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Chemistry for IIT-JEE, NEET, & Foundation Courses

Periodic Table (11th)

Repeaters-2024
Classification of Elements & Periodicity in properties
01. The number of elements present in fifth period is : 11. Consider the following electronic configuration of an
(A) 18 (B) 32 (C) 8 (D) 24 element (P) :
[Xe]4f145d16s2
02. Which of the following sets of atomic numbers
corresponds to elements of group 16 ? Then correct statement about element ‘P’ is :
(A) 8, 16, 32, 54 (B) 16, 34, 54, 86 (A) It belongs to 6th period and 1st group
(C) 8, 16, 34, 52 (D) 10, 16, 32, 50 (B) It belongs to 6th period and 2nd group
(C) It belongs to 6th period and 3rd group
03. The atomic numbers of the metallic and non-metallic
elements which are liquid at room temperature (D) None of these
respectively are : 12. If IUPAC name of an element is “unununium” then
(A) 55, 87 (B) 33, 87 correct statement regarding element is :
(C) 35, 80 (D) 80, 35 (A) It is a inner transition element
04. Give the symbol of the elements of lowest atomic (B) It belongs to 8th period in periodic table
number that has three 2p electrons : (C) It is transition element
(A) Mg (B) P (C) N (D) Si
(D) It is a non-transition element
05. In the fourth period of the periodic table, how many
13. Which of the following metal is expected to have the
elements have one or more 4d electrons ?
highest third ionization enthalpy ?
(A) 2 (B) 18 (C) 0 (D) 6
(A) Cr (Z = 24) (B) V (Z = 23)
06. What would be the atomic number of the alkaline
earth metal of the eighth period ? (C) Mn (Z = 25) (D) Fe (Z = 26)
(A) 113 (B) 120 (C) 119 (D) 106 14. Which of the following isoelectronic ion has the lowest
ionization energy ?
07. Which one of the following is a different pair ?
(A) K+ (B) Cl−
(A) Li, Na (B) Be, Ba
(C) Ca2+ (D) S 2−
(C) N, As (D) O, At
15. The correct order of atomic/ionic radii is :
08. The element having electronic configuration
[Kr]4d104f14,5s25p6,6s2 belongs to : (A) Sc > Ti > V > Cr (B) Co > Ni > Cu > Zn
2− − 2− 3−
(A) s-block (B) p-block (C) S >Cl >O >N (D) None of these
(C) d-block (D) f-block 16. Radius of which ion is closest to that of Li + ion ?
09. The period number and group number of “Tantalum” (A) Na+ (B) Be2+ (C) Mg2+ (D) Al3+
(Z = 73) are respectively : 17. The correct order of increasing radius of the elements Si,
(A) 5, 7 Al, Na and P is :
(B) 6, 13 (A) Si < Al < P < Na (B) P < Si < Al < Na
(C) 6, 5 (C) Al < Si < P < Na (D) Al < P < Si < Na
(D) None of these 18. The correct order of I.E.2. is :
10. Which of the following pair of elements belong to (A) Na > F > O > N (B) O > F > Ne > N
the same period ? (C) Ne > O > F > N (D) O > Ne > F > N
(A) Mg and Sr 19. The atomic number of element unnilennium is :
(B) Ca and Zn (A) 109 (B) 102
(C) Na and Ca (C) 108 (D) 119
(D) Ca and Cl
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20. The elements with atomic numbers 101 and 104 29. Identify the elements X and Y using ionization energy
belong to, respectively : values given below.
(A) group 6 and actinoids Ionization energy (kJ/mol) :
(B) actinoids and group 4 1st 2nd
(C) group 11 and group 4 X 495 4563
(D) actinoids and group 6 Y 731 1450
21. The set that contains atomic numbers of only (A) X = Mg ; Y = Na (B) X = Mg ; Y = F
transition elements, is :
(C) X = Na ; Y = Mg (D) X = F ; Y = Mg
(A) 37, 42, 50, 64 (B) 21, 25, 42, 72
30. The ionic radius of Na+ ion is 1.02 Å. The ionic radii
(C) 9, 17, 34, 38 (D) 21, 32, 53, 64 (in Å) of Mg2+ and Al3+, respectively are :
22. The IUPAC symbol for the element with atomic (A) 1.05 and 0.99 (B) 0.68 and 0.72
number 119 would be :
(C) 0.85 and 0.99 (D) 0.72 and 0.54
(A) une
31. The first ionization energy of magnesium is smaller as
(B) unh compared to that of elements X and Y, but higher than
(C) uun that of Z. The elements X, Y and Z, respectively are :
(D) uue (A) Neon, Sodium and Chlorine
23. In the long form of the periodic table, the valence (B) Argon, Lithium and Sodium
shell electronic configuration of 5s25p4 corresponds (C) Chlorine, Lithium and Sodium
to the element present in :
(D) Argon, Chlorine and Sodium
(A) Group 16 and period 6
32. Consider the elements Mg, Al, S, P and Si, the correct
(B) Group 17 and period 5 increasing order of their first ionization enthalpy is :
