VELAMMAL NEET & IIT ACADEMY

THIRUVOTTIYUR, PADAPPAI & NEDUNGUNDRAM.

XI NEET WT-7 DATE:09/11/2024
CHEMISTRY SECTION-A
51. Which of the following, set of molecules will have zero dipole moment?
(1) Ammonia, beryllium difluoride, water, 1, 4-dichlorobenzene
(2) Boron trifluoride, hydrogen fluoride, carbon dioxide, 1, 3-dichlorobenzene
(3) Nitrogen trifluoride, beryllium difluoride, water, 1, 3-dichlorobenzene
(4) Boron trifluoride, beryllium difluoride, carbon dioxide, 1, 4-dichlorobenzene

52. Which of the following is the correct order of dipole moment ?

(1) NH3 < BF3 < NF3 < H2O (2) BF3 < NF3 < NH3 < H2O
(3) BF3 < NH3 < NF3 < H2O (4) H2O < NF3 < NH3 < BF3

53. The species, having bond angles of 120° is

(1) ClF3 (2) NCl3 (3) BCl3 (4) PH3

54. Consider the molecules CH4, NH3 and H2O. Which of the given statements is false?
(1)The H — O — H bond angle in H2O is smaller than the H — N — H bond angle in NH3.
(2) The H — C — H bond angle in CH4 is larger than the H — N — H bond angle in NH3.
(3) The H — C — H bond angle in CH4, the H — N — H bond angle in NH3, and the
H — O — H bond angle in H2O are all greater than 90°.
(4) The H — O — H bond angle in H2O is larger than the H — C — H bond angle inCH4.

55. Which of the following molecules has the maximum dipole moment?
(1) CO2 (2) CH4 (3) NH3 (4) NF3

56. The correct order of increasing bond length of C – H, C – O, C – C and is

(1) C – H < C C < C – O < C – C (2) C – C < C C < C – O < C – H
(3) C – O < C – H < C – C < (4) C – H < C – O < C – C <

57. Which of the following structures is the most preferred and hence of lowest energy for SO3?

58. The correct order of increasing bond angles in the following triatomic species is

59. The correct order of C – O bond length among CO, , CO2 is

60. The electronegativity difference between N and F is greater than that between N and H yet the dipole
moment of NH3 (1.5 D) is larger than that of NF3 (0.2 D). This is because
(1) in NH3 the atomic dipole and bond dipole are in the opposite directions whereas in NF3 these
are in the same direction
(2) in NH3 as well as in NF3 the atomic dipole and bond dipole are in the same direction
(3) in NH3 the atomic dipole and bond dipole are in the same direction whereas in NF3 these are in
opposite directions
(4) in NH3 as well as in NF3 the atomic dipole and bond dipole are in opposite directions.

61. The correct order in which the O – O bond length increases in the following is
(1) O2 < H2O2 < O3 (2) O3 < H2O2 < O2 (3) H2O2 < O2 < O3 (4) O2 < O3 < H2O2
62. Which of the following would have a permanent dipole moment?
(1) SiF4 (2) SF4 (3) XeF4 (4) BF3

63. H2O is dipolar, whereas BeF2 is not. It is because

(1) the electronegativity of F is greater than that of O
(2) H2O involves hydrogen bonding whereas BeF2 is a discrete molecule
(3) H2O is linear and BeF2 is angular (4) H2O is angular and BeF2 is linear.

64. Which of the following molecules does not possess a permanent dipole moment?
(1) CS2 (2) SO3 (3) H2S (4) SO2
(2)
65. The table shown below gives the bond dissociation energies (Ediss) for single covalent bondsof carbon
(C) atoms with element A, B, C and D. Which element has the smallest atoms?

(1) C (2) D (3) A (4) B

66. Which of the following bonds will be most polar?

(1) N – Cl (2) O – F (3) N – F (4) N – N

67. Which one of the following molecules contains no pi bond?

(1) SO2 (2) NO2 (3) CO2 (4) H2O

68. Which one of the following statements is not correct for sigma- and pi- bonds formed between two carbon
atoms?
(1) Sigma-bond is stronger than a pi-bond.
(2) Bond energies of sigma- and pi-bonds are of the order of 264 kJ/mol and 347 kJ/mol, respectively.
(3) Free rotation of atoms about a sigma-bond is allowed but not in case of a pi-bond.
(4) Sigma-bond determines the direction between carbon atoms but a pi-bond has no primary effect in this
regard.

69. Main axis of a diatomic molecule is z, molecular orbital px and py overlap to form which of the following
orbitals?
(1) p molecular orbital (2) s molecular orbital (3) d molecular orbital (4) No bond will form.

70. Which statement is not correct?

(1) A sigma bond is weaker than a pi bond. (2) A sigma bond is stronger than a pi bond.
(3) A double bond is stronger than a single bond. (4) A double bond is shorter than a single bond.

71. Linear combination of two hybridized orbitals belonging to two atoms and each having one electron leads
to the formation of
(1) sigma bond (2) double bond (3) co-ordinate covalent bond (4) pi bond.

