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AIEEE-2006 MATHS, PHYSICS & CHEMISTRY

AIEEE-2006 QUESTION PAPER

PART-A : MATHEMATICS 7. Let W denote the words in the English
dictionary. Define the relation R by :
R = {(x,y)  W s W the words x and y have at
1. ABC is a triangle, right angled at A. The resultant
JJJG JJJG
of the forces acting along AB, AC with least one letter in common}. Then R is
1 1 1) not reflexive, symmetric and ransitive
magnitudes and respectively is the
AB AC 2) reflexive, symmetric and not transitive
JJJG
force along AD , where D is the foot of the 3) reflexive, symmetric and transitive
perpendicular from A onto BC. The magnitude 4) reflexive, not symmeric and transitive
of the resultant is
8. If A and B are square matrices of size n s n such
AB2 AC 2 ( AB)( AC ) that A2 – B2 = (A – B) (A + B), then which of the
1) 2)
( AB)2 ( AC )2 AB AC following will be always true ?
1) A = B 2) AB = BA
1 1 1
3) 4) 3) either of A or B is a zero matrix
AB AC AD
4) either of A or B is an identity matrix
2. Suppose a population A has 100 observations
¤ ¥¦§ sin 211k Q 2k Q ´
10
101, 102, ......., 200, and another population B i cos µ is

om
9. The value of
k 1 11 ¶
has 100 observations 151, 152, ...... 250. If VA
and V B represent the variances of the two 1) i 2) 1 3) –1 4) – i
a.c
VA 10. All the values of m for which both roots of the
populations, respectively, then V is equations x2 – 2mx +m2 –1 = 0 are greater than
B
–2 but less than 4, lie in the interval
y

1) 1 2) 9/4 3) 4/9 4) 2/3 1) –2 < m < 0 2) m > 3

id

3. If the roots of the quadratic equation 3) –1 < m < 3 4) 1 < m < 4

x 2 + px + q = 0 are tan30 0 and tan15 0 ,
v

11. A particle has two velocities of equal magnitude

respectively then the value of 2 + q – p is inclined to each other at an angle R . If one of
ia

1) 2 2) 3 3) 0 4) 1 them is halved, the angle between the other and

d

the original resultant velocity is bisected by the

6
in

x new resultant. Then R is

4. The value of the integral, ° dx is
3 9 x x 1) 900 2) 1200 3) 450 4) 600
1) 1/2 2) 3/2 3) 2 4) 1 12. At a telephone enquiry system the number of
phone cells regarding relevant enquiry follow
5. The number of values of x in the interval [0,3 Q ] Poisson distribution with an average of 5 phone
satisfying the equation 2sin2x + 5sinx – 3 = 0 is calls during 10-minute time intervales. The
1) 4 2) 6 3) 1 4) 2 probability that there is at the most one phone
call during a 10-minute time period is
6. If (a s b ) s c  a s (b s c ) , where a , b and c 6 5 6 6
1) e 2) 3) 4) 5
are any three vectors such that a .b x 0 , b .c x 0 5 6 55 e
then a and c are 13. A body falling from rest under gravity passes a
1) inclined at an angle of Q / 3 between them certain point P. It was at a distance of 400 m
2) inclined at an angle of Q / 6 between them from P, 4s prior to passing through P. If g = 10
m/s 2, then the height above the point P from
3) perpendicular where the body began to fall is
4) parallel 1) 720 m 2) 900 m 3) 320 m 4) 680 m

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MATHS, PHYSICS & CHEMISTRY AIEEE-2006

Q 21. In an ellipse, the distance between its foci is 6
14. ° xf (sin x )dx is equal to and minor axis is 8. Then its eccentricity is
0
Q Q 3 1 4 1
1) 2) 3) 4)
1) Q° f (cos x )dx 2) Q ° f (sin x )dx 5 2 5 5
0 0
¥ 1 2´ ¥ a 0´
22. Let A  ¦ µ and B  ¦ ,a, b N. Then
§ 0 bµ¶
Q/2 Q/2
Q § 3 4¶
3) 2 ° f (sin x )dx 4) Q ° f (cos x )dx
0 0 1) there cannot exist and B such that AB = BA
15. A straight line through the point A(3, 4) is such 2) there exist more than one but finite number
that its intercept between the axes is bisected at of B's such that AB = BA
A. Its equation is 3) there exists exactly one B such that AB = BA
1) x + y = 7 2) 3x – 4y + 7 = 0 4) there exit infinitely many B's such that AB=BA
3) 4x + 3y = 24 4) 3x + 4y = 25 x 2
23. The function f ( x )  has a local minimum
16. The two lines x = ay + b, z = cy + d; and x = 2 x
a'y+b', z = c'y + d' are perpendicular to each at
other if 1) x = 2 2) x = –2 3) x = 0 4) x = 1
1) aa' + cc' = – 1 2) aa' + cc' = 1 24. Angle between the tangents to the curve y = x2–
a c a c 5x+6 at the points (2, 0) and (3, 0) is
 1 1
om
3) 4)
a’ c’ a’ c’ Q Q Q Q
1) 2) 3) 4)
17. The locus of the vertices of the family of 2 2 6 4
a3 x 2 a2 x 25. Let a 1 ,a 2 ,a 3 , ..... be terms of an A.P. If
a.c
parabolas y   2a is
3 2 a1 a2 ...a p p2 a6
105 3  2, p x q , then a equals
1) xy  2) xy 
y

a1 a2 .... aq q 21
64 4
id

41 7 2 11
35 64 1) 2) 3) 4)
3) xy  4) xy  11 2 7 41
v

16 105 x
f ( x) 
ia

26. The set of points where is

18. The values of a, for which the points A, B, C 1 x
differentiable is
with position vectors 2iˆ ˆj kˆ, iˆ  3 ˆj  5kˆ and
d

1) (d,0) ‡ (0, d) 2) (d, 1) ‡ ( 1, d)

aiˆ 3ˆj kˆ respectively are the vertices of a right-
in

Q 3) (d, d) 4) (0, d)
angled triangle with C  are
2 27. A triangular park is enclosed on two sides by a
1) 2 and 1 2) –2 and –1 fence and on the third side by a straight river
bank. The two sides having fence are of same
3) –2 and 1 4) 2 and –1 length x. The maximum area enclosed by the
Q / 2
park is
19. ° [( x Q)3 cos2 ( x 3Q)]dx is equal to 3 2 x2 1 2
1) x 2) 3) x 4) Qx 2
3 Q / 2 2 8 2
Q4 Q4 Q Q Q 28. At an election, a voter may vote for any number
1) 2) 3) 4) 1
32 32 2 2 4 of candidates, not greater than the number to
be elected. There are 10 candidates and 4 are
3x2 9 x 17 of be elected. If a voter votes for at least one
20. If x is real, the maximum value of 2
3x 9x 7 candidate, then the number of ways in which
is he can vote is
1) 1/4 2) 41 3) 1 4) 17/7 1) 5040 2) 6210 3) 385 4) 1110

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AIEEE-2006 MATHS, PHYSICS & CHEMISTRY

29. If the expansion in powers of x of the function 35. If (a,a2) falls inside the angle made by the lines
1 x
is a0 + a1x + a2x2 + a3x3 + .... , y  , x > 0 and y = 3x, x < 0, then a belongs to
(1  ax )(1  bx ) 2
then an is
¥ 1´
bn  an an  bn 1) ¦§ 0, 2) (3, d)
1) 2) 2 µ¶
ba ba
a n 1  bn 1
bn 1  an 1
¥1 ´ ¥ 1´
3) 4) 3) ¦ ,3µ 4) ¦§ 3,  µ¶
ba ba §2 ¶ 2
30. For natural numbers m, n if (1–y) m(1+y) n =
36. The image of the point (–1,3,4) in the plane
1 + a1y+a2y2 + ..., and a1 = a2 = 10, then (m, n) is
x–2y=0 is
1) (20, 45) 2) (35, 20)
3) (45, 35) 4) (35, 45) ¥ 17 19 ´
a 1) ¦§  , ,4µ
¶ 2) (15, 11, 4)
3 3
31. The value of ° [ x] f ’( x )dx, a  1 , where [x]
1 ¥ 17 19 ´
3) ¦§ 
denotes the greatest integer not exceeding x is
3 3 µ¶
, ,1 4) (8, 4, 4)
1) af(a) – {f(1) + f(2) + ... + f([a])}
2) [a]f(a) – {f(1) + f(2) + ... + f([a])} 37. If z2 + z + 1 = 0, where z is a complex number,
3) [a]f([a]) – {f(1) + f(2) + ... + f(a)}
4) af([a]) – {f(1) + f(2) + ... + f(a)} ¥ 1´
om
then the value of
2
¥ 2 1´
2
¥ 3 1´
2
a.c
¦§ z z µ¶ ¦§ z µ ¦§ z µ
32. If the lines 3x – 4y – 7 = 0 and 2x – 3y – 5 = 0 z2 ¶ z3 ¶
are two diameters of a circle of area 49 Q square 2
¥ 1´
.... ¦ z 6
y

units, the equation of the circle is µ is

§ z6 ¶
id

1) x2 + y2 + 2x – 2y – 47 = 0
1) 18 2) 54 3) 6 4) 12
2) x2 + y2 + 2x – 2y – 62 = 0
v

