KCSE F2 CHEM TOPICALS.lec RAKDAFHA
KCSE F2 CHEM TOPICALS.lec RAKDAFHA
KCSE F2 CHEM TOPICALS.lec RAKDAFHA
CHEMISTRY
A SERIES OF KCSE TOPICAL REVISION
QUESTIONS IN CHEMISTRY.
Lecturer rakdafha
1. STRUCTURE OF THE ATOM
AND THE PERIODIC TABLE
1. In an experiment an unknown mass of anhydrous sodium carbonate was dissolved in water and
the solution made up to 250cm3. 25cm3 of this solution neutralized 20cm3 of 0.25M nitric
acid.
(Na = 23.0 C = 12.0 O = 16.0)
Calculate:
(a) Moles of Nitric acid used
(b) Moles of sodium carbonate in 25cm of the solution
(c) Mass of unknown sodium carbonate used
2. Element A has atomic mass 23 and element B has atomic mass 7 and also have 12neutorns
and 4 neutrons respectively.
(a) Write the electronic arrangement of A and B
(b) Which element has higher ionization energy? Explain
3. The table below shows the relative atomic masses and the percentage abundance of isotope
M1 and M2 of element M.
4. (a) Element V has two isotopes. Two thirds of V and one third of V . What is the
relative atomic mass of element V?
(b) The following refers to element Y
Isotope A B C
Isotope mass 54 56 57
Given that isotope C contains 31 neutrons in its nucleus find the number of protons in
isotope B
5. The table below shows the relative atomic masses and the percentage abundance of the
isotopes L1 and L2 of element L.
Relative atomic mass % abundance
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L1 62.93 69.09
L2 64.93 30.91
Calculate the relative atomic mass of element K.
6. An element M has two isotopes M and M . The relative atomic mass of the naturally
occurring is 63.55. Calculate the percentage of each isotope
9. Carbon and silicon belong to the same group of the periodic table, yet Carbon (IV) oxide is a
gas while silicon (IV) oxide is a solid with a high melting point. Explain this difference
11. Copper (II) oxide and charcoal are black solids. How would you distinguish between the two
solids?
12. (a) Element X is found in period III and group IV. It consists of two isotopes 28X and QX.
A sample of X was found to consist of 90% of 28X.If the relative atomic mass of X is
28.3, work out the number of neutrons in QX
(b) Draw an electrochemical cell for the above cell
13. Study the table below and answer the questions that follows:- (Letters are not the actual
symbols of element)
Element Electronic arrangement Electrical conductivity
L1 2.8.2 Higher electrical conductivity
L2 2.8.1 High electrical conductivity
L3 2.8.3 Highest electrical conductivity
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Mass 40 10 7 11 40
number
(a) Which two letters represent the same element? Give a reason
(b) Give the number of neutrons in an atom of element R
16. The table below gives some elements in the periodic table. Use it to answer the questions that
follow. The letters do not represent the actual symbols of the elements.
Element A B C D E
Atomic number 12 13 14 15 16
Which of the above letters represent:
a) A metallic element which forms ions with the smallest ionic radius? Explain
b) A non metallic element with the largest bbatomic size? Explain
17. The grid below is part of the periodic table. Use it to answer the questions that follow:
(The letters are not the actual symbols).
18. The number of protons, neutrons and electrons in atoms A to F are given in the table
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below the letters do not represent the actual symbol of the elements:-
19. (a) Study the table below and answer the questions that follow.