72. Which of the following does not apply to metallic

bond?
(1) Overlapping valence orbitals (2) Mobile valence electrons
(3) Delocalized electrons (4) Highly directed bonds

73. The angle between the overlapping of one s-orbital and one p-orbital is
(1) 180° (2) 120° (3) 109°28′ (4) 120°, 60°

74. In the structure of ClF3, the number of lone pairs of electrons on central atom ‘Cl’ is
(1) one (2) two (3) four (4) three

75. Predict the correct order among the following :

(1) bond pair - bond pair > lone pair - bond pair > lone pair - lone pair
(2) lone pair - bond pair > bond pair - bond pair > lone pair - lone pair
(3) lone pair - lone pair > lone pair - bond pair > bond pair - bond pair
(4) lone pair - lone pair > bond pair - bond pair > lone pair - bond pair

76. Which of the following species contains three bond pairs and one lone pair around the central atom?
(1) H2O (2) BF3 (3) (4) PCl3
77. Which of the following is not a correct statement?
(1) Multiple bonds are always shorter than corresponding single bonds.
(2) The electron-deficient molecules can act as Lewis acids.
(3) The canonical structures have no real existence.
(4) Every AB5 molecule does in fact have square pyramid structure.

78. Which of the following is not isostructural with SiCl4?

79. The hybridizations of atomic orbitals of nitrogen in respectively are

(1) sp, sp3 and sp2 (2) sp2 , sp3 and sp (3) sp, sp2 and sp3 (4) sp2 , sp and sp3

80. Which of the following pairs of ions is isoelectronic and isostructural?

81. ASSERTION-REASON TYPE QUESTIONS

Directions : Each of these questions contain two statements, Assertion and Reason. Each of these questions also
has four alternative choices, only one of which is the correct answer. You have to select one of the codes (a), (b),
(c) and (d) given below.
(a) Assertion is correct, reason is correct; reason is a correct explanation for assertion.
(b) Assertion is correct, reason is correct; reason is not a correct explanation for assertion
(c) Assertion is correct, reason is incorrect
(d) Assertion is incorrect, reason is correct.
Assertion : CH2Cl2 is non-polar and CCl4 is polar molecule.
Reason : Molecule with zero dipole moment is non-polar in nature

82. Assertion : Lone pair-lone pair repulsive interactions are greater than lone pair-bond pair and bond pair-bond
pair interactions.
Reason : The space occupied by lone pair electrons is more as compared to bond pair electrons.

83. Assertion : In NH3 , N is sp3 hybridised, but angle is found to be 107°.

Reason : The decrease in bond angle is due to repulsion between the lone pair

84. Match the following column-I & II

Column-I Column-II
P Least bond length 1 N2
Q Least bond order 2 HI
R Highest order 3 H2
S Highest bond length 4 HF
1) 4,3,1,2 2)4,1,3,2 3) 2,3,4,1 4) 4,1,2,3
85. Match the following column-I & II
Column-I Column-II
(Hybridisation) (Bond angle)
P sp 1 120
Q sp2 2 180
R sp3 3 120 & 90
S sp3d 4 109.28’
1) 2,1,4,3 2) 2,1,3,4 3) 2,3,4,1 4) 4,1,2,3
CHEMISTRY SECTION-B
86. Which of the following unit conversion of dipole moment is correct?
1) 1D = 3.3356 C.m 2) 1D= 3.3356 x 10-30Cm 3) 1 C m = 3.3356 D 4) 1 C m = 3.3356 10-30D

87. Pure covalent double bond is present in

1) Acetylene 2) Carbon dioxide 3) Ethylene 4) Ethane
88. Linear combination of two atomic orbitals belonging to two atoms and each having one electron
leads to a
1) Sigma bond 2) Double bond 3) Co-ordinate covalent bond 4)H–bond

89. Which one of the following is an incorrect statement

1) A pi bond is formed when a sigma already exists
2) A pi bond may be formed by the overlapping of ‘p’ or ‘d’ orbitals
3) A pi bond is formed by the overlapping of hybrid orbitals
4) A pi bond is formed by the lateral overlapping of atomic orbitals

90. The central atom in IF7 has seven pairs of valence electrons. The shape of the molecule as per
VSEPR theory is
1) Trigonal bipyramid 2) Hexagonal pyramid
3) Pentagonal bipyramid 4) Square bipyramid

91.
In (Nitrate) ion, number of bond pairs and lone pairs of electrons on nitrogen atom are
1) 2,2 2) 3,1 3) 1,3 4) 4,0

92. .  ion according to Valence Shell Electron Pair Repulsion (VSEPR) theory will be
1) Planar triangular 2) Pyramidal 3) Tetrahedral 4) Square planar

93. The shape of formaldehyde molecule as per the VSEPR theory is

1) Linear 2) Planar triangle 3) Pyramid 4) Tetrahedron

94. Which of the following molecule is linear?

95. Shape of hydronium ion is

1) Tetrahedron 2) Square planar 3) Planar triangle 4) Pyramidal

96. Which of the following molecule does not have

a linear arrangement of atoms
1) H2 S 2) C2H2 3) BeH2 4) CO2

97. Shape of phosphorus pentachloride molecule is

1) Octahedron 2) Square pyramid 3) Trigonal bipyramid 4) Pyramidal

98. Which of the following has distorted tetrahedron shape

1) SiH4 2) CCl4 3) H2O 4) CHCl3

99. The shape of Ammonium ion is

1) Tetrahedron 2) Pyramid 3) Square planar 4) Square pyramid
100. Which of the following is not a pyramidal species
 1) NH3 2) H3O+ 3) PH3 4)

CHEMISTRY KEY NEET WT-7 09/11//2024

51 52 53 54 55 56 57 58 59 60
4 2 3 4 3 1 4 4 3 3
61 62 63 64 65 66 67 68 69 70
4 2 4 1 2 3 4 2 1 1
71 72 73 74 75 76 77 78 79 80
1 4 1 2 1 4 4 2 3
81 82 83 84 85 86 87 88 89 90
4 1 1 1 1 4 2 1 3 3
91 92 93 94 95 96 97 98 99 100
4 2 2 2 1 1 3 4 1 4