JEE MAIN

GRAND TEST - 04
Exam Date: (04-01-2025)
Important Instructions:
1) The test is of 3 hours duration.
2) The Test has 75 questions. The maximum marks are 300.
3) There are Three parts in the question paper consisting of Physics, Chemistry and
Mathematics having 25 questions in each part.
4) In the Mathematics, Physics, and Chemistry section, a maximum of 100 marks are rewarded for all
25 questions.
5) In Numerical FIVE of them.
6) Marking Scheme and pattern of questions is as follows:
Subject Q.Nos Type Marking Scheme
1 – 20 MCQ +4 for correct response -1 for incorrect response
Physics
21 – 25 Numerical +4 for correct response -1 for incorrect response
26 – 45 MCQ +4 for correct response -1 for incorrect response
Chemistry
46 – 50 Numerical +4 for correct response -1 for incorrect response
51 – 70 MCQ +4 for correct response -1 for incorrect response
Mathematics
71 - 75 Numerical +4 for correct response -1 for incorrect response

PHYSICS
SECTION-A
1 A uniform thick string of length 5 m is resting on a horizontal frictionless surface . It is pulled
by a horizontal force of 5 N from one end. The tension in the string at 1 m from the force
applied is :
(a) zero (b) 5 N (c) 4 N (d) 1 N
2 A mixture of two moles of hydrogen and one mole of argon gas is taken in a closed container
at room temperature. Consider the following two statements
(i) The average kinetic energy of each molecule of H and Ar are the same.
(ii) The partial pressure due to argon gas is more than that due to hydrogen gas.
(a) Both statement (i) and (ii) are correct
(b) Statement (i) is correct while statement (ii) is incorrect
(c) Both statement (i) and (ii) are incorrect
(d) Statement (i) is incorrect while statement (ii) is correct
3 Seven resistors each of resistance R, are connected as shown in figure. The equivalent
resistance between A and 𝐵 is

(a) 4R/3 (b) 3R/2 (c) 7 R (d) 8R/7

4 Statement-1 : It is easier to remove an orbital electron from an atom, but quite difficult to
remove a nucleon from a nucleus.
Statement-2 : An electron is much lighter than a nucleon.
(a) Statement-1 is True, Statement-2 is True, Statement2 is a correct explanation for statement-
1
(b) Statement-1 is True, Statement-2 is True, Statement-2 is NOT a correct explanation for
Statement-1
(c) Statement-1 is True, Statement-2 is False (d) Statement-1 is False, Statement-2 is True
5 One face of a prism with a refracting angle of 30∘ is coated with silver. A ray incident on other
face at an angle of 45∘ is refracted and reflected from the silvered coated face and retraces its
path. The refractive index of the prism is :
(a) 2 (b) √3 (c) 3/2 (d) √2
6 Truth table for system of four NAND gates as shown in figure is :

(a) (b) (c) (d)

7 Two particles A and B starts from the same point and move in the positive x -direction. Their
velocity-time relationships are shown in the following figures. What is the maximum
separation between them during the time interval shown?

