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    Acidos, Bases, PH e Hidrólisis (2)

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    Emmanuel David Navarro Vera

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    © All Rights Reserved
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    Acidos, Bases, PH e Hidrólisis (2)

    Uploaded by

    Emmanuel David Navarro Vera
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    Acidos, Bases, PH e Hidrólisis (2)

    Uploaded by

    Emmanuel David Navarro Vera

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    2 SELECCIÓN DE EJERCICIOS ÁCIDOS, BASES, pH e HIDRÓLISIS

    Constantes de disociación

    Sustancia Ka1 Ka2


    -4
    Ác. fórmico 1,8 x 10 -
    -5
    Ác. Benzoico 6,3 x 10 -
    -5
    CHÀCOOH 1,8 x 10 -
    -10
    HCN 4,9 x 10 -
    -4
    HF 6,8 x 10 -
    -8 -19
    H¿S 9,5 x 10 1 x 10
    -7 -11
    H¿COÀ 4,2 x 10 4,8 x 10
    -8
    HOCl 3,0 x 10 -
    -5
    NHÀ Kb = 1,8 x 10 -
    2 SELECCIÓN DE EJERCICIOS ÁCIDOS, BASES, pH e HIDRÓLISIS

    - -12 + - -
    50 [OH ] = 5,0 x 10 M, [H ] = [HOOC(CH2)4COO ] = 2,0 x 10
    3
    M, [HOOC(CH2)4COOH] = 0,10 M, [-OOC(CH2)4COO-] = 3,9 x
    10-6 M. 64 0,91 M

    RESPUESTAS SELECCIONADAS

    ma
    Problemas 15.44 al 15.123 (Chang, 10 edición):
    15.44 [CH3COO-] = [H+] = 5.8 x 10-4 M, [CH3COOH] = 0.0181
    M 15.45 4,0 x 10-11 15.46 0,0022 M. 15.47 (a) 1,8% (b) 43%
    15.49 9,1 x 10-4 15.62 pH (HCl) = 1.40, pH (H2SO4) = 1.31.
    15.79 9,15 15.80 4,82. 15.120 [Na+] = 0,200 M, [HCO3-] =
    [OH-] = 4,6 x 10-3 M, [H2CO3] = 2,4 x 10-8 M, [H+] =2,2 x 10-12
    M. 15.123 0,0074 g
    Problemas 16.84 al 16.129 (Brown, 11ra edición):
    16.84 (a) [OH-] = 1,2 x 10-6 M, pH = 8,09. (b) [OH-] = 0,035 M,
    - -6
    pH = 12,54. (c) [OH ] = 9,3 x 10 M, pH = 8,97. 16.87 NaF
    - -6
    16.89 [OH ] = 5,0 x 10 , pH = 8,75. 16.112 pH = 7,01. 16.129
    (a) 4800 (b) 12.
    ma
    Problemas 12 al 15.64 (Petrucci, 10 edición):
    12 83,0 mg/100 mL. 14 pH = 11,70. 15 8,5 mL. 19 pH =
    10,20. 41 0,0098 M. 44 (a) 0,91 (b) 91%. 47 (a) [H3O+] = [HS-]
    -5 2- -19 + - -
    = 8,7 x 10 M, [S ] = 1 x 10 M. (b) [H3O ] = [HS ] = 2,2 x 10
    5
    M, [S2-] = 1 x 10-19 M. (c) [H3O+] = [HS-] = 9,5 x 10-7 M, [S2-]
    -19
    =1 x 10 M.

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