(C) Group 16 and period 5 (A) Al < Mg < S < Si < P (B) Mg < Al < Si < S < P
(D) Group 17 and period 6 (C) Al < Mg < Si < S < P (D) Mg < Al < Si < P < S
24. The element with Z = 120 (not yet discovered) will 33. Match List-I with List-II.
be an/a :
Electronic config. ∆iH
(A) Inner-transition (B) Alkaline earth
(a) 1s2 2s2 (i) 801
(C) Alkali metal (D) Transition metal 2 2 4
(b) 1s 2s 2p (ii) 899
25. The group number, number of valence electrons, and 2 2 3
valency of an element with atomic number 15, (c) 1s 2s 2p (iii) 1314
2 2 1
respectively, are : (d) 1s 2s 2p (iv) 1402
(A) 15, 5 and 3 (B) 15, 6 and 2 Choose the most appropriate answer from the options
(C) 16, 5 and 2 (D) 16, 6 and 3 given below.
26. The correct order of ionic radii for the ions, P 3− , (A) (a) –(i), (b) –(iii), (c) –(iv), (d) –(ii)
S 2− , Ca2+, K+, Cl− is : (B) (a) –(i), (b) –(iv), (c) –(iii), (d) –(ii)
(A) P 3− > S 2− > Cl− > K+ > Ca2+ (C) (a) –(ii), (b) –(iii), (c) –(iv), (d) –(i)
(B) P 3− > S 2− > Cl− > Ca2+ > K+ (D) (a) –(iv), (b) –(i), (c) –(ii), (d) –(iii)
(C) Cl− > S 2− > P 3− > Ca2+ > K+ 34. Considering the elements B, Al, Mg, and K, the correct
(D) K+ > Ca2+ > P 3− > S 2− > Cl− order of their metallic character is :
27. First ionization enthalpy values of the third period (A) B > Al > Mg > K (B) Al > Mg > B > K
elements Na, Mg and Si are respectively 496, 737 (C) Mg > Al > K > B (D) K > Mg > Al > B
and 786 kJ/mol. Then first ∆iH for Al is : 35. Considering the elements F, Cl, O and N, the correct
(A) In between 496 & 737 order of their chemical reactivity in terms of oxidizing
(B) In between 737 & 786 property is :
(C) Close to 786 (A) F > Cl > O > N (B) F > O > Cl > N
(C) Cl > F > O > N (D) O > F > N > Cl
(D) Less than 496
36. The atomic radius of Ag is closest to :
28. Ionic radii of F − & O2− respectively are 1.33 Å and
1.4 Å, while covalent radius of N is 0.74 Å. The (A) Au (B) Ni (C) Hg (D) Cu
correct statement for the ionic radius of N 3− from 37. The first ionization energy (in kJ/mol) of Na, Mg, Al
the following is : and Si respectively, are :
(A) It is bigger than F − and N but smaller than of O2− (A) 496, 737, 577, 786
2− −
(B) It is bigger than O and F (B) 496, 577, 737, 786
2− −
(C) It is smaller than O and F but bigger than of N (C) 496, 577, 786, 737
−
(D) It is smaller than F and N (D) 786, 737, 577, 496
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38. The increasing order of the atomic radii of the 47. The increasing order of the first ionisation enthalpies of
following elements is : the elements B, P, S and F (lowest first) is :
(a) C (b) O (c) F (d) Cl (e) Br (A) F < S < P < B (B) P < S < B < F
(A) (a) < (b) < (c) < (d) < (e) (C) B < P < S < F (D) B < S < P < F
(B) (c) < (b) < (a) < (d) < (e) 48. Which one of the following sets of ions represents a
(C) (d) < (c) < (b) < (a) < (e) collection of isoelectronic species ?
