Hds Galvalite Galvanizing Repair Compound-Zrc Ingles

Download as pdf or txt
Download as pdf or txt
You are on page 1of 8

SAFETY DATA SHEET

1. Identification
Product identifier ZRC Galvilite Galvanizing Repair Compound
Other means of identification
Product code 20012 - 20014
Recommended use Corrosion protection of iron and steel.
Recommended restrictions None known.
Manufacturer / Importer / Supplier / Distributor information
Supplier/Manufacturer ZRC Worldwide
Address 145 Enterprise Drive, Marshfield, MA 02050
Telephone 781-319-0400
Emergency telephone 703-527-3887 CCN15781
(CHEMTREC)

2. Hazard(s) identification
Physical hazards Flammable liquids Category 3
Health hazards Skin corrosion/irritation Category 2
OSHA defined hazards Not classified.

Label elements

Signal word Warning


Hazard statement Flammable liquid and vapor. Causes skin irritation.
Precautionary statement
Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly
closed. Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Wear protective gloves/protective clothing/eye protection/face
protection. Wash thoroughly after handling.
Response Rinse mouth. In case of fire: Use appropriate media to extinguish. If on skin: Wash with plenty of
water. Specific treatment (see this label). If skin irritation occurs: Get medical advice/attention.
Take off contaminated clothing and wash it before reuse.
Storage Store in a well-ventilated place. Keep cool.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise Not classified.
classified (HNOC)
Environmental hazards Hazardous to the aquatic environment, acute Category 1
hazard
Hazardous to the aquatic environment, Category 1
long-term hazard
Supplemental information
Hazard symbol

Hazard statement Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects.
Precautionary statement
Prevention Avoid release to the environment.
Response Collect spillage.

3. Composition/information on ingredients
Mixtures

ZRC Galvilite Galvanizing Repair Compound SDS US


917775 Version #: 03 Revision date: 17-January-2014 Issue date: 14-December-2013 1/8
Chemical name CAS number %
Zinc 7440-66-6 75 - 85

Solvent naphtha (petroleum), 64742-88-7 4-6


medium aliph.

Distillates (petroleum), 64742-47-8 4-5


hydrotreated light

Zinc oxide 1314-13-2 2-3

Solvent naphtha (petroleum), 64742-95-6 0.5 - 0.9


light aromatic

4. First-aid measures
Inhalation Move to fresh air. Get medical attention if any discomfort continues.
Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists.
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Ingestion Rinse mouth. Get medical attention if any discomfort occurs.
Most important Direct contact with eyes may cause temporary irritation. Causes skin irritation. Swallowing may
symptoms/effects, acute and cause gastrointestinal irritation.
delayed
Indication of immediate Provide general supportive measures and treat symptomatically.
medical attention and special
treatment needed
General information In the case of accident or if you feel unwell, seek medical advice immediately (show the label
where possible).

5. Fire-fighting measures
Suitable extinguishing media Dry chemical, CO2, water spray, fog, or foam.
Unsuitable extinguishing Do not use water jet.
media
Specific hazards arising from By heating and fire, harmful vapors/gases may be formed. Vapors may form explosive mixtures
the chemical with air. Vapors may travel considerable distance to a source of ignition and flash back.
Special protective equipment Firefighters must use standard protective equipment including flame retardant coat, helmet with
and precautions for firefighters face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protective
clothing will only provide limited protection.
Fire-fighting Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Use
equipment/instructions standard firefighting procedures and consider the hazards of other involved materials. In the event
of fire, cool tanks with water spray. Move containers from fire area if you can do so without risk. In
case of fire and/or explosion do not breathe fumes. Water runoff can cause environmental
damage.

6. Accidental release measures


Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
protective equipment and low areas. Wear appropriate personal protective equipment. Do not touch damaged containers or
emergency procedures spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before
entering them. Local authorities should be advised if significant spillages cannot be contained. For
personal protection, see section 8 of the SDS.
Methods and materials for Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Stop leak if
containment and cleaning up you can do so without risk. Collect spillage. Scoop up used absorbent into drums or other
appropriate container. Prevent entry into waterways, sewer, basements or confined areas. For
waste disposal, see Section 13 of the SDS.
Environmental precautions Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic
environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid
discharge into drains, water courses or onto the ground.

7. Handling and storage


Precautions for safe handling Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect
material from direct sunlight. Use non-sparking tools and explosion-proof equipment. Do not taste
or swallow. Avoid prolonged exposure. Provide adequate ventilation. Wear appropriate personal
protective equipment. Observe good industrial hygiene practices. When using, do not eat, drink or
smoke. Wash hands thoroughly after handling. Avoid release to the environment. Do not empty
into drains.

