TEST 3

Grade:
SK015
Chemistry 1
Semester 1
Session 2023/2024 100

CHEMISTRY UNIT
PAHANG MATRICULATION COLLEGE

TEST 3
CHAPTER 1, 2, 4, 5, 6 & 7
(2 HOURS)

NAME : ___________________________________________
CLASS : ___________________________________________
LECTURER : ___________________________________________

QUESTION MARKS

1 / 21

2 / 10

3 / 17

4 /9

5 /9

6 / 14
TOTAL / 80

This question paper consists of 7 printed pages.

© Unit Kimia, KMPh
 RELATIVE ATOM MASSES OF SELECTED ELEMENTS
JISIM ATOM RELATIF UNSUR-UNSUR TERPILIH

Element Symbol Proton number Relative atomic mass

Aluminium Al 13 27.0
Silver Ag 47 107.9
Argon Ar 18 40.0
Arsenic As 33 74.9
Gold Au 79 197.0
Barium Ba 56 137.3
Beryllium Be 4 9.0
Bismuth Bi 83 209.0
Boron B 5 10.8
Bromine Br 35 79.9
Iron Fe 26 55.9
Fluorine F 9 19.0
Phosphorus P 15 31.0
Helium He 2 4.0
Mercury Hg 80 200.6
Hydrogen H 1 1.0
Iodine I 53 126.9
Cadmium Cd 48 112.4
Potassium K 19 39.1
Calcium Ca 20 40.1
Carbon C 6 12.0
Chlorine Cl 17 35.5
Cobalt Co 27 58.9
Krypton Kr 36 83.8
Chromium Cr 24 52.0
Copper Cu 29 63.6
Lithium Li 3 6.9
Magnesium Mg 12 24.3
Manganese Mn 25 54.9
Sodium Na 11 23.0
Neon Ne 10 20.2
Nickel Ni 28 58.7
Nitrogen N 7 14.0
Oxygen O 8 16.0
Platinum Pt 78 195.1
Lead Pb 82 207.2
Protactinium Pa 91 231.0
Radium Ra 88 226.0
Radon Rn 86 222.0
Rubidium Rb 37 85.5
Selenium Se 34 79.0
Cerium Ce 58 140.1
Cesium Cs 55 132.9
Silicon Si 14 28.1
Scandium Sc 21 45.0
Tin Sn 50 118.7
Antimony Sb 51 121.8
Strontium Sr 38 87.6
Sulphur S 16 32.1
Uranium U 92 238.0
Tungsten W 74 183.9
Zinc Zn 30 65.4

2
 LIST OF SELECTED CONSTANT VALUES
SENARAI NILAI PEMALAR TERPILIH

Ionization constant for water at 25C Kw = 1.00 x 10−14 mol2 dm−6

Hasil darab ion bagi air pada 25C

Molar volume of gases Vm = 22.4 dm3 mol−1 at STP

Isi padu molar gas = 24 dm3 mol−1 at room temperature

Speed of light in a vacuum c = 3.0  108 m s−1

Laju cahaya dalam vakum

Specific heat of water = 4.18 kJ kg−1 K−1

Muatan haba tentu air = 4.18 J g−1 K-1
= 4.18 J g−1 C−1

Avogadro’s number NA = 6.02 x 1023 mol−1

Nombor Avogadro

Faraday constant F = 9.65 x 104 C mol−1

Pemalar Faraday

Planck constant h = 6.6256 x 10−34 J s

Pemalar Planck

Rydberg constant RH = 1.097 x 107 m−1

Pemalar Rydberg = 2.18 x 10−18 J

Ideal gas constant R = 8.314 J K−1 mol-1

Pemalar gas molar = 0.08206 L atm mol−1 K−1

Density of water at 25C = 1 g cm−3

Ketumpatan air

Freezing point of water = 0.00 C

Takat beku air

Vapour pressure of water Pwater = 23.8 torr

Tekanan wap air

UNIT AND CONVERSION FACTOR

UNIT DAN FAKTOR PERTUKARAN

Volume 1 liter = 1 dm3

Isi padu 1mL = 1 cm3

Energy 1 J = 1 kg m2 s−2 = 1 N m = 107 erg

Tenaga 1 calorie = 4.184 Joule
1eV = 1.602 x 10-19 J

Pressure 1 atm = 760 mm Hg = 760 torr = 101.325 k Pa = 101 325 N m-2

Tekanan

Others 1 Faraday (F) = 96 500 coulomb

Lain-lain 1 Newton (N) = 1 kg m s−2

3
Answer all the questions

1. (a) Table 1 shows the isotopes of magnesium, Mg with its percentage abundance and
isotopic mass.

Isotope Percentage abundance (%) Isotopic mass (u)

24Mg 78.99 23.985
25Mg X 24.986
26Mg 11.01 25.983
Table 1
If the average atomic mass of Mg is 24.31, calculate the percentage abundance, X of
25Mg.

[2 marks]
(b) A sample of vitamin C, which also known as ascorbic acid consists of carbon,
hydrogen and oxygen. If the complete combustion of 1.001 g of the compound
produced 1.503 g of CO2 and 0.414 g of H2O, determine the empirical formula of
the compound.
[4 marks]
(c) Hydrobromic acid, HBr solution contains 47.5 % HBr by mass and has a density of
1.30 g cm-3 at room temperature. Calculate the molarity of the HBr solution.
[4 marks]
(d) The following reaction takes place in acidic condition.
MnO4-(aq) + SO32-(aq) → MnO2(aq) + SO42-(aq)
Write a balance equation for the above reaction.
[3 marks]
(e) The fertiliser urea, (NH2)2CO is prepared by reacting ammonia, NH3 with carbon
dioxide, CO2 according to the following equation.
2NH3(g) + CO2(g) → (NH2)2CO(aq) + H2O(ɩ)
In an experiment, 0.62 mole of NH3 was added to 0.56 mole of CO2.
(i) Determine the limiting reactant.
(ii) Determine the amount (in gram) of (NH2)2CO formed.
(iii) Calculate the mass of excess reactant after the reaction.
[8 marks]

4
2. (a) Figure 1 below shows the line spectrum of hydrogen atom in the ultraviolet region.