(D) (b) < (c) < (d) < (a) < (e) (A) K+, Cl− , Ca2+, Sc3+ (B) Ba2+, Sr2+, K+, S 2−
39. B has a smaller first ionization enthalpy than Be. (C) N 3− , O2− , F − , S 2− (D) Li+, Na+, Mg2+, Ca2+
Consider the following statements 49. Which one of the following statements is incorrect in
(I) It is easier to remove 2p electron than 2s relation to ionization enthalpy?
electron (A) Ionization enthalpy increases for each
(II) 2p electron of B is more shielded from the successive electron.
nucleus by the inner core electrons than the (B) The greatest increase in ionization enthalpy is
2s electrons of Be experienced on the removal of an electron from
(III) 2s electron has more penetration power than core noble gas configuration.
2p electron (C) End of valence electrons is marked by a big jump
(IV) Atomic radius of B is more than Be. in ionization enthalpy.
The correct statements are : (D) Removal of an electron from orbitals bearing lower
(A) I, II and III (B) II, III and IV n value is easier than from orbital having higher n
(C) I, III and IV (D) I, II and IV value
40. The isoelectronic set of ions is : 50. Which one of the following ions has the highest value
of ionic radius ?
(A) N 3− , Li+, Mg2+ , O2− (B) N 3− , O2− , F − , Na+
(A) Li+ (B) B3+ (C) O2− (D) F −
(C) Li+, Na+, O2− , F − (D) F − , Li+, Na+ , Mg2+
51. Incorrect statement is/are :
41. The correct order of the atomic radii of C, Cs, Al
and S is : (i) SO3 > P2O5 > SiO2 > Na2O (acidic strength)
(A) C < S < Cs < Al (ii) CO, NO and N2O all are neutral oxides
(B) S < C < Al < Cs (iii) In [AlCl(H2O)5]+2, covalency of ‘Al’ is 6
(C) S < C < Cs < Al (iv) F > Cl > S > P (∆Heg)
(D) C < S < Al < Cs (A) iii and iv (B) i, ii, ii
42. The ionic radii (in Å) of N 3− , O2− and F − are (C) Only iv (D) i and iv
respectively : 52. Outermost electronic configuration of a group 13
(A) 1.71, 1.40 & 1.36 (B) 1.71, 1.36 & 1.40 element, E, is 4s2, 4p1. The electronic configuration of
an element of p-block period-five placed diagonally to
(C) 1.36, 1.40 & 1.71 (D) 1.36, 1.71 & 1.40 element, E is :
43. The correct order of atomic radii is : (A) [Xe] 5d10 6s2 6p2 (B) [Ar] 3d10 4s2 4p2
(A) Ce > Eu > Ho > N (B) Ho > N > Eu > Ce (C) [Kr] 3d10 4s2 4p2 (D) [Kr] 4d10 5s2 5p2
(C) Eu > Ce > Ho > N (D) N > Ce > Eu > Ho 53. Which one of the following statements for D.I.
44. Which of the following represents the correct order Mendeleev, is incorrect ?
of increasing first ionization enthalpy for Ca, Ba, (A) Element with atomic number 101 is named after him
S, Se and Ar ?
(B) He authored the textbook-Principles of Chemistry
(A) Ca < Ba < S < Se < Ar
(C) He invented accurate barometer
(B) Ca < S < Ba < Se < Ar
(C) S < Se < Ca < Ba < Ar (D) At the time, he proposed Periodic Table of
elements, structure of atom was known
(D) Ba < Ca < Se < S < Ar
54. According to the periodic law of elements, the variation
45. The increasing order of the ionic radii of the given in properties of elements is related to their :
isoelectronic species is :
(A) Atomic masses
(A) S 2− , Cl− , Ca2+, K+ (B) Ca2+, K+, Cl− , S 2−
(B) Nuclear masses
(C) K+, S 2− , Ca2+, Cl− (D) Cl− , Ca2+, K+ , S 2−
(C) Atomic numbers
46. Considering the elements B, C, N, F, and Si, the
correct order of their non-metallic character is : (D) Nuclear neutron-proton number ratios
(A) B > C > Si > N > F 55. Given below are two statements : One is labelled as
Assertion (A) & the other is labelled as Reason (R)
(B) Si > C > B > N > F
(C) F > N > C > B > Si Assertion(A) : Metallic character decreases and non-
metallic character increases on moving
(D) F > N > C > Si > B from left to right in a period.
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Reason (R) : It is due to increase in ionization 63. Which electronic configuration does not belongs to
enthalpy and decrease in electron gain lanthanoids –
enthalpy, when one moves from left to (A) (Xe) 6s2 4f 7 5d1 (B) (Xe) 6s2 4f 14 5d1
right in a period.
