4
C. quick lime D. magnesia
Ans. (1)
 Choose the most appropriate answer from the
“B” ONa
“A” options given below :
O3 , NaOH
Sol. O O (1) B only (2) C and D only
ZnH2O O (alc.)
I 2
O + CHI3
(3) A and B only (4) A only
H H
Ans. (3)
66. Common name of Benzene-1, 2-diol is
Sol. The most common polar and acidic support used is
(1) quinol (2) resorcinol
(3) catechol (4) o-cresol adsorption chromatography is silica. The surface
Ans. (3) silanol groups on their supported to adsorb polar
OH compound and work particularly well for basic
Sol.
substances. Alumina is the example of polar and
OH
basic adsorbent that is used in adsorption
IUPAC name : Benzene-1,2-diol
Common name : catechol chromatography.
 71. The correct order of the first ionization enthalpy is
KOH  alc  (1) Al > Ga > Tl (2) Ga > Al > B
69. 
 major product "P"

Br (3) B > Al > Ga (4) Tl > Ga > Al
Ans. (4)
Product P is
Sol. (i) due to lanthanide contraction T has more I.E.

as compared to Ga and A

(ii) due to scandide contraction Ga has more I.E. as
(1)
compared to A
72. If an iron (III) complex with the formula
–
 Fe  NH3   CN   has no electron in its eg
(2)  x y

orbital, then the value of x + y is

(1) 5 (2) 6
(3) (3) 3 (4) 4
Ans. (2)
III

Sol. Complex is [Fe(NH3 ) 2 (CN) 4 ]
(4) x=2
y=4
Ans. (2) so x + y = 6
73. Fuel cell, using hydrogen and oxygen as fuels,
Sol. Alc.KO
H  A. has been used in spaceship
Br B. has as efficiency of 40% to produce electricity
(Major)
C. uses aluminium as catalysts
70. Correct order of stability of carbanion is D. is eco-friendly
E. is actually a type of Galvanic cell only
(1) A,B,C only (2) A,B,D only
(3) A,B,D,E only (4) A,D,E only
a b c d
Ans. (4)
(1) c > b > d > a (2) a > b > c > d Sol. Fuel cell is used in spaceship and it is type of
(3) d > a > c > b (4) d > c > b > a galvanic cell.
Ans. (4) 74. Choose the Incorrect Statement about Dalton's
Sol. As we know compound (d) is aromatic and the Atomic Theory
compound (a) is anti-aromatic. Hence compound (1) Compounds are formed when atoms of
(d) is most stable and compound (a) is least stable different elements combine in any ratio
among these in compound (b) and (c) carbon atom (2) All the atoms of a given element have
of that positive charge is sp3 hybridised they on the identical properties including identical mass
basis of angle strain theory compound (c) is more (3) Matter consists of indivisible atoms
stable than compound (b). (4) Chemical reactions involve recorganization of
.. atoms
 
 Ans. (1)
> > > Sol. In compound atoms of different elements combine
in fixed ratio by mass.
75. Match List I with List II 77. For a strong electrolyte, a plot of molar conductivity
LIST I LIST II against (concentration)1/2 is a straight line, with a
A. a- Glucose and a-Galactose I. Functional isomers
B. a- Glucose and b-Glucose II. Homologous negative slope, the correct unit for the slope is
C. a- Glucose and a-Fructose III. Anomers
(1) S cm2 mol–3/2 L1/2 (2) S cm2 mol–1 L1/2
D. a- Glucose and a-Ribose IV. Epimers
Choose the correct answer from the options given (3) S cm2 mol–3/2 L (4) S cm2 mol–3/2 L–1/2
below: Ans. (1)
(1) A-III, B-IV, C-II, D-I
Sol.  m   om  A C
(2) A-III, B-IV, C-I, D-II
(3) A-IV, B-III, C-I, D-II Units of A C = S cm2 mole–1
(4) A-IV, B-III, C-II, D-I Uits of A = S cm2 mole–3/2 L1/2
Ans. (3) 78. A first row transition metal in its +2 oxidation state
Sol. Based on biomolecules theory and structure of
has a spin-only magnetic moment value of 3.86 BM.
these named compounds –
The atomic number of the metal is
(A) a-Glucose and a-Galactose (IV) Epimers.
(1) 25 (2) 26
(B) a-Glucose and b-Glucose (III) Anomers
(3) 22 (4) 23
(C) a-Glucose and a-Fructose (I) Functional isomers
Ans. (4)
(D) a-Glucose and a-Ribose (II) Homologous
+2
76. Given below are two statements: Sol. 22Ti  [Ar]3d2
+2
Statement I : The correct order of first ionization 23V  [Ar]3d3
enthalpy values of Li, Na, F and Cl is Na < Li < Cl < F. 25Mn
+2
 [Ar]3d5
Statement II : The correct order of negative +2
26Fe  [Ar]3d6
electron gain enthalpy values of Li, Na, F and Cl is
79. The number of unpaired d-electrons in
Na < Li < F < Cl
In the light of the above statements, choose the [Co(H2O)6]3+ is______