(a) 1.00 m (b) 1.25 m (c) 1.50 m (d) 2.00 m

8 The electric field near the surface of a charged spherical conductor is 100 V/m. The conductor
is at a potential of 100 V . The charge on the conductor is
(a) 9𝜇C (b) 1.11 × 10 C (c) 9 × 10 C (d) 1.11 × 10 C
9 Two concentric coils each of radius equal to 2𝜋 cm are placed at right angles to each other. 3 A
and 4 A are the currents flowing in each coil respectively. The magnetic induction in Wb/m
at the centre of the coils will be ( 𝜇 = 4𝜋 × 10 Wb/Am ):
(a) 12 × 10 (b) 10 (c) 5 × 10 (d) 7 × 10
10 In a series LCR circuit connected to AC source, the power factor is 1 . The angular frequency
is 100𝜋rad/s. The inductance is 4 H , the resistance is 100Ω. Then the capacitance is
(a) 2.5𝜇 F (b) 5𝜇 F (c) 4𝜇 F (d) 8𝜇 F
11 A bomb of mass 9 kg , initially at rest, explodes into two pieces of masses 3 kg and 6 kg . The
kinetic energy of the 3 kg mass is 216 J . The kinetic energy of the 6 kg mass is
(a) 213 J (b) 108 J (c) 432 J (d) 54 J
12 A thermodynamic system is taken through cyclic process. The total work done in the process is
:
 (a) 200 J (b) 300 J (c) 100 J (d) Zero
13 Entries in column I are representing physical quantities whereas entries in column II are
representing dimensions. Match the columns.
Column I Column II
(A) Force (P) M L T
(B) Power (Q) M L T
(C) Work (R) M L T
(D) Unit vector (S) M L T
(a) (A) -P , (B) -S , (C) -R , (D) –Q (b) (A) -S, (B) -P, (C) -Q , (D) -R
(c) (A) -S, (B) -Q, (C) -R, (D) –P (d) (A) -S, (B) -P, (C) -R , (D) –Q
14 𝑇 is the time period of a simple pendulum at a place. If the length of the pendulum is reduced
to 1/16 times of its initial value, the modified time period is :
(a) T (b) 8𝜋 T (c) 4 T (d) T
15 A surface irradiated with light of wavelength 480 nm gives out electrons with maximum
velocity vm/s, the cut off wavelength being 600 nm . The same surface would release
electrons with maximum velocity 2vm/s if it irradiated by light of wavelength
(a) 300 nm (b) 360 nm (c) 384 nm (d) 400 nm
16 An incompressible liquid flows, as shown. The speed of the liquid in the lower branch will be

(a) 1.0 m/s (b) 1.5 m/s (c) 2.5 m/s (d) 3.0 m/s
17 A charged particle of mass 𝑚 and charge 𝑞 moves in a circular orbit of radius 𝑟 with angular
velocity 𝜔. Then ratio of its magnetic moment M to its KE is independent of
(a) m (b) q (c) 𝜔 (d) r
18 Two wires are made of the same material and have the same volume. However wire 1 has
cross-sectional area A and wire 2 has cross-sectional area 3A. If the length of wire 1 increases
by Δ𝑥 on applying force 𝐹, how much force is needed to stretch wire 2 by the same amount?
(a) 4 F (b) 6F (c) 9 F (d) F
19 A body is projected up with a velocity 2 times the escape velocity v from the surface of the
earth. The velocity of the body at a point far away the earth's attraction is
(a) 𝑣 (b) √7v (c) √2v (d) √3𝑣es
20 The mean intensity of radiation on the surface of the Sun is about 10 W/m . The rms value of
the corresponding magnetic field is closet to :
(a) 1 T (b) 10 T (c) 10 T (d) 10 T
SECTION-B
INTEGERTYPEQUESTION
21 A block of ice of mass 120 g at temperature 0∘ C is put in 300 g of water at 25∘ C. The xg of ice
melts as the temperature of the water reaches 0∘ C. The value of 𝑥 is
[Use specific heat capacity of water = 4200Jkg K , Latent heat of ice = 3.5 × 10 Jkg ]
22 A particle executes simple harmonic motion with an amplitude of 5 cm . when the particle is at
4 cm from the mean position, the magnitude of its velocity is SI units is equal to that of its
acceleration. Then, its periodic time is second. The value of 𝑥 is.
 23 In a Young's double slit experiment the intensity at a point where the path difference is .
(  being the wavelength of the light used) is I. If 𝐼 denotes the maximum intensity, then I is
equal to I . The value of x is.......
24 An electric field E⃗ = 4𝑥ı̂ − (y + 1)ȷ̂N/C passes through the box shown in figure. The flux of
the electric field through surface HGCD and BCGF and marked as 𝜙 and 𝜙 respectively.
The difference between ( 𝜙 − 𝜙 ) is (in Nm /C )

25 A boy ties a stone of mass 100 g to the end of a 2 m long string and whirls it around in a
horizontal plane. The string can withstand the maximum tension of 80 N . If the maximum
speed with which the stone can revolve is rev./min. The value of K is : (Assume the string is
massless and unstretchable)
CHEMISTRY
SECTION-A
26 For the given compounds, the correct order of increasing pKa value
(A) ClCH2CH2COOH (B) CCl3COOH (C) BrCH2COOH (D) NC-CH2COOH
(E) CH3COOH
(a) (B) < (D) < (C) < (A) < (E) (b) (D) < (E) < (C) < (B) < (A)
(c) (E) < (D) < (C) < (B) < (A) (d) (E) < (D) < (B) < (A) < (C)
27. During hearing of a court case, the judge suspected that some changes in the documents had been carried
out. He asked the forensic department to check the ink used at two different places. According to you
which technique can give the best results?
(a) Column chromatography (b) Solvent extraction (c) Distillation (d) Thin layer chromatography