Particle Atomic number Ionic configuration Formula of oxide Atomic radii Ionic radii
P 4 ………….. …………… 0.110 0.031
Q …………... 2.8.8 QO 0.200 0.099
R …………… 2.8.8 R2 O 0.230 0.133
S 17 2.8.8 S2O7 0.099 0.181
T 16 …………… ……… 0.104 0.231
20. a) Work out the oxidation number of phosphorous in the following compound H3PO3 b)
Study the equation below:
Mg(s) + 2H2O(l) Mg(OH)2(aq) + H2 (g)
Which species has undergone oxidation .Explain
21. The grid below represents part of the periodic table. The letters do not represent the actual
symbols of the elements. Study it and answer the questions that follow:
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L L
M P T J U X
N Q S V Y
W
(a) Explain why element L appears in two different groups in the grid above
(b) State the name of the chemical family to which P and Q belong
(c) Write the formula of the compound formed between P and V
(d) Compare the melting points of Q and S. Explain
(e) Identify an element whose oxide dissolves in both acids and alkalis
(f) Write the equation for the burning of T in excess air
(g) Using dots (•) and cross (x) to represent electrons, draw a diagram to illustrate
bonding in the sulphide of Q (h) State
one use of element X
22. The grid below is part of the periodic table. The elements are not represented by their actual
symbols. Use the information to answer the questions that follow.
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(iv) Name the type of bond and structure formed when elements R and K react.
(v) Explain why element N doesn’t form compounds with other elements.
(vi) Compare the atomic radii of T and Q. Explain.
23. Study the data given in the following table and answer the questions that follow. The letters
are not the actual symbols of elements.
25. Identify the particles that facilitate the electric conductivity of the following substances
(i) Sodium metal
(ii) Sodium Chloride solution
(iii) Molten Lead Bromide
26. Compare with a reason the atomic radius of Sodium to that of Aluminum.
27. Study the information in the table below and answer the questions that follow:
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Q ……………………………………………………
R ……………………………………………………
28. Ethanol is a liquid at room temperature but does not conduct electricity. Explain.
CHEMICAL FAMILIES
1. Study the information in the table below and answer the questions that follow:
Element Atomic radius (nm) Ionic radius (nm)
W 0.114 0.195
X 0.072 0.136
Y 0.133 0.216
Z 0.099 0.181
(a) Would these form part of a metallic or a non-metallic group? Explain
(b) Suggest an element in the table above likely to be the most reactive. Explain
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(a) What is the general name given to the group in which the elements X, Y and Z belong?
(b) Select two elements which are coloured gases
(c) Explain why Z has the highest boiling point
(d) Write an equation for the reaction of element Z with iron metal
(e) Element Y was dissolved in water and a piece of blue litmus paper was put into the resulting
solution. State and explain the observation that was made on the litmus paper
4. The table below shows elements A, B, C, E, F, and G. Elements in group X have a
valency of 2 while elements in group Y have a valency of 1. Use the table to answer the
questions that follow:-
GROUP X GROUP Y
Element A B C E F G
Atomic radius (nm) 14.0 19.5 19.7 5.2 7.9 11.3
Ionic radius (nm) 7.6 10.5 12.4 12.6 16.1 19.6
(i) Atomic radius increases from A to C and from E to G. Explain
(ii) Explain the difference in the atomic and ionic radii of group X elements
(iii) Elements C and G belong to the same period. Explain why the atomic radius of C is
greater than that of G
(iv) Give the formula of the compound formed when B and F react
(v) What type of bonding is formed in the compound above? Explain
(vi) Starting with the least reactive, arrange the elements in group Y in the order of
reactivity.Explain:
5. The information in the table below relates to elements in the same group of the periodic
table.Study it and answer the question that follows.
7. a) What is an isotope?
b) An element Q consists of 3 isotopes of mass 28, 29, 30 and percentage abundance of
92.2, 4.7, 3.1 respectively. Determine the relative atomic mass of the element?
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8. Study the information in the table below and answer the questions that follow. (The
letters do not represent the actual symbols of the elements)
Element Electronic configuration Ionization energy Kj/mol)
P 2.2 1800
Q 2.8.2 1450
R 2.8.8.2 1150
(a) What is the general name given to the group in which elements P, Q and R belong?
(b) Explain why P has the highest ionization energy
(c) Write a balanced chemical equation for the reaction between element Q and water
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6. Sodium and Magnesium belong to the same period on the periodic table and both are
metals.
Explain why magnesium is a better conductor of electricity than sodium. 7.