3) x2 + y2 – 2x + 2y – 62 = 0 1
38. If 0 < x < Q and cos x sin x 
ia

, then tanx is
4) x2 + y2 – 2x + 2y – 47 = 0 2
d

33. The differential equation whose solution is (1  7) (4  7)

in

1) 2)
Ax 2 + By 2 = 1, where A and B are arbitrary 4 3
constats is of
(4 7) (1 7)
1) second order and second degree 3)  4)
3 4
2) first order and second degree
3) first order and first degree 39. If a1, a2, .... , an are in H.P., then the expression
4) second order and first degree a1a2 + a2 a3 + ... + an–1an is equal to
34. Let C be the circle with centre (0,0) and radius 1) n(a1 + an) 2) (n–1) (a1–an)
3 units. The equation of the locus of the mid 3) na1an 4) (n–1)a1an
points of the chords of the circle C that subtend
2Q dy
an angle of at its centre is 40. If xm.yn = (x + y)m+n, then is
3 dx
3 y x y
1) x
2
y2  2) x2 + y2 = 1 1) 2)
2 x xy
27 9 x
3) x
2
y2  4) x
2
y2  3) xy 4)
4 4 y

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MATHS, PHYSICS & CHEMISTRY AIEEE-2006

PART-B : PHYSICS 47. A material ‘B’ has twice the specific resistance
of ‘A’. A circular wire made of ‘B’ has twice the
41. A particle located at x = 0 at time t = 0, starts diameter of a wire made of ‘A’. Then for the
moving along the positive x-direction with a two wires to have the same resistance, the ratio
velocity ‘v’ that varies as v  B x . The A A / A B of their respective lengths must be
displacement of the particle varies with time as 1 1
1) t3 2) t2 3) t 4) t1/2 1) 2 2) 1 3) 4)
2 4
42. A mass of M kg is suspended by a weightless 48. The Kirchhoff’s first law ¤i0 and second
string. The horizontal force that is required to
displace it until the string makes an angle of law ¤ ¤
iR  E , where the symbols have
45° with the initial vertical direction is their usual meanings, are respectively based on
1) conservation of charge, conservation of
1) Mg ( 2  1) 2) Mg ( 2 1) energy
Mg 2) conservation of charge, conservation of
3) Mg 2 4) momentum
2
3) conservation of energy, conservation of
43. A bomb of mass 16 kg at rest explodes into two charge
pieces of masses of 4 kg and 12 kg. The velocity 4) conservation of momentum, conservation of
of 12 kg mass is 4 ms–1. The kinetic energy of charge
the other mass is
1) 96 J 2) 144 J 3) 288 J 4) 192 J om
49. In a region, steady and uniform electric and
magnetic fields are present. These two fields are
parallel to each other. A charged particle is
a.c
44. A particle of mass 100 g is thrown vertically
released from rest in this region. The path of
upwards with a speed of 5 m/s. the work done the particle will be a
by the force of gravity during the time the
y

1) circle 2) helix
particle goes up is 3) straight line 4) ellipse
id

1) 0.5 J 2) –0.5 J 3) –1.25 J 4) 1.25 J

50. Needles N 1 , N 2 and N 3 are made of a
v

45. A whistle producing sound waves of ferromagnetic, a paramagnetic and a

ia

frequencies 9500 Hz and above is approaching diamagnetic substance respectively. A magnet

a stationary person with speed v ms –1. The when brought close to them will
d

velocity of sound in air is 300 ms–1. If the person 1) attract all three of them
in

can hear frequencies upto a maximum of 10,000 2) attract N1 and N2 strongly but repel N3
Hz, the maximum value of v upto which he can 3) attract N1 strongly, N2 weakly and repel N3
hear the whistle is weakly
1) 30 ms–1 2) 15/ 2 ms–1 4) attract N 1 strongly, but repel N 2 and N 3
weakly
3) 15 2 ms–1 4) 15 ms–1
51. Which of the following units denotes the
46. A electric dipole is placed at an angle of 30° to dimensions ML 2 /Q 2 , where Q denotes the
a non-uniform electric field. The dipole will electric charge?
experience 1) Weber (Wb) 2) Wb/m2
1) a torque only 3) Henry (H) 4) H/m2
2) a translational force only in the direction of 52. A player caught a cricket ball of mass 150 g
the field moving at a rate of 20 m/s. If the catching
3) a translational force only in a direction normal process is completed in 0.1 s, the force of the
to the direction of the field blow exerted by the ball on the hand of the
player is equal to
4) a torque as well as a translational force
1) 300 N 2) 150 N 3) 3 N 4) 30 N

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AIEEE-2006 MATHS, PHYSICS & CHEMISTRY

53. A ball of mass 0.2 kg is thrown vertically 59. The refractive index of glass is 1.520 for red
upwards by applying a force by hand. If the light and 1.525 for blue light. Let D1 and D2 be
hand moves 0.2 m which applying the force an of minimum deviation for red and blue light
and the ball goes upto 2 m height further, find respectively in a prism of this glass. Then
the magnitude of the force. Consider g=10m/s2 1) D1 > D2 2) D1 < D2 3) D1 = D2
1) 22 N 2) 4 N 4) D1 can be less than or greater than depending
3) 16 N 4) 20 N upon the angle of prism

54. Consider a two particle system with particles 60. In a Wheatstone’s bridge, there resistances P, Q
having masses m1 and m2. If the first particle is and R connected in the three arms and the fourth
pushed towards the centre of mass through a arm is formed by two resistances S 1 and S 2
distance d, by what distance should the second connected in parallel. The condition for bridge to
particle be moved, so as to keep the centre of be balanced will be
mass at the same position? P R P 2R
1)  2) 
m2 Q S1 S2 Q S1 S2
1) d 2) m d
1
P R(S1 S2 ) P R(S1 S2 )
m1 m1 3)  4) 
3) m m d 4) m d Q S1S2 Q 2S1S2
1 2 2

61. The current I drawn from the 5 volt source will

55. Starting from the origin, a body oscillates simple
harmonically with a period of 2 s. After what
time will its kinetic energy be 75% of the total
be
om
1) 0.17 A 2) 0.33 A
a.c
energy? 3) 0.5 A 4) 0.67 A
1 1 1 1 62. In a series resonant LCR circuit, the voltage
across R is 100 volts and R = 1 k 8 with
1) s 2) s 3) s 4) s
y

12 6 4 3
C = 2µF. The resonant frequency X is 200rad/s.
id

56. The maximum velocity of a particle, executing

At resonance the voltage across L is
simple harmonic motion with an amplitude 7
v

mm, is 4.4 m/s. The period of oscillation is 1) 4×10–3 V 2) 2.5×10 –2V

ia

1) 100 s 2) 0.01 s 3) 10 s 4) 0.1 s 3) 40 V 4) 250 V

63 Two insulating plates are both uniformly charged
d

57. A string is stretched between fixed points

in such a way that the potential difference
in

separated by 75 cm. It is observed to have

between them is V2 –V1 = 20 V. (i.e. plate 2 is at
resonant frequencies of 420 Hz and 315 Hz.
a higher potential). The plates are separated by
There are no other resonant frequencies
d = 0.1 m and can be treated as infinitely large.
between these two. Then, the lowest resonant
An electron is released from rest on the inner
frequency for this string is
surface of plate 1. What is its speed when it hits
1) 10.5 Hz 2) 105 Hz plate 2? (e=1.6×10–19C,me=9.11×10–31 kg)
3) 1.05 Hz 4) 1050 Hz 1) 32 × 10–19 m/s 2) 2.65 × 106 m/s
58. Assuming the sun to be a spherical body of 3) 7.02 × 1012 m/s 4) 1.87 × 106 m/s
radius R at a temperature of T K, evaluate the
total radiant power, incident on Earth, at a 64. The resistance of a bulb filament is 100 8 at a
distance r from the Sun. temperature of 100°C. If its temperature
coefficient of resistance be 0.005 per °C, its
R  TT 4 4Qr02 R 2 TT 4 resistance will become 200 8 at a temperature
1) 2)
r2 r2 of
Qr02 R 2 TT 4 r02 R 2 TT 4 1) 200°C 2) 300°C
3) 4)
r2 4 Qr 2 3) 400°C 4) 500°C

