DPP 1 Chemical bonding

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Date of Discussion: 15-March 2021

Marks: 72 Time: 25 min DPP No:1


Batch: Spark & Legend Chemical Bonding Topic: Bond Types

1. Which of the following is not correct regarding the properties of ionic compounds?
a) Ionic compounds have high metling and boiling points
b) They are hard & Brittle
c) Ionic compounds in their molten and aqueous solutions do not conduct electricity
d) They are highly soluble in polar solvents

2. The element having lowest ionisation energy among the following is:
a) 1𝑠 , 2𝑠 2𝑝 b) 1𝑠 , 2𝑠 2𝑝 , 3𝑠 c) 1𝑠 , 2𝑠 2𝑝 d) 1𝑠 , 2𝑠 2𝑝

3. Which is electron deficient compound?


a) C H b) B H c) C H d) NaBH

4. CCl is insoluble in water because:


a) CCl is non-polar and water is polar
b) Water is non-polar and CCl is polar
c) Water and CCl both are polar
d) None of the above

5. The number of sigma and pi (𝜋) bonds present in benzene respectively are
a) 12, 6 b) 6, 6 c) 6, 12 d) 12, 3

6. If 𝑍-axis is the molecular axis, then 𝜋-molecularorbitals are formed by the overlap of
a) 𝑠 + 𝑝𝓏 b) 𝑝 + 𝑝 c) 𝑝𝓏 + 𝑝𝓏 d) 𝑝 + 𝑝

7. The total number of valency electrons for PO ion is:


a) 32 b) 16 c) 28 d) 30

8. Lattice energy of an ionic compound depends upon


a) Charge on the ion and size of the ion b) Packing of ions only
c) Size of the ion only d) Charge on the ion only

9. Metallic bonds do not play a role in:


a) Brass b) Copper c) Germanium d) Zinc

10. H O boils at higher temperature than H S because it is capable of forming:


a) Ionic bonds b) Covalent bonds c) Hydrogen bonds d) Metallic bonds

11. The correct increasing covalent nature is:


a) NaCl < 𝐿𝑖𝐶𝑙 < 𝐵𝑒𝐶l b) BeCl < 𝑁𝑎𝐶𝑙 < 𝐿𝑖𝐶𝑙 c) BeCl < 𝐿𝑖𝐶𝑙 < 𝑁𝑎𝐶𝑙 d) LiCl < 𝑁𝑎𝐶𝑙 < 𝐵𝑒𝐶l

12. IP and IP ofMg are 178 and 348 kcal mol . The energy required for the reaction,
Mg ⟶ Mg + 2e is:
a) +170 kcal b) +526 kcal c) -170 kcal d) -526 kcal
13. Which one of the following orders is not in according with the property stated against it?
a) F > 𝐶l > 𝐵r > I ∶ Electronegativity
b) F > 𝐶l > 𝐵r > I : Bond dissociation energy
c) F > 𝐶l > 𝐵r > I : Oxidising power
d) HI > 𝐻𝐵𝑟 > 𝐻𝐶𝑙 > 𝐻𝐹 : Acidic property in water.

14. Metals are good conductors of electricity because they contain


a) Ionic bonds b) A network structure
c) Very few valence electrons d) Free electrons

15. Which is expected to conduct electricity?


a) Diamond b) Molten sulphur c) Molten KCl d) Crystalline NaCl

16. The attraction that non-polar molecules have for each other is primarily caused by:
a) Hydrogen bonding
b) Difference in electronegativities
c) High ionisation energy
d) Van der Waals’ forces

17. For AB bond if per cent ionic character is plotted against electronegativity difference (𝑋 − 𝑋 ), the shape
of the curve would look like

The correct curve is


a) A b) B c) C d) D

18. The formation of the oxide ion O (g)requires first an exothermic and then an endothermic step as shown
below,
O(g) + 𝑒 ⟶ O (g) ; ∆𝐻 = −142 kJ/mol
O (g) + 𝑒 ⟶ O (g) ; ∆𝐻 = 844 kJ/mol
This is because:
a) O ion has comparatively larger size than oxygen atom
b) Oxygen has high electron affinity
c) O ion will lead to resist the addition of another electron
d) Oxygen is more electronegative

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