CHE401A - 6 - Flashing Sheet

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Faculty of Engineering M ass Transfer

Cairo University Fourth Year


Chem ical Engineering Department Sheet 6: Distillation I

o
PA
1- For ideal systems the relative volatility α  o
PB
αx
Prove that the equilibrium relation can be represented by y 
1  (  1) x
o
PT - PB
Also prove that: x 
PA  PB
o o

2- The following vapour pressures were obtained for benzene and toluene:
Temperature, o C Po of benzene, mmHg Po of toluene, mmHg
80 760 300
92 1078 432
100 1344 554
110.4 1748 760
Construct the following diagrams at 1 atmosphere:
a- A temperature-composition diagram
b- An x-y diagram
c- Relative volatility against mole fraction of toluene In liquid

3- 100 moles of al liquid mixture containing 50% Benzene, 25% Toluene and 25% o-Xylene is
flash vaporised at 1 atmosphere and 100 o C. Find the bubble and dew points of the mixture and
also compute the amount of liquid and vapour and their compositions.

4- 100 Kmoles of a mixture of A and B is fed to a simple still. The feed contains 50 mole % A and a
product contains 5 mole % A is required. Calculate the quantity of product obtained. The
equilibrium data is presented as follows:
Mole fraction of A in liquid 0 0.2 0.4 0.6 0.8 1
Mole fraction of A in vapour 0 0.35 0.58 0.75 0.9 1

5- A liquid containing 50% n-heptane and 50% n-octane is differentially distilled at 1 atmosphere to
vaporise 60 mole% of feed. Find the composition of the distillate and the residue. Find the
boiling range during distillation. (The average volatility=2.15)

6- A liquid containing 50% Benzene (A), 25% Toluene (B), 25% o-xylene (C), is flash vaporized
at 1 std atm and 100o C. Compute the amounts of liquid and vapour products and their
compositions.
Equilibrium relation:
Substance (A) (B) (C)
Vapour pressure, mmHg 1370 550 200

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7- Calculate the product compositions and flow rates ( liquid and vapour ) from a flash tank with
feed of the following specifications:
Component Methane Ethane Propane Butane Pentane Hexane heptane
xf 0.3396 0.0646 0.0987 0.0434 0.032 0.03 0.3917

The flash unit operates at 40o F and 35 Psi.


Use the charts to get the k values for the seven components.

8- 10 Kg batch of ethylaniline is to be steam distilled from small amount of non-volatile impurity.


Saturated steam at 25 Psia is used. Initial temperature of ethylaniline is 40 oC and the
distillation takes place at atmospheric pressure.
a- At what temperature will the distillation proceeds?
b- Determine the composition of the vapour phase.
c- How much steam is used?

Data:
 Heat capacity of ethylaniline is 0.4 KCal/Kg.C
 Heat capacity of steam is 0.35 KCal/Kg.C
 Latent heat of vaporization of ethylaniline is 72 Kcal/lb
 Vapour pressures of water and ethyl aniline are given in the table below:

T (o C) 38.5 64.4 80.6 96 99.15 113.2


Pw (mmHg) 51.1 199.7 363.9 657.6 737.2 1225
PEA (mmHg) 1 5 10 20 22.8 40

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APPENDIX

K-Values Charts

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