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MATHS, PHYSICS & CHEMISTRY AIEEE-2006

65. In an AC generator, a coil with N turns, all of 72. When 3Li 7 nuclei are bombarded by protons,
the same area A and total resistance R, rotates and the resultant nuclei are 4Be8, the emitted
with frequency X in a magnetic field B. The particles will be
maximum value of emf generated in the coil is 1) neutrons 2) alpha particles
1) N.A.B. X 2) N.A.B.R. X 3) beta particles 4) gamma photons
3) N.A.B 4) N.A.B.R 73. A solid which is transparent to visible light and
66. The flux linked with a coil at any instant ‘t’ is whose conductivity increases with temperature
given by G = 10t2 – 50t + 250 is formed by
The induced emf at t = 3 s is 1) Metallic binding 2) Ionic binding
1) 190 V 2) –190 V 3) –10 V 4) 10 V 3) Covalent binding
4) Van der Waals binding
67. A thermocouple is made from two metals,
Antimony and Bismuth. If one junction of the 74. If the ratio of the concentration of electrons that
couple is kept hot and the other is kept cold then, 7
an electric current will of holes in a semiconductor is and the ratio
5
1) flow from Antimony to Bismuth at the cold 7
of currents is then what is the ratio of their
junction 4
2) flow from Antimony to Bismuth at the hot drift velocities ?
junction 4 5 4 5
1) 2) 3) 4)
3) flow from Bismuth to Antimony at the cold 7 8 5 4
junction
4) not flow through the thermocouple om
75. In a common base mode of a transistor, collector
current is 5.488 mA for an emit current of 5.60
mA. The value of the base current amplification
a.c
68. The time by a photoelectron to come out after factor ( C ) will be
the photon strikes is approximately
1) 48 2) 49 3) 50 4) 51
1) 10–1 s 2) 10–4 s 3) 10–10 s 4) 10–16 s
y

76. The potential energy of a 1 kg particle free move

1
69. An alpha nucleus of energy mv2 bombards a ¥ x4 x2 ´
id

2 along the x-axis is given by V(x)  ¦ 4  2 µJ

heavy nuclear target of charge Ze. Then the § ¶
v

distance of closest approach for the alpha The total mechanical energy of the particle 2 J.
ia

nucleus will be proportional to Then, the maximum speed (in m/s) is

1 1 1
2) v2 1) 2 2) 3 / 2 3) 2 4) 1/ 2
d

1) 3) 4) 4
Ze m v
in

70. The threshold frequency for a metallic surface 77. A force of –F k̂ acts on O, the origin of the
corresponds to an energy of 6.2 eV, and the coordinate system. The torque about the point
stopping potential for a radiation incident on (1, –1) is
this surface 5 V. The incident radiation lies in 1) –F ˆi  ˆj 2) F ˆi  ˆj
1) X-ray region 2) ultra-violet region
3) –F ˆi ˆj 4) F ˆi ˆj
3) infra-red region 4) visible region
78. A thin circular ring of mass m and radius R is
71. The energy spectrum of C -particles [number rotating about its axis with a constant angular
N(E) as a function of C -energy E] emitted from velocity X . Two objects each of mass M are
a radioactive source is attached gently to the opposite ends of a
diameter of the ring. The ring now rotates with
N(E) N(E) an angular velocity Xa =
1) 2)
E0
E
E0
E Xm X(m 2M)
1) 2)
(m 2M) m
N(E)
3) 4)
N(E) X(m  2M) Xm
3) 4)
E E (m 2M) (m M)
E0 E0

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AIEEE-2006 MATHS, PHYSICS & CHEMISTRY

79. If the terminal speed of a sphere of gold 85. The ‘rad’ is the correct unit used to report the
(density= 19.5 kg/m3) is 0.2 m/s in a viscous measurement of
liquid (density = 1.5 kg/m3) of the same size in 1) the rate of decay of radioactive source
the same liquid. 2) the ability of a beam of gamma ray photons
1) 0.2 m/s 2) 0.4 m/s to produce ions in a target
3) 0.133 m/s 4) 0.1 m/s 3) the energy delivered by radiation to a target.
80. The work of 146 kJ is performed in order to 4) the biological effect of radiation
compress one kilo mole of gas adiabatically and 86. If the binding energy per nucleon in 37 Li and 4
2 He
in this process the temperature of the gas increases nuclei are 5.60 MeV and 7.06 MeV respectively,
by 7° C. The gas is (R = 8.3 J mol–1 K–1)
then in the reaction P 37 Li m 2 24 He energy of
1) monoatomic 2) diatomic proton must be
3) triatomic 1) 39.2 MeV 2) 28.24 MeV
4) a mixture of monoatomic and diatomic 3) 17.28 MeV 4) 1.46 MeV
81. The rms value of the electric field of the light 87. If the lattice constant of t his semiconductor is
coming from the Sun is 720 N/C. The average decreased, then which of the following is
total energy density of the electromagnetic wave correct?
is Condutton band width Ec
1) 3.3 × 10 –3 J/m3 2) 4.58 × 10–6 J/m3 Band gap Eg
3) 6.37 × 10–9 J/m3 4) 81.35 × 10–12 J/m3
82. A coin is placed on a horizontal platform which
undergoes vertical simple harmonic motion of
om
Valence badn width
1) All Ec, Eg, Ev decrease
2) All Ec, Eg, Ev increase
Ev
a.c
angular frequency X . The amplitude of 3) Ec, and Ev increase but Eg decreases
oscillation is gradually increased. The coin will 4) Ec, and Ev, decrease Eg increases
y

leave contact with the platform for the first time 88. In the following, which one of the diodes is
id

1) at the highest position of the platform reverse biased?

2) at the mean position of the platform + 5V
+10V
v
/\/\/\/\

g R R
1) 2)
ia

3) for an amplitude of /\/\/\/\

X2
+ 5V
g2
d

4) for an amplitude of
X2
/\/\/\/\

–10V
/\/\/\/\

R R
in

3) 4)
83. An electric bulb is rated 220 volt –100 watt. –10V
The power consumed by it when operated on – 5V
110 volt will be 89. The circuit has two oppositely connect ideal
diodes in parallel. What is the current following
48
1) 50 watt 2) 75 watt
in the circuit?
3) 40 watt 4) 25 watt /\/\/\/\
1) 1.33 A D1 D2
38 28
\/\/\/\
\/\/\/\

84. The anode voltage of a photocell is kept fixed. 12V

2) 1.71 A
The wavelength M of the light falling on the
cathode is gradually changed. The plate current 3) 2.00 A 4) 2.31 A
I of the photocell varies as follows : 90. A long solenoid has 200 turns per cm and carries
I I a current i. The magnetic field at its centre is
1) 2) 6.28 ×10–2 Weber/m2. Another long solenoid has
O M O M 100 turns per cm and it carries a current i/3.
The value of the magnetic field at its centre is
I I
1) 1.05×10–4 Weber/m2 2) 1.05×10–2 Weber/m2
3) 4)
3) 1.05×10–5 Weber/m2 4) 1.05×10–3 Weber/m2
O M O M

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MATHS, PHYSICS & CHEMISTRY AIEEE-2006

91. Four point masses, each of value m, are placed PART-C : CHEMISTRY
at the corners of a square ABCD of side A The 96. HBr reacts with CH 2 = CH – OCH 3 under
moment of inertia through A and parallel to BD anhydrous conditions at room temperature to
is give
1) m A 2 2) 2 m A 2 3) 3 m A 2 (4) 3 m A 2 1) CH3CHO and CH3Br
92. A wire elongates by A mm when a load W is 2) BrCH2CHO and CH3OH
hanged from it. If the wire goes over a pulley 3) BrCH2 – CH2 – OCH3
and two weights W each are hung at the two 4) H3C – CHBr – OCH3
ends, the elongation of the wire will be (in mm) 97. The IUPAC name of the compound shown
1) A /2 2) A 3) 2 A 4) zero Cl