Using dots and crosses to represent electrons, draw the structures of the following:
(a) Phosphorous chloride (PCl3)
(b) Hydroxonium ion (H3O+)
8. Between aluminium and copper which one is a better conductor? Explain
9. Water has a boiling point of 100oC while hydrogen chloride has a boiling point of – 115oC.
Explain
10. Explain why luminous flame is capable of giving out light and soot
11. When blue litmus paper is dipped in a solution of aluminium chloride it turns red.
Explain
12. Carbon and Silicon are in the same group of the periodic table. Silicon (IV) Oxide melts at
2440oC while solid Carbon (IV) Oxide sublimes at -70oC. In terms of structure and
bonding, explain this difference
14. (a) Explain why aluminium is a better conductor of electricity than magnesium
(b) Other than cost and ability to conduct, give a reason why aluminium is used for
making cables while magnesium is not
15. Explain how electrical conductivity can be used to distinguish between magnesium oxide
And silicon (IV) oxide
16. a) The diagram below represents part of the structure of sodium chloride crystal
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The melting and boiling points of sodium chloride are 801C and 1413C respectively.
Explain why sodium chloride does not conduct electricity at 25C, but does not at
temperature between 801C and 1413C
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(ii) Fullerenes dissolve in methylbenzene while the other forms of carbon do not. Given that soot is a
mixture of fullerenes and other solid forms of carbon, describe how crystals of fullerenes can be
obtained from soot
(iii) The relative molecular mass of one of the fullerenes is 720. What is the molecular mass of this
fullerene
17. (a) Explain the following observations:-
(i) NaCl allows electric current to pass through them in molten state
(ii) Graphite is a non-metal yet it is a conductor of electricity
18. Study the table below and answer the questions that follow:-
Substance A B C D E F
Melting Point (oC ) 801 113 -39 5 -101 1356
119
Boiling point (oC) 1410 445 457 54 -36 2860
Electrical Solid Poor Poor Good Poor Poor Poor
Conductivity liquid Good Poor Good Poor Poor Poor
19. (I) Sodium metal tarnishes when exposed to the air where a white powder is formed on its
surface. A small piece of this sodium metal was dropped into 25g of ethanol and 1200cm3 of
hydrogen gas was evolved at r.t.p. The unreacted ethanol was evaporated and a white solid
remained. (Na=23, molar gas volume at r.t.p = 24dm3, C=12, O =16, H=1)
(a) Write a chemical equation for the reaction between ethanol and sodium metal (b)
Determine the mass of sodium that reacted with ethanol
(c) What mass of ethanol evaporated?
(d) The ethanol was evaporated at 80oC, while the white solid remained unaffected at this
temperature. What is the difference in structure of ethanol and the white solid?
(II) (a) Name an inorganic liquid which liberates hydrogen gas with sodium metal (b)
What two differences would you observe if similar pieces of sodium were
Dropped separately into small beakers containing equal amount of ethanol and the liquid
named in (II)(a) above respectively
20. Study the information in the table below and answer the questions that follow: (The letters do
not represent the actual symbols of the elements)
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21. The table below shows the elements in the third period, the oxides of the third period and their
properties. The letters are not the actual symbols of the elements. Study the information and answer
the questions that follow:
TO2
ii) Using dots and crosses to represent electrons. Show the bonding in the oxide, QO2 c)
i)Explain why elements P conducts electricity but T does not ii) The oxide of P reacts
both acids and alkalis. Give the name of this kind of oxide
22. The table below gives information about elements A1, A2, A3 and A4
(i) In which period of the periodic table is element A2? Give a reason
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25. (a) Using dots ( ) and crosses (x) to represent electrons show bonding in:
NH-2 ( N=7, H=1) S8 (S = 16)
(b) Show bonding in Carbon (II) Oxide by use of (__) or ( ) to represent bonds.
