Scribd Logo
Upload

Welcome to Scribd!

  • 4 views

    BF02645173

    Uploaded by

    紀渥德
    Description of the Li-Rh system

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    BF02645173

    Uploaded by

    紀渥德
    4 views1 page
    Description of the Li-Rh system

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Description of the Li-Rh system

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    4 views1 page

    BF02645173

    Uploaded by

    紀渥德
    Description of the Li-Rh system

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    You are on page 1of 1

    P h a s e D i a g r a m E v a l u a t i o n s : S e c t i o n II

    The Li-Ru (Lithium-Ruthenium) S y s t e m


    By J. S a n g s t e r * a n d A.D. P e l t o n
    Ecole P o l y t e c h n i q u e d e M o n t r e a l

    Equilibrium Diagram proximately 6 at.% were reported in solid (It) and (Pd) [81Loe].
    Thus, the solubility of Li in (Ru) is in all probability very small,
    No Li-Ru phase diagram is available. According to [81Loe], Li but there is no real evidence to say that it is negligible.
    and Ru react completely at 450 *C at compositions above 70 at.%
    Ru in a slow, single-stage reaction. This was taken to indicate that Crystal Structures and Lattice
    only one intermediate phase exists, possibly LiRu3, analogous to Parameters
    Lilr3 and LiRh3 in other Li-Pt group systems. The actual prepara-
    tion method is unclear from the article of [81Loe]. X-ray diffrac-
    tion and metallography were unsuccessfui because of the reac- Li-Ru crystal structure and lattice parameter data are given in
    tivity of the alloys with air. In the Li-Rh system, the existence of Table 1.
    two compounds, LiRh and LiRh3, is fairly well established Cited References
    [91San], as is the existence of Lilr and Lilr3 in the Li-Ir system
    [92San]. In the Li-Os system, no compounds were observed 76Don:H.C. Donkerslootand J.H.N. Van Vucht,"The Crystal Structure
    [81Loe], whereas in the Li-Pt and Li-Pd systems, several com- of IrLi, Ir3Li and LiRh3," J. Less-Common Met., 50(2), 279-282
    pounds were observed [81Loe]. On the basis of the observations (1976). (Equi Diagram; Experimental)
    of [81Loe], it is probable that at least one compound exists in the *81Loe: O. Loebich and C.J. Rauh, "Reactions Between Some Alkali
    Li-Ru system, but no conclusions can be drawn regarding its and Pt Group Metals," Platinum Met. Rev., 25(3), 113-120 (1981).
    stoichiometry, and the existence of other compounds cannot be (Equi Diagram;Review)
    ruled out. 91San: J. Sangster and A.D. Pelton, "The I_J-Rh (Lithium-Rhodium)
    System,"./.PhaseEquilibria, 12(6),681-683 (1991). (Equi Diagram;
    Differential thermal analysis experiments were carried out under Review)
    inert gas atmospheres [81Loe]. No detectable shift in the melting 92San: J. Sangster and A.D. Pelton, "The Ir-I_J (Iridium-Lithium)Sys-
    point of Li was observed, thereby indicating negligible solubility tem," J. Phase Equilibria, to be published (1992). (Equi Diagram;
    of Ru in liquid or solid Li. Review)
    According to [81Loe], the solubility of Li in solid (Ru) is negli- *Indicateskey paper.
    gible, but it does not appear that any measurements were actually
    performed. The solubility of Li in solid Or) was shown by X-ray *Permanent address: Sangster Research Laboratories, Suite M-3,
    studies to be very small [76Don], but Li solubilities of ap- 1270 Sherbrooke St. W., Montr6al, Qu6bec, Canada, H3G 1H7.

    Li-Ruevaluationcontributedby J. Sangster and A.D.Pelton, Centrede Rechercheen CalculThermochimique,EcolePolytechnique,p.o. Box6079,StationA,


    Montr6al,Qu6bec,Canada,H3C3A7.Thisworkwas partiallysupportedby the UnitedStates Departmentof Energyfundsthroughthe JointProgramon Critical
    Compilationof Physicaland ChemicalDatacoordinatedthroughthe Officeof StandardReferenceData,NationalInstituteof Standardsand Technology.Litera-
    ture searchedthrough1988.Dr. Peltonis the ASM/NISTData ProgramCo-CategoryEditorforbinaryalkalialloys.

    Table 1 Li-Ru Crystal Structure and Lattice Parameter Data

    Composition, Pearson Space Strukturbericht Latticeparameters,nm


    Phase at.% Ru symbol group designation Prototype a c
    [ • L i
    ......................................................... 0 c12 Im3m A2 W 0.35093
    aU(a) ..................................................... 0 hi:'2 P63/mmc A3 W 0.3111 0.5~93
    Ru .......................................................... 100 hP2 P6ymmc A3 Mg 0.27058 0.42816
    From[Massalskil]. (a) Below-193"C

    Journal of Phase Equilibria Vol. 12 No. 6 1991 685

    You might also like