Chapter -

I .
2) It I +
gorx21x
*

+Jde-del-

1 702 In (2) + 90XT-

Sel
Assure
·I Tz # (2)
dispices

Tz = 366 . 9927

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log 19 x
Uncc = -

In 10

If we fix the temp the pressure ,

where
liquid
and repor are in
equilibrium is called .
psot
If we fix the the temp
pressure ,
: where liquid and vapour
called
are in
equilibrium is

Tboiling point .
 b

pat
a - -

storo) = 10 tc + C

B
psat (kPa) = e
A--
Tk +c D
-

1 kPa = 7 50 for
.

A-
B 2. 303a - b
: 7.59 e T+C = e tc + C

1 2 3 neb
InCF-5) + A
.
-

. 3 obar
2 -

↑C+173 +C + (+c
e - e

: In (7 5) +A
.
= 2 .
303 a

A =
2 . 303a -
In 75
.

= 230343
.

. 15
 (a) F % 250lbm x 32 169fts
.

= =

, 32
174 Ibmuft Ibe"52 .

96
= 249 .

lbf

Fe = PA =
30 12 in
.

Hg x (1 .
25 f x 0 .
49116 Ibin intly

x 144 in 2/ft2
2214 26 .

lbf

·
f = 249 96 .

+ 2614 26 .
= 2864 .
22
1bf
(b)
p =
?

↑= ing
= 16 .

21 Ibint

(c) IM = fh = 2864 22 .
x # 7 .

=>
(4869 .
17
Ftlbf)
 Patm = 29 86 .

in Ag = 29 .

86 X0 .

491154 psia
14 66
psia
.

P its
=
Ygh =
13 593
.

gas x 26 .
62 in x 32 243
.

13 . 543x153 kg (26 62x0 0254) m 32 .

243x12x0254 m
X
.

I .
x
3
106 m g2

= 59992 . E Pa

1 .
01x10Pa = 14 7 .

psia
14 7 psia
P 65Pax Psic
.

·:
= 39992 . = 13 - 098
1 .

01x105 Par

:
Ptotal =
27 .
758 Psia
 (a) PE 8 ms 980 I
=
mgh =
1kgy9 . x loom :

(b) At PE 2300 pop

peak ,
=
, doo = 741 .

9 Jleg
31 00 DOD

Fraction =
741 95
.

= 0 .
75 = +%
9805

(C) If the temp is not changed , the internal

energy
:

kinetic energy will

and not " changed
.

Q
DEp = m +
 Since
w =
-

, and Q =
-

-
980 =
-

741 .
9 + DO

! DQ = 2238 .
1T

(a) KE
+ My
- (2)(9)2 70 5 J .
= = =

: electrical 0 94X405 17 85/kg

energy
. -
=
=

(b) P = ?
Power = 17: 8
J/kg x 15000 kg/s
= 267kW

(C) no heat transfer, no temp change >

-> DU = 0
, DEp =
O
,
& 0
=

DEv = 1 + &

- r(x, = W
 >
-
(1) V = -17 8
·

+ 40 .
5

2207xe 6 74ms +
Y2
.

= =

-
velocity decrease = 9-6 -

74
= 2 26 .
mst

Du = 2 + m
ab

=> 100 - 40 = 605

(a) Du = 2 - 20

68 + 28 = 2
& = 805

(b) -
Du = x +w

-
60 = 2 + 38
 a = -905 (liberat heat)

(a) F,
150kg X9 813 ms2
mg
= = .

= 1471 95 N
·

PA 101 57x103 Nm2 1735 ma

F2
.

= =
x 0 .

- 17621 .
83 N

F =
19093 78N .

CD)
F
Ps = -

& .
1735 ma
= 110050 . So Nm

= 110 . 051 kPa

Paten = 101 57 . kPa

Ptotal kPa
Pg + Patm = 211 . 621
=

Las ins2X0
W = -

mgh--150kgX9 813 . . 33m

-
=
1221 .
718 Non
=
= 1221 .

7185
-1
= .
22171345
Formula Note

specific volume = V =
It
Molar volume -
V
=

T(F) = (T (() x 1 .

8) + 32

IN =
1kgms2

[ lbf = 32 .
174 1bnft 52
Work done on system
Wreversible
n =

Wactual

Work done by system

IN actual

n
=

W
reversible
 no : of chemical
F = N -
π + 2
not of phase

Constant volume Isochoric

d Du 2
= 0
,
W = 0 ,
=

DU = G DT
,

Constant Pressure
H = u + PV
,
& = DH
DH DU + PAV
CpAT
=

DH =
 Cp5 = c + R

For ideal gas

Isothermal

Du = DH = D

a = -
W = -

RT(n) ) =
-

RT(n(f) = R + m(f)

Isobaric (P P2) ,
=

Du = c DT
,

DH =
CpDT
a = DH
R(Tz 4)
jPdV )
Y
P(Xz
-
-
=

M
-

= -
,
=

Isochoric (V = V2)

DT
DU = -

DH =
CpST
2 =
DU

W = D
 P M

(a) 2
-

3--&
24 &
&
Y

&
-

&

-"
1
-
1