93. Two rigid boxes containing different ideal gases

below is
are placed on a table. Box A contains one moleof
Br
nitrogen at temperature T0, while Box B contains
1) 2-bromo-6-chlorocyclohex-1-ene
one mole of helium at temperature (7/3) T0. The
2) 6-bromo-2-chlorocyclohexene
boxes are then put into thermal contact with each
3) 3-bromo-1-chlorocyclohexene
other and heat flows between them until the 4) 1-bromo-3-chlorocyclohexene
gases reach a common final temperature.
98. The increasing order of the rate of HCN addition
(Ignore the heat capacity of boxes). Then, the
final temperature of the gases, Tf, in terms of T0
is
om
to compounds A – D is
(A) HCHO
(C) PhCOCH3
(B) CH3COCH3
(D) PhCOPh
a.c
5 3
1) Tf  T0 2) Tf  T0 1) A < B < C < D 2) D < B < C < A
2 7 3) D < C < B < A 4) C < D < B < A
y

7 3
3) Tf  T0 4) Tf  T0 99. How many moles of magnesium phosphate,
id

3 2 Mg3(PO4)2 will contain 0.25 mole of oxygen

94. Two spherical conductors A and B of radii 1 atoms?
v

1) 0.02 2) 3.125 × 10–2

mm and 2 mm are separated by a distance of 5
ia

3) 1.25 × 10–2 4) 2.5 × 10–2

cm and are uniformly charged. If the spheres
100. According to Bohr’s theory, the angular
d

are connected by a conducting wire then in

momentum of an electron in 5th orbit is
in

equilibrium condition, the ratio of the

h h h h
magnitude of the electric fields at the surface of 1) 25 2) 1.0 3) 10 4) 2.5
Q Q Q Q
spheres A and B is
101. Which of the following molecules/ions does not
1) 1 : 4 2) 4 : 1 3) 1 : 2 4) 2 : 1 contain unpaired electrons?
95. An inductor (L = 100 mH), a resistor (R = 100 8 ) 1) O22  2) B2 3) N 2 4) O2
and a battery (E = 100 V) are initially connected 102. Total volume of atoms present in a face-centre
in series as shown in the figure. After a long time cubic unit cell of a metal is (r is atomic radius)
the battery is disconnected after short circuiting 20 3 24 3 12 16
1) Qr 2) Qr 3) Qr 3 4) Qr 3
the points A and B. The current in the circuit after 3 3 3 3
1m sec is 103. A reaction was found to be second order with
1) 1 A respect to the concentration of carbon
L
monoxide. If the concentration of carbon
2) 1/e A monoxide is doubled, with everything else kept
\/\/\/\/

3) e A R the same, the rate of reaction will

A B 1) remain unchanged 2) triple
4) 0.1 A E 3) increase by a factor of 4 4) double

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AIEEE-2006 MATHS, PHYSICS & CHEMISTRY

104. Which of the following chemical reactions 111. Among the following the one that gives positive
depicts the oxidizing behaviour of H2SO4 ? iodoform test upon reaction with I2 and NaOH
1) 2HI H 2 SO 4 m I 2 SO 2 2H 2 O is

2) Ca(OH)2 H 2 SO 4 m CaSO 4 2H 2 O 1) CH3CH2CH(OH)CH2CH3

2) C6H5CH2CH2OH
3) NaCl H 2 SO 4 m NaHSO 4 HCl
CH3
4) 2PCl 5 H 2 SO 4 m 2POCl3 2HCl SO 2 Cl 2
3) H3C 4) PhCHOHCH3
OH
105. The IUPAC name for the complex
[Co(NO2)(NH3)5]Cl2 is 112. The increasing order of stability of the following
1) nitrito-N-pentaamminecobalt (III) chloride free radicals is
v v v v
2) nitrito-N-pentaamminecobalt (II) chloride 1) (CH3 )2 C H  (CH 3 )3 C  (C6 H 5 )2 C H  (C6 H 5 )3 C
v v v v
3) pentaammine nitrito-N-cobalt (II) chloride 2) (C6 H 5 )3 C  (C6 H 5 )2 CH  (CH3 )3 C  (CH3 )2 C H
v v v v
4) pentaammine nitrito-N-cobalt (III) chloride 3) (C6 H 5 )2 C H  (C6 H 5 )3 C  (CH3 )3 C  (CH 3 )2 CH
v v v v
106. The term anomers of glucose refers to 4) (CH 3 )2 C H  (CH3 )3 C  (C 6 H 5 )3 C  (C6 H 5 )2 CH
1) isomers of glucose that differ in configu-
rations at carbons one and four 113. Uncertainty in the position of an electron
(C-1and C-4) (mass = 9.1 × 10–31 kg) moving with a velocity
300 ms–1, accurate upto 0.001%, will be

om
2) a mixture of (D)-glucose and (L)-glucose
3) enantiomers of glucose 1) 19.2 × 10–2 m 2) 5.76 × 10–2 m
4) isomers of glucose that differ in configuration 3) 1.92 × 10–2 m 4) 3.84 × 10–2 m
a.c
at carbon one (C-1) 114. Phosphorus pentachloride dissociates as
107. In the transformation of 238 234
if one follows, in a closed reaction vessel,
92 U to 92 U,
emission is an B -particle, what should be the
y

ZZX PCl (g) + Cl (g)

PCl5(g) YZZ 3 2
other emission(s) ?
id

If total pressure at equilibrium of the reaction

1) Two C  2) Two C  and one C mixture is P and degree of dissociation of PCl5
v

3) One C and one H 4) One C and one C is x, the partial pressure of PCl3 will be
ia

108. Phenyl magnesium bromide reacts with ¥ x ´ ¥ 2x ´

1) ¦§
x 1µ¶
2) ¦§
1  x µ¶
d

methanol to give P P
in

1) a mixture of anisole and Mg(OH)Br

2) a mixture of benzene and Mg(OMe)Br ¥ x ´ ¥ x ´
3) ¦§
x  1µ¶
4) ¦§
1  x µ¶
P P
3) a mixture of toluene and Mg(OH)Br
4) a mixture of phenol and Mg(Me)Br
115. The standard enthalpy of formation (% f H 0 ) at

109. CH 3 Br Nu m CH 3  Nu Br 
298 K for methane, CH4(g), is –74.8 kJ mol–1.
The decreasing order of the rate of the above The additional information required to determine
reaction with nucleophiles (Nu–) A to D is the average energy for C – H bond formation
[Nu–=(A)PhO–, (B) AcO–, (C) HO–, (D) CH3O–] would be
1) D > C > A > B 2) D > C > B > A 1) the dissociation energy of H2 and enthalpy
3) A > B > C > D 4) B > D > C > A of sublimation of carbon
110. The pyrimidine bases present in DNA are 2) latent heat of vapourization of methane
1) cytosine and adenine 3) the first four ionization energies of carbon
2) cytosine and guanine and electron gain enthalpy of hydrogen
3) cytosine and thymine 4) the dissociation energy of hydrogen
4) cytosine and uracil molecule, H2

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MATHS, PHYSICS & CHEMISTRY AIEEE-2006

116. Among the following mixtures, dipole-dipole 123. In which of the following molecules/ions are
as the major interaction, is present in all the bonds not equal ?
1) benzene and ethanol 1) SF4 2) SiF4 3) XeF4 4) BF4–
2) acetonitrile and acetone 124. What products are expected from the
3) KCl and water disproportionation reaction of hypochlorous
acid?
4) benzene and carbon tetrachloride
1) HClO3 and Cl2O 2) HClO2 and HClO4
117. Fluorobenzene (C6H5F) can be synthesized in 3) HCl and Cl2O 4) HCl and HClO3
the laboratory
125. Nickel (Z = 28) combines with a uninegative
1) by heating phenol with HF and KF
monodentate ligand X– to form a paramagnetic
2) from aniline by diazotisation followed by complex [NiX 4 ] 2– . The number of unpaired
heating the diazonium salt with HBF4 electron(s) in the nickel and geometry of this
3) by direct fluorination of benzene with F2 gas complex ion are, respectively
4) by reacting bromobenzene with NaF solution 1) one, tetrahedral 2) two, tetrahedral
118. A metal, M forms chlorides in its +2 and +4 3) one, square planar 4) two, square planar
oxidation states. Which of the following 126. In Fe(CO)5, the Fe – C bond possesses
statements about these chlorides is correct ? 1) Q -character only
1) MCl2 is more volatile than MCl4 2) both T and Q characters
2) MCl2 is more soluble in anhydrous ethanol
than MCl4
3) MCl2 is more ionic than MCl4
3)
om
ionic character 4) T -character only
127. The increasing order of the first ionization
enthalpies of the elements B, P, S and F (lowest
a.c
4) MCl2 is more easily hydrolysed than MCl4 first) is
119. Which of the following statements is true? 1) F < S < P < B 2) P < S < B < F
y

