Document: SDS 11

Battery Electrolyte (Sulfuric Acid) Issue No: 2

Safety Data Sheet Issue Date: 10-01-2019

according to Regulation (EU) 2015/830

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Product form : Mixture
Product name : Battery Acid Pack (Sulfuric Acid)

1.2. Relevant identified uses of the substance or mixture and uses advised against

1.2.1. Relevant identified uses

Use of the substance/mixture : Battery Electrolyte

1.2.2. Uses advised against

No additional information available

1.3. Details of the supplier of the safety data sheet

Supplier: GS Yuasa Battery Europe Ltd
Address: Unit 22, Rassau Industrial Estate,
Ebbw Vale, NP23 5SD
United Kingdom

National Contacts France: GS Yuasa Battery France S.A.

Contact: Christian RAYNAUD (Technical Manager)
Tel: (+33) 0474-95-90-95
e-mail: christian.raynaud@gs-yuasa.fr
Language: French & English

Germany: GS Yuasa Battery Germany GmbH

Contact: Joachim HEER (UPS / Project Manager)
Tel: (+49) 0211-41790-15
e-mail: Joachim.Heer@gs-yuasa.de
Language: German & English

Iberia: GS Yuasa Battery Iberia S.A.

Contact: Antonio PULIDO MARTINEZ (Director Commercial Industrial)
Tel: (+34) 091-748-89-19
e-mail: antonio.pulido@gs-yuasa.es
Language: Spanish & English

Italy: GS Yuasa Battery Italy Srl.

Contact: Marco FILIPPI (Technical Manager)
Tel: (+39) 02-3800-91-08
e-mail: marco.filippi@gs-yuasa.it
Language: Italian & English

UK: GS Yuasa Battery Sales UK Ltd.

Contact: Matt JORDAN (General Manager)
Tel: (+44) 01793-833-562
e-mail: Matt.Jordan@gs-yuasa.uk
Language: English language only

1.4. Emergency telephone number

Emergency number : +44(0)1793833555 (09:00– 17:00 Mon to Fri)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture/Substance: SDS EU 2015: According to Regulation (EU) 2015/830
(REACH Annex II)
Skin corrosion/irritation Category 1A H314
Full text of H statements : see section 16

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2.2. Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP]

Hazard pictograms (CLP) :

GHS05
Signal word (CLP) : Danger
Hazard statements (CLP) : H314 - Causes severe skin burns and eye damage
Precautionary statements (CLP) : P260 - Do not breathe dust/fume/gas/mist/vapours/spray
P264 - Wash ... thoroughly after handling
P271 - Use only outdoors or in a well-ventilated area
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P284 - [In case of inadequate ventilation] wear respiratory protection
P301+P330+P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting

2.3. Other hazards

No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Not applicable

3.2. Mixture

Name Product identifier % Classification according to

Regulation (EC) No.
1272/2008 [CLP]
water (CAS No) 7732-18-5 60 Not classified
(EC no) 231-791-2
Sulfuric acid (CAS No) 7664-93-9 40 Skin Corr. 1A, H314
(EC no) 231-639-5
(EC index no) 016-020-00-8
(REACH-no) not available

Specific concentration limits:

Name Product identifier Specific concentration limits
Sulfuric acid (CAS No) 7664-93-9 (5 =< C < 15) Eye Irrit. 2, H319
(EC no) 231-639-5 (5 =< C < 15) Skin Irrit. 2, H315
(EC index no) 016-020-00-8 (C >= 15) Skin Corr. 1A, H314
(REACH-no) not available

Full text of H-statements: see section 16

SECTION 4: First aid measures

4.1. Description of first aid measures
First-aid measures after inhalation : If a battery ruptures, move to fresh air in case of accidental inhalation of mist. If breathing is
irregular or stopped, administer artificial respiration. If breathing is difficult, give oxygen. Seek
medical attention immediately.
First-aid measures after skin contact : Rinse immediately with plenty of water for 15 minutes. Remove contaminated clothing,
including shoes, after flushing has begun. If a battery ruptures, do not rub or scratch exposed
skin. Immediately call a POISON CENTER or doctor/physician.
First-aid measures after eye contact : Rinse immediately with plenty of water for 15 minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If battery ruptures, do not rub or scratch exposed eye.
First-aid measures after ingestion : If solution of a battery chemicals have been swallowed and the person is conscious, give one
glass of water. Do NOT induce vomiting. Vomiting may occur spontaneously. Never give
anything by mouth to an unconscious person. Get immediate medical attention.