26. In terms of structure and bonding, explain why diamond is the hardest naturally occurring
Substance
28. Elements A, B, C, and D are not actual symbols, have atomic numbers 19, 9, 12 and 10 respectively.
(a) Which two elements represent non-metals
(b) Write the formula of the compound formed between elements B and C and identity
the bond present in the compound
(Si= 14, H = 1)
31. Below is a table oxides of some period three elements
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Explain why AlCl3 solid has a much lower boiling point than MgCl2 solid
SALTS
1. Study the flow chart below and answer the questions that follow:
a) Name reagent Z.
b) Describe the process which takes place in step 2.
c) Identify the white solid.
2. a) Starting from solid magnesium oxide, describe how a solid sample of magnesium
hydroxide can be prepared.
b) Give one use of magnesium hydroxide.
3. Starting with lead (II) oxide, describe how you would prepare a solid sample of
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5. Study the information in the table below and answer the questions that follow:-
(a) Complete the table by filling in the blank spaces (i) , (ii) (iii), and (iv)
(b) Identify the particles which are electrically charged
6. Sodium Carbonate Decahydrate crystals were left exposed on a watch glass for two days.
(a) State the observations made on the crystals after two days.
(b) Name the property of salts investigated in the above experiment
7. Starting with sodium oxide, describe how a sample of crystals of sodium hydrogen
carbonate may be prepared
8. In an experiment, ammonium chloride was heated in test-tube. A moist red litmus paper placed at the
mouth of test first changed blue then red. Explain these observations:-
9. Using dots (•) and cross (x), show the structure of ammonium ion 10. a) Give the name of each
of the processes described below which takes place when salts are exposed to air for sometime
i) Anhydrous copper sulphate becomes wet ii)
Magnesium chloride forms an aqueous solution
iii) Fresh crystals of sodium carbonate, Na2CO3.10H2O become covered with white
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17. When exposed to air, crystals of hydrated sodium carbonate loses water of
crystallizations;-
i) Name this process
ii) Write the formula of hydrated sodium carbonate
18. A student poured sodium iodide solution into a small portion of solution Q, a yellow
precipitate was formed.
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20. A piece of marble chips was strongly heated in air for about 30 minutes. Some drops of
water were added drop by drop to the product when it was still warm.
Using equation, explain:
i) What happens when the piece of marble chips is heated?
ii) The reaction that takes place when water is added to the final warm product. 21. Starting
withbarium nitrate solution,describe how a pure sample of barium carbonate can be prepared in
the laboratory
22. Potassium nitrate crystals in a test-tube were heated strongly for some time. State the observation
made:
(a) When a glowing splint is introduced into the test-tube during the heating
(b) At the end of the heating
23. Name the process which takes place when:
(a) Anhydrous iron (III) chloride absorb water vapour from the air to form solution
(b) Zinc chloride vapour changes directly to zinc chloride solid
24. (a) Starting form solid magnesium oxide, describe how a solid sample of magnesium
hydroxide can be prepared
(b) Give one use of magnesium hydroxide
25. The diagram below represents a set-up that was used to show that part of air s used
during burning
26. In an experiment the following solids were provided to form three students; Ca(NO3)2(s), NaH2PO4(s);
Mg(OH)Cl(s) and Fe(NH4)2(SO4)2. 6H2O. They were then told to dissolve the given solids in
differently in 20ml of water.
(a) Classify the given salts accordingly
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(b) (i) Explain the process which takes place when FeCl3 is dissolved in water
(ii) A student placed a moist litmus paper on the product in (i) above. State and explain the
observation made
↑↑↑↑
HEAT
(a) Write an ionic equation for the reaction that occurred at the cathode
(b) State and explain what happened at the anode
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2. When an electric current was passed through two molten substances E and F in separate
voltammeters. The observations recorded below were made:-
Substance Observation Type of structure
E Conducts electric current and a gas is formed at
one of the electrodes
F Conducts an electric current and is not
decomposed
Complete the table above
(i) State the observation made on the bulb when each of the following solution were put
onto the beaker
(a) Sugar solution
(b) (i) Salt solution
(ii) Classify the substance in (i) above as either electrolyte or non-electrolyte
(b) If in the above set-up of apparatus, the substance to be tested is Lead II Bromide,
what modification should be included in the set-up?