3) B < P < S < F 4) B < S < P < F

1) H3PO3 is a stronger acid than H2SO3
id

2) In aqueous medium HF is a stronger acid 128. An ideal gas is allowed to expand both reversibly
than HCl and irreversibly in an isolated system. If Ti is
v

the initial temperature and T f is the final

3) HClO4 is a weaker acid than HClO3
ia

temperature, which of the following statements

4) HNO3 is a stronger acid than HNO2 is correct?
d

120. The molar conductivities ˜ 0NaOAc and ˜ 0HCl at 1) (Tf)irrev > (Tf)rev
in

infinite dilution in water at 25oC are 91.0 and 2) Tf > Ti for reversible process but Tf = Ti for
426.2 S cm 2 /mol respectively. To calculate irreversible process
˜0HOAc , the additional value required is 3) (Tf)rev = (Tf)irrev
1) ˜0H2 O 2) ˜ 0KCl 3) ˜0NaOH 4) ˜ 0NaCl 4) Tf = Ti for both reversible and irreversible
processes
121. Which one of the following sets of ions 129. In Langmuir’s model of adsorption of a gas on
represents a collection of isoelectronic species? a solid surface
1) K+ , Cl–, Ca2+, Sc3+ 2) Ba2+, Sr2+, K+, S2– 1) the rate of dissociation of adsorbed molecules
3) N3–, O2–, F–, S2– 4) Li+, Na+, Mg2+, Ca2+ from the surface does not depend on the
122. The correct order of increasing acid strength of surface covered
the compounds is 2) the adsorption at a single site on the surface may
a) CH3CO2H b) MeOCH2CO2H involve multiple molecules at the same time
3) the mass of gas striking a given area of surface
c) CF3CO2H d) (Me)2 CO2H
is proportional to the pressure of the gas
1) b < d < a < c 2) d < a < c < b 4) the mass of gas striking a given area of surface
3) d < a < b < c 4) a < d < c < b is independent of the pressure of the gas

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AIEEE-2006 MATHS, PHYSICS & CHEMISTRY

130. Rate of a reaction can be expressed by Arrhenius 135. The decreasing values of bond angles from NH3
equation as: k=Ae–E /RT (106 o) to SbH 3 (101 o) down group-15 of the
In this equation, E represents periodic table is due to
1) the energy above which all the colliding 1) increasing bp-bp repulsion
molecules will react 2) increasing p-orbital character in sp3
2) the energy below which colliding molecules 3) decreasing lp-bp repulsion
will not react
4) decreasing electronegativity
3) the total energy of the reacting molecules at
a temperature, T Me
4) the fraction of molecules with energy greater
than the activation energy of the reaction
Me }}m
%

136. N
131. The structure of the major product formed in Et
OH
n-Bu
Cl
}}}m
NaCN
DMF
The alkene formed as a major product in the
the following reaction is
I above elimination reaction is
CN Cl
1) Me 2) CH2 = CH2
1) 2) NC
CN I Me Me

om
Cl CN 3) 4)
3) 4)
CN I 137. The “spin-only” magnetic moment [in units of
Bohr magneton,( N B)] of Ni 2+ in aqueous
a.c
132. Reaction of trans - 2 - phenyl - 1 bromo-
cyclopentane on reaction with alcoholic KOH solution would be (Atomic number of Ni = 28)
produces 1) 2.84 2) 4.90 3) 0 4) 1.73
y

1) 4-phenylcyclopentene 138. The equilibrium constant for the reaction

id

2) 2-phenylcyclopentene ZZX SO2 (g) 1 O2 (g)

SO3 (g) YZZ
3) 1-phenylcyclopentene 2
v

4) 3-phenylcyclopentene –2
is K c = 4.9 × 10 . The value of K c for the
ia

133. Increasing order of stability among the three ZZX 2SO (g) will be
reaction 2SO (g) + O (g) YZZ
2 2 3
d

main conformations (i.e. Eclipse, Anti, Gauche) 1) 416 2) 2.40 × 10–3

in

of 2-fluoroethanol is 3) 9.8 × 10–2 4) 4.9 × 10–2

1) Eclipse, Gauche, Anti 139. Following statements regarding the periodic
2) Gauche, Eclipse, Anti trends of chemical reactivity of the alkali metals
3) Eclipse, Anti, Gauche and the halogens are given. Which of these
4) Anti, Gauche, Eclipse statements gives the correct picture?
134. The structure of the compound that gives a 1) The reactivity decreases in the alkali metals
tribromo derivative on treatment with bromine but increases in the halogens with increase
water is in atomic number down the group
CH3 CH2OH 2) In both the alkali metals and the halogens
the chemical reactivity decreases with
increase in atomic number down the group
1) 2)
3) Chemical reactivity increases with increase
OH in atomic number down the group in both
CH3
CH3 the alkali metals and halogens
OH 4) In alkali metals the reactivity increases but
3) 4) in the halogens it decreases with increase in
OH atomic number down the group

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MATHS, PHYSICS & CHEMISTRY AIEEE-2006

140. Given the data at 25oC, 146. The enthalpy changes for the following
Ag l  m Agl e  ;E 0  0.152 V processes are listed below:
Ag m Ag e  ;E 0  0.800 V Cl2(g) = 2Cl(g), 242.3 kJ mol–1
What is the value of log Ksp for AgI? I2(g) = 2I(g), 151.0 kJ mol–1
¥ RT ´
¦§ 2.303 F  0.059Vµ¶ ICl(g) = I(g) + Cl(g), 211.3 kJ mol–1
1) –8.12 2) +8.612 I2(s) = I2(g), 62.76 kJ mol–1
3) –37.83 4) –16.13 Given that the standard states for iodine and
141. The following mechanism has been proposed chlorine are I 2 (s) and Cl 2 (g), the standard
for the reaction of NO with Br2 to form NOBr : enthalpy of formation for ICl(g) is
NO(g) + Br2(g) U NOBr2(g) 1) –14.6 kJ mol–1
m
NOBr2(g)+NO(g) 2NOBr(g) 2) –16.8 kJ mol–1
If the second step is the rate determining step, 3) +16.8 kJ mol–1
the order of the reaction with respect to NO(g)
4) +244.8 kJ mol–1
is
1) 1 2) 0 3) 3 4) 2 147. How many EDTA (ethylenediaminetetraacetic
142. Lanthanoid contraction is caused due to acid) molecules are required to make an
octahedral complex with a Ca2+ ion?

om
1) the appreciable shielding on outer electrons
by 4f electrons from the nuclear charge 1) Six 2) Three
2) the appreciable shielding on outer electrons 3) One 4) Two
a.c
by 5d electrons from the nuclear charge
3) the same effective nuclear charge from Ce to OH O Na+
Lu 148. CHCl3 NaOH }}
m
y

4) the imperfect shielding on outer electrons by CHO

id

4f electrons from the nuclear charge The electrophile involved in the above reaction
is
v

143. Resistance of a conductivity cell filled with a

solution of an electrolyte of concentration „
ia

0.1 M is 100 8 . The conductivity of this solution

1) dichloromethyl cation (CHCl )
2
d

is 1.29 S m–1. Resistance of the same cell when 2) dichlorocarbene(:CCl2)

filled with 0.2 M of the same solution is 520 8 .
in

The molar conductivity of 0.02 M solution of 3) trichloromethyl anion (CCl3 )

the electrolyte will be „
4) formyl cation (CHCl2 )
1) 124 × 10–4 S m2 mol–1
2) 1240 × 10–4 S m2 mol–1 149. 18 g of glucose (C6H12O6) is added to 178.2 g
3) 1.24 × 10–4 S m2 mol–1 of water. The vapour pressure of water for this
4) 12.4 × 10–4 S m2 mol–1 aqueous solution at 100oC is
144. The ionic mobility of alkali metal ions in 1) 759.00 Torr 2) 7.60 Torr
aqueous solution is maximum for 3) 76.00 Torr 4) 752.40 Torr
1) K+ 2) Rb+ 3) Li+ 4) Na+
150. (%H  %U) for the formation of carbon
145. Density of a 2.05 M solution of acetic acid in
monoxide (CO) from its elements at 298 K is
water is 1.02 g/mL. The molality of the solution
is (R = 8.314 J K–1 mol–1)
1) 1.14 mol kg–1 2) 3.28 mol kg–1 1) –1238.78 J mol–1 2) 1238.78 J mol–1
3) 2.28 mol kg–1 4) 0.44 mol kg–1 3) –2477.57 J mol–1 4) 2477.57 J mol–1