4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation : If a battery ruptures, may be harmful or fatal if inhaled in a confined area. May cause severe
irritation and burns of the nose, throat and respiratory tract.

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Symptoms/injuries after skin contact : Direct contact with internal components of a battery can be severely irritating to the skin and
may result in redness, swelling, burns and severe skin damage. Skin contact may aggravate an
existing dermatitis condition. Skin contact may aggravate dermatitis.
Symptoms/injuries after eye contact : If a battery ruptures, direct contact with the liquid or exposure to vapours or mists may cause
tearing, redness, swelling, corneal damage and irreversible eye damage. May cause severe
burns.
Symptoms/injuries after ingestion : Severe irritation or burns to the mouth, throat, oesophagus, and stomach. May be fatal if
swallowed.

4.3. Indication of any immediate medical attention and special treatment needed
Aspiration of this material may cause chemical pneumonia.

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media : Use extinguishing media appropriate for surrounding fire. If a battery ruptures, use dry
chemical, soda ash, lime, sand or carbon dioxide.
Unsuitable extinguishing media : None known.

5.2. Special hazards arising from the substance or mixture

Fire hazard : Sulfuric acid will not burn but can start fires with organic material, nitrates, carbides, chlorates,
and metal powders.
Explosion hazard : Reacts violently with water. It can react explosively with organic materials. . Reacts with most
metals to produce hydrogen gas, which can form an explosive mixture with air. Hydrogen may
accumulate in containers, avoid ignition sources. Addition of water to acid causes heat and
potentially explosive mixtures. Spill over into sewers may generate hydrogen gas or sulfides.
Hazardous decomposition products in case of : Sulfur oxides.
fire

5.3. Advice for firefighters

Protective equipment for firefighters : Use self-contained breathing apparatus and chemically protective clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
General measures : Avoid contact with spilled material. Do not touch damaged containers or spilled material unless
wearing appropriate protective equipment.

6.1.1. For non-emergency personnel

Protective equipment : Wear suitable protective clothing, gloves and eye/face protection.
Emergency procedures : Evacuate area.

6.1.2. For emergency responders

Protective equipment : Wear suitable protective clothing, gloves and eye/face protection.
Emergency procedures : Evacuate unnecessary personnel.

6.2. Environmental precautions

Avoid release to the environment.

6.3. Methods and material for containment and cleaning up

For containment : For small spills, absorb or cover with dry earth, sand, or other inert non-combustible absorbent
material and place into waste containers for later disposal.
Methods for cleaning up : Small spills:collect all released material in a plastic lined metal container. . Take up liquid spill
into absorbent material or Neutralize with sodium bicarbonate. Large spills:contain liquid using
absorbent materila, by digging trenches. Take up liquid spill into inert absorbent material, e.g.:
sand/earth. Dispose in a safe manner in accordance with local/national regulations.

6.4. Reference to other sections

No additional information available

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Additional hazards when processed : Protect from physical damage.
Precautions for safe handling : Avoid all eye and skin contact and do not breathe vapour and mist. Since emptied containers
retain product residue, follow label warnings even after container is emptied. Non-static
creating clothing and conductive shoes should be worn.

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Hygiene measures : Do not eat, drink or smoke when using this product. Wash contaminated clothing prior to re-
use. Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work.

7.2. Conditions for safe storage, including any incompatibilities

Technical measures : Provide local exhaust or general room ventilation.
Storage conditions : Store in a dry, cool and well-ventilated place. Keep away from heat and direct sunlight.
Incompatible products : alkaline substances.
Special rules on packaging : Store in original container or corrosive resistant and/or lined container.