28. The major product (P) in the following reaction is

(a) (b) (c) (d)

29. Two isomers ‘A’ and ‘B’ with molecular formula C6H12 give different products on oxidation with KMnO4
in acidic medium. Isomer ‘A’ forms ketone only whereas isomer ‘B’ gives same ketone and a carboxylic
acid. Isomer ‘B’ is
(a) Hex-3-ene (b) 3-methylpent-2-ene
(c) 2-methylpent-2-ene (d) 2,3-dimethylbut-2-ene
30. For the following sequence of reactions, the correct products are

(a) (b)

(c) (d)

31. Match list I with list II

List I List II
A. XeO2F2 I. Tetrahedral
B. SOCl2 II. Bent T-shaped
C. BF4 III. See-saw
D. ICl3 IV. Pyramidal
(a) A-III, B-IV,C-I,D-II (b) A-I, B-IV, C-III, D-II
(c) A-II, B-III,C-I, D-IV (d) A-III, B-I, C-III, D-II
32. The complex with lowest magnitude of crystal field splitting energy (∆ o) is
(a) [Co(CN)6]3- (b) [Cr(CN)6]3- (c) [Fe(CN)6]4- (d) [Fe(CN)6]3-

33. The products obtained from a reaction of potassium iodide and neutral potassium permanganate are
(a) Mn2+, I2 (b) MnO2, IO3 MnO2, I2 (d) Mn2+, IO3

34. The energy of an electron in the first Bohr orbit of He+ is 8.72 × 1018J. Energy of electron is 3rd orbit
Bohr orbit of Li2+ is
(a) 8.72 × 1018J (b) 2.18 × 1018J (c) 19.62 × 1018J (d) 4.905 × 1018J

35. When 200 mL of 0.1M HCl is neutralized by sufficient volume of 0.2 M NaOH, increase in temperature is
‘T1’ and 200 mL of 0.1M H2SO4 is neutralized by sufficient volume of 0.1 M NaOH, increase in
temperature is ‘T2’. T1 : T2 is ___
(a) 1 : 1 (b) 1 : 2 (c) 2 : 1 (d) 1 : 4
36. Which of the following statement is not correct about rusting of iron?
(a) Coating of iron surface by magnesium prevents rusting.
(b) When pH increases, rusting of iron enhances.
(c) Dissolved acidic oxides in water enhances the process.
(d) Rusting process can occur in presence of dry air.

37. ‘R’ formed in the following sequence of reaction is

 (a) (b) (c) (d)

38. Choose the correct answer from the options given below

List I List II
A. Glucose + Fehling solution I. Sorbitol
B. Glucose + NaBH4 II. Oxime
C. Glucose + Ac2O(excess) III Gluconic acid
D. Glucose + Hydroxylamine IV. Pentacetate
(a) A-II, B-III, C-IV, D-II (b) A-III, B-IV, C-I, D-II
(c) A-III, B-I, C-IV, D-II (d) A-II, B-III, C-IV, D-I

39. Reducing character of hydrides of group 15 elements follows order

(a) NH3<PH3<AsH3<SbH3 (b) NH3<PH3>AsH3>SbH3
(c) NH3>PH3<AsH3>SbH3 (d) NH3>PH3>AsH3>SbH3