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AIEEE-2006 MATHS, PHYSICS & CHEMISTRY

123456789012345678901234
123456789012345678901234
123456789012345678901234
AIEEE 2006 ANSWERS
PART-A : MATHEMATICS 76) 2 77) 3 78) 1 79) 4 80) 2
1) 4 2) 1 3) 2 4) 2 5) 1 81) 2 82) 3 83) 4 84) 3 85) 4
6) 4 7) 2 8) 2 9) 4 10) 3 86) 3 87) 4 88) 1 89) 3 90) 2
11) 2 12) 4 13) 1 14) 4 15) 3 91) 4 92) 2 93) 4 94) 4 95) 2
16) 1 17) 1 18) 1 19) 3 20) 2
PART-C : CHEMISTRY
21) 1 22) 4 23) 4 24) 2 25) 4
96) 4 97) 3 98) 3 99) 2 100) 4
26) 3 27) 3 28) 3 29) 4 30) 4
101) 1 102) 4 103) 3 104) 1 105) 4
31) 2 32) 4 33) 4 34) 4 35) 3
106) 4 107) 1 108) 2 109) 1 110) 3
36) 1 37) 4 38) 3 39) 4 40) 1
111) 4 112) 1 113) 3 114) 1 115) 1
PART-B : PHYSICS
116) 2 117) 2 118) 3 119) 4 120) 4
41) 2 42) 1 43) 3 44) 3 45) 4
121) 1 122) 3 123) 1 124) 4 125) 2
46) 4 47) 1 48) 1 49) 3 50) 3
51) 2
56) 2
52) 4
57) 2
53) 4
58) 3
54) 4
59) 2
55) 2
60) 3
126) 2
131) 4
om 127) 4
132) 4
128) 1 129) 3 130) 2
133) 3 134) 1 135) 4
a.c
61) 3 62) 4 63) 2 64) 2 65) 1 136) 2 137) 1 138) 1 139) 4 140) 4
141) 4 142) 4 143) 4 144) 2 145) 3
y

66) 3 67) 1 68) 3 69) 3 70) 2

id

71) 4 72) 4 73) 3 74) 4 75) 2 146) 3 147) 3 148) 2 149) 4 150) 1

.AIEEE 2006 HINTS AND SOLUTIONS.

v

.
ia

PART-A : MATHEMATICS 3. (2) x2 + px + q = 0

d

tan 300 + tan 150 = –p

in

1. (4) Magnitude of resultant tan 300. tan 150 = q

2 2
¥ 1 ´ ¥ 1 ´ AB2 AC 2 tan 30 0 tan150 p
 ¦ µ ¦§ AC µ¶  AB. AC tan 450   1
§ AB ¶ 1  tan 30 tan15
0 0
1 q

BC BC 1
C
 p 1 q
  
AB. AC AD.BC AD D  q  p 1 =2 q  p  3

¤
A B 6
x
T 2 di2 4. (2) I  ° dx
2. (1) x . (Here deviations are taken from
3 9 x x
n
the mean)
9 x
6
Since A and B both has 100 consecutive integers, I ° dx
therefore both have same standard deviation and 3 9 x x
hence the variance.

¤
6
V 3
= A  1 (As di2 is same in both the cases). 2 I  ° dx  3  I 
VB 3
2

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MATHS, PHYSICS & CHEMISTRY AIEEE-2006

5. (1) 2 sin2 x + 5 sin x –3 = 0 e  m mr
 (sin x + 3) ( 2 sin x –1) = 0
12. (4) P( X  r ) 
r!
1 P(X b 1) = P(X = 0) + P(X = 1)
 sin x 
2
=in (0, 3Q ), x has 4 values
6
 e 5 5 s e 5 
6. (4) (a s b ) s c  a s (b s c ), a .b x 0, b .c x 0 e5
1 2 1
 (a .c )b  (b .c )a  (a .c )b  ( a .b ).c 13. (1) We have h  gt and h 400  g(t 4)2
2 2
(a .b )c  (b .c )a
Subtracting we get 400 = 8g + 4 gt

 t = 8 sec
a || c
h
7. (2) Clearly ( x, x )  R x W . So, R is reflexive
1
Let ( x, y)  R , then ( y, x )  R as x and y have at = h  s 10 s 64  320m Q(t)
2 400m
least one letter in common. So, R is symmetric.
But R is not transitive for example = Desired height = 320+400=720 m P(t+4)

Let x = DELHI, y = DWARKA and z = PARK Q Q

then ( x, y)  R and ( y, z)  R but ( x, z ) Ž R . 14. (4) I  ° xf (sin x )dx  ° ( Q  x ) f (sin x )dx
Q 0 0

om
8. (2) A2 – B2 = (A – B) (A + B)  Q° f (sin x )dx  1
A2 – B2 = A2 + AB – BA – B2 0
 AB  BA Q
2 I  Q° f (sin x )dx
a.c
9. (4)
0
Q Q/2
¤ ¥ 2k Q 2k Q ´
¤
2k Q 2k Q
¤ Q
10 10 10
¦§ sin 11 i cos 11 µ¶  sin 11 i cos 11 I f (sin x )dx  Q
y

f (sin x )dx
k 1 k 1 k 1 2 °0 °
id

0
= 0 + i (–1) = –i. Q/2
Q
v

° f (cos x )dx
10. (3) Equation x2 – 2mx + m2 – 1 = 0
ia

0
(x – m)2 –1 = 0
15. (3) The equation of axes is xy = 0
(x – m +1) (x – m –1) = 0

d

the equation of the line is

x = m –1, m +1
in

–2 < m –1 and m + 1 < 4 x.4 y.3

 12  4 x 3 y  24
m > –1 and m < 3 2
–1 < m < 3 x b zd
16. (1) Equation of lines y
a c
x  b’ z d’
u
sin R
R2 R1 y
R
 aa' + 1 + cc' = 0.
a’ c’
11. (2) tan  2 u Lines are perpendicular
4 u R/ 4 R/ 4
u cos R R /2

2 u
u/2
a3 x 2 a2 x
17. (1) Parabola : y   2a
R 1 R 1 R 3 2
 sin sin cos R  sin R cos
4 2 4 2 4
Vertex : (B, C )
3RR R R ¥ a4 a3 ´ ¥ 1 8´ 4
= 2sin  sin  3sin  4sin3 ¦ 4. .2aµ ¦
§ 4 3µ¶
a
4 4 4 4 a / 2
2
3 §4 3 ¶
B 3
 C 
2a /3 4a, a3 4 3
1 R 2 R 4 a
= sin    300 or R  1200 3 3
4 4 4

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AIEEE-2006 MATHS, PHYSICS & CHEMISTRY

35 a 35 x 2 1
 s3   a 23. (4) is of the form x r 2 & equality
12 4 16 2 x x
holds for x = 1
3 ¥ 35 ´ 105
BC    a
4 a ¦§ 16 µ¶ 64 dy
 2x  5
24. (2)
JJJG dx
18. (1)  BA  iˆ  2 ˆj 6 kˆ
JJJG = m1 = (2x –5)(2,0)= –1, m2 = (2x –5)(3, 0)=1
C A  (2  a )iˆ 2 ˆj 25. (4)
JJJG
CB  (1  a )iˆ 6 kˆ p
<2 a1 ( p  1)d >
JJJGJJJG
CA.CB.  0  (2  a )(1  a )  0
2
q
p2
 2
q
 22aa 1 ( p  1)d p

