ch_sp5

Godavari
Foundation’s
Godavari English Medium School, Jalgaon
Final Exam 2023-2024
Subject: Chemistry Class: XI
Date:20/03/24
Time Allowed: 3Hrs M.M. :

70 General Instructions :
i. All questions are compulsory.

ii. Q. No. 1 to 5 are very short answer type questions and carry one mark each.
iii. Q. No. 6 to 10 are very short answer type questions and carry two marks each.
iv. Q. No. 11 to 22 are short answer type questions and carry three marks each.
v. Q. No. 23 is value based questions carries four marks.
vi. Q. No. 24 to 26 are long answer type questions and carry five marks each.
vii. Use log tables, if necessary, use of calculator is not allowed.
1. Define limiting reagent

2. Write the general electronic configuration of d-block elements?
3. Write Vander Waal's equation for n moles of a real gas.
4. What is the state of hybridization of each carbon atom in C6H6?
5. Predict the sign of the entropy change for the following:
6.
i. Define Pauli’s exclusion principle.
ii. Write electronic configuration of an atom having 2K, 8L, 5M electrons.
Or
The mass of an electron is 9.1 x 10-31 kg. If its kinetic energy is 3.0 x 10-25 J. Calculate
its wavelength. (Given h = 6.626 x 10-34 J s)
7. The concentration of hydrogen ion in a sample of soft dark is 3.8 x 10-3 M. What is its pH
? (log 3.8 = 0.58)
8. What happens when (write equation only):
i. Beryllium carbide reacts with water.
ii. Sodium Sulphate solution is added to an aqueous solution of barium nitrate.
9. Propanal and Pentan-3-one are the ozonolysis product of an alkene. What is the
structural formula of the alkene?
10. Write reactions to justify amphoteric nature of aluminium.
11.
a. Write the IUPAC name of the following:
i.
ii.
b. Which isomerism is shown by following pair of compounds:

CH3COOH and HCOOCH3
12. Account for the following:

a. An anion is always bigger than its present atom.
b. Chlorine (Cl) has move negative electron gain enthalpy the fluorine (F).
c. Noble gases have positive electron gain enthalpy.
OR
What happen when:
a. Boric acid is added to water.
b. Al is treated with dil. NaOH.
c. BF3 is treated with NH3
13. Give the shapes of following covalent molecules using VSEPR theory:
i. PCI5
ii. BrF3
iii. H2O
14. A sample of drinking water was found to be severely contaminated with chloroform
CHCl3, supposed to be carcinogen. The level on contamination was 15 ppm (by mass).
i. Express this in percent by mass.

ii. Determine the molality of chloroform in the water sample.
15.
a. State Hess's law.
b. Use standard enthalpies of formation, calculate the value of for the reaction.
16.
a. The molecular orbital theory to predict why the BE molecule does not exist.
b. Compare the stability of and O2 on the basis of M.O. theory.
17.
a. Calculate the total pressure in a mixture of 8g of oxygen and 4g of hydrogen confined
in a vessel of 1 dm3 at 27°C.
Given R = 0.083 bar dm3 K-1 mol-1

b. Criticial temperature of CO2 and CH4 are 31.1°C and - 81.9°C respectively. Which of
there has stronger intermolecular forces and why?
Or
a. What would be the S.I. units of a quantity PV2T2/n ?
b. Calculate the temperature of 4.0 moles of a gas occupying 5 dm3 at 3.32 bar (R= 0.083
bar dm3 K-1 mol-1)

18.
a. What is the oxidation no. of Cr. in ?
b. Balance the equation: (Acidic medium)
19. Complete the following chemical reactions.
a.
b.
c.
20. Give reason for the following:
a. PbCl4 is a powerful oxidising agent.
b. Graphite acts as a good lubricant.

c. Boron halides don't dimerise like BH3
21.
a. Draw the structure of (i) BeCl2 (vapour) and (ii) BeCl2 solid
b. Complete the equation:

22. Arrange the following in order of property mentioned against each:
a.
(increasing order of stability)

b. HCOOH, CH3COOH, CH3CH2COOH (Increasing acidic strength)
c.
Value Based Questions
23. Environmental pollution is causing a serious threat on the earth. Due to combustion of
fossil fuels, a number of poisonous and harmful gases enter into the atmosphere. Every
country has made strict laws for industries and individual citizens to keeps pollution
under control.
Now answer the following questions:
a. Why is it advised not to sleep with burning coke angithi in a closed room on winter
nights?
b. What does the combustion of motor fuels cause pollution of the atmosphere?
c. Name one natural source and one human activity by which SO2, enters into
atmosphere?
24.
a. Explain the following with example:
i. Common ion effect
ii. Buffer solution.
b. At a certain temperature and total pressure of 105 Pa, iodine vapours contains 40% by
volume of I atoms.
Calculate Kp for the equilibrium.

Or
a. Define Le- Chatelier's principle.
b. What is the hybridisation of the central tom in (i) H3O+, (ii) XeF2, (iii) XeF4 ? What
are their shapes
c. Equilibrium constant for the reason is 4.0. What will be the equilibrium constant
for the reverse reaction.
d. Calculate the pH of 10-8 M HCl solution.

25.
a. Define Heisenberg's uncertainty principle. Write its mathematical expression.
b. Calculate the uncertainty in the velocity of a cricket ball on mass 150 g. If the
uncertainty in its position is of the order of 1 .
(h = 6.6 x 10-34 Kg m2s-1)
Or
a. Which of the following orbitals are not possible

1p, 2s, 2p, 3S
b. Which of the following sets of quantum number are not possible? Give reasons.
i. n = 0, l = 0, ml = 0, ms = +1/2
ii. n = 1, l = 0, ml = 0, ms = -1/2
c. Electrons are emitted with zero velocity from a metal surface when it is expressed to
radiation of wavelength . Calculate threshold frequency and work

function of the metal.
26.
a. Define the following with example:
i. Wurtz reaction
ii. Markovnikoff’s Rule.
b. Give the main product of the region:
i.
ii.
iii.
Or
a. How can you convert the following:

i. Propan-1-ol to propan-2-ol
ii. Ethyl chloride to n-Butane
b. Complete the following reactions:
i.
ii.
iii.

ch_sp5

Uploaded by

Copyright:

Available Formats

ch_sp5

Uploaded by

Document Information

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

ch_sp5

Uploaded by

Copyright:

Available Formats

Godavari

Time Allowed: 3Hrs M.M. :

i. All questions are compulsory.

1. Define limiting reagent

5. Predict the sign of the entropy change for the following:

its wavelength. (Given h = 6.626 x 10-34 J s)

b. Which isomerism is shown by following pair of compounds:

12. Account for the following:

i. Express this in percent by mass.

b. Compare the stability of and O2 on the basis of M.O. theory.

in a vessel of 1 dm3 at 27°C.

Given R = 0.083 bar dm3 K-1 mol-1

there has stronger intermolecular forces and why?

a. What would be the S.I. units of a quantity PV2T2/n ?

bar dm3 K-1 mol-1)

b. Graphite acts as a good lubricant.

b. Complete the equation:

(increasing order of stability)

Value Based Questions

Calculate Kp for the equilibrium.

a. Define Le- Chatelier's principle.

are their shapes

d. Calculate the pH of 10-8 M HCl solution.

uncertainty in its position is of the order of 1 .

(h = 6.6 x 10-34 Kg m2s-1)

a. Which of the following orbitals are not possible

radiation of wavelength . Calculate threshold frequency and work

a. How can you convert the following:

You might also like