40. The number of incorrect statement/s from the following is ______________

(a) All zero order reactions are complex reactions
(b) Time required for concentration of reactant to decrease 1/8 th of its initial concentration is 3 times of its
half-life period for a zero order reaction.
(c) Order of reaction can be zero, positive, negative and fractional.
(d) Rate and rate constant units of zero order reaction are same.
41. Arrange the following solutions in the decreasing order of pOH
(A) 0.01 M H2SO4; (B) 0.01 M Ca(OH)2; (C) – 0.01 M (CH3COO)2Ba; (D) – 0.01 M KCl
(a) (B) < (C) < (D) < (A) (b) (A) < (D) < (C) < (B)
(c) (B) < (D) < (C) < (A) (d) (C) < (B) < (A) < (D)
42. Which one of the following only exist?
(a) BI4 BBr4 BCl4 BF4
43. Identify the correct statements about group 16 elements:
(A) Dioxygen is diatomic gas and has less melting and boiling point in the group.
(B) Common oxidation states of these elements except oxygen is +4 and +6.
(C) All elements of the group show allotropy.
(D) Bonds in +4 and +6 oxidation states are mainly covalent.
(E) Acidic character decreases from H2O to H2Te.
(a) (A), (B), (D) only (b) (A), (C), (D) only
(c) (A), (B), (C) and (D) only (d) All are correct.

44. Match List I and List II

List I List II
(Precipitating reagent) (Cation)
 A. Dil.HCl + H2S(g) I. Ca2+
B. NH4Cl(s) + NH4OH II. Cu2+
C. NH4Cl(s) + NH4OH + H2S(g) III. Cr3+
D. NH4OH + Na2CO3 IV. Zn2+
(a) A-II, B-III, C-IV, D-I (b) A-I, B-III, C-II, D-IV
(c) A-III, B-II, C-IV, D-I (d) A-IV, B-II, C-III, D-I
45. Which one of the following species responds to an external magnetic field?
(a) [Zn(H2O)4]2+ (b) [Cr(CO)6] (c) [Cu(CN)4]2- (d) [PtCl4]2-
Numericals
46. Number of following molecules/ions having bond order more than 2 is____
N2+, O2, O22-, CO, CO+, NO+, NOCN
47. The osmotic pressure of a dilute solution of 0.01 M glucose solution is 5 × 10 5 Pa at 273 K. Osmotic
pressure of same concentrated solution of CaCl 2 which has 50 % ionization at 2730C is _____×105 Pa.
48. Total number of all possible alkenes are formed in the following reaction

49. Number of compounds which will form yellow colour liquid with HNO 2 is _________.

50. A solution of sugar is obtained by mixing 600 g of its 40% solution and 400 g of its 25% solution(both by
mass). The mass percentage of the resulting sugar solution is ____(Nearest integer)

MATHEMATICS
SECTION-A
√
51 The smallest positive value of 𝑥 (in degrees) satifying the equation log sin 𝑥 = 2 −
log (tan 𝑥), is
(a) (b) (c) (d)

52 The domain set of definition of the function 𝑓(𝑥) = cos(sin 𝑥) + sin is

(a) −1 ≤ 𝑥 ≤ 1 (b) 𝑥 ≥ 1 (c) 𝑥 ≤ 1 (d) 𝑥 = ±1
53 The perpendicular distance of the point 𝚤ˆ + 𝚥ˆ + 𝑘ˆ from the line joining the points 3𝚤ˆ + 4𝚥ˆ − 𝑘ˆ
and 2𝚤ˆ + 𝚥ˆ − 𝑘ˆ is
√
(a) (b) (c) (d) 2√10
√ √

54 Sum of n terms of the series

+ + + + ⋯ ….. is
(a) 1 − 3 ⋅ 5 (b) n − + 5 (c) n + − 5 (d) n − + 5

55 The value of the product (sin 162∘ )(cos 216∘ )(tan 195∘ )(tan 105∘ ), is
(a) 1 (b) (c) (d)
56 In an experiment with 15 observations on 𝑥, the following results were available
∑x = 2830, ∑x = 170
One observation that was 20 , we found to be wrong and was replaced by the correct value 30 .
Then, the corrected variance is
(a) 78.00 (b) 188.66 (c) 177.33 (d) 8.33
57 The relation R defined on the set A = {1,2,3,4,5} by 𝑅 = {(𝑥, 𝑦): |𝑥 − 𝑦 | < 16} is given by
(a) {(1,1), (2,1), (3,1), (4,1), (2,3)} (b) {(2,2), (3,2), (4,2), (2,4)}
(c) {(3,3), (3,4), (5,4), (4,3), (3,1)} (d) None of these
58 The equation of the circle whose radius 5 and which touches the circle 𝑥 + 𝑦 − 2𝑥 − 4𝑦 −
20 = 0 externally at the point (5,5), is
(a) 𝑥 + 𝑦 − 18𝑥 − 16𝑦 − 120 = 0 (b) 𝑥 + 𝑦 − 18𝑥 − 16𝑦 + 120 = 0
(c) 𝑥 + 𝑦 + 18𝑥 + 16𝑦 − 120 = 0 (d) 𝑥 + 𝑦 + 18𝑥 − 16𝑦 + 120 = 0
59 The locus of the mid-point of the line segment joining the focus to a moving point on the
parabola 𝑦 = 4𝑎𝑥 is another parabola with directrix
(a) 𝑥 = −𝑎 (b) 𝑥 = −𝑎/2 (c) 𝑥 = 0 (d) 𝑥 = 𝑎/2