A B
frequency increase
Figure 1
(i) Calculate the wavelength (in nm) of photon emitted to produce line B.
(ii) Calculate the energy of an electron at its excited state before it drops to produce
line A.
[4 marks]
2 2 6 2 6 2 1
(b) The electronic configuration of an atom C is 1s 2s 2p 3s 3p 4s 3d .
(i) Write a possible set of quantum numbers for the 12th electron.
(ii) Draw the shape of orbitals for the valence electron.
(iii) Determine the rule used to arrange the 6th and 7th electron in the 2p orbitals.
[4 marks]
(c) State the actual electronic configuration of copper. Explain why the expected
electronic configuration of copper is different from the actual electronic
configuration.
[2 marks]
3. (a) The suprachiasmatic nucleus, SCN is a bilateral structure use as the central
pacemaker of the circadian timing system and regulates most circadian rhythms in
the body. Two possible Lewis structure of SCN are given below:

S C N S C N
I II
(i) Show formal charge on each atom of structure I and II.
(ii) Determine the most plausible structure. Explain.
[3 marks]
(b) Illustrate the hybridization process in ozone, O3 and determine its molecular shape.
Draw and label the overlapping of the orbital.
[10 marks]
(c) Table 2 shows the molar mass and boiling point of NCl3 and BCl3.

Compound Molar mass (g mol-1) Boiling point (0C)

NCl3 120.5 71.0
BCl3 117.3 12.6

Table 2
Explain the difference in boiling point of the two compounds.
[2 marks]

5
 (d) Copper, Cu is a good electrical conductor while carbon, C in its diamond allotropes
is a poor electrical conductor. Discuss this statement based on band theory.
[2 marks]
4. (a) A vessel of 120 mL capacity contains a certain amount of gas D at 35 oC and 1.2
atm. The gas D is transferred to another vessel of volume 180 mL at the same
temperature. Calculate the pressure of the gas D at the new vessel.
[2 marks]
(b) A piece of solid carbon dioxide, CO2 with a mass of 5.50 g is placed in a 10.0 L
vessel that already contains air at 705 torr and 297.15 K. Determine the partial
pressure of CO2 and the total pressure, PT in the container at 297.15 K after the CO2
has totally vaporized.
[2 mark]
(c) Table 3 shows the boiling point for a few liquids.

Ethanal, Ethanol, Methanol,

Liquid
CH3CHO CH3CH2OH CH3OH
Boiling point / OC 20 78 65

Table 3

(i) Based on Table 3, arrange these liquids in order of increasing vapour pressure.
(ii) State the relationship between intermolecular forces and vapour pressure.
[2 marks]
(d) Figure 2 and Figure 3 shows the phase diagram of water, H2O and carbon dioxide,
CO2.

PressurePressure
(atm) (atm) Pressure (atm)

E F E F
Temperature (oC) Temperature (OC)
Figure 2: H2O Figure 3: CO2

(i) Compare the freezing/melting curve between H2O and CO2.

(ii) Explain the anomalous behavior of H2O.
(iii) State the kinetic energy changes from point F to E.
[3 marks]

6
5. A mixture of sulphur dioxide, SO2 and oxygen, O2 gas in a 1.0 L reaction vessel was
allowed to react at 700 K and produce sulphur trioxide, SO3 gas as the following equation.

2SO2 (g) + O2 (g) ⇌ 2SO3 (g) H = - 202.0 kJ

At any instant of mixing, the amount of SO2, O2 and SO3 are 0.010 mol, 0.010 mol and 10
mol respectively and the temperature maintained at 700 K. The equilibrium constant, K c
for this reaction is 4.3 x 106.
(a) Determine whether the reaction is at equilibrium at this temperature. If not, predict
to which direction will the reaction proceed.
[7 marks]
(b) Describe the effect of equilibrium position if temperature of the system is decrease.
[2 marks]
6. (a) Nitrous acid, HNO2 is used to make diazonium salts, which are widely used in the
preparation of azo dyes.
(i) An aqueous solution of 0.235 M HNO2 has a pH of 1.85. Calculate the
dissociation constant, Ka of this solution.
(ii) The pH of a buffer solution containing 0.235 M HNO2 and 0.240 M of sodium
nitrite, NaNO2 is 3.05. Calculate the pH when 0.01 mol of sodium hydroxide,
NaOH is added to 1.0 L of this buffer solution.
[8 marks]
(b) A student carried out a titration experiment at 25 oC by adding 0.1 M KOH into
conical flask containing 25 cm3 0.1 M HClO. Sketch a graph and label the
equivalence point on the graph.
[2 marks]
(c) The concentration of the Ag+ ion in a saturated solution of silver sulphate, Ag2SO4
at 298 K is 1.5 x 10-2 M. Calculate the solubility product, Ksp of Ag2SO4 at the same
temperature.
[4 marks]

END OF QUESTION PAPER

PREPARED BY: NFAG, FY, SBAH, REVISED BY: HES & SR APPROVED BY: KU
AMH, YM, & HH