(C) (Xe) 6s2 4f 1 5d1 (D) (Xe) 6s2 4f 14 5d2
In the light of the above statements, choose the most
appropriate answer from the options given below. 64. Match the Column (I) with Column (II) :
(A) Assertion is false but reason is true Column (I) Column (II)
(i) (Kr) 5s2 4d10 (P) Ce
(B) Both assertion and reason are correct and reason (ii) (Xe) 6s2 4f1 5d1 (Q) Pd
is the correct explanation of assertion (iii) (Kr) 4d10 (R) Cu
(C) Both assertion and reason are correct but reason (iv) (Ar) 4s1 3d10 (S) Cd
is not the correct explanation of assertion Code (i) (ii) (iii) (iv)
(D) Assertion is true but reason is false (A) S P R Q
56. In general, the property (magnitudes only) that (B) S Q P R
shows an opposite trend in comparison to other (C) S P Q R
properties across a period is :
(D) P S Q R
(A) Ionization enthalpy (B) Electronegativity
65. Number of incorrect statement(s) is/are –
(C) ∆Heg (D) Atomic radius
(i) IE2 of Cu is more than Zn
57. The five successive ionization enthalpies of an
element are 800, 2427, 3658, 25024 and 32824 kJ (ii) IE3 of Al is more than Mg
mol−1 . The number of valence electrons in the (iii) IE1 of Mg is more than Si
element is :
(iv) IE2 of Mg is more than Na
(A) 5 (B) 4
(v) IE of Be is more than C
(C) 3 (D) 2
(A) 4 (B) 5 (C) 3 (D) 2
58. Consider the following ionization enthalpies of two
elements ‘A’ and ‘B’ : 66. Which pair of elements are called Transuranium
element –
Element Ionization enthalpy (kJ/mol)
(A) Th, Pa (B) Np, Nd
1st 2nd 3rd
(C) Gm, Gd (D) Am, Fm
A 899 1757 14847
67. Atomic radius of Cl2 is ?
B 737 1450 7731
(Bond distance in the chlorine molecule (Cl2) is 198 pm)
Which of the following statement is CORRECT ?
(A) Both ‘A’ and ‘B’ belong to group-2 where (A) More than 99 pm (B) Equal to 99 pm
‘A’ comes below ‘B’ (C) Equal to 100 pm (D) Less than 99 pm
(B) Both ‘A’ and ‘B’ belong to group-2 where 68. Correct code is :
‘B’ comes below ‘A’
(i) Li > At > I > Br > Cl > F (atomic radii)
(C) Both ‘A’ and ‘B’ belong to group-1 where
‘B’ comes below ‘A’ (ii) H > Li > Na > K > Rb > Cs (∆Heg)
(D) Both ‘A’ and ‘B’ belong to group-1 where (iii) F > Cl > Br > I > At (∆Heg)
‘A’ comes below ‘B’ (iv) Cl > F > S > O (∆Heg)
59. The following statements concern elements in the (v) Al > Mg > Na (EN)
periodic table. Which of the following is TRUE ?
(A) T T F T T (B) F T F T T
(A) For group 15 elements, the stability of +5
oxidation state increases down the group (C) F F F F F (D) T T F T F
(B) Elements of group 16 have lower ionization 69. P, Q, R and S in the given fig is –
enthalpy values compared to those of group
15 in the corresponding periods
Ne
(C) The group 13 elements are all metals
(D) All the elements in group 17 are gases ΔHi R F
60. Symbol for atomic number 107 is : S
P C
(A) Rf (B) Bh (C) Sg (D) Hs
Li Q
61. IUPAC name of ‘Rg’ is :
At. No
(A) Ununnilium (B) Unnilunium
(A) P = Be, Q = B, R = O, S = N
(C) Unununium (D) Ununquadium
(B) P = B, Q = Be, R = N, S = O
62. Number of unpaired electrons present in ‘Cr’ and
‘Cu’ are respectively – (C) P = Be, Q = B, R = N, S = O
(A) 5, 1 (B) 6, 1 (C) 5, 2 (D) 6, 2 (D) P = B, Q = Be, R = O, S = N

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70. The energy required to convert all atoms present in P Q R S
1.2 g magnesium to Mg2+ ions if IE1, and IE2 of (A) 3 1 4 2
magnesium are 120 kJ mol−1 and 240 (B) 1 3 4 2
−1
kJ mol respectively.