(q  1)d q
<2 a1 (q  1)d >
 a  2,1
1
2
Q / 2
¥ p  1´
a1 ¦
§ 2 µ¶
d
19. (3) I  ° [( x Q)3 cos2 ( x 3Q)]dx 
p
3 Q2 ¥ q  1´ q
a1 ¦ µ d
Put x Q t § 2 ¶
a6 a6 11
Q/2 Q/2 For a , p = 11, q = 41 m 
I ° [t
3
cos t ]dt  2
2
°
2
cos t dt 21 a21 41

 °
Q2
Q/2
[1 cos 2t ]dt 
Q
2
0
0

om « x
®®1  x , x  0
26. (3) f ( x )  ¬
® x , x r0
« x
®®
 f ’( x )  ¬1  x
2

® x , xr0
, x0
a.c
0
®­1 x ®­1 x 2
20. (2) y 
3x2 9 x 17
=f'(x) exist at everywhere.
3x  9 x 7
y

2
27. (3)
id

2
3x (y–1) +9x(y –1) + 7y – 17 = 0
1 2 x x
Dr0 ' x is real Sol: Area = x sin R R
v

2
81(y–1) 2–4x3(y–1)(7y–17) r 0
1 ¥ Q´
ia

 ( y  1)( y  41) b 0 1 b y b 41 Amax  x 2 ¦ at sin R  1, R µ

2 § 2¶
d

21. (1) 2ae = 6  ae = 3

in

28. (3) 10C1 + 10C2 + 10C3 + 10C4

2b = 8 
b=4 = 10 + 45 + 120 + 210 = 385
2 2 2
b =a (1–e )
29. (4) (1–ax)–1(1–bx)–1=(1+ax+a2x2+....)
16 = a2–a2e2
(1+bx+b2x2+..)
a2 = 16 + 9 = 25
3 3 =coefficient of
a = 5 =e   xn = bn +abn–1+ a2bn–2 +..+an–1b+an
a 5
¨1 2 · ¨a 0· bn 1
 an 1
bn 1
 an 1
 = an 
22. (4) A  © ¸ B© ¸ ba ba
ª3 4 ¹ ª0 b ¹
30. (4) (1–y)m(1+y)n = [1–mC1y+mC2y2–...]
¨ a 2b ·
AB  © ¸
ª3 a 4 b ¹ [1+nC1y+nC2y2 + ...]
¨ a 0 · ¨1 2 · ¨ a 2 a · « m(m  1) n(n  1) º
BA  ©  1 (n  m ¬  mn » y2 .....
¸© ¸© ¸ ­ 2 2 ¼
ª 0 b ¹ ª3 4 ¹ ª3b 4b ¹
AB = BA only when a = b = a1 = n – m = 10 and

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MATHS, PHYSICS & CHEMISTRY AIEEE-2006

m2 n2  m  n  2mn From (1) and (2)
a2   10 So, n–m=10
2
 m+n = 80
9 13
and (m–n)2
–(m+n)=20
B , C , H 4
5 5
= m = 35, n = 45 No option matches.
31. (2) Let a = k + h, where [a] = k and 0 b h  1
37. (4) z2 + z + 1 = 0  z  X or X2
a 2 3 k k h
=°[x] f ’(x)dx  °1f ’(x)dx 1 1
° 2 f ’(x)dx ... ° (k  1)dx ° kf ’(x)dx
so, z  X X 2  1 , z 2 2
 X 2 X  1 ,
1 1 2 k1 k z z
1
{f(2) – f(1)} + 2{f(3) – f(2)}+3{f(4) – f(3)}+ ..... z3  X3 X3  2
+ (k–1) – {f(k) – f(k–1)} +k{f(k+h) – f(k)} z3
= –f(1) – f(2) – f(3) ..... –f(k) + k f(k+h) 1 1 1
z4 4
 1 , z 5 5
 1 and z 6 2
= [a] f(a) – {f(1) + f(2) + f(3) + .... +f([a])} z z z6

32. (4) Point of intersection of 3x–4y–7=0 and = The given sum 1 + 1 + 4 + 1 + 1 + 4 = 12

2x–3y–5=0 is (1, –1), which is the centre of the 1 1
38. (3) cos x sin x   1 sin 2 x 
circle and radius = 7 2 4
=
Equation is (x–1)2 + (y+1)2 = 49 3
x2 + y2 – 2x + 2y – 47 = 0
 sin 2 x   , so x is obtuse
4

33. (4) Ax2 + By2 = 1

dy
... (1) and
om 2 tan x
1 tan x 2

3
4
 3 tan 2 x 8 tan x 3  0
a.c
Ax By  0 .... (2) 8 p 64  36 4 p 7
dx = tan x  
2
6 3
d2 y ¥ dy ´
y

A By B¦ µ  0 ... (3) 4  7
dx 2 § dx ¶ ' tanx < 0 = tan x 
id

3
From (2) and (3) 1 1 1 1 1 1
v

39. (4)     .....    d (say)

«® 2º a2 a1 a3 a2 an an 1
ia

d2 y ¥ dy ´ ® dy
x ¬  By  B¦ µ » By  0 a1  a2 a2  a3
®­
2 § dx ¶ Then a1a2  , a2 a3 
dx ¼® dx
d

, ......... ,
d d
in

2
d2 y ¥ dy ´ dy a a
 xy  x¦ µ  y  0 an1an  n 1 n
dx 2 § dx ¶ dx d
a1  an
Q h2 k23 9
=a1a2 + a2a3 + ....... + an1an 
d
Also,
34. (4) cos  h 2
k 
2

(n  1)d  a1  an  (n  1)a1an
3 3 4 1 1

an a1 d
a 1
35. (3) a2 – 3a < 0 and a  0 a 3
2
40. (1)
36. (No option) If B, C, H
2 2
be the image then

xm.yn = (x + y)m+n mlnx + nlny = (m+n)ln(x+y)
m n dy m n ¥ dy ´
= 
B 1 ¥ C 3´ y dx x y ¦§ dx µ¶
1
 2¦ 0 x
2 § 2 µ¶
¥ m m n ´ ¥ m n n ´ dy
=B  1  2C  6  0  B  2C  7 ¦   
... (1) § x x y µ¶ ¦§ x y y µ¶ dx
B 1 C3 H 4 my  nx ¥ my  nx ´ dy
and   .... (2)  ¦
dy y
 
1 2 0 µ
x( x y) § y( x y) ¶ dx dx x

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AIEEE-2006 MATHS, PHYSICS & CHEMISTRY

PART-B : PHYSICS 56. (2) v max  AX
dx dx 2Q 2 QA
B x °  ° B dt  x B t 2 T   0.01sec
41. (2)
dt x X vmax
42. (1) F A sin 45 = Mg ( A – A cos 45) n (n 1)
57. (2) (v)  315, v  420
2A 2A
F = Mg ( 2 –1)
Qr02 TQT 4 R 2 r02
43. (3) m1v1 = m2v2 58. (3) ( TT 4
– 4 QR 2
) 
4 Qr 2 r2
1 1
KE  m 2 v22  s 4 s 144  288J 59. (2) D = ( N – 1)A
2 2
D2 > D1
¥ v2 ´
 mgh   mg ¦ 2g µ  1.25J. P R(S1 S2 )
60. (3) Q  S S
44. (3)
§ ¶
1 2
f(300)
45. (4) fapp   v  15m / s 5
300  v 61. (3) i   0.5
10
46. (4) A torque as well as a translational force 100
62. (4) i   0.1A
SA A A S A 1000
47. (1) R1  R 2  B 2B
QR A2
QR B 0.1

A A SB R 2A
 
2SA R 2A
A B SA R B SA – 4R A
2 2
A
 B 2
AA
1 2 om
VL  VC 

63 (2) mv  eV
200 s 2 s 10 6
 250V
a.c
2
48. (1) 2eV
Conservation of charge, conservation of energy v  2.65 s 106 m / s
y

m
% t)]
id

49. (3) Straight line 64. (2) 200 = 100 [1 +(0.005 ×

50. (3) attracts N1 strongly, N2 weakly and Repel T – 100 = 200
v

N3 weakly T = 300° C
ia

51. (3) Henry (H) 65. (1) NBA X

 0.15 × 20
d

52. (4) (mv– 0) dG

66. (3) e    (20t  50)  10 volt
in

3 dt
F  30N
0.1 67. (1) Flow from Antimony to Bismuth at cold
53. (4) mgh = Fs junction
F = 20 N 68. (3) 10–10 sec.
54. (4) m1 d + m2 x = 0 1
69. (3)
m1d m
x
m2 1242eV
70. (2) M  z 1100A 0
1 2 3¥1 2 ´ 11.2
55. (2) mv  ¦ mvmax µ
2 4§2 ¶ Ultraviolet region