7.3. Specific end use(s)

No additional information available

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Sulfuric acid (7664-93-9)

EU IOELV TWA (mg/m³) 0.05 mg/m³ (taking into account potential limitations
and interferences which take place in the presence of
other Sulphur compounds-mist)
Austria MAK (mg/m³) 0.1 mg/m³ (corresponds to 0.05 mg/m3 Thoracic-
inhalable fraction)
Austria MAK Short time value (mg/m³) 0.2 mg/m³ (inhalable fraction)
Belgium Limit value (mg/m³) 0.2 mg/m³
Bulgaria OEL TWA (mg/m³) 0.05 mg/m³ (When choosing a suitable method for
monitoring exposure should take into account potential
constraints and interactions that may occur in the
presence of other sulfur compounds-respirable
aerosol)
Croatia GVI (granična vrijednost izloženosti) (mg/m³) 0.05 mg/m³
Cyprus OEL TWA (mg/m³) 0.05 mg/m³ (vapor)
Czech Republic Expoziční limity (PEL) (mg/m³) 1 mg/m³
0.05 mg/m³ (concentrated-mist)
Denmark Grænseværdie (langvarig) (mg/m³) 0.05 mg/m³ (thoracic fraction-mist)
Estonia OEL TWA (mg/m³) 1 mg/m³ (fume)
Finland HTP-arvo (8h) (mg/m³) 0.05 mg/m³
Finland HTP-arvo (15 min) 0.1 mg/m³
France VME (mg/m³) 0.05 mg/m³ (thoracic fraction)
France VLE (mg/m³) 3 mg/m³
Germany TRGS 900 Occupational exposure limit value (mg/m³) 0.1 mg/m³ (The risk of damage to the embryo or fetus
can be excluded when AGW and BGW values are
observed-inhalable fraction)
Gibraltar OEL TWA (mg/m³) 0.05 mg/m³ (when selecting an appropriate exposure
monitoring method, account should be taken of
potential limitations and interferences that may arise in
the presence of other sulphur compounds-thoracic
fraction)
Greece OEL TWA (mg/m³) 0.05 mg/m³ (mist)
Hungary AK-érték 0.05 mg/m³
Ireland OEL (8 hours ref) (ppm) 0.05 ppm
Ireland OEL (15 min ref) (ppm) 0.15 ppm (calculated)
Italy OEL TWA (mg/m³) 0.05 mg/m³ (When choosing a suitable method for
monitoring exposure should take into account potential
constraints and interactions that may occur in the
presence of other sulfur compounds, respirable
fraction-thoracic fraction, mist)
Latvia OEL TWA (mg/m³) 0.05 mg/m³ (possible limitations and the impact that
may result from the presence of other Sulfur
components should be taken into account when
choosing an appropriate exposure monitoring method-
fog, which is defined as the thoracic fraction)
Lithuania IPRV (mg/m³) 0.05 mg/m³ (vapor)
Lithuania TPRV (mg/m³) 3 mg/m³ (fog-vapor)

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Sulfuric acid (7664-93-9)

Luxembourg OEL TWA (mg/m³) 0.05 mg/m³
Malta OEL TWA (mg/m³) 0.05 mg/m³ (mist)
Netherlands Grenswaarde TGG 8H (mg/m³) 0.05 mg/m³ (defined as thoracic fraction-mist)
Poland NDS (mg/m³) 0.05 mg/m³ (thoracic fraction)
Portugal OEL TWA (mg/m³) 0.05 mg/m³ (thoracic fraction-mist)
Romania OEL TWA (mg/m³) 0.05 mg/m³
Slovakia NPHV (priemerná) (mg/m³) 0.1 mg/m³
Slovenia OEL TWA (mg/m³) 0.05 mg/m³ (inhalable fraction, fog)
Spain VLA-ED (mg/m³) 0.05 mg/m³ (indicative limit value-mist)
Sweden nivågränsvärde (NVG) (mg/m³) 0.1 mg/m³
Sweden kortidsvärde (KTV) (mg/m³) 0.2 mg/m³
United Kingdom WEL TWA (mg/m³) 0.05 mg/m³ (mist)
Norway Grenseverdier (AN) (mg/m³) 0.1 mg/m³ (inhalable fraction)
Norway Grenseverdier (Korttidsverdi) (mg/m3) 0.1 mg/m³ (inhalable fraction)
Switzerland VME (mg/m³) 0.1 mg/m³ (inhalable dust)
Switzerland VLE (mg/m³) 0.1 mg/m³ (inhalable dust)
Australia TWA (mg/m³) 1 mg/m³
Australia STEL (mg/m³) 3 mg/m³
Canada (Quebec) VECD (mg/m³) 3 mg/m³
Canada (Quebec) VEMP (mg/m³) 1 mg/m³
USA - ACGIH ACGIH TWA (mg/m³) 0.2 mg/m³ (thoracic fraction)
USA - IDLH US IDLH (mg/m³) 15 mg/m³
USA - NIOSH NIOSH REL (TWA) (mg/m³) 1 mg/m³
USA - OSHA OSHA PEL (TWA) (mg/m³) 1 mg/m³