60 If it is known that the third term of the binomial expansion x + x is 10 then x is

equal to
(a) 10 (b) 1000 (c) 100 (d) 5
61 Two vectors 𝑝⃗, 𝑞⃗ on a plane satisfy |𝑝⃗ + 𝑞⃗| = √13, |p⃗ − q⃗| = 1 and |p⃗| = √3. The angle
between p⃗ and q⃗, is equal to
(a) (b) (c) (d)

62 Let 𝑓: 0, → 𝑅 be continuous and satisfy 𝑓 (𝑥) = for all 𝑥 ∈ 0, . If 𝑓(0) = 3 then

f has the value equal to
(a) (b) 2 (c) 4 (d) None

63 The number of ways in which alphabets of the word MATHOPHOBIA can be arranged so that
no two identical vowels are separated and no two identical consonants occur together is
! ! × !
(a) (b) 8 ! (c) (d)

64 Let 𝛼, 𝛽 ∈ 𝑅 be such that Lim → = 2. Then

(a) 3𝛼 + 𝛽 = 3 (b) 2𝛼 + 𝛽 = 2 (c) 𝛼 + 𝛽 = 1 (d) 𝛼 − 𝛽 = 0
65 The values of a, for which the points A, B, C with position vectors 2𝚤ˆ − 𝚥ˆ + 𝑘ˆ , 𝚤ˆ − 3𝚥ˆ − 5𝑘ˆ and
a 𝚤ˆ − 3𝚥ˆ + 𝑘ˆ respectively are the vertices of a right angled triangle with C = , is
(a) 2, 1 (b) −2, −1 (c) −2,1 (d) 2, −1
66 In a game, a man wins Rs 5 for getting a number greater than 4 and loses Rs 1 otherwise, when
a fair die is thrown. The man decided to throw a die thrice but to quit as and when he gets a
number greater than 4 . Find the expected value of the amount he wins/ loses.
(a) (b) (c) (d)

67 The equations of the line passing through the point (1,2, −4) and perpendicular to the two lines
= = and = = will be -
(a) = = (b) = = (c) = = (d) None of these
68 The remainder left out when 8 − (62) is divided by 9 is -
(a) 0 (b) 2 (c) 7 (d) 8
69 The system of equations
x − ycos 𝜃 + zcos 2𝜃 = 0
−𝑥cos 𝜃 + 𝑦 − 𝑧cos 𝜃 = 0
xcos 2𝜃 − ycos 𝜃 + z = 0
has non trivial solution for 𝜃 equals
(a) 𝑛𝜋 only, 𝑛 ∈ 𝐼 (b) n𝜋 + only, n ∈ I (c) (2n − 1) only, n ∈ I(d) all value of 𝜃

70 If 𝐴 and 𝐵 are two non-singular matrices of order 3 such that AA = 2I and A = A − A ⋅

adj(2 B ), then det. (B) equals
[Note : P and adj. P denote transpose and adjoint matrices of matrix P respectively.]
(a) 4 (b) 4√2 (c) 16 (d) 16√2
SECTION-B
INTEGERTYPE QUESTION

71 f(x) = cos cot sin(tan x) then number of solution(s) of the equation √3f(x) − 1 = 0
is (are)
−𝑥 + 2, 𝑥≤1
72 The area of the closed figure bounded by 𝑥 = −1, 𝑥 = 2 and 𝑦 = and the
2𝑥 − 1, 𝑥>1
abscissa axis is A . Then the value of 3 A is .
73 Find the number of functions f: {a, b, c} → {1,2,3,4, 5,6} which are not injective.
74 A function 𝑦 = 𝑓(𝑥) satisfies the differential equation f(x) ⋅ sin 2x − cos x +
(1 + sin x)f (x) = 0 with initial condition 𝑦(0) = 0. The value of 5𝑓(𝜋/6) is equal to
75 All possible 5 lettered words are formed using all the letters of the word "COCOA" and a word
from it is randomly selected. The chance that any two alike letters are not adjacent in the
selected word is , then find the value of 𝑚 + 𝑛.
 KEY