(C) 1 3 2 4
(A) 18 kJ mol−1 (B) 36 kJ mol−1 (D) 3 1 2 4
(C) 360 kJ mol−1 (D) 24 kJ mol−1 05. Pair of noble gases having identical ΔHeg is –
Answer Key (A) Ne, He (B) Ne, Ar
01 A 26 A 51 C (C) Kr, Xe (D) Ar, Kr
02 C 27 A 52 D
03 D 28 B 53 D 06. Correct option is –
04 C 29 C 54 C (A) IE2 of Mg is more than Al
05 C 30 D 55 D
(B) IE1 of K is more than Ca
06 B 31 D 56 D
07 D 32 C 57 C (C) IE2 of P is more than S
08 D 33 C 58 B (D) IE1 of Cl is more than P
09 C 34 D 59 B
10 B 35 B 60 B
07. Sum of unpaired electrons in the given ions, is –
11 C 36 A 61 C Cu+, V+2, Mn+3, Ti+2, Co+3 , Sc+3 , Zn+2
12 C 37 A 62 B (A) 11 (B) 12 (C) 13 (D) 14
13 C 38 B 63 D
14 D 39 A 64 C 08. Correct set of IUPAC symbol for Hs, Rf, Md & Rg is –
15 A 40 B 65 A (A) Uno, Unq, Unu, Uuu (B) Unq, Uno, Uue, Uuu
16 C 41 D 66 D (C) Uno, Unq, Unu, Une (D) Une, Unq, Unu, Uuu
17 B 42 A 67 B
18 C 43 C 68 A 09. Match the column I with column II –
19 A 44 D 69 C Column I (Atomic no) Column II (Block)
20 B 45 B 70 A
21 B 46 A (P) 50 (1) f – block
22 D 47 D
23 C 48 A (Q) 60 (2) d – block
24 B 49 D (R) 75 (3) p – block
25 A 50 C
(A) P → 3, Q → 2, R → 1
(B) P → 3, Q → 1, R → 2
Sample Paper (NEET-2024) (C) P → 1, Q → 3, R → 2
01. In which of the following pair of elements difference in (D) P → 1, Q → 2, R → 3
electronegativity is maximum – 10. Assertion (A) – Atomic radii of Al is 143pm which is
(A) Cs, I (B) Rb, K (C) Li, Si (D) B, Al more than Ga (134 pm)
02. Which one of the following statements is incorrect in Reason (R) – In 4th Period , 3d-orbitals gives poor
relation to ionization enthalpy ? shielding effect
(A) Ionization enthalpy increases for each successive (A) (A) and (R) both are correct statements but reason
electron is not correct explanation for assertion.
(B) The greatest increase in ionization enthalpy is (B) (A) and (R) both are correct statements and reason
experienced on removal of electron from core is correct explanation for assertion.
noble gas configuration (C) (A) and (R) both are wrong.
(C) End of valence electrons is marked by a big jump (D) (A) is wrong but (R) is correct
in ionization enthalpy 11. Correct order of EN is –
(D) Removal of electron from orbitals bearing lower n (A) S > O > Si > P > Cl (B) O > Cl > S > Si > P
value is easier than from orbital having higher n (C) O > Cl > S > P > Si (D) Cl > O > P > Si > S
value 12. Assertion : Electron gain enthalpy of ‘O’ or ‘F’ is less
03. Consider the following statements – negative than that of the succeeding
I. 2p electrons of B is more shielded from the nucleus element (S & Cl).
by the inner core electrons than 2s electrons of Be Reason : When one electron is added to ‘O’ or ‘F’,
II. 2p electrons has more penetration power than added electron suffers significant repulsion
2s-electrons from other electrons present in this level.
(A) Only I is incorrect (B) Only II is incorrect (A) (A) and (R) both are correct statements but reason
(C) Both are incorrect (D) Both are correct is not correct explanation for assertion.
04. Match the column I with column II – (B) (A) and (R) both are correct statements and reason
Column I Column II is correct explanation for assertion.
P. Br > I > S > O 1. EN (C) (A) and (R) both are wrong.
(D) (A) is wrong but (R) is correct
Q. F > Cl > Br > I 2. IE 13. Correct order of ∆egH is –
R. Li > Be > B > C 3. ΔHeg (A) Cl > Se > Te > F > O (B) F > Cl > Se > Te > O
S. F>N>O>C 4. Size (C) F > Se > Te > Cl > O (D) Cl > F > Se > Te > O

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14. Select appropriate answer for the given IUPAC names – (A) a → i , b → ii , c → iii , d → iv
(I) IUPAC name of “Sg” is Unnilhexium (B) a → ii , b → i , c → iv , d → iii
(II) IUPAC name of “Md” is Unnilunium (C) a → ii , b → iv , c → i , d → iii
(III) IUPAC name of “Rf” is Ununquadium (D) a → iv , b → i, c → iii , d → ii
(IV) IUPAC name of “Rg” is Unununium 22. Assertion (A) : Electron gain enthalpy becomes less
(A) all are correct negative as we go down a group.