8.2. Exposure controls

Appropriate engineering controls : Mechanical ventilation is recommended. Emergency eye wash fountains and safety showers
should be available in the immediate vicinity of any potential exposure.
Personal protective equipment : Safety glasses. Gloves. Insufficient ventilation: wear respiratory protection. Protective clothing.
Materials for protective clothing : Plastic apron or overall. neoprene/natural rubber
Hand protection : Wear suitable gloves tested to EN374. Use neoprene gloves
Eye protection : Chemical goggles or face shield with safety glasses. DIN EN 166
Skin and body protection : Wash contaminated clothing before reuse. IF ON SKIN: Wash with plenty of soap and water.
Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. half-mask with filter
according to EN 149.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Clear. liquid.
Colour : transparent.
Odour : penetrating. Sharp. pungent.
Odour threshold : No data available
pH : No data available
Relative evaporation rate (butyl acetate=1) : <1
Melting point : No data available
Freezing point : No data available
Boiling point : 95 - 95.5 °C

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Flash point : Non-flammable

Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : 10 mm Hg
Relative vapour density at 20 °C : >1
Relative density : No data available
Density : 1.215 - 1.35 g/m³
Solubility : Soluble in water.
Water: 100 %
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available

9.2. Other information

No additional information available

SECTION 10: Stability and reactivity

10.1. Reactivity
Stable under normal conditions.

10.2. Chemical stability

Stable at normal conditions.

10.3. Possibility of hazardous reactions

Hazardous polymerization will not occur.

10.4. Conditions to avoid

Mechanical impact. Heat sources.

10.5. Incompatible materials

alkali. metals. Combustible materials. Organic materials. Oxidising agents. amines. Bases. Chlorates. iron. Nitrates. Perchlorates. Permanganates.
Phosphorus. Steel. zinc. Peroxides. cyanides. nitromethane. Benzene.

10.6. Hazardous decomposition products

carbon oxides. Sulphur oxides. Toxic and irritating gases are released following thermal decomposition or combustion.

SECTION 11: Toxicological information

11.1. Information on toxicological effects
Acute toxicity : Inhalation: Fatal if inhaled.
Sulfuric Acid-
LD50 oral rat 2140 mg/kg bodyweight
LC50 inhalation rat (mg/l) 510 mg/m³
ATE CLP (vapours) 0.050 mg/l/4h
ATE CLP (dust,mist) 0.005 mg/l/4h
Sulfuric acid (7664-93-9)
LD50 oral rat 2140 mg/kg
LC50 inhalation rat (mg/l) 510 mg/m³ (Exposure time: 2 h)
Skin corrosion/irritation : Causes severe skin burns and eye damage.
Serious eye damage/irritation : Serious eye damage, category 1, implicit
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified

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Specific target organ toxicity (repeated : Not classified

exposure)
Aspiration hazard : Not classified

SECTION 12: Ecological information

12.1. Toxicity

Sulfuric acid (7664-93-9)

LC50 fish 1 82 mg/l (Exposure time:24 h - Species: Brachydanio rerio [static])

12.2. Persistence and degradability

Sulfuric Acid-
Persistence and degradability Possibly hazardous short term degradation products are not likely. However, long term
degradation products may arise. The products of degradation are more Toxic.

12.3. Bioaccumulative potential

Sulfuric acid (7664-93-9)

BCF fish 1 (no bioaccumulation)
12.4. Mobility in soil
No additional information available

12.5. Results of PBT and vPvB assessment

No additional information available

12.6. Other adverse effects

No additional information available

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Regional legislation (waste) : Dispose of contents/container to comply with applicable local, national and international
regulations.
Waste treatment methods : Recycling the product is recommended. Waste must be disposed of in accordance with federal,
state, and local environmental control regulations.
Waste disposal recommendations : Consult the appropriate local waste disposal expert about waste disposal. . Since emptied
containers retain product residue, follow label warnings even after container is emptied.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN

14.1. UN number
UN-No. (ADR) : 2796
UN-No. (IMDG) : 2796
UN-No. (IATA) : 2796
UN-No. (ADN) : 2796
UN-No. (RID) : 2796

14.2. UN proper shipping name

Proper Shipping Name (ADR) : SULPHURIC ACID / BATTERY FLUID, ACID
Proper Shipping Name (IMDG) : SULPHURIC ACID
Proper Shipping Name (IATA) : Sulphuric acid
Proper Shipping Name (ADN) : Not applicable
Proper Shipping Name (RID) : Not applicable
Transport document description : UN 2796 SULPHURIC ACID / BATTERY FLUID, ACID, 8, II, (E)
Transport document description (IMDG) : UN 2796 SULPHURIC ACID, 8, II

14.3. Transport hazard class(es)

ADR
Transport hazard class(es) (ADR) : 8
Danger labels (ADR) : 8

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IMDG
Transport hazard class(es) (IMDG) : 8
Danger labels (IMDG) : 8

IATA
Transport hazard class(es) (IATA) : 8
Hazard labels (IATA) : 8

ADN
Transport hazard class(es) (ADN) : Not applicable

RID
Transport hazard class(es) (RID) : 8
Danger labels (RID) : 8

14.4. Packing group

Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : Not applicable
Packing group (RID) : Not applicable

14.5. Environmental hazards

Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available

14.6. Special precautions for user

- Overland transport
Classification code (ADR) : C1
Limited quantities (ADR) : 1l
Excepted quantities (ADR) : E2
Packing instructions (ADR) : P001, IBC02
Mixed packing provisions (ADR) : MP15
Portable tank and bulk container instructions : T8
(ADR)

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Portable tank and bulk container special : TP2

provisions (ADR)
Tank code (ADR) : L4BN
Vehicle for tank carriage : AT
Transport category (ADR) : 2
Hazard identification number (Kemler No.) : 80
Orange plates :

Tunnel restriction code (ADR) : E

EAC code : 2R

- Transport by sea
Limited quantities (IMDG) : 1L
Excepted quantities (IMDG) : E2
Packing instructions (IMDG) : P001
IBC packing instructions (IMDG) : IBC02
IBC special provisions (IMDG) : B20
Tank instructions (IMDG) : T8
Tank special provisions (IMDG) : TP2
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-B
Stowage category (IMDG) : B
Properties and observations (IMDG) : Colourless liquid, mixture not exceeding 1.405 relative density. Highly corrosive to most
metals. Causes burns to skin, eyes and mucous membranes.
MFAG-No : 157

- Air transport
PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y840
PCA limited quantity max net quantity (IATA) : 0.5L
PCA packing instructions (IATA) : 851
PCA max net quantity (IATA) : 1L
CAO packing instructions (IATA) : 855
CAO max net quantity (IATA) : 30L
ERG code (IATA) : 8L

- Inland waterway transport

No data available

- Rail transport
No data available

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1. EU-Regulations

Contains no REACH substances with Annex XVII restrictions

Contains no substance on the REACH candidate list
Contains no REACH Annex XIV substances

15.1.2. National regulations

Germany
VwVwS Annex reference : Water hazard class (WGK) 1, low hazard to waters (Classification according to VwVwS, Annex
4)
12th Ordinance Implementing the Federal : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Immission Control Act - 12.BImSchV
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Netherlands
SZW-lijst van kankerverwekkende stoffen : Sulfuric acid is listed
SZW-lijst van mutagene stoffen : None of the components are listed
NIET-limitatieve lijst van voor de voortplanting : None of the components are listed
giftige stoffen – Borstvoeding
NIET-limitatieve lijst van voor de voortplanting : None of the components are listed
giftige stoffen – Vruchtbaarheid
NIET-limitatieve lijst van voor de voortplanting : None of the components are listed
giftige stoffen – Ontwikkeling

Denmark
Classification remarks : Emergency management guidelines for the storage of flammable liquids must be followed
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product

15.2. Chemical safety assessment

CSA has not been established

SECTION 16: Other information

Indication of changes:
According to Regulation (EU) 2015/830 (REACH Annex II).

Full text of H- and EUH-statements:

Skin Corr. 1A Skin corrosion/irritation Category 1A
H314 Causes severe skin burns and eye damage

SDS EU (REACH Annex II)

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be
construed as guaranteeing any specific property of the product

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