ZRC Galvilite Galvanizing Repair Compound SDS US


917775 Version #: 03 Revision date: 17-January-2014 Issue date: 14-December-2013 2/8
Conditions for safe storage, Keep away from heat, sparks and open flame. Keep container tightly closed. Store in a cool, dry
including any incompatibilities place out of direct sunlight. Store in a well-ventilated place. For further information, please refer to
Section 10 of the SDS.

8. Exposure controls/personal protection


Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

Components Type Value Form


Zinc oxide (CAS 1314-13-2) PEL 5 mg/m3 Fume.
5 mg/m3 Respirable fraction.
15 mg/m3 Total dust.
US. ACGIH Threshold Limit Values

Components Type Value Form


Zinc oxide (CAS 1314-13-2) STEL 10 mg/m3 Respirable fraction.
TWA 2 mg/m3 Respirable fraction.
US NIOSH Pocket Guide to Chemical Hazards: Ceiling Limit Value and Time Period (if specified)

Components Type Value Form


Zinc oxide (CAS 1314-13-2) Ceiling 15 mg/m3 Dust.
US NIOSH Pocket Guide to Chemical Hazards: Recommended exposure limit (REL)

Components Type Value Form


Distillates (petroleum), TWA 100 mg/m3
hydrotreated light (CAS
64742-47-8)
Zinc oxide (CAS 1314-13-2) TWA 5 mg/m3 Dust.
5 mg/m3 Fume.
US NIOSH Pocket Guide to Chemical Hazards: Short Term Exposure Limit (STEL)

Components Type Value Form


Zinc oxide (CAS 1314-13-2) STEL 10 mg/m3 Fume.
Biological limit values No biological exposure limits noted for the ingredient(s).
Appropriate engineering Explosion-proof general and local exhaust ventilation.
controls
Individual protection measures, such as personal protective equipment
Eye/face protection Do not get in eyes. If contact is likely, safety glasses with side shields are recommended.
Skin protection
Hand protection Use protective gloves made of: Rubber (natural, latex).
Other Wear suitable protective clothing.
Respiratory protection When workers are facing concentrations above the exposure limit they must use appropriate
certified respirators.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such
considerations as washing after handling the material and before eating, drinking, and/or smoking. Routinely
wash work clothing and protective equipment to remove contaminants.

9. Physical and chemical properties


Appearance Gray liquid.
Physical state Liquid.
Form Liquid.
Color Gray.
Odor Aliphatic. Hydrocarbon.
Odor threshold Not available.
pH Not available.
Melting point/freezing point Not available.
Initial boiling point and boiling 291.2 - 404.6 °F (144 - 207 °C)
range
Flash point 111.2 °F (44.0 °C) Setaflash
Evaporation rate < 1 (n-Butyl acetate=1)
ZRC Galvilite Galvanizing Repair Compound SDS US
917775 Version #: 03 Revision date: 17-January-2014 Issue date: 14-December-2013 3/8
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower 0.9 %
(%)
Flammability limit - upper 7%
(%)
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure Not available.
Vapor density > 1 (25°C / 77°F)
Relative density 2.88 (25°C / 77°F)
Solubility(ies) Slightly soluble in water.
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity 1800 mPa·s (25°C / 77°F)
Other information
Bulk density 24 lb/gal
VOC (Weight %) 385 g/l (3.3 lb/gal)

10. Stability and reactivity


Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous No dangerous reaction known under conditions of normal use.
reactions
Conditions to avoid Heat, flames and sparks. Avoid temperatures exceeding the flash point.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition Carbon oxides. Zinc oxides.
products

11. Toxicological information


Information on likely routes of exposure
Ingestion May cause discomfort if swallowed.
Inhalation Under normal conditions of intended use, this material is not expected to be an inhalation hazard.
Skin contact Causes skin irritation.
Eye contact Direct contact with eyes may cause temporary irritation.
Symptoms related to the Direct contact with eyes may cause temporary irritation. Causes skin irritation. Swallowing may
physical, chemical and cause gastrointestinal irritation.
toxicological characteristics
Information on toxicological effects
Acute toxicity Not classified.
Components Species Test Results
Distillates (petroleum), hydrotreated light (CAS 64742-47-8)
Acute
Dermal
LD50 Rabbit > 2000 mg/kg
Inhalation
LC50 Rat > 5.28 mg/l, 4 hours
Oral
LD50 Rat > 5000 mg/kg

ZRC Galvilite Galvanizing Repair Compound SDS US


917775 Version #: 03 Revision date: 17-January-2014 Issue date: 14-December-2013 4/8
Components Species Test Results
Solvent naphtha (petroleum), medium aliph. (CAS 64742-88-7)
Acute
Dermal
LD50 Rabbit 3000 mg/kg
Oral
LD50 Rat > 5000 mg/kg
Skin corrosion/irritation Causes skin irritation.
Serious eye damage/eye Not classified.
irritation
Respiratory sensitization Not classified.
Skin sensitization Not classified.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. Not
classifiable as to carcinogenicity to humans.
Reproductive toxicity Not classified.
Specific target organ toxicity - Not classified.
single exposure
Specific target organ toxicity - Not classified.
repeated exposure
Aspiration hazard Not classified.
Chronic effects Prolonged exposure may cause chronic effects.