A 2X2 cos2 Xt  A2 X2
3
4 N(E)
Q 1 71. (4)
3
cos Xt  Xt   t  sec E
2 6 6 E0

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MATHS, PHYSICS & CHEMISTRY AIEEE-2006

72. (4) Gamma-photon 89. (3) D1 is reverse biased therefore it will act like
an open circuit.
73. (3) Covalent binding
12
ne 7 Ie i  2.00 A
74. (4) n  5 , I  7 / 4 6
n n
B1n 2 i 2 (6.28 s 10 2 )(100 s i / 3)
90. (2) B2  
(Vd )e I n 5
 es n  n1i1 200(i)
(Vd )n In ne 4
75. (2) lb= le– lc
 1.05 s 102 W / m 2
lc 91. (4) I  2m(A / 2)2  3A2
C  49
lb
92. (2)
76. (2) k Emax = ET – Umin
93. (4)
Umin ( p 1) =–1/4 J
3 5 7
3 %U  0  R(Tf  T0 ) 1 s R(Tf  T0 )  0
KEmax = 9/4 J  U  J 2 2 3
2 3
G Tf  T0
77. (3) U  ( ˆi ˆj) s ( Fk)
ˆ  F(iˆ ˆj) 2
78. (1) Li = Lf E A rB 2
94. (4) E  r  1
mR 2
X  (mR
¥ mX ´
Xa  ¦
§ m 2M µ¶
2
2MR ) Xa
2
B

om
A

95. (2) I = I0 e–Rt /L =

l
A
a.c
e
vs (Ss  SA ) PART-C : CHEMISTRY
79. (4) v  (S  S )
y

96. (4) Electrophilic addition reaction more

g g A
favourable.
id

Br
vs = 0.1 m/s „ Br
|
H2C  CH  OCH3 }}}
mH2 C CH  OCH3 }}}
mH3C  CH  OCH3
HBr
v

80. (2) 146 = Cv % T |


H
ia

Cv = 21 J/mol K 97. (3) Double bond is given higher preference.

98. (3)
81. (2) Uav  F0 E 2rms  4.58 s 106 J / m3
d

99. (2) One mole Mg3(PO4)2contains 8 moles of ‘O’

in

E2rms  4.58 s 106 J / m3

8n = 0.25
82. (3) A X 2 = g
 A = g/ X 2
n
0.25
8

25
8 s 100
 3.125 s 10 2
V12 V22
83. (4)  = Resistance 100. (4) mvr 
nh 5h
  2.5
h
P1 P2 2Q 2Q Q
 P2 = 25 W 101. (1)
84. (3) ¥ 4 3´ ¥ 4 3 ´ 16 3
102. (4) V  n s ¦§ Qr µ¶  4 s ¦§ Qr µ¶  Qr
85. (4) 3 3 3

86. (3) EP=(8 × 7.06 – 7 × 5.60) MeV = 17.28 MeV 103. (3) R t [W]2 ; R' t [2CO]2 ; R t 4[W]2 ; R t 4M

87. (4) 104. (1) H2SO4 oxidises iodide to iodines

88. (1) 105. (4) Naming of ligands is in the order NH 3 and

NO2–
106. (4) C1 is anomeric

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AIEEE-2006 MATHS, PHYSICS & CHEMISTRY

126. (2) Because of back bonding
107. (1) 238
92 U m234
92 U
4
He 2 01 e
2
108. (2) Benzene is formed 127. (4)
109. (1) CH3O– is more reactive PhO– is least 128. (1) B is lowest p has stable p3 configuration.
110. (3) DNA has two pyrimidine bases.
111. (4) Iodoform is given by methyl ketone 129. (3) Conceptual
112. (1) Trihenyl free radical is most stable. 130. (2) Conceptual
h 131. (4) Nucleophilic substitution of Cl–by CN–
113. (3) %x.% r
4 Qm 132. (4) According to E2 mechanism.
h 6.63 s 10 34
%x r  133. (3) Eclipse least stable ganche most stable.
4 Q m% V 0.001
4 s 3.14 s 9.1 s 10 31 s 300 s
100 134. (1) ortho pare of bromiantion to –OH group.
6.63 s 10 34 135. (4) Repulsions will be less with lower
31 3 = 0.01933 electronagativity
4 s 3.14 s 9.1 s 3 s 10 s 10
136. (2) Ethylene
ZZX
114. (1) PCl 5 (g) YZZ PCl3 (g) Cl2 (g) 137. (1) N n n 2 , where Ni2+ has n = 2
(1x) x x

¥ x ´
PPCl3  ¦ sP 100 s 100
2
¥ ´ 104
§ 1 x µ¶
1
K ’c ¦  
115. (1) Energy required to get H and C atoms
116. (2) CH2 = CHCN and CH3COCH3 are polar
138. (1)
om
= 4.1649 × 100
2 µ
§ 4.9 s 10 ¶ 4.9 s 4.9
 24.01
= 416.49
a.c
139. (4) Most reactive metal is Cs and non metal is
117. (2) From C6H5HBF4 F.

140. (4) Agl(s) e  YZZ

ZZX Ag(s) l  ;E 0  0.152
y

118. (3) M2+ has lower polarisation power than M4+

id

119. (4) N with +5 state from stronger acid

Ag(s) m Ag e ; E 0  0.8
120. (4) M CH3COONa  M CH3COO M 0Na ..........(1)
0 0
v

Agl(s) m Ag I; E 0  0.952

ia

M0HCl  MH0 M0Cl  ..........(2) 0.059

E 0cell  log K
d

M0NaCl  M0Na M0Cl ..........(3) n

in

0.059
M 0CH3COOH  (1) (2)  (3) 0.952  log K sp
1
121. (1) Each species with 18 electrons 0.952
log K sp   16.135
122. (3) CF3COOH is most acidic 0.059
141. (4) NO(g) + Br2(g) U NOBr2(g)
m
123. (1) S in SF4 has one Lone pair
NOBr2(g)+NO(g) 2NOBr(g)
124. (4) 3 HOCl }}
m 2 HCl HClO33 R = K[NOBr2] [NO],
[NOBr2 ]
125. (2) 2 6 8
28Ni: ………. 3s , 3p , 3d , 4s
2
K.Kc [NO] [Br2][NO], where K c  [NO][Br ]
2
Ni2+: 3s2, 3p6, 3d8 = K'[NO]2 [Br2]
3d 4s 4p 142. (4) Poor slidding by f–electrons
143. (4) There is one mistake in Question paper.
Assuming concentration of solution is 0.2 M
sp3 instead of 0.02 M. Since resistance of 0.2 M is
520 8 .
Tetrahedral geometry

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MATHS, PHYSICS & CHEMISTRY AIEEE-2006

1 ¥ A´ 1 ¥ A´
R  1008 ; K  R ¦§ a µ¶ ;1.29  100 ¦§ a µ¶ ¥1
 ¦ s 62.76
1
s 151.0
1 ´
s 243.3µ  (211.3)
§2 2 2 ¶
¥ A´ 1
¦§ a µ¶  129m ; R  5208,C  0.2M = 228.03 – 211.3 %H  16.73
1 ¥ A´ 1 147. (3) EDTA4– is hexadentate ligaud
K ¦ µ (129)81m 1
R § a ¶ 520 148. (2) CCl 2 is electrophile in Reimer–Tiemann
N  K s Vin cm3 reaction.
1 1000 18 1
 s 129 s s 10 6 m3 P 0  Ps n 760  Ps 0.1
520 0.2    180  10 
149. (4) Ps N Ps 178.2 9.9 9.9
129 1000
 s s 106  1.24 s 10 3  12.4 s 10 4 18
520 0.2 1
760  Ps  Ps
144. (2) Hydrate Rb+ has small size. 99
145. (3) One L solution has 2.05 mol solute and 960g = 760 s 99  Ps s 99  Ps
solvent
760 s 99

P
760 s 99  100Ps Ps   752.4
1 1 100
146. (3) l2 (s) Cl2 m lCl(g)
2 2

om
150. (1)
¨1 1 1 · 1
%H  © %H l2 (s)ml2 (g) N11 Ncl cl ¸  < N1cl > %H  %U  %ng RT   s 8.314 s 298  1238.78
ª2 2 2 ¹ 2
a.c
y
v id
d ia
in

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