PHYSICS

1 C 2 C 3 D 4 B 5 D 6 A 7 B 8 B 9 C 10 A
11 B 12 B 13 D 14 D 15 A 16 A 17 D 18 C 19 D 20 D
21 90 22 3 23 4 24 18 25 600

CHEMISTRY
26 A 27 D 28 D 29 C 30 D 31 A 32 B 33 B 34 B 35 A
36 D 37 B 38 C 39 D 40 B 41 A 42 D 43 C 44 A 45 C
46 5 47 20 48 11 49 3 50 34

MATHS

51 B 52 D 53 C 54 B 55 C 56 A 57 D 58 B 59 C 60 A
61 A 62 C 63 D 64 A 65 A 66 A 67 A 68 B 69 D 70 D
71 1 72 16 73 96 74 2 75 7

SOLUTIONS
12

13 D
21

22

23
 24

For plane HGCD, A  6j
 
Q1  E.A1   y 2  1 .6
30
 
Q2  E.A 2

A 2  4i
| 4x || 4 | 16x  48
Q2  Q1  48  30
18

25

26. 1
Sol: Based on pKa values, refer NCERT carbonyl compounds chapter.
27. 4
Sol: Conceptual.
28. 4
Sol:
29. 3

Sol:
30. 4

Sol:

31. 1
Sol: XeO2F2 – sp3d, see-saw; SOCl2 – sp3, pyramidal; BF4sp3, Tetrahedral; ICl3 – sp3d, Bent T-shaped
32. 2
Sol: Cyanide is a strong ligand, Co3+ and Fe2+ have d6 configuration, Cr3+ has d3 and Fe3+ has d5 configuration.
So, as number of d-electrons increases magnitude of CFSE increases.
33. 2
Sol: 2MnO4– + H2O + I–  2MnO2 + 2OH– + IO3–
34. 2
2.18 1018  Z2
Sol: Energy of electron in nth Bohr orbit= J / atom
n2
35. 1
Sol: Volume of 0.2M NaOH required for 200 mL of 0.1 M HCl is 100 mL.
Heat liberated=0.02 × 57.4 kJ
Volume of 0.1 M NaOH required for 200 mL of 0.1 M H2SO4 is 400 mL.
Heat liberated=0.04×57.4 kJ.
0.02  57.4
x 300  1 ( q  msT)

y 0.04  57.4
600
36. 4
Sol: Rusting process can take place only in presence of water and air.
37. 2
38. 3
Glucose + Fehling solutionGluconic acid; Glucose + NaBH4Sorbitol
Glucose + Ac2O(excess)Glucose pentacetate; Glucose + HydroxylamineOxime.
39. 4
Sol: Reducing character of hydrides decreases down the group.
40. 2
Sol: For a zero order reaction, half-life period depends on initial concentration.
41. 1
Sol: As acidic strength increases pH decreases and pOH increases.
42. 4
Sol: In case of Boron, Only BF4exists.
43. 3
Sol: Acidic character of hydrides increases from H2O to H2Te.
44. 1
Sol: Dil.HCl + H2S(g) – Group II (Cu2+) reagent
NH4Cl(s) + NH4OH – Group III (Cr3+) reagent
NH4Cl(s) + NH4OH + H2S(g) – Group IV (Zn2+) reagent
NH4OH + Na2CO3 – Group V (Ca2+) reagent
45. 3
Sol: [Cu(CN)4]2- is paramagnetic.
46. 5
Sol: Bond order of N2+, CO, CO+, NO+, CN- is more than 2.
47. 20
5 105 0.011  R  273
Sol:   20 105
 0.01 (1  0.5(3  1))R  546
48. 11

49. 3
Sol: Secondary amines will form yellow colour liquid with nitrous acid.
50. 34
600(0.40)  400(0.25)
Sol: Mass percentage   100  34%
1000