correct answer from the options given below : (1) 4 (2) 2

(1) Both Statement I and Statement II are true (3) 0 (4) 1
(2) Both Statement I and Statement II are false Ans. (3)
(3) Statement I is false but Statement II is true Sol.  [Co(H2O)6]+3
(4) Statement I is true but Statement II is false
eg
Ans. (1)
d6
Sol.. (i) Na < Li < Cl < F
    Co+3
I.E.1 in kJ/mol 496 520 1256 1681
t2g
(ii) Na < Li < F < Cl
    No unpaired electrons
eg H in kJ/mol –53 –60 –328 –349
80. The number of species from the following that Sol. As isothermal U = 0
have pyramidal geometry around the central atom and process is irreversible
is________ Q = –W = – [– Pext (V2 – V1)]
Q = 5 (20 – 60) = – 200 atm-L
S2 O32 ,SO24 ,SO32 ,S2O27
84. From 6.55 g of aniline, the maximum amount of
(1) 4 (2) 3
acetanilide that can be prepared will be___×10–1 g.
(3) 1 (4) 2 Ans. (95)
Ans. (3) O
Sol.
S O O O NH2 NH – C – CH3
Sol. ··
S S S S O
, S
,
O O– O O– O O– O – O –
O
+ CH3 – C – Cl
O– O– O– O O
Pyramidal
tetrahedral with respect to central atom 93 g aniline form 135 gm acetanlide
135
SECTION-B so 6.55 g anilne form  6.55  9.5
93
81. The maximum number of orbitals which can be
95 × 10–1
identified with n = 4 and ml = 0 is_____ 85. Consider the following reaction, the rate
Ans. (4) expression of which is given below
n=4, A+BC
Sol. 4s 4p 4d 4f
rate = k [A]1/2 [B]1/2
m  1 1 1 1
The reaction is initiated by taking 1M
So answer is 4. concentration A and B each. If the rate constant (k)
82. Number of compounds/species from the following is 4.6 × 10–2 s–1, then the time taken for A to
with non-zero dipole moment is_____ become 0.1 M is_____sec. (nearest integer)

BeCl2, BCl3, NF3, XeF4, CCl4, H2O H2S, HBr, Ans. (50)
2.303 1
CO2, H2, HCl Sol. K log
t 0.1
Ans. (5)
2.303
4.6 × 10–2 =
Sol. Polar molecule : NF3 , H 2O, H 2S, HBr, HCl t
(µ  0)
t = 50 sec.
Non Polar molecule : BeCl2 , BCl3 , XeF4 , CCl4 , CO 2 , H 2
(µ  0) 86. Phthalimide is made to undergo following
So answer is 5. sequence of reactions.
83. Three moles of an ideal gas are compressed (i)KOH
isothermally from 60 L to 20 L using constant (ii)Benzylchloride
Phthalimide ' P'
pressure of 5 atm. Heat exchange Q for the
Total number of  bonds present in product 'P'
compression is – ____ Lit. atm.
is/are
Ans. (200) Ans. (8)
Sol. O O 89. 2.7 Kg of each of water and acetic acid are mixed,
.. +
K OH –
. . The freezing point of the solution will be –x °C.
N–H N K
Consider the acetic acid does not dimerise in
O O
(Phthalimide) water, nor dissociates in water x = ______(nearest
SN2
–KCl
CH2 – Cl integer)
[Given : Molar mass of water = 18 g mol–1,
O
acetic acid = 60 g mol–1]
.. Kf
N – CH2 H2 O : 1.86 K kg mol–1
Kf
O acetic acid : 3.90 K kg mol–1
(P)
freezing point : H2O = 273 K, acetic acid = 290 K]
Total number of -bonds present in product P is 8
Ans. (31)
87. The total number of 'sigma' and 'Pi' bonds in
Sol. As moles of water > moles of CH3COOH
2-oxohex-4-ynoic acid is____.
water is solvent.
Ans. (18)
T°F – (TF)S = KF × M
Sol. O
      2700 / 60
HO–C–C–CH2–C  C–CH3 0 – (TF)S = 1.86 ×
  2700 / 1000
O
2-Oxohex-4-ynoic acid (TF)S = –31°C.
90. Vanillin compound obtained from vanilla beans,
Number of -bonds = 14
Number of -bonds = 4 has total sum of oxygen atoms and  electrons is__

= 18 Ans. (11)
88. A first row transition metal with highest enthalpy Sol. Vanillin compound is an organic compound
of atomisation, upon reaction with oxygen at high molecular formula C8H8O3. It is a phenolic aldehyde.
temperature forms oxides of formula M2On (where Its functional compounds include aldehyde, hydroxyl
n = 3,4,5). The 'spin-only' magnetic moment value and ether. It is the primary component of the extract
of the amphoteric oxide from the above oxides of the vanilla beans.
is___ BM (near integer) H O
(Given atomic number : Sc : 21, Ti : 22, V : 23,
Cr : 24, Mn : 25, Fe : 26, Co : 27, Ni : 28 ,Cu : 29,
Zn : 30) OCH3
Ans. (0) OH
Sol. 'V' has highest enthalpy of atomisation (515 kJ/mol) Total sum of oxygen atoms and -electrons is 3 + 8 = 11
among first row transition elements. Total number of oxygen atoms = 3
V2O5
Total number of -bonds = 4
Here 'V' is in +5 oxidation state
 Total number of -electrons = 8
V+5  1s2 2s2 2p6 3s2 3p6 (no unpaired electrons)