(c) Write an Ionic equation at the electrodes and state the observation:-
Anode
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4. (a) The diagram below shows the set up used to investigate the effect of an electric current on
molten lead (II) bromide
(iv) Copper II chloride solution dissolves in excess ammonia solution to form a deep blue
solution. Give the ion responsible for the deep blue solution
(v) A solution of hydrogen chloride is an electrolyte but a solution of hydrogen chloride
in methylbenzene in a non-electrolyte. Explain
6. (i) State Faraday’s first law of electrolysis
(ii) The diagram below shows a set-up used for the electrolysis of molten Lead
bromide:-
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State the observations that would be made at the anode and cathode as the electrolysis
progressed
7. (a) (i) Describe how you would prepare pure crystals of lead II nitrate in the laboratory
from lead II oxide
(ii) Write an equation for the reaction that takes place in (a)(i) above
(b) (i) State what happens when lead II nitrate is strongly heated
(ii) Write an equation for the reaction in b(i) above
(c) (i) State what is observed when ammonia solution is gradually added to a solution of
lead II nitrate until the alkali is in excess
(ii) Write an ionic equation for the reaction that takes place in (i) above
8. The diagram show an experiment for investigating electrical conduction in lead (II) fluoride. Study
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Bulb
Gas
Boiling tube
Lead (II)
fluoride
9. Study the diagram below and use it to answer the questions that follow:-
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(a) Name :
I. Liquid Y ………………………………………………………. II. Liquid
N………………………………………………………….
(b) Write the equation for the reaction taking place in;
I. Chamber Q
II. Chamber R
12. In an experiment to investigate the conductivity of substances, a student used the set-up
Shown below.
The student noted that the bulb did not light.
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2. Below is a simplified scheme of solvay process. Study it and answer the questions that follow:
a) Identify gas R.
b) Write an equation for the process that takes place in the filter
3. A burning magnesium continues to burn inside a gas jar full of carbon (IV) oxide.
Explain.
4. The diagram below shows a jiko when in use
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(b) Write an equation for the reaction that took place in the combustion
tube (c) Give one use of P
6. (a) Identify two substance that are reacted to regenerate ammonia gas in the solvary process
(b) Write down a balanced chemical equation for the reaction above
7. When the oxide of element H was heated with powdered Carbon, the mixture glowed and Carbon
(IV) oxide was formed. When the experiment was repeated using the oxide of
element J,there was no apparent reaction
(a) Suggest one method that can be used to extract element J from its oxide
(b) Arrange the elements H, J and Carbon in order of their decreasing reactivity
8. (i) Diamond and silicon (IV) Oxide have a certain similarity in terms of structure and
bonding.State it
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(a) Explain the observation made in the combustion tube during the experiment
(b) Write an equation for the reaction that takes place in the combustion tube
12. Diamond and graphite are allotropes of carbon:-
(a) What is meant by allotropes?
(b) How do they differ in their structure and bonding
13. Study the experimental set-up below:
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(f) Complete the diagram above to show how excess gas x can be collected
16.a) (i) Name three starting materials in the manufacturer of sodium carbonate.
(ii) Which substances are recycled in this process? b) State one commercial use for
(i) Sodium carbonate.
17. [a] (i) State one use of carbon (IV) Oxide gas apart from fire extinguisher
(ii) Give two properties that make carbon (IV) Oxide to be used as fire extinguisher
(b) PbO(s) + CO(g) Pb(s) + CO2(g)
Which property of carbon (II) Oxide is demonstrated by the above equation?
(c) Aluminium carbonate does not exist. Give a reason
(d) Ammonium carbonate decomposes when heated. Write a chemical equation to
represent this decomposition
18. State and explain the observation made when a piece of charcoal is dropped in a jar
containing concentrated nitric (V) acid
19. When Carbon (IV) oxide is passed through lime water, a white precipitate is formed but when
excess Carbon (IV) Oxide is passed, the white precipitate disappears;
(a) Explain why the white precipitate disappears
(b) Give an equation for the reaction that takes place in (a) above 20. The set-
up below was used to prepare a carbon (II) oxide gas.
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