12. Ecological information


Ecotoxicity Very toxic to aquatic life with long lasting effects.
Components Species Test Results
Zinc (CAS 7440-66-6)
Aquatic
Crustacea LC50 Daphnia magna 0.068 mg/l, 48 hours
Fish LC50 Bony fish superclass (Osteichthyes) 0.52 - 3.59 mg/l, 96 hours
Zinc oxide (CAS 1314-13-2)
Aquatic
Crustacea LC50 Water flea (Daphnia magna) 0.098 mg/l, 48 Hours
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulative potential Accumulation in aquatic organisms is expected.
Mobility in soil Not available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations


Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material
and its container must be disposed of as hazardous waste. Do not allow this material to drain into
sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used
container. Dispose of contents/container in accordance with local/regional/national/international
regulations.
Hazardous waste code D001: Waste Flammable material with a flash point <140 F
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused Dispose of in accordance with local regulations.
products
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.

14. Transport information


DOT
UN number UN1263
UN proper shipping name Paint

ZRC Galvilite Galvanizing Repair Compound SDS US


917775 Version #: 03 Revision date: 17-January-2014 Issue date: 14-December-2013 5/8
Transport hazard class(es) 3
Subsidiary class(es) -
Packing group III
Environmental hazards
Marine pollutant Yes
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
IATA
UN number UN1263
UN proper shipping name Paint
Transport hazard class(es) 3
Subsidiary class(es) -
Packaging group III
Environmental hazards Yes
Labels required 3
ERG Code Not available.
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
IMDG
UN number UN1263
UN proper shipping name Paint
Transport hazard class(es) 3
Subsidiary class(es) -
Packaging group III
Environmental hazards
Marine pollutant Yes
Labels required Not available.
EmS F-E, S-E
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Transport in bulk according to This substance/mixture is not intended to be transported in bulk.
Annex II of MARPOL 73/78 and
the IBC Code
General information Limited Quantity exemption may apply.

15. Regulatory information


US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Zinc (CAS 7440-66-6) LISTED
Zinc oxide (CAS 1314-13-2) LISTED
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - Yes
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely No
hazardous substance
SARA 311/312 Hazardous Yes
chemical
SARA 313 (TRI reporting)
Chemical name CAS number % by wt.
Zinc 7440-66-6 75 - 85
Zinc oxide 1314-13-2 2-3
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.

ZRC Galvilite Galvanizing Repair Compound SDS US


917775 Version #: 03 Revision date: 17-January-2014 Issue date: 14-December-2013 6/8
Safe Drinking Water Act Not regulated.
(SDWA)
Food and Drug Not regulated.
Administration (FDA)
US state regulations
US. Massachusetts RTK - Substance List
Distillates (petroleum), hydrotreated light (CAS 64742-47-8)
Zinc (CAS 7440-66-6)
Zinc oxide (CAS 1314-13-2)
US. New Jersey Worker and Community Right-to-Know Act
Distillates (petroleum), hydrotreated light (CAS 10000 lbs
64742-47-8)
Zinc (CAS 7440-66-6) 500 lbs
Zinc oxide (CAS 1314-13-2) 500 lbs
US. Pennsylvania RTK - Hazardous Substances
Distillates (petroleum), hydrotreated light (CAS 64742-47-8)
Zinc (CAS 7440-66-6)
Zinc oxide (CAS 1314-13-2)
US. Rhode Island RTK
Zinc (CAS 7440-66-6)
Zinc oxide (CAS 1314-13-2)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any
chemicals currently listed as carcinogens or reproductive toxins.
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Not listed.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS) Yes
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of Existing Commercial Chemical Yes
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) No
Korea Existing Chemicals List (ECL) Yes
New Zealand New Zealand Inventory Yes
Philippines Philippine Inventory of Chemicals and Chemical Substances Yes
(PICCS)
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

16. Other information, including date of preparation or last revision


Issue date 14-December-2013
Revision date 17-January-2014
Version # 03
NFPA Ratings

2
2 0

References HSDB® - Hazardous Substances Data Bank


IARC Monographs. Overall Evaluation of Carcinogenicity

ZRC Galvilite Galvanizing Repair Compound SDS US


917775 Version #: 03 Revision date: 17-January-2014 Issue date: 14-December-2013 7/8
Disclaimer The information in the sheet was written based on the best knowledge and experience currently
available.

ZRC Galvilite Galvanizing Repair Compound SDS US


917775 Version #: 03 Revision date: 17-January-2014 Issue date: 14-December-2013 8/8

You might also like