(B) all are correct except (I) Reason (R) : Size of the atom increases on going down
(C) all are correct except (III)
the group and the added electron would
(D) all are correct except (II)
15. IE2 of Na, Mg, Al are in the order – be farther from the nucleus.
(A) Na > Mg > Al (B) Na > Al > Mg (A) (A) and (R) both are correct statements but reason
(C) Mg > Al > Na (D) Mg > Na > Al is not correct explanation for assertion.
16. Maximum difference in atomic radius is in – (B) (A) and (R) both are correct statements and reason
(A) C , O (B) C , F (C) Be , B (D) Li , O is correct explanation for assertion.
17. Electronic configuration of ‘Cr’, ‘Mn’ and ‘Gd’ are (C) (A) and (R) both are wrong.
respectively- (D) (A) is wrong but (R) is correct
(A) [Ar] 4s1 3d5 , [Ar] 4s2 3d5 , [Xe] 6s2 4f7 5d1 23. Assertion : Electron-electron repulsion in 2p subshell
(B) [Ar] 4s2 3d4 , [Ar] 4s2 3d5 , [Xe] 6s2 4f7 5d1 of Oxygen is more than Nitrogen
(C) [Ar] 4s1 4p5, [Ar] 4s2 4p5 , [Xe] 6s2 4f8 Reason : 2p electrons of oxygen is more shielded
(D) [Ar] 4s1 3d5 , [Ar] 4s1 3d6 , [Xe] 6s2 4f7 5d1 than 2p electrons of nitrogen
18. Consider the given two statements – (A) (A) and (R) both are correct statements but reason
(I) Cr+3 & Fe+3 both contains equal number of unpaired is not correct explanation for assertion.
electrons. (B) (A) and (R) both are correct statements and reason
(II) Ce+3, Pr+3 & Nd+3 all are Paramagnetic. Then – is correct explanation for assertion.
(A) Both are correct (B) only I is correct (C) (A) is correct but (R) is wrong.
(C) only II is correct (D) Both are incorrect (D) (A) is wrong but (R) is correct
19. Which of the following species will have the 24. The number of d-electrons in Fe2+ (Z = 26) is not equal
largest and the smallest size? Mg, Mg+2, Al, Al3+ to the number of electrons that are mentioned in which
(A) largest – Al , smallest – Al+3 one of the following –
(B) largest – Mg , smallest – Al+3 (A) total p-electrons in Cl (Z = 17)
(C) largest – Mg+2 , smallest – Al (B) total d-electrons in Fe (Z = 26)
(D) largest – Mg , smallest – Mg+2 (C) total p-electrons in Ne (Z = 10)
20. Electronic configurations of some elements is given in (D) total s-electrons in Mg (Z = 12)
column I and electron gain enthalpies are given in 25. Assertion : Members of the noble gas family are very
column II. Match the configuration with electron gain little reactive chemically.
enthalpy. Reason : Members of the noble gas family have
Column (I) Column (II) completely filled valence shells of their
Elec. Config. ΔHeg kJ mol-1 atoms.
(A) (A) and (R) both are correct statements but reason
(a) 1s2 2s2 2p6 (i) – 53 is not correct explanation for assertion.
2 2 6 1
(b) 1s 2s 2p 3s (ii) – 328 (B) (A) and (R) both are correct statements and reason
(c) 1s2 2s2 2p5 (iii) – 141 is correct explanation for assertion.
2 2 4 (C) (A) and (R) both are wrong.
(d) 1s 2s 2p (iv) + 116
(D) (A) is wrong but (R) is correct
(A) a → i , b → ii , c → iii , d → iv 26. Assertion : Negative electron gain enthalpy of oxygen
(B) a → iv , b → iii , c → i , d → ii is less than that of fluorine but greater than
(C) a → iv , b → i , c → ii , d → iii that of nitrogen.
(D) a → iv , b → i, c → iii , d → ii Reason : IE follow the order N >O >F
21. Match the correct ionisation enthalpies and electron (A) (A) and (R) both are correct statements but reason
gain enthalpies of following elements. is not correct explanation for assertion.
Element ∆H1 ∆H2 ∆egH (B) (A) and (R) both are correct statements and reason
(a) Most reactive (i) 419 3051 - 48 is correct explanation for assertion.
non-metal (C) (A) is correct but (R) is wrong.
(b) Most reaction metal (ii) 1681 3374 - 328 (D) (A) is wrong but (R) is correct
27. Set containing isoelectronic species is –
(c) Least reactive (iii) 738 1451 - 40
(A) C22- , NO+ , CN- , O22+ (B) CO , NO , O2 , CN-
element
(C) CO2 , NO2 , O2 , N2O5 (D) CO , CO2 , NO , NO2
(d) Metal forming binary (iv) 2372 5251 + 48
halide
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28. For one of the elements, various successive ionization 34. The correct sequence which shows decreasing order of
enthalpies (in kJ mol-1) are given below: the ionic radii of the elements is :
I.E. 1st 2nd 3rd 4th 5th (A) Al3+ > Mg2+ > Na+ > F- > O2-
577.5 1810 2750 11,580 14,820 (B) Na+ > Mg2+ > Al3+ > O2- > F-
The element is – (C) Na+ > F- > Mg2+ > O2- > Al3+
(D) O2– > F- > Na+ > Mg2+ > Al3+
(A) P (B) Mg (C) Si (D) Al
+3 +3 +3 +3 35. Match the element in Column I with its
29. Arrange Ce , La , Pm and Yb in increasing order
electronegativity on the pauling scale in Column II.
of their size
Selection the correct match.
(A) Yb+3 < Pm+3 < Ce+3 < La+3
Column- I Column-II
(B) Ce+3 < Yb+3 < Pm+3 < La+3
(C) Yb+3 < Pm+3 < La+3 < Ce+3 (P) Carbon (1) 0.7
(D) Pm+3 < La+3 < Ce+3 < Yb+3 (Q) Nitrogen (2) 1.6
30. Match the atomic numbers of the elements with the (R) Aluminium (3) 2.5
period to which they belong. Select the correct match. (S) Cesium (4) 3.0
(Atomic number) (Period) P Q R S
(P) 31 (1) 5
(A) 2 3 4 1
(Q) 50 (2) 3
(R) 56 (3) 4 (B) 4 3 1 2
(S) 14 (4) 6
(C) 3 4 2 1
p Q R S
(A) 4 3 1 2 (D) 4 1 2 3
(B) 2 4 1 3 Section - B : Attempt Any 10 out of 15
(C) 3 4 2 1 36. Correct statements is/are-
(D) 3 1 4 2 (1) Electron configuration of ‘Gd’ is [Xe] 6s24f7
31. Match the elements in Column I with their (2) Electron configuration of ‘Cm’ is [Rn] 7s24f8
characteristics in column II. Select the correct match. (3) Electron configuration of ‘Fm’ is [Rn] 7s2 4f12
(P) Copper (1) Non-metal (4) Electron configuration of ‘Yb’ is [Xe] 6s2 4f14
(Q) Fluorine (2) Transition (A) all are correct
(R) Silicon (3) Lanthanoid (B) 3 and 4
(S) Cerium (4) Metalloid (C) 2 and 3
P Q R S (D) 2, 3 and 4
37. The molecular formula of chloride EKa – Aluminium
(A) 4 3 2 1
and EKa – Silicon respectively are –
(B) 3 1 2 3 (A) GaCl3 and SiCl4
(C) 2 1 4 3 (B) GaCl3 and AlCl3
(D) 3 4 2 1 (C) AlCl3 and SiCl4
(D) GaCl3 and GeCl4
32. The electronegativity of the elements increases in the 38. The IUPAC nomenclature of an element with electronic
order – configuration [Rn] 5f14 6d1 7s2 is :
(A) C, N, Si, P (B) N, Si, C, P (A) Unnilbium (B) Unnilunium
(C) Si, P, C, N, (D) P, Si, N, C (C) Unnilquadium (D) Unniltrium
33. Match the family of elements in Column I with 39. Modern periodic table is based on the atomic number of
corresponding metals in Column II. Select the correct the elements. The experiment which proved the
match– significance of the atomic number was
(P) Noble gas (1) Gold (A) Millikan’s oil drop experiment
(B) Mosley’s work on X- ray spectra
(Q) Representative elements (2) Uranium
(C) Bragg’s work on X- ray diffraction
(R) Transition elements (3) Radon (D) Discovery of X- ray by Rontgen
(S) Inner transition elements (4) Nitrogen 40. Covalent radii of atoms varies in range of 72 pm to
P Q R S 133 pm from F to I while that of noble gases He to Xe
varies from 120 pm to 220 pm. This is because in case
(A) 3 4 1 2 of noble gases
(B) 4 1 2 3 (A) Covalent radius is very large
(B) Van der waal radius is considered
(C) 4 3 2 1 (C) Metallic radii is considered
(D) 1 2 3 4 (D) None of these
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41. Which of the following sequence correctly represents the 47. Number of exothermic reaction(s) is/are –
decreasing acidic nature of oxides?  F(g) + e- → F-(g)
(A) Li2O > BeO > B2O3 > CO2 > N2O3  S(g) + e- → S-(g)
(B) N2O3 > CO2 > B2O3 > BeO > Li2O  Cl(g) + e- → Cl-(g)
(C) CO2 > N2O3 > B2O3 > BeO > Li2O  O-(g) + e- → O-2(g)
(D) B2O3 > CO2 > N2O3 > Li2O > BeO  Ne(g) + e- → Ne-(g)
42. Match the following :  H(g) + e- → H-(g)
Oxide Nature (A) 5 (B) 2
(a) CO (i) Basic
(C) 3 (D) 4
(b) BaO (ii) Neutral
(c) Al2O3 (iii) Acidic 48. Consider the following statements & INCORRECT
(d) Cl2O7 (iv) Amphoteric statement is/are –
Which of the following is correct option? (1) [Xe] 6s2 4f14 5d1 is a d – block element
(a) (b) (c) (d) (2) [Rn] 7s2 5f14 6d2 is a f – block element
(A) (ii) (i) (iv) (iii) (3) [Kr] 5s0 4d10 is a d – block element
(B) (iii) (iv) (i) (ii) (4) [Ar] 4s2 3d10 4p4 is group 16 element
(C) (iv) (iii) (ii) (i) (5) [Kr] 4d10 5s1 is a s-block element
(D) (i) (ii) (iii) (iv) Select CORRECT option among the following is -
43. Match Column – I with Column – II. (A) 2, 3 & 5 (B) 1, 3 & 4
(C) 2 & 5 (D) 1, 2 & 5
(A) Element with largest (p) Boron
49. The correct order of decreasing electronegativity values
size in second period
(B) Element with smallest (q) Fluorine among the elements :
size in group 13 I- Beryllium,
(C) Element with (r) Bromine II- Oxygen,
maximum non- III- Nitrogen
metallic character IV- Magnesium is –
(D) Element with smallest (s) Lithium (A) II > III > I > IV (B) III > IV > II > I
size in fourth period
(C) I > II > III > IV (D) I > II > IV > III
(A) a – (s), b – (p), c – (r), d – (q)
50. Match Column – I with Column – II and select the
(B) a – (p), b – (s), c – (q), d – (r)
correct answer by the gives codes.
(C) a – (s), b – (q), c – (p), d – (r)
Column – I (Atoms) Column –II (Properties)
(D) a – (s), b – (p), c – (q), d – (r)
44. Consider the following statements: (a) He (p) Highly electronegative
(i) Atomic radii decreases across a row of the periodic (b) F (q) Most electropositive
table when we move from left to right.
(ii) Atomic radii increases down the column as we move (c) Rb (r) Strongest reducing agent
from top to bottom. (d) Li (s) Highest ionization energy
(iii) Although the order of elements is based on atomic
numbers, vertical families share similar chemical (A) a – (s), b – (q), c – (r), d – (p)
properties. (B) a – (p), b – (s), c – (q), d – (r)
(iv) Radius of an anion is smaller than that of parent (C) a – (s), b – (p), c – (r), d – (q)
atom. (D) a – (s), b – (p), c – (q), d – (r)
Which of the statement(s) given above is/ are correct?
(A) (i) and (iv) (B) (i) and (iii) Answer Key
1 A 11 C 21 B 31 C 41 B
(C) (ii) and (iv) (D) (i), (ii) and (iii) 2 D 12 B 22 B 32 C 42 A
45. Statement I : Metals will be found on the right side of 3 B 13 D 23 C 33 A 43 D
the periodic table. 4 A 14 C 24 A 34 D 44 D
Statement II : The elements P, S and O belong to the 5 D 15 B 25 B 35 C 45 B
6 D 16 D 26 C 36 B 46 C
same period.
7 C 17 A 27 A 37 D 47 D
(A) Both Statement I & II are correct 8 A 18 C 28 D 38 D 48 D
(B) Both Statement I & II are incorrect 9 B 19 B 29 A 39 B 49 A
(C) Statement I is correct but statement II is incorrect 10 B 20 C 30 D 40 B 50 D
(D) Statement II is correct but statement I is incorrect
46. Statement I : Metallic radii of Ti is more than Mn. Sample Paper (NEET-2024) Video Solution Scan
Statement II : Electronegativity refers to the tendency
of atom to share electrons with other atom.
(A) Both Statement I & II are correct
(B) Both Statement I & II are incorrect
(C) Statement I is correct but statement II is incorrect
(D) Statement II is correct but statement I is incorrect Part-01 Part-02
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